A.

R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

A.R COACHING CENTRE

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS
Kallakurichi-606 202, Contact: 9361561415. www.arccphysics.in
PG TRB: 2020-21
Subject Name: Unit-VI: Spectroscopy Time: 60minutes
Date:17.10.2020 Slip Test - 1 Maximum Marks:60

1. Mach the following:

(A) Change of configuration – (1) NMR
(B) Change of orientation – (2) Electronic spectra
(C) Change of spin – (3) Microwave spectra
(D) Change electron distribution – (4) Infrared spectra

Codes:
a) (A) – 1, (B) – 4, (C) – 2, (D) – 3.
b) (A) – 1, (B) – 4, (C) – 3, (D) – 2.
c) (A) – 4, (B) – 3, (C) – 1, (D) – 2.
d) (A) – 4, (B) – 1, (C) – 3, (D) – 2.
2. Frequency range of vibrational spectra is
a) 3 × 1012 − 3 × 1014 𝐻𝑧
b) 3 × 1014 − 3 × 1016 𝐻𝑧
c) 3 × 1016 − 3 × 1018 𝐻𝑧
d) 3 × 108 − 3 × 1020 𝐻𝑧
3. For orange light of wavelength is 6.2 × 10−7 𝑚, then the wave number is
a) 12231.05 𝑐𝑚−1
b) 14712.07 𝑐𝑚−1
c) 16129.03 𝑐𝑚−1
d) 18973.01 𝑐𝑚−1
4. The various form of energies of a molecule is (in wave function)
a) 𝜓 = 𝜓𝑒 + 𝜓𝑣 + 𝜓𝑟 + 𝜓𝑡
b) 𝜓 = 𝜓𝑒 − 𝜓𝑣 − 𝜓𝑟 − 𝜓𝑡
c) 𝜓 = 𝜓𝑒 + 𝜓𝑣 + 𝜓𝑟 − 𝜓𝑡
d) 𝜓 = 𝜓𝑒 𝜓𝑣 𝜓𝑟 𝜓𝑡
5. If any one moment of inertia is zero, which type of molecule is
a) Linear molecule
b) Symmetric top
c) Spherical top
d) Asymmetric top
6. Example of spherical top molecule is
a) 𝐶2 𝐻2
b) 𝐶𝐻3 𝐹
c) 𝐶𝐶𝑙4
d) 𝐶𝐻2 𝐶𝐻𝐶𝑙

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 1

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

7. In rotational spectrum, correct one is

a) ∆𝐽 = −1 → 𝐴𝑏𝑠𝑜𝑟𝑝𝑡𝑖𝑜𝑛
b) ∆𝐽 = +1 → 𝐸𝑚𝑖𝑠𝑠𝑖𝑜𝑛
c) ∆𝐽 = +1 → 𝐴𝑏𝑠𝑜𝑟𝑝𝑡𝑖𝑜𝑛
d) ∆𝐽 = −1 → 𝐸𝑚𝑖𝑠𝑠𝑖𝑜𝑛 (𝑜𝑟) 𝐴𝑏𝑠𝑜𝑟𝑝𝑡𝑖𝑜𝑛
8. The energy eigen values of the rigid rotor is the solution of
a) Frank -Condon equation.
b) Schrodinger equation.
c) Hookes law.
d) Born and Oppenheimer approximation.
9. The majority substance belonging in
a) Linear molecule
b) Symmetric molecule
c) Asymmetric molecule
d) Spherical top molecule
10. Linear molecules do not produce any change in dipole moment hence we have
a) Rotational spectrum
b) Vibration Spectrum
c) Both (A) and (B)
d) Neither (A) nor (B)
11. Rotational quantum number J has each level is _______fold degenerate.
a) 𝐽
b) ( 𝐽 + 1)
c) 2( 𝐽 + 1)
d) (2𝐽 + 1)
12. Bond length of diatomic molecule is/are
𝐼
a) 𝑟 = √𝜇
1
1 1 2
b) 𝑟 = [𝐼 (𝑚 + 𝑚 )]
1 2
c) Both (a) and (b)
d) None of these
13. The mass of the nucleus changes leading to a change in the
a) Inter bond distance (r)
b) Electron charge distribution
c) Moment of inertia (I)
d) All of these
14. An isotopic effect in rotational spectra of wave number changes is
a) ∆𝜈̅̅ = 2𝐵𝐽 𝑐𝑚−1
b) ∆𝜈̅ = 2𝐵( 𝐽 + 1) 𝑐𝑚−1
c) ∆𝜈̅ = 2𝐵( 𝐽 + 1) (1 − 𝜌2 ) 𝑐𝑚−1
d) ∆𝜈̅ = 2𝐵𝐽 (1 + 𝜌2 ) 𝑐𝑚−1

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 2

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

15. Component of microwave spectrometer is

a) Klystron
b) Sample cell
c) Stark electrode
d) All of these
16. The relation between rotational constant (B) and Centrifugal distortion constant (D) is
4𝐵 2
a) 𝐷 = 𝜈2
̅
4𝐵 3
b) 𝐷 = ̅2
𝜈
4𝜈
̅
c) 𝐷 = 𝐵2
̅2
4𝜈
d) 𝐷 = 𝐵3
17. A molecule is both IR and Raman active if it has
a) No centre of symmetric.
b) No permanent dipole moment.
c) Vertical optical axis.
d) High force constant.
18. A molecular motion in which all atoms move in phase and with the same frequency is called
a) Bending vibration.
b) Asymmetric vibration.
c) Symmetric vibration.
d) Normal vibration.
19. In rotational spectra a series of spectrum with wave number values are
a) Discreate spaced
b) Equally spaced
c) Unequally spaced
d) None of these
20. Morse function is called
a) Vibrational function
b) Rotational function
c) Potential function
d) Electronic function
21. Among the following molecules given which one of the them is microwave active?
a) 𝐻2
b) 𝐻𝑐𝑙
c) 𝐶𝑂2
d) 𝐶𝑙2
22. A spring of force constant K is cute in to three equal parts. The force constant of each part is
a) 3𝐾
b) 𝐾 + 3
c) 𝐾/3
d) 𝐾

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 3

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

23. Three values of rotational energies of molecules are given below in different units 𝑃 = 10 𝑐𝑚−1 ,
𝑄 = 10−23 𝐽, 𝑅 = 104 𝑀𝐻𝑧. Choose the correct arrangement in the increasing order of energy
a) 𝑃, 𝑅, 𝑄
b) 𝑅, 𝑄, 𝑃
c) 𝑅, 𝑃, 𝑄
d) 𝑄, 𝑅, 𝑃
24. In symmetric bending mode of 𝐶𝑂2 molecule is/are
a) Raman active
b) IR active
c) Both (a) and (b)
d) None of these
25. All vibrations producing a change in the electric dipole moment of a molecule yield
a) Raman spectra
b) Rotational spectra
c) Infrared spectra
d) U-V spectra
26. Calculate the frequency of oscillation of hydrogen molecule of its force constant is 4.8 × 102 𝑁𝑚−1
and mass of the hydrogen atom is 1.67 × 10−27 𝑘𝑔.
a) 2.04 × 1013 𝐻𝑧
b) 2.04 × 1014 𝐻𝑧
c) 1.2 × 1013 𝐻𝑧
d) 1.2 × 1014 𝐻𝑧
27. The bond length R of carbon monoxide 𝐶𝑂 is 0.113 𝑛𝑚 and reduced mass is 1.4 × 10−26 𝑘𝑔, then the
moment of inertia of the 𝐶𝑂 molecule is
a) 14.6 × 10−45 𝑘𝑔𝑚2
b) 14.6 × 10−46 𝑘𝑔𝑚2
c) 1.46 × 10−46 𝑘𝑔𝑚2
d) 1.46 × 10−47 𝑘𝑔𝑚2
28. Choose the example of prolate symmetric top molecule:
a) 𝑁𝐻3
b) 𝑆𝐹6
c) 𝐵𝐹3
d) 𝐶2 𝐻2
29. The energy level of the lowest state of the vibrational energy of the diatomic molecule is
1
a) ℎ𝜈0 𝑐𝑚−1
2
1
b) ℏ𝜔0 𝑐𝑚−1
2
1
c) 𝜈0 𝑐𝑚−1
2
1
d) 𝜈̅0 𝑐𝑚−1
2

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 4

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

30. The temperature of the sample is increased, the intensity of hot bands is
a) increase
b) decrease
c) no change
d) zero
31. The diatomic molecules obey
a) Schrodinger equation
b) Hooke’s law
c) Born and Oppenheimer approximation
d) Frank -Condon equation
32. The lowest vibrational energy of the diatomic molecule is
a) Zero
b) Non zero
c) Infinite
d) Both (a) and (b)
33. The anharmonic oscillator behaves like the harmonic oscillator but with oscillation frequency that
decreasing with (𝜈 −vibrational quantum number)
a) decreasing(𝜈)
b) increasing(𝜈)
c) No change(𝜈)
d) both (a) and (b)
34. Condition for infrared spectrum:
(𝜇𝑖 −The dipole moment, Q-The normal coordinate)
𝜕𝜇
a) ( 𝜕𝑄𝑖 ) = 0
0
𝜕𝜇𝑖
b) ( 𝜕𝑄 ) ≠ 0
0
𝜕𝑄
c) (𝜕𝜇 ) = 0
𝑖 0
𝜕𝑄
d) (𝜕𝜇 ) ≠ 0
𝑖 0
35. A diatomic molecule can execute rotation and vibrations quite independently. This is called
a) Hooke law
b) Schrodinger approximation
c) Born and Oppenheimer approximation
d) Morse function
36. Energy of the vibrating diatomic molecule of the second hot band is
a) ∆𝜀 = 3𝜔 ̅𝑒 (1 − 4𝜒𝑒 ) 𝑐𝑚−1
b) ∆𝜀 = 𝜔 ̅𝑒 (1 − 4𝜒𝑒 ) 𝑐𝑚−1
c) ∆𝜀 = 3𝜔 ̅𝑒 (1 + 4𝜒𝑒 ) 𝑐𝑚−1
d) ∆𝜀 = 𝜔 ̅𝑒 (1 − 6𝜒𝑒 ) 𝑐𝑚−1

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 5

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

37. Fundamental vibrational energy of a HCl molecule is

a) 2886 𝑐𝑚−1
b) 5668 𝑐𝑚−1
c) 8347 𝑐𝑚−1
d) 9941 𝑐𝑚−1
38. According to the diatomic vibrating rotator:
(1) Low frequency side referred as P ranch.
(2) High frequency side referred as R branch.
ℏ
(3) The spacing between line in both P and R branch is Δ𝜈 =
2𝜋𝐼
(4) Q-Branch present.
Codes:
a) All are correct.
b) (1), (2), (3) are correct.
c) (2), (3), (4) are correct.
d) (1), (2), (4) are correct.
39. In vibration-rotation spectrum, equilibrium frequency of a CO is
a) 2143.26 𝑐𝑚−1
b) 4260.04 𝑐𝑚−1
c) 2169.74 𝑐𝑚−1
d) 1915.01 𝑐𝑚−1
40. The number of fundamental vibration modes of C6 H6 molecule is
a) 4
b) 29
c) 30
d) 31
41. If the molecule is linear, there is _____ rotation about the bond axis.
a) 0
b) 1
c) 2
d) 3
42. All three fundamentals vibration of SO2 molecule has
a) IR active.
b) Raman active.
c) both (a) and (b).
d) neither (a) nor (b).
43. The number of fundamental vibration modes of a planer AB3 molecule is
a) 4
b) 5
c) 6
d) 7

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 6

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

44. Absorption wave number of the rotational spectrum is

a) 𝜈̅𝐽 = 2𝐵𝐽
b) 𝜈̅𝐽 = 2𝐵 ( 𝐽 + 1)
c) 𝜈̅𝐽 = 2𝐵𝐽 ( 𝐽 + 1)
d) 𝑛𝑜𝑛𝑒 𝑜𝑓 𝑡ℎ𝑒𝑠𝑒
45. Quantized vibrational energy level of the diatomic molecule is expressed in
a) Classical mechanics
b) Semi-classical mechanics
c) Quantum mechanics
d) Both (a) and (b)
46. For linear molecule the relative values of their three principle moment of inertia is
a) 𝐼𝐵 = 𝐼𝐶 , 𝐼𝐴 = 0
b) 𝐼𝐵 = 𝐼𝐶 , 𝐼𝐴 ≠ 0
c) 𝐼𝐵 ≠ 𝐼𝐶 , 𝐼𝐴 = 0
d) 𝐼𝐴 = 𝐼𝐵 = 𝐼𝐶
47. A molecule of n atom has_____ degrees of freedom.
a) n
b) 3n
c) 3n-5
d) 3n-6
48. During normal vibration, the centre of gravity of the poly atomic molecule is
a) Positive
b) negative
c) zero
d) remain unchanged
49. The energy eigen values of rotational spectra of diatomic molecule is/are
ℏ2
a) 𝐸𝑗 = 𝐽( 𝐽 + 1) 𝑗𝑜𝑢𝑙𝑒𝑠
2𝐼
ℎ2
b) 𝜀𝑗 = 8𝜋2 𝐼𝐶 𝐽( 𝐽 + 1) 𝑐𝑚−1
ℎ
c) 𝜀𝑗 = 8𝜋2 𝐼 𝐽( 𝐽 + 1) 𝑐𝑚−1
d) 𝑏𝑜𝑡ℎ (𝑎) 𝑎𝑛𝑑 (𝑏)
50. The energy curve of a diatomic molecule is
a) elliptical
b) hyperbola
c) parabola
d) straights line
51. In rotation-vibration (IR) spectra of the diatomic molecule, the lines corresponding to ∆𝐽 = +1 is
called
a) Q-branch
b) R-branch
c) P-branch
d) S-branch

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 7

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

52. For an anharmonic oscillator selection rule ∆𝐽 = ±1corresponds to

a) Fundamental vibration
b) First overtone
c) Second overtone
d) Hot band
53. The average spacing between adjacent rotational lines of CO molecule is 3.8626 cm -1. The value of
rotational constant B is
a) 7.7252 cm-1
b) 3.8626 cm-1
c) 1.9313 cm-1
d) 2.3020 cm-1
54. Which of the molecules has a non-zero electric dipole moment?
a) 𝐶𝐻4
b) 𝐶𝐶𝑙4
c) 𝐶𝑂2
d) 𝐻2 𝑂
55. The first absorption spectrum of 𝐶 12 𝑂12 is at 3.842 cm-1 while that 𝐶 13 𝑂13 at 3.673 cm-1. The ratio of
their moment of inertia is
a) 1.851
b) 1.046
c) 1.286
d) 1.038
56. The rotational level whose quantum number is given by the expression _____ has the maximum
population.
𝐾𝑇 1
a) 𝐽 = √ +
2𝐵ℎ𝑐 2

𝐾𝑇 1
b) 𝐽 = √4𝐵ℎ𝑐 − 2

2𝐾𝑇 1
c) 𝐽 = √ 𝐵ℎ𝑐 + 4

4𝐾𝑇 1
d) 𝐽 = √ 𝐵ℎ𝑐 − 4
57. The rotational frequency of a diatomic molecule is
ℏ2
a) 𝑛 = 𝐽(𝐽 + 1)
2𝐼
ℎ2
b) 𝑛 = 8𝜋2 𝐼𝐶 𝐽(𝐽 + 1)
ℎ2
c) 𝑛 = 4𝜋2 𝐼 √𝐽(𝐽 + 1)
ℎ2
d) 𝑛 = 8𝜋2 𝐼 √𝐽(𝐽 + 1)

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 8

 A.R COACHING CENTRE FOR PHYSICS, KALLAKURICHI, CELL:9361561415

58. For CO molecule rotational constant is 1.9313 𝑐𝑚−1 and centrifugal distortion is 6.1214 ×
10−6 𝑐𝑚−1 then fundamental vibrational frequency is
a) 2.6 × 106 𝑐𝑚−1
b) 2.6 × 103 𝑐𝑚−1
c) 7.2 × 106 𝑐𝑚−1
d) 7.2 × 103 𝑐𝑚−1
59. A diatomic molecule disassociates into atom if it is present in the vibration state of vibrational
quantum number is
1
a) 𝑉 = +1
2𝜒𝑒
1
b) 𝑉 = 2𝜒 − 1
𝑒
1
c) 𝑉 = 4𝜒 + 1
𝑒
1
d) 𝑉 = 4𝜒 − 1
𝑒
60. The potential energy of harmonic vibration is
1
a) 𝑈 = 2 𝐾(𝑥2 − 𝑥1 )2
1
b) 𝑈 = 2 𝐾(𝑥2 + 𝑥1 )2
c) 𝑈 = 𝐾(𝑥2 − 𝑥1 )
d) 𝑈 = 𝐾(𝑥2 + 𝑥1 )

If need key answer download from: www.arccphysics.in

PG TRB (PHYSICS) - 2020-21

❖ PG TRB -2020-21 New batch will be started from 11.10.2020 onwords.

❖ PG TRB-2020-21 ONLINE class also started soon.
❖ Well-Experienced Professors for TRB exam.
❖ Each unit has minimum 2-slip test(question-50),1-problem test(question-50),
1-full unit test(question-150).Finally 4-half portion test,5-model test.(ONLINE)
❖ 5- Test for Educational Methodology.
❖ Complete materials for all units based on latest PG TRB syllabus.
❖ Materials preparation for each unit using minimum 5-7 standard reference book.
❖ Excellent coaching for theory and problems solving (Work sheet method).
❖ Regular test with discussion. Online test will be conducted.
❖ For Registration, sample materials and question paper visit our
website. www.arccphysics.in
❖ FOR MORE DETAILS CONTACT-9361561415

PG-TRB, POLY-TRB, ENGG-TRB, TNSET COACHING FOR PHYSICS, WEBSITE: www.arcccphysics.in 9