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Legaspi Hw1 Part2 (Linear)

The document provides data on the adsorption of contaminants from water onto a solid substrate. It gives concentration and adsorption capacity values and evaluates several common isotherm models (Langmuir, Freundlich) by nonlinear regression in Excel solver to determine which model best fits the data based on the R2 value.

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Frendick Legaspi
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48 views4 pages

Legaspi Hw1 Part2 (Linear)

The document provides data on the adsorption of contaminants from water onto a solid substrate. It gives concentration and adsorption capacity values and evaluates several common isotherm models (Langmuir, Freundlich) by nonlinear regression in Excel solver to determine which model best fits the data based on the R2 value.

Uploaded by

Frendick Legaspi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Use excel-solver nonlinear regression to find the best fit isotherm

model for the data set by maximizing R^2 (Brown's Method). Also
do linear regression using basic excel graphing. Compare R2 and
decide which to use.

Given:
Ce,ppm qe or q
0 0.6
0.5 2.73
1 3.32
2 4.44
5 7.22
8 9.34
10 11.35
15 15.54
20 16.78

Langmuir-1
Ce,ppm qe or q Ce/qe Linest Function Slope:y=mx+c qm
0 0.6 0 0.052636 0.253884 b
0.5 2.73 0.18315 0.007925 0.075612 qm=1/m R^2
1 3.32 0.301205 0.863045 0.158304 b=m/c
2 4.44 0.45045 44.1117 7
5 7.22 0.692521 1.105441 0.17542 x=Ce
8 9.34 0.856531 y=1/qe
10 11.35 0.881057 m 0.052636
15 15.54 0.965251 c 0.253884
20 16.78 1.191895 R^2 0.863045

Langmuir-2
Ce,ppm qe or q 1/Ce 1/qe Linest Function Slope:y=mx+c
0 0.6 #DIV/0! 1.666667 0.158922 0.088505
0.5 2.73 2 0.3663 0.023574 0.019229 qm=1/c
1 3.32 1 0.301205 0.883372 0.042699 b=1/(m*qm)
2 4.44 0.5 0.225225 45.44561 6
5 7.22 0.2 0.138504 0.082858 0.010939 x=1/Ce
8 9.34 0.125 0.107066 y=1/qe
10 11.35 0.1 0.088106 m 0.158922
15 15.54 0.066667 0.06435 c 0.088505
20 16.78 0.05 0.059595 R^2 0.883372

Langmuir-3
Ce,ppm qe or q qe/Ce Linest Function Slope:y=mx+c
0 0.6 #DIV/0! -2.635524 14.3158
0.5 2.73 5.46 0.872503 2.23035 m= -2.635524
1 3.32 3.32 0.603288 3.675064 qm= c
2 4.44 2.22 9.124324 6 c= 14.3158
5 7.22 1.444 123.234 81.03659 b= -1/m
8 9.34 1.1675
10 11.35 1.135 m -2.635524 x=qe/Ce
15 15.54 1.036 c 14.3158 y=qe
20 16.78 0.839 R^2 0.603288

Langmuir-4
Ce,ppm qe or q qe/Ce Linest Function Slope:y=mx+c
0 0.6 #DIV/0! -0.228906 4.101219
0.5 2.73 5.46 0.07578 0.77162 m= -0.228906
1 3.32 3.32 0.603288 1.083079 qm= c/b
2 4.44 2.22 9.124324 6 c= 4.101219
5 7.22 1.444 10.70339 7.038365 b= -m
8 9.34 1.1675
10 11.35 1.135 m -0.228906 x=qe
15 15.54 1.036 c 4.101219 y=qe/Ce
20 16.78 0.839 R^2 0.603288

Freundlich
Ce,ppm qe or q log(Ce) log(qe) Linest Function Slope:y=mx+c
0 0.6 Err:502 -0.221849 0.516111 0.535423
0.5 2.73 -0.30103 0.436163 0.027185 0.022666 m= 1/n
1 3.32 0 0.521138 0.983626 0.041553 m= 0.516111
2 4.44 0.30103 0.647383 360.4435 6 c= log(Kf)
5 7.22 0.69897 0.858537 0.622369 0.01036 c= 0.535423
8 9.34 0.90309 0.970347
10 11.35 1 1.054996 m 0.516111 x=log(Ce)
15 15.54 1.176091 1.191451 c 0.535423 y=log(qe)
20 16.78 1.30103 1.224792 R^2 0.983626
18.99847
0.207322
0.863045

qm 11.29878
b 0.556908
R^2 0.883372

qm 14.3158
b 0.379431
R^2 0.603288

qm 17.91659
b 0.228906
R^2 0.603288

n 1.937567
Kf 3.431018
R^2 0.983626

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