Drying Chapter From NZIFST
Drying Chapter From NZIFST
Drying Chapter From NZIFST
DRYING
Drying is one of the oldest methods of preserving food. Primitive societies practised the
drying of meat and fish in the sun long before recorded history. Today the drying of foods is
still important as a method of preservation. Dried foods can be stored for long periods
without deterioration occurring. The principal reasons for this are that the microorganisms
which cause food spoilage and decay are unable to grow and multiply in the absence of
sufficient water and many of the enzymes which promote undesired changes in the chemical
composition of the food cannot function without water.
Preservation is the principal reason for drying, but drying can also occur in conjunction with
other processing. For example in the baking of bread, application of heat expands gases,
changes the structure of the protein and starch and dries the loaf. Losses of moisture may also
occur when they are not desired, for example during curing of cheese and in the fresh or
frozen storage of meat, and in innumerable other moist food products during holding in air.
Drying of foods implies the removal of water from the food. In most cases, drying is
accomplished by vaporizing the water that is contained in the food, and to do this the latent
heat of vaporization must be supplied. There are, thus, two important process-controlling
factors that enter into the unit operation of drying:
• Air and contact drying under atmospheric pressure. In air and contact drying, heat is
transferred through the foodstuff either from heated air or from heated surfaces. The
water vapour is removed with the air.
• Vacuum drying. In vacuum drying, advantage is taken of the fact that evaporation of
water occurs more readily at lower pressures than at higher ones. Heat transfer in vacuum
drying is generally by conduction, sometimes by radiation.
• Freeze drying. In freeze drying, the water vapour is sublimed off frozen food. The food
structure is better maintained under these conditions. Suitable temperatures and pressures
must be established in the dryer to ensure that sublimation occurs.
BASIC DRYING THEORY
Pure water can exist in three states, solid, liquid and vapour. The state in which it is at any
time depends on the temperature and pressure conditions and it is possible to illustrate this on
a phase diagram, as in Fig. 7.1.
If we choose any condition of temperature and pressure and find the corresponding point on
the diagram, this point will lie, in general, in one of the three labelled regions, solid, liquid, or
gas. This will give the state of the water under the chosen conditions.
Under certain conditions, two states may exist side by side, and such conditions are found
only along the lines of the diagram. Under one condition, all three states may exist together;
this condition arises at what is called the triple point, indicated by point O on the diagram.
For water it occurs at 0.0098oC and 0.64 kPa (4.8 mm of mercury) pressure.
If heat is applied to water in any state at constant pressure, the temperature rises and the
condition moves horizontally across the diagram, and as it crosses the boundaries a change of
state will occur. For example, starting from condition A on the diagram adding heat warms
the ice, then melts it, then warms the water and finally evaporates the water to condition A'.
Starting from condition B, situated below the triple point, when heat is added, the ice warms
and then sublimes without passing through any liquid state.
Liquid and vapour coexist in equilibrium only under the conditions along the line OP. This
line is called the vapour pressure/temperature line. The vapour pressure is the measure of the
tendency of molecules to escape as a gas from the liquid. The vapour pressure/temperature
curve for water is shown in Fig. 7.2, which is just an enlargement for water of the curve OP
of Fig. 7.1.
Boiling occurs when the vapour pressure of the water is equal to the total pressure on the
water surface. The boiling point at atmospheric pressure is of course 100oC. At pressures
above or below atmospheric, water boils at the corresponding temperatures above or below
100oC, as shown in Fig. 7.2 for temperatures below 100oC.
The energy, which must be supplied to vaporize the water at any temperature, depends upon
this temperature. The quantity of energy required per kg of water is called the latent heat of
vaporization, if it is from a liquid, or latent heat of sublimation if it is from a solid. The
heat energy required to vaporize water under any given set of conditions can be calculated
from the latent heats given in the steam table in Appendix 8, as steam and water vapour are
the same thing.
EXAMPLE 7.1. Heat energy in air drying
A food containing 80% water is to be dried at 100oC down to moisture content of 10%. If the
initial temperature of the food is 21oC, calculate the quantity of heat energy required per unit
weight of the original material, for drying under atmospheric pressure. The latent heat of
vaporization of water at 100oC and at standard atmospheric pressure is 2257kJkg-1. The
specific heat capacity of the food is 3.8 kJkg-1oC-1 and of water is 4.186 kJkg-1oC-1. Find also
the energy requirement/kg water removed.
Steam is often used to supply heat to air or to surfaces used for drying. In condensing, steam
gives up its latent heat of vaporization; in drying, the substance being dried must take up
latent heat of vaporization to convert its liquid into vapour, so it might be reasoned that 1kg
of steam condensing will produce 1kg vapour. This is not exactly true, as the steam and the
food will in general be under different pressures with the food at the lower pressure. Latent
heats of vaporization are slightly higher at lower pressures, as shown in Table 7.1. In
practice, there are also heat losses and sensible heat changes that may require to be
considered.
TABLE 7.1
LATENT HEAT AND SATURATION TEMPERATURE OF WATER
In freeze drying the latent heat of sublimation must be supplied. Pressure has little effect on
the latent heat of sublimation, which can be taken as 2838 kJ kg-1.
We have been discussing the heat energy requirements for the drying process. The rates of
drying are generally determined by the rates at which heat energy can be transferred to the
water or to the ice in order to provide the latent heats, though under some circumstances the
rate of mass transfer (removal of the water) can be limiting. All three of the mechanisms by
which heat is transferred - conduction, radiation and convection - may enter into drying. The
relative importance of the mechanisms varies from one drying process to another and very
often one mode of heat transfer predominates to such an extent that it governs the overall
process.
where q is the heat transfer rate in Js–1, hs is the surface heat-transfer coefficient Jm-2s-1oC-1, A
is the area through which heat flow is taking place, m2, Ta is the air temperature and Ts is the
temperature of the surface which is drying, oC.
To take another example, in a roller dryer where moist material is spread over the surface of a
heated drum, heat transfer occurs by conduction from the drum to the foodstuff, so that the
equation is
q = UA(Td – Ts)
where U is the overall heat-transfer coefficient, Td is the drum temperature (usually very
close to that of the steam), Ts is the surface temperature of the food (boiling point of water or
slightly above) and A is the area of drying surface on the drum.
The value of U can be estimated from the conductivity of the drum material and of the layer
of foodstuff. Values of U have been quoted as high as 1800 Jm-2s-1oC-1 under very good
conditions and down to about 60 Jm-2 s-1 oC-1 under poor conditions.
For freeze drying, energy must be transferred to the surface at which sublimation occurs.
However, it must be supplied at such a rate as not to increase the temperature at the drying
surface above the freezing point. In many applications of freeze drying, the heat transfer
occurs mainly by conduction.
As drying proceeds, the character of the heat transfer situation changes. Dry material begins
to occupy the surface layers and conduction must take place through these dry surface layers
which are poor heat conductors so that heat is transferred to the drying region progressively
more slowly.
Dryer Efficiencies
Heat has to be supplied to separate the water from the food. The minimum quantity of heat
that will remove the required water is that needed to supply the latent heat of evaporation, so
one measure of efficiency is the ratio of that minimum to the energy actually provided for the
process. Sensible heat can also be added to the minimum, as this added heat in the food often
cannot be economically recovered.
Yet another useful measure for air drying such as in spray dryers, is to look at a heat balance
over the air, treating the dryer as adiabatic with no exchange of heat with the surroundings.
Then the useful heat transferred to the food for its drying corresponds to the drop in
temperature in the drying air, and the heat which has to be supplied corresponds to the rise of
temperature of the air in the air heater. So this adiabatic air-drying efficiency, , can be
defined by:
where T1 is the inlet (high) air temperature into the dryer, T2 is the outlet air temperature
from the dryer, and Ta is the ambient air temperature. The numerator, the gap between T1
and T2, is a major factor in the efficiency.
In 100kg of raw material there is 80% moisture, that is 80kg water and 20kg dry material,
total weight of dry product = 20 x (10/9)
= 22.2 kg
weight of water = (22.2 - 20)
= 2.2 kg.
water removed = (80 - 2.2)
= 77.8 kg.
The specific heat of air is 1.0 Jkg-1oC-1 and the density of the air 1.06kgm –3 (Appendix 3)
Heat given up by air/100 kg potato = 1.0 x (80 - 71) x 49,800 x 1.06
= 4.75 x l05kJ.
Whichever of these is chosen depends on the objective for considering efficiency. For
example in a spray dryer, the efficiency calculated on the air temperatures shows clearly and
emphatically the advantages gained by operating at the highest feasible air inlet temperature
and the lowest air outlet temperatures that can be employed in the dryer.
After sufficient energy has been provided to vaporize or to sublime moisture from the food,
some way must be found to remove this moisture. In freeze-drying and vacuum systems it is
normally convenient to condense the water to a liquid or a solid and then the vacuum pumps
have to handle only the non-condensible gases. In atmospheric drying a current of air is
normally used.
In heat transfer, heat energy is transferred under the driving force provided by a temperature
difference, and the rate of heat transfer is proportional to the potential (temperature)
difference and to the properties of the transfer system characterized by the heat-transfer
coefficient. In the same way, mass is transferred under the driving force provided by a partial
pressure or concentration difference. The rate of mass transfer is proportional to the potential
(pressure or concentration) difference and to the properties of the transfer system
characterized by a mass-transfer coefficient.
dw = kg A Y (7.3)
dt
where dw is the mass (moisture) being transferred kgs-1in time dt, A is the area through which
the transfer is taking place, kg' is the mass transfer coefficient in this case in units kgm-2s-1 ,
and Y is the humidity difference in kgkg-1. Unfortunately the application of mass transfer is
not as straightforward as heat transfer. One reason is that the movement pattern of moisture
changes as drying proceeds. Initially, the mass (moisture) is transferred from the surface of
the material and later, to an increasing extent, from deeper within the food to the surface and
thence to the air. So the first stage is to determine the relationships between the moist surface
and the ambient air and then to consider the diffusion through the food. In studying the
surface/air relationships, it is necessary to consider mass and heat transfer simultaneously.
Air for drying is usually heated and it is also a major heat transfer medium. Therefore it is
necessary to look carefully into the relationships between air and the moisture it contains.
PSYCHROMETRY
The capacity of air for moisture removal depends on its humidity and its temperature. The
study of relationships between air and its associated water is called psychrometry.
Humidity (Y) is the measure of the water content of the air. The absolute humidity is the mass
of water vapour per unit mass of dry air and the units are therefore kg kg-1. Absolute humidity
is often called just ‘humidity’, as in this text. It is named absolute humidity or humidity ratio
in charts.
Air is said to be saturated with water vapour at a given temperature and pressure if its
humidity is a maximum under these conditions. If further water is added to saturated air, it
must appear as liquid water in the form of a mist or droplets. Under conditions of saturation,
the partial pressure of the water vapour in the air is equal to the saturation vapour pressure of
water at that temperature.
The total pressure of a gaseous mixture, such as air and water vapour, is made up from the
sum of the pressures of its constituents, which are called the partial pressures. Each partial
pressure arises from the molecular concentration of the constituent and the pressure exerted
by each gas is that which corresponds to the number of moles present and the total volume of
the system. The partial pressures are added to obtain the total pressure.
The mole fraction of the water is the number of moles of water to the total number of moles
(water + dry air)
The molecular weight of air is 29, and of water 18
So the mole fraction of water = 0.03 /18 (1.00/29 + 0.03/18)
= 0.0017/(0.034 + 0.0017)
= 0.048
Therefore the water vapour pressure = 0.048 x l00kPa
= 4.8kPa.
The relative humidity (RH) is defined as the ratio of the partial pressure of the water vapour
in the air (p) to the partial pressure of saturated water vapour at the same temperature (ps).
Therefore:
RH = p/ps
From steam tables, the saturation pressure of water vapour at 60oC is 19.9 kPa.
Therefore the relative humidity = p/ps
= 4.8/19.9
= 0.24
or 24%.
If such air were cooled, then when the percentage relative humidity reached 100% the air
would be saturated and this would occur at that temperature at which p = ps = 4.8 kPa.
Interpolating from the steam tables, or reading from the water vapour pressure/temperature
graph, this occurs at a temperature of 32oC and this temperature is called the dew-point of the
air at this particular moisture content. If cooled below the dew-point, the air can no longer
retain this quantity of water as vapour and so water must condense out as droplets or a fog,
and the water remaining as vapour in the air will be that corresponding to saturation at the
temperature reached.
The humidity Y can therefore be related to the partial pressure pw of the water in air vapour by
the equation:
Y = l8 pw /[29(P – pw)] (7.4)
where P is the total pressure. In circumstances where pw is small compared with P, and this is
approximately the case in air/water systems at room temperatures, Y 18 pw / 29P.
Corresponding to the specific heat capacity, cp, of gases, is the humid heat, cs of moist air. It
is used in the same way as a specific heat capacity, the enthalpy change being the mass of dry
air multiplied by the temperature difference and by the humid heat. The units are Jkg-1oC and
the numerical values can be read off a psychrometric chart. It differs from specific heat
capacity at constant pressure in that it is based only on the mass of the dry air. The specific
heat of the water it contains is effectively incorporated into the humid heat which therefore is
numerically a little larger than the specific heat capacity to allow for this.
Wet-bulb Temperatures
A useful concept in psychrometry is the wet-bulb temperature, as compared with the ordinary
temperature, which is called the dry-bulb temperature. The wet-bulb temperature is the
temperature reached by a water surface, such as that registered by a thermometer bulb
surrounded by a wet wick, when exposed to air passing over it. The wick and therefore the
thermometer bulb decreases in temperature below the dry-bulb temperature, until the rate of
heat transfer from the warmer air to the wick is just equal to the rate of heat transfer needed
to provide for the evaporation of water from the wick into the air stream.
where a and s denote actual and saturation temperatures and humidities; hc is the heat transfer
coefficient and kg' the mass transfer coefficient from the air to the wick surface; is the latent
heat of evaporation of water.
As the relative humidity of the air decreases, so the difference between the wet-bulb and dry-
bulb temperatures, called the wet-bulb depression, increases and a line connecting wet-bulb
temperature and relative humidity can be plotted on a suitable chart. When the air is
saturated, the wet-bulb temperature and the dry-bulb temperature are identical.
Therefore if (Ta – Ts) is plotted against (Ys – Ya) remembering that the point (Ts, Ys) must
correspond to a dew-point condition, we then have a wet-bulb straight line on a
temperature/humidity chart sloping down from the point (Ts, Ys) with a slope of:
- ( kg'/hc)
A further important concept is that of the adiabatic saturation condition. This is the situation
reached by a stream of water, in contact with the humid air. Both ultimately reach a
temperature at which the heat lost by the humid air on cooling is equal to the heat of
evaporation of the water leaving the stream of water by evaporation.
Under this condition with no heat exchange to the surroundings, the total enthalpy change
(kJkg-1dry air)
Now it just so happens, for the water/air system at normal working temperatures and
pressures that for practical purposes the numerical magnitude of the ratio:
This has a useful practical consequence. The wet bulb line and the adiabatic saturation line
coincide when the Lewis number = 1.
It is now time to examine the chart we have spoken about. It is called a psychrometric chart.
Psychrometric Charts
The two main axes are temperature (dry bulb) and humidity (absolute). The saturation curve
(Ts, Ys) is plotted on this dividing the whole area into an unsaturated and a two-phase region.
Taking a point on the saturation curve (Ts, Ys) a line can be drawn from this with a slope:
- ( kg'/hc) = (- /cs)
running down into the unsaturated region of the chart (that “below” the saturation line). This
is the wet bulb or adiabatic cooling line and a net of such lines is shown. Any constant
temperature line running between the saturation curve and the zero humidity axis can be
divided evenly into fractional humidities which will correspond to fractional relative
humidities [for example, a 0.50 ratio of humidities will correspond to a 50%RH because of
eqn. (7.2) if P » pw].
This discussion is somewhat over-simplified and close inspection of the chart shows that the
axes are not exactly rectangular and that the lines of constant dry-bulb temperature are not
exactly parallel. The reasons are beyond the scope of the present discussion but can be found
in appropriate texts such as Keey (1978). The chart also contains other information whose
use will emerge as familiarity grows.
This chart can be used as the basis of many calculations. It can be used to calculate relative
humidities and other properties.
On the humidity chart (Appendix 9a) follow down the wet-bulb line for a temperature of
20oC until it meets the dry-bulb temperature line for 25oC. Examining the location of this
point of intersection with reference to the lines of constant relative humidity, it lies between
60% and 70%RH and about 4/10 of the way between them but nearer to the 60% line.
Therefore the RH is estimated to be 64%. Similar examination of the enthalpy lines gives an
estimated enthalpy of 57 kJ kg-1, and from the volume lines specific volume of 0.862 m3 kg-1.
Once the properties of the air have been determined other calculations can easily be made.
On heating, the air condition moves, at constant absolute humidity as no water vapour is
added or subtracted, to the condition at the higher (dry bulb) temperature of 40oC. Reading
from the chart at 40oC and humidity 0.0125kgkg-1, the enthalpy is 73 kJ kg-1, specific volume
is 0.906m3kg-1 and RH 27%.
Mass of 1000m3 is 1000/0.906 = 1104kg,
H = (73 - 57) = 16kJkg-1
So rate of heating required
= 1104 x 16kJh -1
= (1104 x 16)/3600kJs -1
= 5kW
If the air is used for drying, with the heat for evaporation being supplied by the hot air
passing over a wet solid surface, the system behaves like the adiabatic saturation system. It is
adiabatic because no heat is obtained from any source external to the air and the wet solid,
and the latent heat of evaporation must be obtained by cooling the hot air. Looked at from the
viewpoint of the solid, this is a drying process; from the viewpoint of the air, it is
humidification.
Using the psychrometric chart (high-temperature version, Appendix 9(b), to take in the
conditions), the inlet air condition shows the humidity ratio of the drying air to be 0.01kg kg-1
and its specific volume to be 0.96 m3 kg -1. Through the dryer, the condition of the air follows
a constant wet-bulb line at around 27oC, so at 35oC its condition is a humidity ratio of 0.0207.
Water removed = (0.0207 - 0.010)
= 0.0107kgkg -1 of air.
3
So each kg, i.e. 0.96 m , of air passing will remove 0.0107kg water,
Volume of air to remove 20 kg h -1
= (20/0.0107) x 0.96
= 1794m3h -1
If air is cooled, then initially its condition moves along a line of constant humidity,
horizontally on a psychrometric chart, until it reaches the saturation curve at its dew-point.
Further cooling then proceeds down the saturation line to the final temperature, with water
condensing to adjust the humidity as the saturation humidity cannot be exceeded.
On the psychrometric chart, the saturation temperature is 40oC and proceeding at constant
humidity from this, the 45oC line is intersected at a point indicating:
relative humidity = 76%
In dryers, it is sometimes useful to reheat the air so as to reduce its relative humidity and thus
to give it an additional capacity to evaporate more water from the material being dried. This
process can easily be followed on a psychrometric chart.
From the psychrometric chart (normal temperatures, Appendix 9(a)), the humidity of the
initial air is 0.0062kgkg-1, specific volume is 0.834m3 kg-1, and enthalpy 35kJkg-1. Proceeding
at constant humidity to a temperature of 140oC, the enthalpy is found (high temperature chart,
Appendix 9(b)) to be 160 kJkg-1. Proceeding along a wet-bulb line to an RH of 60% gives the
corresponding temperature as 48oC and humidity as 0.045 kg kg–1.
Reheating to 140oC keeps humidity constant and enthalpy goes to 268 kJ kg-1.
Thence along a wet-bulb line to 60 % RH gives humidity of 0.082 kgkg-1.
Consideration of psychrometric charts, and what has been said about them, will show that
they can be used for calculations focused on the air, for the purposes of air conditioning as
well as for drying.
Assuming that the air changes are calculated at the conditions in the working space.
Methods depend largely upon the concepts that have been presented in the preceding
sections, but because they are often needed it seems useful to set them out specifically.
Instruments for the measurement of humidity are called hygrometers.
• Wet- and dry-bulb thermometers. The dry-bulb temperature is the normal air temperature
and the only caution that is needed is that if the thermometer bulb, or element, is exposed
to a surface at a substantially higher or lower temperature the possibility of radiation
errors should be considered. A simple method to greatly reduce any such error is to
interpose a radiation shield, e.g. a metal tube, which stands off from the thermometer bulb
1cm or so and prevents direct exposure to the radiation source or sink. For the wet bulb
thermometer, covering the bulb with a piece of wicking, such as a hollow cotton shoelace
of the correct size, and dipping the other end of the wick into water so as to moisten the
wet bulb by capillary water flow, is adequate. The necessary aspiration of air past this
bulb can be effected by a small fan or by swinging bulb, wick, water bottle and all
through the air, as in a sling psychrometer. The maximum difference between the two
bulbs gives the wet-bulb depression and a psychrometric chart or appropriate tables will
then give the relative humidity.
• The hair hygrometer. Hairs expand and contract in length according to the relative
humidity. Instruments are made which give accurately the length of the hair and so they
can be calibrated in humidities.
The equilibrium vapour pressure above a food is determined not only by the temperature but
also by the water content of the food, by the way in which the water is bound in the food, and
by the presence of any constituents soluble in water. Under a given vapour pressure of water
in the surrounding air, a food attains a moisture content in equilibrium with its surroundings
when there is no exchange of water between the food and its surroundings. This is called its
equilibrium moisture content.
It is possible, therefore, to plot the equilibrium vapour pressure against moisture content or to
plot the relative humidity of the air in equilibrium with the food against moisture content of
the food. Often, instead of the relative humidity, the water activity of the food surface is used.
Water activity (aw) is the ratio of the partial pressure of water in the food to the vapour
pressure of water at the same temperature. The equilibrium curves obtained vary with
different types of foodstuffs and examples are shown in Fig. 7.4.
Thus, for the potato as shown in Fig. 7.4, at a temperature of 20oC in an atmosphere of
relative humidity 30% (giving a water activity of 0.3), the equilibrium moisture content is
seen to be 0.1kg water/kg dry potato. It would not be possible to dry potatoes below 10%
using an air dryer with air at 20oC and relative humidity 30%. It will be noted from the shape
of the curve that above a certain relative humidity, about 80% in the case of potatoes, the
equilibrium content increases very rapidly with increase in relative humidity.
There are marked differences between foods, both in shape of the curves and in the amount of
water present at any relative humidity and temperature, in the range of relative humidity
between 0 and 65%. The sigmoid (S-shaped) character of the curve is most pronounced, and
the moisture content at low humidities is greatest, for food whose dry solids are high in
protein, starch, or other high molecular weight polymers. The moisture contents at low
humidities are low for foods high in soluble solids. Fats and crystalline salts and sugars, in
general absorb negligible amounts of water when the RH is low or moderate. Sugars in the
amorphous form absorb more than in the crystalline form.
AIR DRYING
In air drying, the rate of removal of water depends on the conditions of the air, the properties
of the food and the design of the dryer.
Moisture can be held in varying degrees of bonding. Formerly, it was considered that water in
a food came into one or other of two categories, free water or bound water. This now appears
to be an oversimplification and such clear demarcations are no longer considered useful.
Water is held by forces, whose intensity ranges from the very weak forces retaining surface
moisture to very strong chemical bonds. In drying, it is obvious that the water that is loosely
held will be removed most easily. Thus it would be expected that drying rates would decrease
as moisture content decreases, with the remaining water being bound more and more strongly
as its quantity decreases.
In many cases, a substantial part of the water is loosely bound. This water can, for drying
purposes, be considered as free water at the surface. A comparison of the drying rates of
sand, a material with mostly free water, with meat containing more bound water shows the
effect of the binding of water on drying rates. These are shown in Fig. 7.5.
The behaviour in which the drying behaves as though the water were at a free surface, is
called constant rate drying. If W is the mass of the material being dried and its moisture
content on a dry basis is X, then the mass of dry material is:
w = W x [X/(1+X)]
and the mass of associated water is X.
Then for constant rate drying:
dwX = w dX = constant.
dt dt
However in food, unlike impervious materials such as sand, after a period of drying at a
constant rate it is found that the water then comes off more slowly. A complete drying curve
for fish, adapted from Jason (1958), is shown in Fig. 7.6. The drying temperature was low
and this accounts for the long drying time.
A more generalized drying curve plotting the rate of drying as a percentage of the constant
rate (dwX/dt)/ (dwX/dt)constant, against moisture content as ratio of moisture constant to
critical moisture (X/Xc), is shown in Fig. 7.7. Note is used for time in the Figure.
Another point of importance is that many foods such as potato do not show a true constant
rate drying period. They do, however, often show quite a sharp break after a slowly and
steadily declining drying rate period and the concept of constant rate is still a useful
approximation.
The end of the constant-rate period, when X = Xc at the break point of drying rate curves,
signifies that the water has ceased to behave as if it were at a free surface and that factors
other than vapour pressure differences are influencing the rate of drying. Thereafter the
drying rate decreases and this is called the falling-rate period of drying. The rate controlling
factors in the falling rate period are complex, depending upon diffusion through the food, and
upon the changing energy-binding pattern of the water molecules. Very little theoretical
information is available for drying of foods in this region and experimental drying curves are
the only adequate guide to design.
In the constant rate period, the water is being evaporated from what is effectively a free water
surface. The rate of removal of water can then be related to the rate of heat transfer, if there is
no change in the temperature of the material and therefore all heat energy transferred to it
must result in evaporation of water. The rate of removal of the water is also the rate of mass
transfer, from the solid to the ambient air. These two - mass and heat transfer - must predict
the same rate of drying for a given set of circumstances.
Considering mass transfer, which is fundamental to drying, the driving force is the difference
of the partial water vapour pressure between the food and the air. The extent of this
difference can be obtained, knowing the temperatures and the conditions, by reference to
tables or the psychrometric chart. Alternatively, the driving force may be expressed in terms
of humidity driving forces and the numerical values of the mass transfer coefficients in this
case are linked to the others through the partial pressure/humidity relationships such as eqns.
(7.4) and (7.5)
Heat energy supply rate per square metre = 6.9 x 10-5 x 2.435 x 103 kJs -1
= 0.168 kJs -1
= 0.168 kW.
The problem, in applying such apparently simple relationships to provide the essential rate
information for drying, is in the prediction of the mass transfer coefficients. In the section on
heat transfer, methods and correlations were given for the prediction of heat transfer
coefficients. Such can be applied to the drying situation and the heat transfer rates used to
estimate rates of moisture removal. The reverse can also be applied.
Mass balances are also applicable, and can be used, in drying and related calculations.
Because the equations for predicting heat transfer coefficients, for situations commonly
encountered, are extensive and much more widely available than mass transfer coefficients,
the heat transfer rates can be used to estimate drying rates, through the Lewis number.
Remember that Le = (hc/cs kg') = 1 for the air/water system, from eqn. 7.4.
Strictly speaking the Lewis number, which arises in gaseous diffusion theory, is (hc/cpkg') but
for air of the humidity encountered in ordinary practice cs cp 1.02 kJkg-1oC -1. Therefore
numerically, if hc is in Jm-2s-1oC-1, and kg' in kgm-2s-1, kg' = hc/1000, the values of hc can be
predicted using the standard relationships for heat transfer coefficients which have been
discussed in Chapter 4.
hc = 14 Jm-2 s-1oC -1
1000 x 0.0140
1000 x kg' as the Lewis relationship predicts.
A convenient way to remember the interrelationship is that the mass transfer coefficient from
a free water surface into air expressed in gm-2s-1 is numerically approximately equal to the
heat transfer coefficient from the air to the surface expressed in Jm-2s-1oC -1.
The highest rate of drying is normally the constant rate situation, then as drying proceeds the
moisture content falls and the access of water from the interior of the food to the surface
affects the rate and decreases it. The situation then is complex with moisture gradients
controlling the observed drying rates. Actual rates can be measured, showing in the idealized
case a constant rate continuing up to the critical moisture content and thereafter a declining
rate as the food, on continued drying, approaches the equilibrium moisture content for the
food. This is clearly shown by the drying curve of Fig. 7.7 and at low moisture contents the
rates of drying become very low. The actual detail of such curves depends, of course, on the
specific material and conditions of the drying process.
Drying rates, once determined experimentally or predicted from theory, can then be used to
calculate drying times so that drying equipment and operations can be designed. In the most
general cases, the drying rates vary throughout the dryer with time as drying proceeds, and
with the changing moisture content of the material. So the situation is complicated. However,
in many cases a simplified approach can provide useful results. One simplification is to
assume that the temperature and RH of the drying air are constant.
In this case, for the constant rate period the time needed to remove the quantity of water
which will reduce the food material to the critical moisture content Xc (that corresponding to
the end of the constant rate period and below which the drying rate falls) can be calculated by
dividing this quantity of moisture by the rate.
and Xo is the initial moisture content and Xc the final moisture content ( the critical moisture
content in this case) both on a dry basis, w is the amount of dry material in the food and
(dw/dt)const is the constant drying rate. Where the drying rate is reduced by a factor f at
various moisture levels, this can be incorporated to give:
and this has to be integrated piecemeal down to Xf where the subscript f denotes the final
water content and f expresses the ratio of the actual drying rate to the maximum drying rate
corresponding to the free surface-moisture situation.
During the falling rate period, the procedure outlined above can be extended, using the drying
curve for the particular material and the conditions of the dryer. Sufficiently small differential
quantities of moisture content to be removed have to be chosen, over which the drying rate is
effectively constant, so as to give an accurate value of the total time. As the moisture content
above the equilibrium level decreases so the drying rates decrease, and drying times become
long.
Equation (7.7) can be applied, over small intervals of moisture content and multiplying the
constant rate by the appropriate reduction factor (f) read of from Fig. 7.7.
t= w (X )/ f(dw/dt )const
This can be set out in a table. Note the temperature and humidity of the air were assumed to
be constant throughout the drying.
Moisture content X 1.0 0.8 0.6 0.4 0.3 0.25 0.20 0.18 0.16
w(X1 - X2) 4 4 4 2 1 1 0.4 0.2
f (from Fig.7.7) 0.85 0.47 0.24 0.12 0.07 0.05 0.03 0.02
f kg'A(Ys -Ya) x 10-3 6.06 3.35 1.71 0.86 0.50 0.36 0.21 0.14
t = 14641s = 4.65h
The example shows how as the moisture level descends toward the equilibrium value so the
drying rate becomes slower and slower.
In terms of the mass transfer equations, the humidity or partial pressure driving force is
tending to zero as the equilibrium moisture content is approached. In terms of the heat
transfer equations, the surface temperature rises above the wet-bulb temperature once the
surface ceases to behave as a wet surface. The surface temperature then climbs towards the
dry-bulb temperature of the air as the moisture 1evel continues to fall, thus leading to a
continuously diminishing temperature driving force for surface heat transfer.
This calculation procedure can be applied to more complicated dryers, considering them
divided into sections, and applying the drying-rate equations and the input and output
conditions to these sections sequentially to build up the whole situation in the dryer.
CONDUCTION DRYING
So far the drying considered has been by hot air. Other methods of drying that are quite
commonly encountered are drying by contact with a hot surface; a continuous version of this
is the drum or roller dryer where the food is coated as a thin paste over the surface of a slowly
revolving heated horizontal cylinder. In such a case, the food dries for as much of one
revolution of the cylinder as is mechanically feasible, after which it is scraped off and
replaced by fresh wet material. The amount of drying is substantially controlled by the rate of
heat transfer and estimates of the heat transfer rate can be used for calculations of the extent
of drying.
q = UA t
= 556 x 0.75( x D x 1) x (138 - 100)
= 4.98 x 104Js-1.
= 49.8 kJs-1
Latent heat of evaporation of water = 2257kJkg–1
Rate of evaporation = q/
= 49.8/2257
= 0.022kgs-1.
Residence time of food on drum: at 2 rev min-1
1 revolution takes 30s, but the material is on for 3/4 rev.
Residence time = (3/4) x 30
= 22.5 sec.
Water removed = 22.5 x 0.022
= 0.495 kg.
Initial quantity of water = 0.71 x 0.75
= 0.53 kg
and dry solids = 0.71 x 0.25
= 0.18kg.
Residual water = (0.53-0.495)
= 0.035 kg.
DRYING EQUIPMENT
In an industry so diversified and extensive as the food industry, it would be expected that a
great number of different types of dryer would be in use. This is the case and the total range
of equipment is much too wide to be described in any introductory book such as this. The
principles of drying may be applied to any type of dryer, but it should help the understanding
of these principles if a few common types of dryers are described.
The major problem in calculations on real dryers is that conditions change as the drying air
and the drying solids move along the dryer in a continuous dryer, or change with time in the
batch dryer. Such implications take them beyond the scope of the present book, but the
principles of mass and heat balances are the basis and the analysis is not difficult once the
fundamental principles of drying are understood. Obtaining adequate data may be difficult.
Tray Dryers
In tray dryers, the food is spread out, generally quite thinly, on trays in which the drying takes
place. Heating may be by an air current sweeping across the trays, by conduction from heated
trays or heated shelves on which the trays lie, or by radiation from heated surfaces. Most tray
dryers are heated by air, which also removes the moist vapours.
Tunnel Dryers
These may be regarded as developments of the tray dryer, in which the trays on trolleys move
through a tunnel where the heat is applied and the vapours removed. In most cases, air is used
in tunnel drying and the material can move through the dryer either parallel or counter current
to the air flow. Sometimes the dryers are compartmented, and cross-flow may also be used.
In these the food is spread over the surface of a heated drum. The drum rotates, with the food
being applied to the drum at one part of the cycle. The food remains on the drum surface for
the greater part of the rotation, during which time the drying takes place, and is then scraped
off. Drum drying may be regarded as conduction drying.
In a fluidized bed dryer, the food material is maintained suspended against gravity in an
upward-flowing air stream. There may also be a horizontal air flow helping to convey the
food through the dryer. Heat is transferred from the air to the food material, mostly by
convection.
Spray Dryers
In a spray dryer, liquid or fine solid material in a slurry is sprayed in the form of a fine
droplet dispersion into a current of heated air. Air and solids may move in parallel or
counterflow. Drying occurs very rapidly, so that this process is very useful for materials that
are damaged by exposure to heat for any appreciable length of time. The dryer body is large
so that the particles can settle, as they dry, without touching the walls on which they might
otherwise stick. Commercial dryers can be very large, 10m diameter, 20m high.
Pneumatic Dryers
In a pneumatic dryer, the solid food particles are conveyed rapidly in an air stream, the
velocity and turbulence of the stream maintaining the particles in suspension. Heated air
accomplishes the drying and often some form of classifying device is included in the
equipment. In the classifier, the dried material is separated, the dry material passes out as
product and the moist remainder is recirculated for further drying.
Rotary Dryers
The foodstuff is contained in a horizontal inclined cylinder through which it travels, being
heated either by air flow through the cylinder, or by conduction of heat from the cylinder
walls. In some cases, the cylinder rotates and in others the cylinder is stationary and a paddle
or screw rotates within the cylinder conveying the material through.
Trough Dryers
The materials to be dried are contained in a trough-shaped conveyor belt, made from mesh,
and air is blown through the bed of material. The movement of the conveyor continually turns
over the material, exposing fresh surfaces to the hot air.
Bin Dryers
In bin dryers, the foodstuff is contained in a bin with a perforated bottom through which
warm air is blown vertically upwards, passing through the material and so drying it.
Belt Dryers
The food is spread as a thin layer on a horizontal mesh or solid belt and air passes through or
over the material. In most cases the belt is moving, though in some designs the belt is
stationary and the material is transported by scrapers.
Vacuum Dryers
Batch vacuum dryers are substantially the same as tray dryers, except that they operate under
a vacuum, and heat transfer is largely by conduction or by radiation. The trays are enclosed in
a large cabinet, which is evacuated. The water vapour produced is generally condensed, so
that the vacuum pumps have only to deal with non-condensible gases. Another type consists
of an evacuated chamber containing a roller dryer.
Freeze Dryers
The material is held on shelves or belts in a chamber that is under high vacuum. In most
cases, the food is frozen before being loaded into the dryer. Heat is transferred to the food by
conduction or radiation and the vapour is removed by vacuum pump and then condensed. In
one process, given the name accelerated freeze drying, heat transfer is by conduction; sheets
of expanded metal are inserted between the foodstuffs and heated plates to improve heat
transfer to the uneven surface and moisture removal. The pieces of food are shaped so as to
present the largest possible flat surface to the expanded metal and the plates to obtain good
heat transfer. A refrigerated condenser may be used to condense the water vapour.
When a moist surface is cooled by an air flow, and if the air is unsaturated, water will
evaporate from the surface to the air. This contributes to the heat transfer, but a more
important effect is to decrease the weight of the foodstuff by the amount of the water
removed. The loss in weight may have serious economic consequences, since food is most
often sold by weight, and also in many foodstuffs the moisture loss may result in a less
attractive surface appearance.
To give some idea of the quantities involved, meat on cooling from animal body temperature
to air temperature loses about 2% of its weight, on freezing it may lose a further 1% and
thereafter if held in a freezer store it loses weight at a rate of about 0.25% per month. After a
time, this steady rate of loss in store falls off; but over the course of a year the total store loss
may easily be of the order of 2-2.5%. A further consequence is deposition of frost and ice
reducing heat transfer on the cooling evaporator surfaces.
To minimize these weight losses, the humidity of the air in freezers, chillers and stores and
the rate of chilling and freezing, should be as high as practicable. The design of the
evaporator equipment can help if a relatively large coil area has been provided for the
freezing or cooling duty. The large area means that the cooling demand can be accomplished
with a small air-temperature drop. This may be seen from the standard heat transfer equation:
q = UA T
For fixed q (determined by the cooling demand) and for fixed U (determined by the design of
the freezer) a larger A will mean a smaller T, and vice versa. Since the air leaving the coils
will be nearly saturated with water vapour as it leaves, the larger the T the colder the air at
this point, and the dryer it becomes. The dryer it becomes (the lower the RH) the greater its
capacity for absorbing water from the product. So a low T decreases the drying effect. The
water then condenses from the air, freezes to ice on the coils and must be removed, from time
to time, by defrosting. Similarly for fixed U and A, a larger q means a larger T, and
therefore better insulation leading to a lower q will decrease weight losses.
SUMMARY
1. In drying:
(a) the latent heat of vaporization must be supplied and heat transferred to do this.
(b) the moisture must be transported out from the food.
3. For most foods, drying proceeds initially at a constant rate given by:
= q/
for air drying. After a time the rate of drying decreases as the moisture content of the food
reaches low values.
4. Air is saturated with water vapour when the partial pressure of water vapour in the air
equals the saturation pressure of water vapour at the same temperature.
5. Humidity of air is the ratio of the weight of water vapour to the weight of the dry air in
the same volume.
6. Relative humidity is the ratio of the actual to the saturation partial pressure of the water
vapour at the air temperature.
PROBLEMS
2. The efficiency of a spray dryer is given by the ratio of the heat energy in the hot air
supplied to the dryer and actually used for drying, divided by the heat energy supplied to
heat the air from its original ambient temperature. (a) Calculate the efficiency of a spray
dryer with an inlet air temperature of 150oC, an outlet temperature of 95oC, operating
under an ambient air temperature of 15oC. (b) Suggest how the efficiency of this dryer
might be raised.
((a) 41%, (b) by either decreasing air outlet temperature or increasing air inlet
temperature if the product could tolerate this)
3. Calculate (a) the humidity of air at a temperature of 65oC and in which the RH is 42% and
(b) check from a psychrometric chart.
(0.075 kgkg-1)
6. A steady stream of 1300m3h-1 of room air at 16oC and 65%RH is to be heated to 150oC to
be used for drying. (a) Calculate the heat input required to accomplish this. If the air
leaves the dryer at 90oC and at 5%RH, (b) calculate the quantity of water removed per
hour by the dryer, and (c) the quantity of water removed per hour from the material being
dried.
((a) 58.8kW(b) 37.6kgh-1 (c) 27.6kgh-1)
7. In a particular situation, the heat transfer coefficient from a food material to air has been
measured and found to be 25 Jm-2s-1oC -1. If this material is to be dried in air at 90oC and
15%RH, estimate the maximum rate of water removal.
(1.35kgm-2h-1)
8. Food on exposure to unsaturated air at a higher temperature will dry if the air is
unsaturated. Steak slices are stored in a chiller at 10oC.
(a) Estimate the maximum weight loss of steak pieces, 15cm x 5cm x 2cm, in air at 10 oC
and 50%RH moving at 0.5ms -1. The pieces are laid flat on shelves to age. Assuming
that the meat behaves as a free water surface, estimate the percentage loss of weight in
1 day of exposure. Specific weight of meat is 1050kgm-3.
(b) If the RH of the air were increased to 80%, what would be the percentage loss?
(c) If the meat pieces were also exposed to nearby surfaces at the temperature of the air
(dry bulb), what would then be the percentage loss? Assume net emissivity is 0.8.
((a) 12% (b) 4.5% (c) 18.4%)
9. Assume that the food material from worked Example 7.17 is to be dried in air at 130oC
with a relative humidity of 1.6%. Under these conditions the equilibrium moisture content
in the food is 12% on a dry basis. Estimate the time required to dry it from 350% down to
16.3% on a dry basis. Constant rate drying exists down to 100% moisture content on a dry
basis. All moisture contents on dry basis.
(5.8h; 2.03h constant rate, 3.8h falling rate)