CBSE 2021-2022

CHEMISTRY PRACTICAL (TERM 1)

P-BLOCK ELEMENT
TERM-1

SUBMITTING TO SUBMITTED BY

Mrs.PUSHPA SAHU HARSH URMALIYA

XII (PCM)
 GENERAL INTRODUCTION
 The p-Block elements: Elements belonging to groups 13 to 18 of the
periodic table are called p-block elements.
 General electronic configuration of p-block elements: The p-block
elements are characterized by the ns2np1-6 valence shell electronic
configuration.
 Representative elements: Elements belonging to the s and p-blocks in the
periodic table are called the representative elements or main group
elements.
 Inert pair effect: The tendency of ns2 electron pair to participate in bond
formation decreases with the increase in atomic size. Within a group the
higher oxidation state becomes less stable with respect to the lower
oxidation state as the atomic number increases. This trend is called ‘inert
pair effect’. In other words, the energy required to unpair the electrons
is more than energy released in the formation of two additional bonds.
GROUP 15 ELEMENTS
 Nitrogen family: The elements of group 15 – nitrogen (N), phosphorus
(P), arsenic (As), antimony (Sb) and bismuth (Bi) belong to configuration
is  .
 Atomic and ionic radii:
1. Covalent and ionic radii increase down the group.
2. There is appreciable increase in covalent radii from N to P.
3. There is small increase from As to Bi due to presence of completely filled
d or f orbitals in heavy elements.
 Ionisation energy:
1. It goes on decreasing down the group due to increase in atomic size.
2. Group 15 elements have higher ionisation energy than group 14
elements due to smaller size of group 15 elements.
3. Group 15 elements have higher ionization energy than group 16
elements because they have stable electronic configuration i.e., half-
filled p-orbitals.
 Allotropy: All elements of Group 15 except nitrogen show allotropy.
 Catenation:
1. Nitrogen shows catenation to some extent due to triple bond but
phosphorus shows catenation to maximum extent.
2. The tendency to show catenation decreases down the group.
 Oxidation states:
1. The common oxidation states are +3, +5 and –3.
2. The tendency to show –3 oxidation state decreases down the group
because of decrease in electronegativity by the increase in atomic size.
3. The stability of +5 oxidation state decreases whereas stability of +3
oxidation state increases due to inert pair effect.
4. Nitrogen shows oxidation states from –3 to +5.
5. Nitrogen and phosphorus with oxidation states from +1 to +4 undergo
oxidation as well as reduction in acidic medium. This process is called
disproportionation.

 Reactivity towards hydrogen:

1. All group 15 elements from trihydrides,  .
2. It belongs to   hybridisation.
3. The stability of hydrides decreases down the group due to decrease in
bond dissociation energy down the group.

 Boiling point:

1. Boiling point increases with increase in size due to increase in van der
Waals forces.
2. Boiling point of NH3 is more because of hydrogen bonding.
 Bond angle:
1. Electronegativity of N is highest. Therefore, the lone pairs will be
towards nitrogen and hence more repulsion between bond pairs.
 Therefore bond angle is the highest. After nitrogen, the electronegativity
decreases down the group.
2. Basicity decreases as NH3> PH3> AsH3> SbH3< BiH3. This is because
the lone pair of electrons are concentrated more on nitrogen and hence
the basicity will be maximum in the case of NH3. It will decrease down
the group as the electronegativity decreases down the group. The
reducing power of hydrides increases down the group due to decrease
in bond dissociation energy down the group.
 Reactivity towards oxygen:
1. All group 15 elements from trioxides ( ) and pentoxides ( ).
2. Acidic character of oxides decreases and basicity increases down the
group. This is because the size of nitrogen is very small.
3. It has a strong positive field in a very small area. Therefore, it attracts the
electrons of water O-H bond to itself and release H+ ions easily.
4. As we move down the group, the atomic size increases and so, the
acidic character of oxide decreases and basicity increases down the
group.
 Reactivity towards halogen:
Group 15 elements form trihalides and pentahalides.

1. Trihalides: These are covalent compounds and become ionic down the
group with  hybridisation, pyramidal shape.
2. Pentahalidesa). They are lewis acids because of the presence of vacant d
– orbitals.b). They possess   hybridisation and hence possess
trigonalbirpyamidal shape.
3. PCl5 is ionic in solid state and exist as 
4. In PCl5, there are three equatorial bonds and two axial bonds. The axial
bonds are longer than equatorial bonds because of greater repulsion
from equatorial bonds.
5. Nitrogen does not form pentahalides due to absence of d– orbitals.
 Reactivity towards metals: All elements react with metals to form binary
compounds in –3 oxidation state.
  Anomalous behaviour of nitrogen: The behaviour of nitrogen differs from
rest of the elements.
Reasons:
i. It has a small size.
ii. It does not have d – orbitals
iii. It has high electronegativity
iv. It has high ionization enthalpy
 Dinitrogen:
a) Preparation:

b) Physical Properties:
i) It is a colourless, odourless, tasteless and non – toxic gas.
ii) It is chemically un-reactive at ordinary temperature due to triple bond in N
≡ N which has high bond dissociation energy.
 Ammonia:
1. Ammonia molecule is trigonal pyramidal with nitrogen atom at the apex.
2. It has 3 bond pairs and 1 lone pair.
3. N is  hybridised.
4. Preparation:
Haber’s process:

Pressure 200 10 Pa Temperature 773 K Catalyst is FeO with small amounts

of   and 
 Nitric Acid:
Ostwald Process: The NO thus formed is recycled and the aqueous   can
be concentrated by distillation upto ~ 68% by mass. Further concentration to
98% can be achieved by dehydration with concentrated  . Nitric acid is
strong oxidizing agent in the concentrated as well as in the dilute state.

Phosphorus:
a) It shows the property of catenation to maximum extent due to most stable
P – P bond.
b) It has many allotropes, the important ones are:
i) White phosphorus
ii) Red phosphorus
iii) Black phosphorus
 White phosphorus:
1. Discrete tetrahedral P4 molecules
2. Very reactive
3. Glows in dark
4. Translucent waxy solid
5. Soluble in  but insoluble in water
6. It has low ignition temperature, therefore, kept under water
 Red phosphorus
1. Polymeric structure consisting of chains of P4 units linked together
2. Less reactive than white phosphorus
3. Does not glow in dark
4. Has an iron grey lustre
5. Insoluble in water as well as 
 Black phosphorus
1. Exists in two forms –   black phosphorus and   black phosphorus
2. Very less reactive
3. Has an opaque monoclinic or rhombohedral crystals

 Phosphine
1. It is highly poisonous, colourless gas and has a smell of rotten fish.
 2. Preparation

 Chlorides of Phosphorous:
a) Phosphorus Trichloride
i) It is a colourless oily liquid.
ii) Preparation

iii) With water,
It gets hydrolysed in the presence of moisture.

iv) Pyramidal shape, sp3 hybridisation

v) With acetic acid

vi). With alcohol

b) Phosphorus pentachloride

1. Yellowish white powder.

2. Trigonalbipyramidal shape, sp3dhybridisation .
3. Preparation
4.

5. With water
6.

7. With acetic acid

8.
9. With alcohol
10.With metals

GROUP 16 ELEMENTS
 Oxidation states:
1. They show -2, +2, +4, +6 oxidation states.
2. Oxygen does not show +6 oxidation state due to absence of d – orbitals.
3. Po does not show +6 oxidation state due to inert pair effect.
4. The stability of -2 oxidation state decreases down the group due to
increase in atomic size and decrease in electronegativity.
5. Oxygen shows -2 oxidation state in general except in  and 
6. Thus, the stability of +6 oxidation state decreases and +4 oxidation state
increases due to inert pair effect.
 Ionisation enthalpy:
1. Ionisation enthalpy of elements of group 16 is lower than group 15 due
to half-filled p-orbitals in group 15 which is more stable.
2. However, ionization enthalpy decreases down the group.
 Electron gain enthalpy:
1. Oxygen has less negative electron gain enthalpy than S because of small
size of O.
2. From S to Po electron gain enthalpy becomes less negative to Po
because of increase in atomic size.
 Melting and boiling point:
1. It increases with increase in atomic number.
2. Oxygen has much lower melting and boiling points than sulphur
because oxygen is diatomic (  ) and sulphur is octatomic ( ).
 Reactivity with hydrogen:
1. All group 16 elements form hydrides.
2. They possess bent shape.
3. Bond angle: 
  Acidic nature: 
This is because the H-E bond length increases down the group.
Therefore, the bond dissociation enthalpy decreases down the group.
 Thermal stability: 
This is because the H-E bond length increases down the group.
Therefore, the bond dissociation enthalpy decreases down the group.
 Reducing character: 
This is because the H-E bond length increases down the group.
Therefore, the bond dissociation enthalpy decreases down the group.
 Reactivity with oxygen:  and 
1. Reducing character of dioxides decreases down the group because
oxygen has a strong positive field which attracts the hydroxyl group and
removal of  becomes easy.
2. Acidity also decreases down the group.
3. is a gas whereas SeO2 is solid. This is because   has a chain
polymeric structure whereas SO2 forms discrete units.
 Reactivity with halogens: EX2, EX4 and EX6
1. The stability of halides decreases in the
order 
2. This is because E-X bond length increases with increase in size.
3. Among hexa halides, fluorides are the most stable because of steric
reasons.
4. Dihalides are   hybridised and so, are tetrahedral in shape.
5. Hexafluorides are only stable halides which are gaseous and have   
hybridisation and octahedral structure.
6.  is a liquid while H2S is a gas. This is because strong hydrogen
bonding is present in water. This is due to small size and high
electronegativity of O.
Oxygen:
The compounds of oxygen and other elements are called oxides.
 Oxides: The compounds of oxygen and other elements are called oxides.
 Types of oxides:

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1. Acidic oxides: Non- metallic oxides are usually acidic in nature.
2. Basic oxides: Metallic oxides are mostly basic in nature. Basic oxides
dissolve in water forming bases e.g.,
3. Amphoteric oxides: They show characteristics of both acidic as well as
basic oxides. 

4. Neutral oxides: These oxides are neither acidic nor basic. Example: Co,
NO and N2O
 Ozone:
1. Preparation: It is prepared by passing silent electric discharge through
pure and dry oxygen 10 – 15 % oxygen is converted to ozone.

2. Structure of Ozone: Ozone has angular structure. Both O = O bonds are

of equal bond length due to resonance.
 Sulphur:
1. Sulphur exhibits allotropy:
1. Yellow Rhombic (  – sulphur)
2. Monoclinic (- sulphur)
2.
3. At 369 K both forms are stable. It is called transition temperature.
4. Both of them have S8 molecules.
 5. The ring is puckered and has a crown shape.
6. Another allotrope of sulphur – cyclo   ring adopts a chair form.
7. S2is formed at high temperature ( 1000 K).
8. It is paramagnetic because of 2 unpaired electrons present in anti
bonding * orbitals like O2.
Sulphuric acid:
By contact process

1. Preparation:
2. Exothermic reaction and therefore low temperature and high pressure
are favourable.
3. It is dibasic acid or diprotic acid.
4. It is a strong dehydrating agent.
5. It is a moderately strong oxidizing agent.
GROUP 17 ELEMENTS
 Atomic and ionic radii: Halogens have the smallest atomic radii in their
respective periods because of maximum effective nuclear charge.
 Ionisation enthalpy: They have very high ionization enthalpy because of
small size as compared to other groups.
 Electron gain enthalpy:
1. Halogens have maximum negative electron gain enthalpy because these
elements have only one electron less than stable noble gas
configuration.
2. Electron gain enthalpy becomes less negative down the group because
atomic size increases down the group.
 Electronegativity:
1. These elements are highly electronegative and electronegativity
decreases down the group.
2. They have high effective nuclear charge.
 Bond dissociation enthalpy:
1. Bond dissociation enthalpy follows the order: 
2. This is because as the size increases bond length increases.
3. Bond dissociation enthalpy of Cl2 is more than F2 because there are
large electronic repulsions of lone pairs present in F2.
 Colour: All halogens are coloured because of absorption of radiations in
visible region which results in the excitation of outer electrons to higher
energy levels.
 Oxidising power:
1. All halogens are strong oxidisingagents because they have a strong
tendency to accept electrons.
2. Order of oxidizing power is: 
 Reactivity with Hydrogen:
1. Acidic strength: HF <HCl<HBr< HI
2. Stability: HF >HCl>HBr> HI. This is because of decrease in bond
dissociation enthalpy.
3. Boiling point: HCl<HBr< HI < HF. HF has strong intermolecular H
bonding. As the size increases van der Waals forces increases and hence
boiling point increases.
4. % Ionic character: HF >HCl>HBr> HI Dipole moment: HF >HCl>HBr> HI.
Electronegativity decreases down the group.
5. Reducing power: HF <HCl<HBr< HI
 Reactivity with metals:
1. Halogens react with metals to form halides.
2. Ionic character: MF >MCl>MBr> MI. The halides in higher oxidation
state will be more covalent than the one in the lower oxidation state.
  Interhalogen compounds:
Reactivity of halogens towards other halogens:
1. Binary compounds of two different halogen atoms of general formula
X   are called interhalogen compounds where n = 1, 3, 5, or 7. All
these are covalent compounds.
2. Interhalogen compounds are more reactive than halogens because X-X
is a more polar bond than X-X bond.
3. All are diamagnetic.
4. Their melting point is little higher than halogens.
5. XX’ (CIF, BrF, BrCl, ICl, IBr, IF) (Linear shape) XX’ 3 ( )
(Bent T- shape) XX’5 – , (square pyramidal shape) XX’7 –
 (Pentagonal bipyramidal shape)
 Oxoacids of halogens:

1. Fluorine forms only one oxoacid HOF (Fluoric (I) acid or hypofluorous
acid) due to high electronegativity.
2. Acid strength: 
3. Reason:
4. Acid strength: HOF >HOCl>HOBr> HOI. This is because Fluorine is most
electronegative.
GROUP 18 ELEMENTS:
 Ionisation enthalpy:
1. They have very high ionization enthalpy because of completely filled
orbitals.
2. Ionisation enthalpy decreases down the group because of increase in
size.
 Atomic radii: Increases down the group because the number of shells
increases down the group.
 Electron gain enthalpy: They have large electron gain enthalpy because of
stable electronic configuration.
  Melting and boiling point: It has low melting and boiling point due to the
presence of only weak dispersion forces.
 Shapes:
 is linear,   is square planar and   is distorted octahedral.   is
known but no true compound of He Ne and Arare known.
 Compounds of Xe and F:




 and   are powerful fluorinating agents.
 Compounds of Xe and O:

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