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    ACTIVITY 6.1 KSP and Precipitation

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    Joseph Xerxel Cabilte
    This document describes an experiment involving precipitation reactions and calculations related to solubility product constants (Ksp). It involves: 1) Precipitating silver chloride from solutions of silver nitrate and sodium chloride. 2) Writing Ksp expressions and determining which solvent (water or diluted HCl) would better dissolve the precipitate, based on the common ion effect. 3) Writing balanced ionic equations and Ksp expressions for slightly soluble calcium sulfate, sodium sulfate, cerium hydroxide, and magnesium oxysilicate. 4) Calculating molar solubilities and Ksp values based on given solubility data and concentrations. This determines whether precipitation of calcium hydrogen phosphate will occur.

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    ACTIVITY 6.1 KSP and Precipitation

    Uploaded by

    Joseph Xerxel Cabilte
    46 views2 pages
    This document describes an experiment involving precipitation reactions and calculations related to solubility product constants (Ksp). It involves: 1) Precipitating silver chloride from solutions of silver nitrate and sodium chloride. 2) Writing Ksp expressions and determining which solvent (water or diluted HCl) would better dissolve the precipitate, based on the common ion effect. 3) Writing balanced ionic equations and Ksp expressions for slightly soluble calcium sulfate, sodium sulfate, cerium hydroxide, and magnesium oxysilicate. 4) Calculating molar solubilities and Ksp values based on given solubility data and concentrations. This determines whether precipitation of calcium hydrogen phosphate will occur.

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    ACTIVITY 6.1 Ksp and Precipitation

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    This document describes an experiment involving precipitation reactions and calculations related to solubility product constants (Ksp). It involves: 1) Precipitating silver chloride from solutions of silver nitrate and sodium chloride. 2) Writing Ksp expressions and determining which solvent (water or diluted HCl) would better dissolve the precipitate, based on the common ion effect. 3) Writing balanced ionic equations and Ksp expressions for slightly soluble calcium sulfate, sodium sulfate, cerium hydroxide, and magnesium oxysilicate. 4) Calculating molar solubilities and Ksp values based on given solubility data and concentrations. This determines whether precipitation of calcium hydrogen phosphate will occur.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    46 views2 pages

    ACTIVITY 6.1 KSP and Precipitation

    Uploaded by

    Joseph Xerxel Cabilte
    This document describes an experiment involving precipitation reactions and calculations related to solubility product constants (Ksp). It involves: 1) Precipitating silver chloride from solutions of silver nitrate and sodium chloride. 2) Writing Ksp expressions and determining which solvent (water or diluted HCl) would better dissolve the precipitate, based on the common ion effect. 3) Writing balanced ionic equations and Ksp expressions for slightly soluble calcium sulfate, sodium sulfate, cerium hydroxide, and magnesium oxysilicate. 4) Calculating molar solubilities and Ksp values based on given solubility data and concentrations. This determines whether precipitation of calcium hydrogen phosphate will occur.

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    © All Rights Reserved
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    ACTIVITY 6.

    1
    KSP and Precipitation

    NAME(s):
    SCHEDULE:

    PART I
    In one of the most famous reactions in chemistry, addition of colorless aqueous silver nitrate to
    an equally colorless solution of sodium chloride produces an opaque white precipitate of AgCl:

    AgCl (s) ⇌ Ag+ (aq) + Cl¯ (aq)

    Add silver nitrate dropwise to 1 mL of sodium chloride, until precipitation occurs. Observe
    initial color of the precipitate formed and the color at the end

    1. Write a Ksp expression for this equilibrium (2 POINTS)

    2. Which solvent would dissolve the precipitate better: pure water or a solution of diluted
    hydrochloric acid? Explain why this is so and name the effect involved (3 POINTS)

    PART II
    Write the BALANCED ionic equation for the dissolution AND the solubility product for each of
    the following slightly soluble compounds (2 POINTS EACH)

    1. CaSO4

    2. Na2SO4

    3. Ce(OH)3

    4. Mg₂O₈Si₃

    PART III
    Calculate for what is being asked (1 POINT FOR SOLUTION; 2 POINTS FOR CORRECT
    ANSWER)

    1. The molar solubility of barium sulfate is 3 grams per 550 mL. Calculate for the Ksp. MW
    of barium sulfate: 233.4 g/mol
    2. The Ksp of magnesium fluoride is 2.3 × 10–6. Calculate the molar solubility of magnesium
    fluoride.
    3. The Ksp of sodium chloride is 1.7 × 10 –5. What will its molar solubility be if it was added
    to a solution containing 4.5 g of calcium chloride in 500mL solution (MW of calcium
    chlroide: 111 g/mol)? Apply the common ion effect.
    4. The Ksp value for the compound is given below. Determine whether CaHPO 4 will
    precipitate from a solution with [Ca2+] = 0.002 M and [HPO42-] = 0.0005 M by calculating
    for Q:

    CaHPO Ksp=5 ×
    4 10−5

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