BUCKMAN LABORATORIES, INC. /AQL) MATERIAL SAFETY DATA SHEET BUSAN 115 Revision date: 11/3/2008 Buckman Laboratories, Inc, 1256 North McLean Boulevard 24 Hour Emergency Phone: (901) 767-2722 Memphis, TN 38108 Phone 1-800-BUCKMAN |_SECTION1 OSHA HAZARD CLASSIFICATIONS Expected to be corrosive to eyes and skin, Sensitizer Avoid breathing yapors or spray mists. SECTION 2 HAZARDOUS COMPONENTS. Chemical Name CAS Number by Weight Ty Sodium dodeeylbenzene sulfonate 25155-30-0 at Not available. 2-Butosyethanol 11-762 3 OSHA PEL 22 (United States). TWA: $0 ppm TWA: 240 magia’ ACGIH TLY (United States). TWA: 20 ppm TWA: 97 mg/m? Buckman Laboratories reports the component(s} listed above as known OSHA hazardous material(s) contained in this product [sections FIRST AD INFORMATION Bre ¥lush immediately with copious amounts of tap water or normal saline (minimum of 15 Exposure: minutes). Take exposed individual to a health care professional, preferably an ophthalmologist, for further evaluation. Ee ‘Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and Exposure: wash thoroughly before reuse. If irritation persists consult a health care professional. Inhalaton: ¥f exposure by inhalation is suspected, immediately move exposed individual to fresh air. If individual experiences nausea, headache, dizziness, has difficulty in breathing or is eyanotic, seck a health care professional immediately. Ingestion: — DO NOT INDUCE VOMITING. Rinse with copious amounts of water or milk, first. Inrigate the esophagus and dilute stomach contents by slowly giving one (1) to two (2) glasses of water or milk, Avoid giving alcohol or alcobol related products. In cases where the individual is semi- comatose, comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In ease of intentional ingestion of the produet seek medical assistance immediately; take individual to nearest medical facility. ‘SRCTIONS PRIMARY ROUTES OF EXPOSURE 1. Effects from Acute Exposure: ive Very hazardous in case of eye contact (Irritant, corrosive). Inflammation of the eye is Exposure: characterized by redness, watering, and itching. ‘Skin ‘Very hazardous in case of skin contact (Sensitizer), Hazardous in case of skin contact Exosure: (corrosive, irritant), Skin contact may produce burns, Skin inflammation is eheracterized by itching, sealing, reddening, or, eceasionally, blistering. Inhalation: Hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure, Ingestion: Tngestion is not expected to be a primary route of exposure. 2. Effects from Chronic Exposure: Repeated dermal exposures may cause allergic contact dermatitis type reactions in susceptible individuals, Repeated exposures may affect liver, kidney and cardiovascular system, SECTIONS Toxicological Information ‘a Acute Effects: ‘Acute Oral = (LDS Acute Dermal (LD50)=>2000 mg/kg Rabbit Tectant/ Sensitication Effet ‘Very hazardous in case of eye contact (irritant, corrosive). Inflammaation of the eye is characterized by redness, watering, and itching. Very hazardous in case of skin contact (Sensitizer), Hazardous in case of skin contact (corrosive, irritant), Skin contact may produce barns. Skin inflammation is characterized by itebing, scaling, reddening, or, occasionally, blistering, Hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure. Carcinogenie Potential: ‘Not tested by Buckman Laboratories. Not shown as a carcinogen by OSHA, IARC, or NTP. Target Organs Effects: May cause damage to the following organs: upper respiratory tract, skin, eyes. Other Health Effects: ‘Repeated/prolonged exposure may cause allergic skin reactions. 2-Butoxyethanol can affect the liver and kidneys after repeated exposures. It can have an anaesthetic effect. Birth defects are unlikely animal tests on the active ingredient were negative. Chronic feeding studies did not reveal any significant adverse effects. [ section Environmental Toxicological Information LCS50=0.32 mg/l 48 hours Daphnia magna L.C50=0.18 mg/l 96 hours Bluegill sunfish L.C50=0.05 mg/l 96 hours Rainbow trout ¥-C50~ 0.16 mg/l 96 hours Sheepshead minnow .50=0.07 mg/l 96 hours Mysid shrimpi SECTION? Physical and Chemical Propertie: Appearance. Otor Pale yellow liquid Mild. casi. 1.02 glens3 at 25°C (77°R) Flash Point CLOSED CUP: >99°C (210.2°F), (Setaflash,) Meling/Freesing Point Not available. Boiling Point nn The lowest known value is 171.2°C (340.2°F) (2-Butoxyethanol). Seay Soluble in cold water. Soluble in hot water. PH (Nea . 3 [Acidic] pH (100 ppm in wate. Not available, Vapor Pressure. 0.27 mm of Bg (@ 20°C ) 4 Parton Coefficient mu The product is more soluble in oil; log(oil/water) = Oxidicing Reducing Properties. Not available, Viscosity . . Not available. Additional pH Information uu, Not available, NOTE: The physical data presented above are typical values and should not be construed as specifications, SECTION 8 Fire and Explosion Information - Not available, Water fog, carbon dioxide, foam, dry chemical. Flammable Limits. Extinguishing Medi S-acial Firefighting pial Fieh Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. SECTION 9 Reactivity Information ] Stabitity Stable under normal conditions of use and storage. Store at temperatures between 39F 4C)-190F G70), ~ Oxidizing and reducing agents, amines, mercaptans. Do not store in vessels or containers made of stecl. Incompatiiley Hazardous Decomposition eat Oxides of carbon, sulfur, and nitrogen, SECTION 10 Handling Precautions poe —| Provide dilution ventilation ¢o control vapor and.\or mist level, ‘When misting may occur in the work area, a NIOSH/MSHA approved respirator may be required, Use a Fespirator approved for the material and level of exposure. A comprehensive respiratory protection program is needed when respirators must be used. Eye wash fountains in the work place are STRONGLY recommended, Chemical resistant gloves, indirect ventilation goggles, body-protective clothing, and chemical resistant safety shoes are required.Satisfactory Materials of Construction == Polypropylene \ “eflon viton Polyethylene - high density Kelrez Vinylester coating NOTE: With respect to all other materials not listed above, user should be aware that use of such materials with this product may be hazardous and result in damages to such materials and other property and personal injuries, No data concerning such materials not listed above should be implied by the user., [ SECTION 12 Spill, Leak, and Disposal Procedures SPILL AND LEAK RESPONSE GUIDELINES: Important: Before responding to a spill or leak ofthis produet, review each section of this MSDS, Follow the recommendations tziven ia the Handling Precautions sections. Check the Fire and Explosion Data seetion to determine if the use of non-sparking tools is merited. lusure that spilled or leaked product does not come into contact with materials listed as incompatible. I irritating fumes are present, consider evacuation of enclosed areas. Exmergency Response Assistance: Emergeney technical assistance is available at any ti calling (901) 767-2722, we from Buckman Laboratories, Ine, by Initially minimize area effected by the spill or leak. Block any potential routes to water systems (e.g, sewers, streams, lakes, et.). ‘Based on the product's toxicological and chemical properties, and on the size and location of the spill or leak, assess the impact on | ‘antaminated environments (eg. water systenss, ground, air equipment, ete.). There are no metbods available to completely | nninate any toxicity this produet may have on aquatic environments. Minimize adverse effects on these environments, Buckman | Laboratories, Inc. can be contacted for technical assistance. Determine if federal, state, and/or local release notification is required (see Regulatory Classifications section ofthis MSDS). Reeover as much of the pure product as possible into appropslate ‘containers. Later, determine if this recovered produet ean be used for its intended purpose. Address clean-up of contaminated enviroments. Spill or leak residuals may have to be collected and disposed of. Clay, sol, or commercially available absorbents may be used to recover any material that can uot readily be recovered as pure product. Flushing residual material to an industrial sewer, if present atthe site ofa spill or leak incident, may be acceptable i authorized approval is obiained. If product and/or spilMMeak residuals are flushed to an industrial sewer, insure that they do not come into contact with incompatible materials, ‘Contact the person(s) responsible for the operation of your facility's industrial sewer system prior to intentionally fusbing or pumping spills or leaks of this product to the industrial sewer, DISPOSAL GUIDELINES Note: Follow federal, state, and local regulations governing the disposal of waste materials. "Neat Product: Contact your Buckman representative or Buckuan Laboratories, Inc, at (901) 278-0330. (Contaminated Materials: Determine if waste containing this produet can be handled by available industrial efiuent system or other on-site waste management unit. If offsite management is required, contact a company experienced in industrial waste ‘management, This product is not specifically listed in 40 CFR 261 as a Resource Conservation and Recovery Act (RCRA) hazardous waste, However, spill o leak residuals may met the eriteria of a characteristic hazardous waste under this Act. Check: the characteristies of the material to be disposed of and/or the physical and reactivity data given in this MSDS for the neat product. Container Disposal: Empty containers, as defined by appropriate sections of the RCRA, are not RCRA hazardous wastes However, insure proper management of any residuals remaining in container.SECTION 13, Transportation and Shipping Information DOT Skipping Information: UN3268 , CORROSIVE LIQUID, ACIDIC, ORGANIC, N.OS., (2 N-octyl-4-isothiazolin-3-ene) , Class 8, P.G, TM, (ERG Guide 153) IMOAMDG Shipping Information: UN3265 , CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S., (2-N-vetyl-4-isothiazolin-3-one) , Class 8, P.G, HI, MARINE POLLUTANT, (EmS No. F-A,S-B, ERG Guide 153, HazMat Code 4931466 ) IATA Shipping Information: UN3265 , CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S,, (2 N-oetyl-+-isothiazolin- 8, P.G, IIT, (ERG Guide 153, ERG Code 81) me), Class ‘Wheu shipped in a single package containing MORE THAN 2,966 GAL (25,000 LBS), this product contains 2 reportable quantity of SODIUM DODECYLBENZENE SULEONATE. The shipping deseription should be preceded or followed by the letters "RQ" and "SODIUM DODECYLBENZENE SULFONATE" should be added to the technical names following the proper shipping name. Untess otherwise stated, the shipping information provided above applies only 0 non-bulk containers of this product, Proper shipping ‘name and general shipping information may vary depending on packaging and mode of shipment, All products shipped from Buckman Jocations have been properly packaged and labeled according to appropriate hazardous materials shipping regulations. If any ‘alteration of packaging, product, or mode of transportation is further intended, diferent shipping information, including but not limited 10 proper shipping name, RO designation, and labeling may apply. For further information pertaining tothe shipping requirements for this product, contact Buckman's Transportation Department or DOT Coordinator. SECTION 14 Regulatory Information ~ae following Regulations are known to apply to the use and disposal of this produet. Additional Federal, tate and Local regulations may also be applicable. SARA (Superfund Amendments and Reauthorization Act) SARA 302 Extremely Hazardous Substances List. No components of this product are listed. SARA 312 Hazard Category No components of this produet are listed. SARA 313 Toxic Chemicals List. 2-Butoxyethanol (as glycol ether) CERCLA (Comprehensive Environmental Response, Compensation and Liability ct) Sodium dodecylbenzene sulfonate RQ = 1000 Ibs. BORA Resource Conversation and Recovery Act) Listed Hazardous Waste ‘No components of this product are listed. CWA (Clean Water Act) Listed Substances ‘No components of this product are listed. EDA (Food and Drug Administration This product is not approved for food contact uses TSCA (Toxic Substances Control Act) Applicability ‘All components are listed on the TSCA Inventory. Registered pesticides are exempt from the requirements of TSCA. i FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act This product is a registered pesticide. EPA Reg. No. 707-236-1448 HMIS/NPCA Rating .. Veith 3 Flammebiity 1 ReactivityHeth 3 Flammability 1 Reactivity @ State Regulations Various Stae Right To Know Acts ‘Non-proprietary hazardous chemicals are listed in Section 2 of this MSDS. Should you require further information on specific proprietary or inert ingredients please contact Buckman Laboratories’ Regulatory Affairs Department. ‘The information on this Material Safety Daca Sheet ruflocts the latest information and data that we have on hazards, properties, end handling ofthis product under the recommended conditions of use, Any use ofthis product ot mothod of application which is not described in the Data Sheet is the responsibility ofthe user. This Material Data Safety Sheet was prepared co comply with the OSHA Harari Commnication regulations. While some components are claimed Trade Secret under OSHA Hazard Cooumunication regulations, all known OSHIA harards associated with the Trade Secret eomapment(s), If contained in this predact, are fully disclosed. ‘Buckman Laboratories, Inc. warrants that this product conforms to its chemical description and is reasonably ft for the parpose referred to inthe directions for nse when used in accordance with the directions under normal conditions. Buyer assumes the rsk of any ‘use contrary to such directions, ‘Seller makes no other warranty of representation of any kind, express or implied, concerning the product including NO IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS OF THE GOODS FOR ANY OTHER PARTICULAR PURPOSE. No sich ‘warranties shall be implied by law and no agent of seller iy authorized to alter this warranty in any Way except in weiting with a specific veference to this warranty. ‘The exclusive remedy against seller shall bein claim for damages uot to excced the purchase price of the product, without regard to ‘whether such a claim is based upon breach of warranty or tort. | || Any controversy or claim arising out or relating to this contract, or breach thereof, shall be settle by arbitration in accordance with the || commereiat arbitration rales of the American Arbitration Association, and judgement upon the rendered by the Arbitrators) amy be entered in any court having jurisdietion thereof.