DOW CORNING CORPORATION

Material Safety Data Sheet

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Version: 1.4
Revision Date: 2010/10/15
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT

1. PRODUCT AND COMPANY IDENTIFICATION

Dow Corning Corporation 24 Hour Emergency Telephone: (989) 496-5900

South Saginaw Road Customer Service: (989) 496-6000
Midland, Michigan 48686 Product Disposal Information: (989) 496-6315
CHEMTREC: (800) 424-9300

MSDS No.: 01889834 Revision Date: 2010/10/15

Generic Description: Silicone grease.

Physical Form: Grease
Color: Translucent white
Odor: Odorless

NFPA Profile: Health 0 Flammability 1 Instability/Reactivity 0

Note: NFPA = National Fire Protection Association

2. HAZARDS IDENTIFICATION

POTENTIAL HEALTH EFFECTS

Acute Effects

Eye: Direct contact may cause temporary redness and discomfort.

Skin: No significant irritation expected from a single short-term exposure.

Inhalation: No significant effects expected from a single short-term exposure.

Oral: Low ingestion hazard in normal use.

Prolonged/Repeated Exposure Effects

Skin: No known applicable information.

Inhalation: No known applicable information.

Oral: No known applicable information.

Signs and Symptoms of Overexposure

No known applicable information.

Medical Conditions Aggravated by Exposure

No known applicable information.

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The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.

3. COMPOSITION/INFORMATION ON INGREDIENTS

None present. This is not a hazardous material as defined in the OSHA Hazard Communication Standard.

4. FIRST AID MEASURES

Eye: If irritation occurs, flush eye(s) with lukewarm gently flowing water for 5 minutes. Obtain
medical attention.

Skin: No health effects expected. If irritation does occur flush with lukewarm, gently flowing water
for 5 minutes. If irritation persists, obtain medical advice.

Inhalation: If symptoms are experienced remove source of contamination or move victim to fresh air. If
irritation persists, obtain medical advice.

Oral: If irritation or discomfort occur, obtain medical advice.

Notes to Physician: Treat according to person's condition and specifics of exposure.

5. FIRE FIGHTING MEASURES

Flash Point: > 214 °F / > 101.1 °C (Closed Cup)

Autoignition Temperature: Not determined.

Flammability Limits in Air: Not determined.

Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.

Unusual Fire Hazards: None.

6. ACCIDENTAL RELEASE MEASURES

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Containment/Clean up: Determine whether to evacuate or isolate the area according to your local emergency plan.
Observe all personal protection equipment recommendations described in Sections 5 and 8.
For large spills, provide diking or other appropriate containment to keep material from
spreading. If diked material can be pumped, store recovered material in appropriate
container. Clean up remaining materials from spill with suitable absorbant. Clean area as
appropriate since spilled materials, even in small quantities, may present a slip hazard. Final
cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or
cleaning materials appropriately, since spontaneous heating may occur. Local, state and
federal laws and regulations may apply to releases and disposal of this material, as well as
those materials and items employed in the cleanup of releases. You will need to determine
which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this
MSDS provide information regarding certain federal and state requirements.

Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.

7. HANDLING AND STORAGE

Use with adequate ventilation. Avoid eye contact.

Use reasonable care and store away from oxidizing materials.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Component Exposure Limits

There are no components with workplace exposure limits.

Engineering Controls

Local Ventilation: None should be needed.

General Ventilation: Recommended.

Personal Protective Equipment for Routine Handling

Eyes: Use proper protection - safety glasses as a minimum.

Skin: Washing at mealtime and end of shift is adequate.

Suitable Gloves: Handle in accordance with good industrial hygiene and safety practices.

Inhalation: No respiratory protection should be needed.

Suitable Respirator: None should be needed.

Personal Protective Equipment for Spills

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Eyes: Use proper protection - safety glasses as a minimum.

Skin: Washing at mealtime and end of shift is adequate.

Inhalation/Suitable No respiratory protection should be needed.

Respirator:

Precautionary Measures: Avoid eye contact. Use reasonable care.

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical Form: Grease

Color: Translucent white
Odor: Odorless
Specific Gravity @ 25°C: 1.1
Viscosity: Not determined.
Freezing/Melting Point: Not determined.
Boiling Point: Not determined.
Vapor Pressure @ 25°C: Not determined.
Vapor Density: Not determined.
Solubility in Water: Not determined.
pH: Not determined.
Volatile Content: Not determined.
Flash Point: > 214 °F / > 101.1 °C (Closed Cup)
Autoignition Temperature: Not determined.
Flammability Limits in Air: Not determined.

Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.

10. STABILITY AND REACTIVITY

Chemical Stability: Stable.

Hazardous Hazardous polymerization will not occur.

Polymerization:
Conditions to Avoid: None.

Materials to Avoid: Oxidizing material can cause a reaction.

Hazardous Decomposition Products

Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition
products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde.
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11. TOXICOLOGICAL INFORMATION

Special Hazard Information on Components

No known applicable information.

12. ECOLOGICAL INFORMATION

Environmental Fate and Distribution

Complete information is not yet available.

Environmental Effects

Complete information is not yet available.

Fate and Effects in Waste Water Treatment Plants

Complete information is not yet available.

Ecotoxicity Classification Criteria

Hazard Parameters (LC50 or EC50) High Medium Low
Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100
Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.

This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.

13. DISPOSAL CONSIDERATIONS

RCRA Hazard Class (40 CFR 261)

When a decision is made to discard this material, as received, is it classified as a hazardous waste? No

State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional
information is required.

14. TRANSPORT INFORMATION

DOT Road Shipment Information (49 CFR 172.101)

Not subject to DOT.

Ocean Shipment (IMDG)

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Not subject to IMDG code.

Air Shipment (IATA)

Not subject to IATA regulations.

Call Dow Corning Transportation, (989) 496-8577, if additional information is required.

15. REGULATORY INFORMATION

Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.

TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings

Section 302 Extremely Hazardous Substances (40 CFR 355):

None.

Section 304 CERCLA Hazardous Substances (40 CFR 302):

None.

Section 311/312 Hazard Class (40 CFR 370):

Acute: No
Chronic: No
Fire: No
Pressure: No
Reactive: No

Section 313 Toxic Chemicals (40 CFR 372):

None present or none present in regulated quantities.

Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold.

Supplemental State Compliance Information

California

Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.

None known.

Massachusetts
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CAS Number Wt % Component Name

7631-86-9 7.0 - 13.0 Silica, amorphous

New Jersey

CAS Number Wt % Component Name

63148-62-9 > 60.0 Polydimethylsiloxane

7631-86-9 7.0 - 13.0 Silica, amorphous

70131-67-8 5.0 - 10.0 Dimethyl siloxane, hydroxy-terminated

Pennsylvania

CAS Number Wt % Component Name

63148-62-9 > 60.0 Polydimethylsiloxane

7631-86-9 7.0 - 13.0 Silica, amorphous

70131-67-8 5.0 - 10.0 Dimethyl siloxane, hydroxy-terminated

16. OTHER INFORMATION

Prepared by: Dow Corning Corporation

These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.

(R) indicates Registered Trademark