SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Sikalastic®-871 JW (A)

Product code : 000000608389

Type of product : liquid

Manufacturer or supplier's details

Company : P.T. Sika Indonesia
JL. Raya Cibinong - Bekasi km 20
Limusnunggal Cileungsi
Bogor 16820
Telephone : +62 21 823 0025
Telefax : +62 21 823 0026
E-mail address : [email protected]
Emergency telephone num- : 0800-31401236
ber

2. HAZARDS IDENTIFICATION

GHS Classification
Acute toxicity (Inhalation) : Category 4

Skin corrosion/irritation : Category 2

Serious eye damage/eye irri- : Category 2A

tation

Respiratory sensitisation : Category 1

Skin sensitisation : Category 1

Carcinogenicity : Category 2

Specific target organ toxicity - : Category 3 (Respiratory system)

single exposure

Specific target organ toxicity - : Category 2

repeated exposure
(Inhalation)

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

H332 Harmful if inhaled.

H334 May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or re-
peated exposure if inhaled.

Precautionary statements : Prevention:

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P284 Wear respiratory protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P333 + P313 If skin irritation or rash occurs: Get medical ad-
vice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ at-
tention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components
Chemical name CAS-No. Concentration (%)
4,4'-methylenediphenyl diisocyanate 101-68-8 >= 30 - < 60
methylenediphenyl diisocyanate 26447-40-5 >= 1 - < 10

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

4,4`-Methylenediphenyl diisocyanate, oligomers 25686-28-6 >= 1 - < 10

4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Most important symptoms : irritant effects

and effects, both acute and sensitising effects
delayed Asthmatic appearance
Cough
Respiratory disorder
Allergic reactions
Excessive lachrymation
Headache
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficul-
ties if inhaled.
May cause respiratory irritation.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated
exposure if inhaled.

Notes to physician : Treat symptomatically.

5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.

Hazardous combustion prod- : No hazardous combustion products are known

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

ucts

Specific extinguishing meth- : Standard procedure for chemical fires.

ods

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Deny access to unprotected persons.
gency procedures

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Avoid formation of aerosol.

Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Follow standard hygiene measures when handling chemical
products

Conditions for safe storage : Store in original container.

Keep in a well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Store in accordance with local regulations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

Components CAS-No. Value type Control parame- Basis

(Form of ters / Permissible
exposure) concentration
4,4'-methylenediphenyl diiso- 101-68-8 NAB 0,005 ppm ID OEL
cyanate
Further information: Respiratory sensitization
TWA 0,005 ppm ACGIH
4,4`-Methylenediphenyl diiso- 25686-28-6 NAB 0,005 ppm ID OEL
cyanate, oligomers
Further information: Respiratory sensitization
TWA 0,005 ppm ACGIH
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection : Chemical-resistant, impervious gloves complying with an ap-

proved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : colourless

Odour : pungent

Odour Threshold : No data available

pH : No data available

Melting point/range / Freezing : No data available

point

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

Boiling point/boiling range : No data available

Flash point : ca. 200 °C (392 °F)

Method: closed cup

Evaporation rate : No data available

Flammability : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : 0,01 hPa (0,01 mmHg)

Relative vapour density : No data available

Density : 1,1 g/cm3 (20 °C (68 °F) ())

Solubility(ies)
Water solubility : insoluble

Partition coefficient: n- : No data available

octanol/water

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : > 7 mm2/s (40 °C)

Explosive properties : No data available

Molecular weight : No data available

VOC-EU (solvent) : Not applicable

10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : Stable under recommended storage conditions.

tions

Conditions to avoid : No data available

Incompatible materials : No data available

No decomposition if stored and applied as directed.

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if inhaled.
Components:
4,4'-methylenediphenyl diisocyanate:
Acute inhalation toxicity : Acute toxicity estimate: 1,5 mg/l
Test atmosphere: dust/mist
Method: Expert judgement

4,4`-Methylenediphenyl diisocyanate, oligomers:

Acute oral toxicity : LD50 Oral (Rat): > 5.000 mg/kg

Acute inhalation toxicity : Acute toxicity estimate: 1,5 mg/l

Test atmosphere: dust/mist
Method: Expert judgement

Acute dermal toxicity : LD50 Dermal (Rabbit): > 9.400 mg/kg

Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Skin sensitisation: May cause an allergic skin reaction.
Respiratory sensitisation: May cause allergy or asthma symptoms or breathing difficulties if in-
haled.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Suspected of causing cancer.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
May cause respiratory irritation.
STOT - repeated exposure
May cause damage to organs through prolonged or repeated exposure if inhaled.
Aspiration toxicity
Not classified based on available information.

12. ECOLOGICAL INFORMATION

Ecotoxicity
No data available
Persistence and degradability
No data available

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : There is no data available for this product.
mation

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Do not re-use empty containers.

14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 2206
Proper shipping name : ISOCYANATES, TOXIC, N.O.S.
Class : 6.1
Packing group : III
Labels : 6.1
IATA-DGR
UN/ID No. : UN 2206
Proper shipping name : Isocyanates, toxic, n.o.s.
Class : 6.1
Packing group : III
Labels : Toxic Substances
Packing instruction (cargo : 663
aircraft)
Packing instruction (passen- : 655
ger aircraft)
IMDG-Code
UN number : UN 2206
Proper shipping name : ISOCYANATES, TOXIC, N.O.S.

Class : 6.1
Packing group : III
Labels : 6.1
EmS Code : F-A, S-A
Marine pollutant : no

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture

Minister of Industry Regulation No. 23/M-IND/PER/4/2013 concerning the Revision of Minis-

ter of Industry Regulation No. 87/M-IND/PER/9/2009 concerning Globally Harmonized Sys-
tem of Classification and Labelling of Chemicals.

Regulation of the Minister of Health No. 472 of 1996 on the Safeguarding of Substances
Hazardous to Health
Hazardous substances that must be registered : Not applicable

Government Regulation No. 74 of 2001 on the Management of Hazardous and Toxic Sub-
stances
Hazardous substances approved for use : Not applicable

Prohibited substances : Not applicable

Restricted substances : Not applicable

Regulation of the Minister of Trade No. 44 of 2009 on Procurement, Distribution and Su-
pervision of Hazardous Materials
Types of Hazardous Materials governed by Import : Not applicable
Regulations

Types of Hazardous Materials of which the Distri- : Not applicable

bution and Supervision is Regulated

The components of this product are reported in the following inventories:

AICS : Not in compliance with the inventory

NZIoC : On the inventory, or in compliance with the inventory

KECI : Not in compliance with the inventory

PICCS : Not in compliance with the inventory

IECSC : Not in compliance with the inventory

TCSI : Not in compliance with the inventory

MY EHS Register : Not in compliance with the inventory

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SAFETY DATA SHEET

Sikalastic®-871 JW (A)
Version 1.0 SDS Number: 000000608389 Revision Date: 2019/04/23

16. OTHER INFORMATION

Date format : yyyy/mm/dd

The information contained in this Safety Data Sheet corresponds to our level of knowledge at
the time of publication. All warranties are excluded. Our most current General Sales Condi-
tions shall apply. Please consult the product data sheet prior to any use and processing.

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