Zep 50 Ca Aero DZ: Safety Data Sheet

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Material name : ZEP 50 CA AERO DZ

Material number : 000000000000361301


Manufacturer or supplier's details
Company : Zep Inc.

Address : 350 Joe Frank Harris Parkway, SE


Emerson, GA 30137

Telephone : 404-352-1680

Emergency telephone numbers

For SDS Information : Compliance Services 1-877-428-9937


For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded
For a Transportation : CHEMTREC: 800-424-9300 - All Calls Recorded.
Emergency In the District of Columbia 202-483-7616
Recommended use of the chemical and restrictions on use
Recommended use : Vehicle Maintenance

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance Aerosol containing a liquefied gas
Colour amber
Odour characteristic

GHS Classification
Flammable aerosols : Category 1
Gases under pressure : Liquefied gas
Skin irritation : Category 2
Eye irritation : Category 2A
Skin sensitisation : Category 1
Carcinogenicity : Category 2
GHS label elements
Hazard pictograms :

Signal word : Danger

Hazard statements : H222 Extremely flammable aerosol.


H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

H351 Suspected of causing cancer.

Precautionary statements : Prevention:


P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components

Chemical name CAS-No. Concentration [%]


sodium dodecylbenzenesulfonate 25155-30-0 >= 5 - < 10
2-(2-butoxyethoxy)ethanol 112-34-5 >= 3 - < 5
d-limonene 5989-27-5 >= 3 - < 5
propane 74-98-6 >= 1 - < 3
butane 106-97-8 >= 1 - < 3
Amides, coco, N,N-bis(hydroxyethyl) 68603-42-9 >= 1 - < 3
tetrapotassium pyrophosphate 7320-34-5 >= 1 - < 3
Sulfonic acids, C14-16-alkane hydroxy and C14- 68439-57-6 >= 1 - < 3
16-alkene, sodium salts
benzyl alcohol 100-51-6 >= 1 - < 3
2,2'-iminodiethanol 111-42-2 >= 0.1 - < 1
The exact percentages of disclosed substances are withheld as trade secrets.

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.


Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Get medical attention immediately.

If inhaled : If unconscious, place in recovery position and seek medical


advice.
If symptoms persist, call a physician.

In case of skin contact : If skin irritation persists, call a physician.


Remove contaminated clothing and shoes.
Wash off immediately with plenty of water for at least 15
minutes.
Wash contaminated clothing before re-use.

In case of eye contact : Remove contact lenses.


Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.

If swallowed : Keep respiratory tract clear.


Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Take victim immediately to hospital.

Most important symptoms : Chronic effects are delayed and symptoms may not be
and effects, both acute and observed during an exposure.
delayed Effects are dependent on exposure (dose, concentration,
contact time).
Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
Causes serious eye irritation.
May cause an allergic skin reaction.
Review section 2 of SDS to see all potential hazards.
Causes skin irritation.

Notes to physician : Treat symptomatically. Symptoms may be delayed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Alcohol-resistant foam


Carbon dioxide (CO2)
Dry chemical
Water spray jet

Unsuitable extinguishing : High volume water jet


media

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.

Hazardous combustion : Carbon dioxide (CO2)


products Carbon monoxide
Sulphur oxides
Smoke
Specific extinguishing : Use extinguishing measures that are appropriate to local
methods circumstances and the surrounding environment.

Further information : Collect contaminated fire extinguishing water separately. This


must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

Special protective equipment : Wear self-contained breathing apparatus for firefighting if


for firefighters necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Use personal protective equipment.


protective equipment and Ensure adequate ventilation.
emergency procedures Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Environmental precautions : Prevent product from entering drains.


Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Always replace cap after use.
Dispose of rinse water in accordance with local and national
regulations.

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Persons susceptible to skin sensitisation problems or asthma,


allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.
Do not breathe vapours or spray mist.

Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Keep in a dry, cool and well-ventilated place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Materials to avoid : Do not freeze.


Strong oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters


Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
2-(2-butoxyethoxy)ethanol 112-34-5 TWA 10 ppm ACGIH
(Inhalable
fraction and
vapor)
d-limonene 5989-27-5 TWA 30 ppm US WEEL
propane 74-98-6 TWA 1,000 ppm ACGIH
TWA 1,000 ppm NIOSH REL
1,800 mg/m3
TWA 1,000 ppm OSHA Z-1
1,800 mg/m3
TWA 1,000 ppm OSHA P0
1,800 mg/m3
PEL 1,000 ppm CAL PEL
1,800 mg/m3
butane 106-97-8 TWA 800 ppm NIOSH REL
1,900 mg/m3
TWA 800 ppm OSHA P0
1,900 mg/m3
PEL 800 ppm CAL PEL
1,900 mg/m3
benzyl alcohol 100-51-6 TWA 10 ppm US WEEL
2,2'-iminodiethanol 111-42-2 TWA 1 mg/m3 ACGIH
(Inhalable
fraction and
vapor)
TWA 3 ppm NIOSH REL
15 mg/m3
TWA 3 ppm OSHA P0

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

15 mg/m3
PEL 0.46 ppm CAL PEL
2 mg/m3

Engineering measures : effective ventilation in all processing areas

Personal protective equipment


Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Hand protection
Material : Protective gloves
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

Eye protection : Tightly fitting safety goggles


Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.

Skin and body protection : Impervious clothing


Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures : When using do not eat or drink.


When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Aerosol containing a liquefied gas

Colour : amber
Odour : characteristic
Odour Threshold : No data available
pH : 11.5
Melting point/freezing point : Not applicable
Boiling point : No data available
Flash point :
Not applicable
Evaporation rate : No data available
Flammability (solid, gas) : Extremely flammable aerosol.

Upper explosion limit : No data available


Lower explosion limit : No data available

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Vapour pressure : No data available


Relative vapour density : No data available
Density : 1.012 g/cm3
Solubility(ies)
Water solubility : partly soluble
Partition coefficient: n- : No data available
octanol/water
Auto-ignition temperature : not determined
Thermal decomposition : No data available

Viscosity
Viscosity, kinematic : No data available
Heat of combustion : > 30 kJ/g

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : Stable under normal conditions.

Possibility of hazardous : Vapours may form explosive mixture with air.


reactions No decomposition if stored and applied as directed.

Conditions to avoid : Heat, flames and sparks.


Extremes of temperature and direct sunlight.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Carbon oxides


products Phosphorus compounds
Sulphur oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Aggravated Medical : None known.


Condition
Symptoms of Overexposure : Chronic effects are delayed and symptoms may not be
observed during an exposure.
Effects are dependent on exposure (dose, concentration,
contact time).
Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
Amides, coco, N,N- 68603-42-9
bis(hydroxyethyl)
2,2'-iminodiethanol 111-42-2
ACGIH Confirmed animal carcinogen with unknown relevance to
humans
2,2'-iminodiethanol 111-42-2
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate : 149.9 mg/l


Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

Components:
sodium dodecylbenzenesulfonate:
Acute oral toxicity : LD50 Oral Rat: 438 mg/kg

d-limonene:
Acute oral toxicity : LD50 Oral Rat: 4,400 mg/kg

Acute dermal toxicity : LD50 Dermal Rabbit: > 5,000 mg/kg

benzyl alcohol:
Acute dermal toxicity : LD50 Rabbit: 1,250 mg/kg

Skin corrosion/irritation
Product:
Remarks: Irritating to skin.

Serious eye damage/eye irritation


Product:
Remarks: Irritating to eyes.

Respiratory or skin sensitisation


Product:

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Remarks: Causes sensitisation.

Germ cell mutagenicity


No data available
Carcinogenicity
No data available

Reproductive toxicity
No data available

STOT - single exposure


No data available

STOT - repeated exposure


No data available
Aspiration toxicity
No data available

Further information
Product:
Remarks: No data available

Components:
Amides, coco, N,N-bis(hydroxyethyl):
Remarks: No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Partition coefficient: n- : Remarks: No data available
octanol/water
Components:
2-(2-butoxyethoxy)ethanol :
Partition coefficient: n- : Pow: 1
octanol/water
butane :
Partition coefficient: n- : Pow: 2.89
octanol/water

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Amides, coco, N,N-bis(hydroxyethyl) :


Partition coefficient: n- : Remarks: No data available
octanol/water
benzyl alcohol :
Partition coefficient: n- : Pow: 0.87
octanol/water
2,2'-iminodiethanol :
Partition coefficient: n- : Pow: 1.43
octanol/water
Mobility in soil
No data available
Other adverse effects
No data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).

Additional ecological : An environmental hazard cannot be excluded in the


information event of unprofessional handling or disposal., Toxic to
aquatic life.

Components:
Amides, coco, N,N-bis(hydroxyethyl) :
Additional ecological : No data available
information

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.

Contaminated packaging : Empty remaining contents.


Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14. TRANSPORT INFORMATION

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Transportation Regulation: 49 CFR (USA):


ORM-D, CONSUMER COMMODITY

Transportation Regulation: IMDG (Vessel):


UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: IATA (Cargo Air):


UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: IATA (Passenger Air):


UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: TDG (Canada):


UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.

SECTION 15. REGULATORY INFORMATION

TSCA list : No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification


requirements.

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ


(lbs) (lbs)
sodium dodecylbenzenesulfonate 25155-30-0 1000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ


(lbs) (lbs)

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)


Gases under pressure
Respiratory or skin sensitisation
Carcinogenicity
Skin corrosion or irritation
Serious eye damage or eye irritation

SARA 302 : No chemicals in this material are subject to the reporting


requirements of SARA Title III, Section 302.

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

SARA 313 : The following components are subject to reporting levels


established by SARA Title III, Section 313:
2-(2-butoxyethoxy)ethanol 112-34-5 4.9286 %
2-butoxyethanol 111-76-2 0.0751 %

California Prop. 65

WARNING: This product can expose you to chemicals


including Amides, coco, N,N-bis(hydroxyethyl), 2,2'-
iminodiethanol, 7-methyl-3-methyleneocta-1,6-diene, which
is/are known to the State of California to cause cancer. For
more information go to www.P65Warnings.ca.gov.

The components of this product are reported in the following inventories:

DSL All components of this product are on the Canadian DSL


TSCA On TSCA Inventory

For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III:


Flammability

HEALTH 3*
4
Instability
Health

3 0 FLAMMABILITY 4
PHYSICAL HAZARD 2
0 = not significant, 1 =Slight,
Special hazard.
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

OSHA - GHS Label Information:

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SAFETY DATA SHEET

ZEP 50 CA AERO DZ
Version 3.0 Revision Date 03/12/2018 Print Date 05/21/2018

Hazard pictograms :

Signal word : Danger:


Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
Suspected of causing cancer.
Precautionary statements :
Prevention: Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Keep away from heat/sparks/open
flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition
source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing
dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wear
protective gloves/ protective clothing/ eye protection/ face protection.
Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin
irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get
medical advice/ attention. Take off contaminated clothing and wash before reuse.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122
°F.
Disposal: Dispose of contents/container in accordance with local regulation.

Version: 3.0
Revision Date: 03/12/2018
Print Date: 05/21/2018

We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.

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