SAFETY DATA SHEET

Date of issue/Date of revision 24 June 2020

Version 14

Section 1. Identification
Product name : PR 1440 B 2 Part B
Product code : PR 1440 B 2 Part B
Other means of : Not available.
identification
Product type : Solid.

Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications.
Use of the substance/ : Sealants
mixture
Uses advised against : Not applicable.

Manufacturer : PPG Aerospace PRC-DeSoto

12780 San Fernando Road
Sylmar, CA 91342
Phone: 818 362 6711
Emergency telephone : (412) 434-4515 (U.S.)
number (514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : CARCINOGENICITY - Category 2
substance or mixture TOXIC TO REPRODUCTION - Category 2
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 8.3%
(Oral), 54.1% (Dermal), 91.5% (Inhalation)
GHS label elements
Hazard pictograms :

Signal word : Warning

Hazard statements : Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
Precautionary statements

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Section 2. Hazards identification

Prevention : Obtain special instructions before use. Wear protective gloves. Wear protective
clothing. Wear eye or face protection.
Response : IF exposed or concerned: Get medical advice or attention.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : This product either contains formaldehyde or is capable of releasing formaldehyde
elements above 0.5 ppm under certain conditions. Formaldehyde is a known cancer hazard, a
skin sensitizer and a respiratory sensitizer. Emits toxic fumes when heated.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product name : PR 1440 B 2 Part B

Ingredient name % CAS number

calcium carbonate ≥20 - ≤50 471-34-1
titanium dioxide ≥1.0 - ≤5.0 13463-67-7
toluene <1.0 108-88-3

SUB codes represent substances without registered CAS Numbers.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects

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Product name PR 1440 B 2 Part B

Section 4. First aid measures

Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : No specific fire or explosion hazard.

from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
halogenated compounds
metal oxide/oxides
Formaldehyde.

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.

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Section 5. Fire-fighting measures

Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum
dust with equipment fitted with a HEPA filter and place in a closed, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not ingest. If during normal use the material presents a
respiratory hazard, use only with adequate ventilation or wear appropriate respirator.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Special precautions : If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

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Product code PR 1440 B 2 Part B Date of issue 24 June 2020 Version 14
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Section 7. Handling and storage

Conditions for safe storage, : Do not store below the following temperature: 5°C (41°F). Store in accordance with
including any local regulations. Store in original container protected from direct sunlight in a dry, cool
incompatibilities and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Store locked up. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
calcium carbonate ACGIH TLV (United States).
TWA: 3 mg/m³ Form: Respirable
TWA: 10 mg/m³ Form: Total dust
OSHA PEL (United States).
TWA: 5 mg/m³ Form: Respirable
TWA: 15 mg/m³
titanium dioxide OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
toluene OSHA PEL Z2 (United States, 2/2013).
AMP: 500 ppm 10 minutes.
CEIL: 300 ppm
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
Key to abbreviations
A = Acceptable Maximum Peak S = Potential skin absorption
ACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitization
C = Ceiling Limit SS = Skin sensitization
F = Fume STEL = Short term Exposure limit values
IPEL = Internal Permissible Exposure Limit TD = Total dust
OSHA = Occupational Safety and Health Administration. TLV = Threshold Limit Value
R = Respirable TWA = Time Weighted Average
Z = OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.

Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
controls local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.

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Section 8. Exposure controls/personal protection

Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety glasses with side shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Gloves : For prolonged or repeated handling, use the following type of gloves:

Recommended: natural rubber (latex)

Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.

Section 9. Physical and chemical properties

Appearance
Physical state : Solid.
Color : Beige.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: Not applicable.
Auto-ignition temperature : Not available.

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Section 9. Physical and chemical properties

Decomposition temperature : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Evaporation rate : Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 1.57
Density ( lbs / gal ) : 13.1
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Kinematic (40°C (104°F)): Not applicable.
VOC : 16 g/l
% Solid. (w/w) : 99

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Decomposition products may include the following materials: carbon monoxide, carbon
products dioxide, smoke, oxides of nitrogen.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity

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Section 11. Toxicological information

Product/ingredient name Result Species Dose Exposure
calcium carbonate LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat 6450 mg/kg -
titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Dermal Rabbit 8.39 g/kg -
LD50 Oral Rat 5580 mg/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitization
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary : There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Classification
Product/ingredient name OSHA IARC NTP
titanium dioxide - 2B -
toluene - 3 -
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -

Reproductive toxicity
Conclusion/Summary : There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
toluene Category 3 - Narcotic effects
Specific target organ toxicity (repeated exposure)

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Section 11. Toxicological information

Name Category Route of Target organs
exposure
toluene Category 2 - -

Target organs : Contains material which may cause damage to the following organs: upper respiratory
tract, skin, eyes.

Aspiration hazard
Name Result
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary : There are no data available on the mixture itself. This product either contains
formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain
conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory
sensitizer. Exposure to component solvent vapor concentrations in excess of the stated
occupational exposure limit may result in adverse health effects such as mucous
membrane and respiratory system irritation and adverse effects on the kidneys, liver
and central nervous system. Symptoms and signs include headache, dizziness, fatigue,
muscular weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. There is
some evidence that repeated exposure to organic solvent vapors in combination with
constant loud noise can cause greater hearing loss than expected from exposure to
noise alone. Ingestion may cause nausea, diarrhea and vomiting. This takes into
account, where known, delayed and immediate effects and also chronic effects of
components from short-term and long-term exposure by oral, inhalation and dermal
routes of exposure and eye contact.
Short term exposure

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Section 11. Toxicological information

Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
PR 1440 B 2 Part B N/A 3672.7 N/A N/A N/A
calcium carbonate 6450 2500 N/A N/A N/A
toluene 5580 8390 N/A 49 N/A

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
calcium carbonate Acute EC10 >14 mg/l Algae 72 hours
titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
toluene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
toluene 2.73 8.32 low

Mobility in soil

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Section 12. Ecological information

Soil/water partition : Not available.
coefficient (KOC)

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures

14. Transport information

DOT IMDG IATA
UN number Not regulated. Not regulated. Not regulated.
UN proper shipping - - -
name
Transport hazard class - - -
(es)
Packing group - - -
Environmental hazards No. No. No.
Marine pollutant Not applicable. Not applicable. Not applicable.
substances

Additional information
DOT : None identified.
IMDG : None identified.
IATA : None identified.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not applicable.

to IMO instruments

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Section 15. Regulatory information

United States
United States inventory (TSCA 8b) : All components are active or exempted.
SARA 302/304
SARA 304 RQ : Not applicable.
Composition/information on ingredients
No products were found.

SARA 311/312
Classification : CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
Composition/information on ingredients
Name % Classification
titanium dioxide ≥1.0 - ≤5.0 CARCINOGENICITY - Category 2
toluene <1.0 FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
California Prop. 65
WARNING: Reproductive Harm - www.P65Warnings.ca.gov.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 1 * Flammability : 0 Physical hazards : 0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
Health : 1 Flammability : 0 Instability : 0
Date of previous issue : 4/2/2020
Organization that prepared : EHS
the MSDS

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Section 16. Other information

Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.

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