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    Tarea de Electrolisis

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    Gabriela Acosta Deledesma
    The document is a laboratory report for an electrolysis experiment conducted by students Gabriela Acosta Deledesma, Cindy Flores Baca, and Gian Carlos Poemape Padilla at the University of El Callao Faculty of Chemical Engineering Department of Chemical Engineering. It details the calculations and results from electrolyzing solutions of SnSO4, NaCl, and CrCl3.

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    Tarea de Electrolisis

    Uploaded by

    Gabriela Acosta Deledesma
    19 views5 pages
    The document is a laboratory report for an electrolysis experiment conducted by students Gabriela Acosta Deledesma, Cindy Flores Baca, and Gian Carlos Poemape Padilla at the University of El Callao Faculty of Chemical Engineering Department of Chemical Engineering. It details the calculations and results from electrolyzing solutions of SnSO4, NaCl, and CrCl3.

    Original Description:

    ANALISIS INSTRUMENTAL

    Original Title

    TAREA DE ELECTROLISIS

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    The document is a laboratory report for an electrolysis experiment conducted by students Gabriela Acosta Deledesma, Cindy Flores Baca, and Gian Carlos Poemape Padilla at the University of El Callao Faculty of Chemical Engineering Department of Chemical Engineering. It details the calculations and results from electrolyzing solutions of SnSO4, NaCl, and CrCl3.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    19 views5 pages

    Tarea de Electrolisis

    Uploaded by

    Gabriela Acosta Deledesma
    The document is a laboratory report for an electrolysis experiment conducted by students Gabriela Acosta Deledesma, Cindy Flores Baca, and Gian Carlos Poemape Padilla at the University of El Callao Faculty of Chemical Engineering Department of Chemical Engineering. It details the calculations and results from electrolyzing solutions of SnSO4, NaCl, and CrCl3.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    UNIVERSIDAD NACIONAL DEL CALLAO

    FACULTAD DE INGENIERÍA QUÍMICA

    ESCUELA PROFESIONAL DE INGENIERÍA QUÍMICA

    LABORATORIO DE ANÁLISIS INSTRUMENTAL

    TAREA: ELECTROLISIS

    DOCENTE:

     RODRIGUEZ VILCHEZ, RICARDO

    ALUMNO:

     ACOSTA DELEDESMA GABRIELA IBET


     FLORES BACA CINDY
     POEMAPE PADILLA, GIAN CARLOS

    CALLAO – PERÚ

    2021
    SOLUCIÓN:

    𝐶𝐴𝑇𝑂𝐷𝑂: 𝑆𝑛+2 + 2𝑒 → 𝑆𝑛0

    mol L mol
    SnS𝑂4 = 0.1 ⋅ ⋅ 1500ml ⋅ = 0.15
    L 1000ml L

    𝑀 = 118.71 𝑔/𝑚𝑜𝑙

    𝐼 = 2.8𝐴

    60𝑠
    𝑡𝑖𝑒𝑚𝑝𝑜 = 70𝑚𝑖𝑛 ∗ = 4200𝑠
    1𝑚𝑖𝑛

    𝑀 ∗ 𝐼 ∗ 𝑡 118.71 ∗ 2.8 ∗ 4200


    𝑚𝑎𝑠𝑎 𝑑𝑒𝑝𝑜𝑠𝑖𝑡𝑎𝑑𝑎(𝑔) = = = 7.233𝑔
    𝑛∗𝐹 2 ∗ 96500

    Concentración de la solución al finalizar la electrolisis:

    𝑉 = 2.7𝐿

    Calculamos el número de moles con la masa depositada en el cátodo:

    mol
    𝑆𝑛+2 = 7.233𝑔 ∗ = 0.06093𝑚𝑜𝑙
    118.71g

    Calculo de la concentración:

    𝑚𝑜𝑙𝑒𝑠 0.06093𝑚𝑜𝑙
    𝑀𝑂𝐿𝐴𝑅𝐼𝐷𝐴𝐷 = = = 𝟎. 𝟎𝟐𝟐𝟓𝟔𝑴
    𝑉𝑜𝑙𝑢𝑚𝑒𝑛 2.7𝐿
    SOLUCIÓN:

    a) 𝑚 = 1𝑘𝑔
    26.9815𝑔
    𝑀=
    𝑚𝑜𝑙

    𝑛𝐹 ∗ 𝑚 1 ∗ 96500 ∗ 1000𝑔
    𝑸= = = 𝟑𝟓𝟕𝟔. 𝟓𝟐𝟓𝒌𝑪
    𝑀 26.9815𝑔/𝑚𝑜𝑙

    b) 𝐼 = 40000𝐴

    𝑚 = 1𝑘𝑔

    1000𝑔 ∗ 1 ∗ 96500
    𝒕𝒊𝒆𝒎𝒑𝒐 = = 𝟖𝟗. 𝟒𝟏𝟑𝒔
    26.9815𝑔/𝑚𝑜𝑙 ∗ 40000𝐴
    SOLUCIÓN:

    Para la solución de NaCl:


    𝟔𝟎𝒎𝒊𝒏 𝟔𝟎𝒔
    𝑻𝒊𝒆𝒎𝒑𝒐 = 𝟓𝒉 ∗ ∗ = 𝟏𝟖𝟎𝟎𝟎𝒔
    𝟏𝒉 𝟏𝒎𝒊𝒏

    𝒎𝒂𝒔𝒂 𝒅𝒆𝒑𝒐𝒔𝒊𝒕𝒂𝒅𝒂(𝒈) = 𝟏. 𝟑𝟎𝒈 𝒅𝒆 𝑯𝟐

    𝑛 ∗ 𝐹 ∗ 𝑚 2 ∗ 96500 ∗ 1.30𝑔
    𝐼= = = 6.969𝐴
    𝑀∗𝑡 2𝑔
    ∗ 𝟏𝟖𝟎𝟎𝟎𝒔
    𝑚𝑜𝑙

    Para el catión de 𝐶𝑢+ :


    𝑀 ∗ 𝐼 ∗ 𝑡 𝟔𝟑. 𝟓𝟒𝒈/𝒎𝒐𝒍 ∗ 6.969𝐴 ∗ 𝟏𝟖𝟎𝟎𝟎𝒔
    𝑚𝑎𝑠𝑎 𝑑𝑒𝑝𝑜𝑠𝑖𝑡𝑎𝑑𝑎(𝐶𝑢+ ) = =
    𝑛∗𝐹 𝟏 ∗ 𝟗𝟔𝟓𝟎𝟎
    = 𝟖𝟐. 𝟓𝟗𝟔𝒈

    Para el 𝑂2 :
    𝑀 ∗ 𝐼 ∗ 𝑡 𝟑𝟔𝒈/𝒎𝒐𝒍 ∗ 6.969𝐴 ∗ 𝟏𝟖𝟎𝟎𝟎𝒔
    𝑚𝑎𝑠𝑎 𝑑𝑒𝑝𝑜𝑠𝑖𝑡𝑎𝑑𝑎(𝑂2 ) = = = 𝟒𝟔. 𝟕𝟗𝟕𝒈
    𝑛∗𝐹 𝟏 ∗ 𝟗𝟔𝟓𝟎𝟎
    SOLUCIÓN:

    60𝑚𝑖𝑛 60𝑠
    𝑇𝑖𝑒𝑚𝑝𝑜 = 2ℎ ∗ ∗ = 7200𝑠
    1ℎ 1𝑚𝑖𝑛

    𝑚𝑎𝑠𝑎 𝑑𝑒𝑝𝑜𝑠𝑖𝑡𝑎𝑑𝑎 𝑑𝑒 𝐶𝑟 +3 = 1.1𝑔

    𝑀 = 51.99𝑔/𝑚𝑜𝑙

    𝑛 ∗ 𝐹 ∗ 𝑚 3 ∗ 96500 ∗ 1.1𝑔
    𝐼= = = 0.8507𝐴
    𝑀∗𝑡 51.99𝑔
    ∗ 7200𝑠
    𝑚𝑜𝑙

    Calculamos la masa de H2(g) depositada en el cátodo:

    2𝑔
    𝑀 ∗ 𝐼 ∗ 𝑡 𝑚𝑜𝑙 ∗ 0.8507𝐴 ∗ 7200𝑠
    𝑚𝑎𝑠𝑎 𝑑𝑒𝑝𝑜𝑠𝑖𝑡𝑎𝑑𝑎(𝑔) = = = 0.06347𝑔
    𝑛∗𝐹 2 ∗ 96500

    Calculo del número de moles de H2:

    0.06347𝑔
    𝑚𝑜𝑙𝑒𝑠 = = 0.0317𝑚𝑜𝑙 𝑑𝑒 𝐻2
    2𝑔/𝑚𝑜𝑙

    𝑇 = 70º𝐶 = 343º𝐾

    𝑃 = 12000𝑃𝑎

    𝑃𝑎 ∗ 𝐿
    𝑅 = 8314.472
    𝑚𝑜𝑙 ∗ º𝐾

    Reemplazando para calcular el volumen del 𝑯𝟐 :

    𝑃𝑎 ∗ 𝐿
    𝑛 ∗ 𝑅 ∗ 𝑇 0.0317𝑚𝑜𝑙 ∗ 8314.472 𝑚𝑜𝑙 ∗ º𝐾 ∗ 343º𝐾
    𝑉= = = 𝟕. 𝟓𝟑𝟑𝟔𝑳
    𝑃 12000𝑃𝑎

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