SAFETY DATA SHEET

according to Regulation (EC) No. 453/2010

ZINC BROMIDE BRINE 20.5 PPG

Revision Date: 23-Oct-2014 Revision Number: 14

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product Identifier
Product Name ZINC BROMIDE BRINE 20.5 PPG

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Additive
Sector of use SU2 - Mining, (including offshore industries)
Product category PC20 - Products such as pH-regulators, flocculants, precipitants, neutralization agents,
other unspecific
Process categories PROC4 - Use in batch and other process (synthesis) where opportunity for exposure
arises

1.3. Details of the supplier of the safety data sheet

Halliburton Manufacturing Services, Ltd.
Halliburton House, Howemoss Crescent
Kirkhill Industrial Estate
Dyce
Aberdeen, AB21 0GN
United Kingdom

Emergency Phone Number: +44 1224 795277 or +1 281 575 5000

www.halliburton.com
For further information, please contact
E-Mail address: [email protected]
1.4. Emergency telephone number
+44 1224 795277 or +1 281 575 5000

Emergency telephone - §45 - (EC)1272/2008

Europe 112
Croatia Centar za kontrolu otrovanja (CKO): (+385 1) 23-48-342 (Poison Control Center (PCC) -
Institute for Medical Research and Occupational Health)
Denmark Poison Control Hotline (DK): +45 82 12 12 12
France ORFILA (FR): + 01 45 42 59 59
Germany Poison Center Berlin (DE): +49 030 30686 790
Italy Poison Center, Milan (IT): +39 02 6610 1029
Netherlands National Poisons Information Center (NL): +31 30 274 88 88 (NB: this service is only
available to health professionals)
Norway Poisons Information (NO):+ 47 22 591300
Poland Poison Control and Information Centre, Warsaw (PL): +48 22 619 66 54; +48 22 619 08
97
Spain Poison Information Service (ES): +34 91 562 04 20
United Kingdom NHS Direct (UK): +44 0845 46 47

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture
REGULATION (EC) No 1272/2008
Acute Oral Toxicity Category 4 - H302

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Skin Corrosion / irritation Category 1 B - H314
Serious Eye Damage / Eye Irritation Category 1 - H318
Skin Sensitization Category 1 - H317
Chronic Aquatic Toxicity Chronic 2 - H411

Classification according to EU Directives 67/548/EEC or 1999/45/EC

For the full text of the R-phrases mentioned in this Section, see Section 16

Classification C - Corrosive.

Risk Phrases R34 Causes burns.

R22 Harmful if swallowed.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

2.2. Label Elements

Hazard Pictograms

Signal Word Danger

Hazard Statements
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)

P280 - Wear protective gloves/eye protection/face protection
P301+ P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 - Immediately call a POISON CENTRE or doctor/physician
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing

Contains
Substances CAS Number
Zinc bromide 7699-45-8

2.3. Other Hazards

None known

SECTION 3: Composition/information on Ingredients

Substances EINECS CAS Number PERCENT EEC EU - CLP Substance REACH No.
(w/w) Classification Classification
Zinc bromide 231-718-4 7699-45-8 60 - 100% C; R34 Acute Tox. 4 (H302) No data available
Xn; R22 Skin Corr. 1B (H314)
R43 Eye Dam. 1 (H318)
N; R51/53 Skin Sens. 1 (H317)
Chronic Aquatic Tox. 2
(H411)

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For the full text of the R-phrases mentioned in this Section, see Section 16

3.1. Substances Not applicable

3.2. Mixtures Mixture

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration,
preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical
attention.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of
water for at least 15 minutes and get medical attention immediately after
flushing.
Skin In case of contact, immediately flush skin with plenty of soap and water for at
least 15 minutes. Get medical attention. Remove contaminated clothing and
launder before reuse.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and
seek medical attention. Never give anything by mouth to an unconscious
person.

4.2. Most Important symptoms and effects, both acute and delayed
May cause eye, skin, and respiratory burns. May cause allergic skin reaction. May be harmful if swallowed.

4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically

SECTION 5: Firefighting Measures

5.1. Extinguishing media
Suitable Extinguishing Media
All standard fire fighting media
Extinguishing media which must not be used for safety reasons
None known.

5.2. Special hazards arising from the substance or mixture

Special Exposure Hazards
Decomposition in fire may produce toxic gases.

5.3. Advice for firefighters

Special Protective Equipment for Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Use appropriate protective equipment.
See Section 8 for additional information

6.2. Environmental precautions

Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.

6.4. Reference to other sections

See Section 8 and 13 for additional information.

SECTION 7: Handling and Storage

7.1. Precautions for Safe Handling
Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing before reuse.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice

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7.2. Conditions for safe storage, including any incompatibilities

Store away from oxidizers. Store away from acids. Store in a cool, dry location. Keep container closed when not in use.

7.3. Specific End Use(s)

Exposure Scenario No information available
Other Guidelines No information available

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters
Exposure Limits
Substances CAS Number EU UK OEL Netherlands France OEL
Zinc bromide 7699-45-8 Not applicable Not applicable Not applicable Not applicable

Substances CAS Number Germany MAK/TRK Spain Portugal Finland

Zinc bromide 7699-45-8 MAK: 0.1 mg/m3 Not applicable Not applicable Not applicable
MAK: 2 mg/m3

Substances CAS Number Austria Ireland Switzerland Norway

Zinc bromide 7699-45-8 Not applicable Not applicable Not applicable Not applicable

Substances CAS Number Italy Poland Hungary Czech Republic

Zinc bromide 7699-45-8 Not applicable Not applicable Not applicable Not applicable

Substances CAS Number Denmark

Zinc bromide 7699-45-8 Not applicable

Derived No Effect Level (DNEL) No information available.

Worker

General Population

Predicted No Effect Concentration (PNEC) No information available.

8.2. Exposure controls

Engineering Controls Use in a well ventilated area.
Personal protective equipment
If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal
protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific
application of this product.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard
EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection
of and instruction on using all personal protective equipment, including respirators,
should be performed by an Industrial Hygienist or other qualified professional.
Dust/mist respirator. (N95, P2/P3)
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct
contact (recommended: protection index 6, corresponding to > 480 minutes permeation
time as per EN 374): Nitrile gloves. (>= 0.4 mm thickness)
This information is based on literature references and on information provided by glove
manufacturers, or is derived by analogy with similar substances. Please note that in
practice the working life of chemical-resistant protective gloves may be considerably
shorter than the permeation time determined in accordance with EN 374 as a result of
the many influencing factors (e.g. temperature). If signs of wear and tear are noticed
then the gloves should be replaced. Manufacturer's directions for use should be
observed because of great diversity of types.
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.

Environmental Exposure Controls No information available

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SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Physical State: Liquid Color: Clear light yellow
Odor: Mild Odor Threshold: No information available

Property Values
Remarks/ - Method
pH: 0.5 - 1.5
Freezing Point/Range -8 °C
Melting Point/Range No data available
Boiling Point/Range 136 °C
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.5
Water Solubility Miscible with water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

VOC Content (%) No data available

SECTION 10: Stability and Reactivity

10.1. Reactivity
Not applicable
10.2. Chemical Stability
Stable
10.3. Possibility of Hazardous Reactions
Will Not Occur
10.4. Conditions to Avoid
None anticipated
10.5. Incompatible Materials
Strong acids.
10.6. Hazardous Decomposition Products
Hydrogen bromide. Toxic fumes.

SECTION 11: Toxicological Information

11.1. Information on Toxicological Effects
Acute Toxicity
Inhalation Causes severe respiratory irritation.
Eye Contact Causes severe eye irritation. May cause eye burns.
Skin Contact Causes severe skin irritation. May cause skin burns on prolonged contact.
Ingestion Causes burns of the mouth, throat and stomach. May cause headache, dizziness,
nausea, vomiting, gastrointestinal irritation and central nervous system depression.

Chronic Effects/Carcinogenicity May cause bromism characterized by disturbances of the central nervous system, skin
and digestive tract. May cause birth defects.

Toxicology data for the components

Substances CAS LD50 Oral LD50 Dermal LC50 Inhalation

Number
Zinc bromide 7699-45-8 1470 mg/kg (Rat) > 2000 mg/kg (Rabbit) No data available

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Substances CAS Skin corrosion/irritation
Number
Zinc bromide 7699-45-8 Causes severe skin irritation with tissue destruction. (rabbit)

Substances CAS Eye damage/irritation

Number
Zinc bromide 7699-45-8 Causes severe eye irritation which may damage tissue. (rabbit)

Substances CAS Skin Sensitization

Number
Zinc bromide 7699-45-8 Skin sensitizer in guinea pig.

Substances CAS Respiratory Sensitization

Number
Zinc bromide 7699-45-8 No information available

Substances CAS Mutagenic Effects

Number
Zinc bromide 7699-45-8 Not regarded as mutagenic.

Substances CAS Carcinogenic Effects

Number
Zinc bromide 7699-45-8 No information available.

Substances CAS Reproductive toxicity

Number
Zinc bromide 7699-45-8 Did not show teratogenic effects in animal experiments. (similar substances)

Substances CAS STOT - single exposure

Number
Zinc bromide 7699-45-8 May cause respiratory irritation.

Substances CAS STOT - repeated exposure

Number
Zinc bromide 7699-45-8 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Aspiration hazard

Number
Zinc bromide 7699-45-8 Not applicable

SECTION 12: Ecological Information

12.1. Toxicity
Ecotoxicity Effects

Substances CAS Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to

Number Microorganisms Invertebrates
Zinc bromide 7699-45-8 EC50(728h): 6.6 mg/L LC50(96h): 115.9 mg/L No information available EC50(48h) 2.4 mg/L
(Skeletonema costatum) (Scophthalmus (Acartia tonsa)
maximus) EC50(48h): 8.8 mg/L
EC50(7d): 0.76 mg/L (Daphnia magna)
(Pimephales promelas)

12.2. Persistence and degradability

The methods for determining biodegradability are not applicable to inorganic substances.
Substances CAS Number Persistence and Degradability
Zinc bromide 7699-45-8 The methods for determining biodegradability are
not applicable to inorganic substances.

12.3. Bioaccumulative potential

Substances CAS Number Log Pow

Zinc bromide 7699-45-8 No information available

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12.4. Mobility in soil
No information available

12.5. Results of PBT and vPvB assessment

No information available.

12.6. Other adverse effects

Endocrine Disruptor Information
This product does not contain any known or suspected endocrine disruptors

SECTION 13: Disposal Considerations

13.1. Waste treatment methods
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.

SECTION 14: Transport Information

IMDG/IMO
UN Number: UN3082
UN Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Contains Zinc Bromide)
Transport Hazard Class(es): 9
Packing Group: III
Environmental Hazards: , Marine Pollutant
EMS: EmS F-A, S-F

RID
UN Number: UN3082
UN Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Contains Zinc Bromide)
Transport Hazard Class(es): 9
Packing Group: III
Environmental hazard: Not applicable

ADR
UN Number: UN3082
UN Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Contains Zinc Bromide)
Transport Hazard Class(es): 9
Packing Group: III
Environmental hazard: Not applicable

IATA/ICAO
UN Number: UN3082
UN Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Contains Zinc Bromide)
Transport Hazard Class(es): 9
Packing Group: III
Environmental hazard: Not applicable

14.1. UN Number: UN3082

14.2. UN Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Contains Zinc Bromide)

14.3. Transport Hazard Class(es): 9

14.4. Packing Group: III

14.5. Environmental Hazards: , Marine Pollutant

14.6. Special Precautions for User: None

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable

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SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

International Inventories
EINECS Inventory This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.
Canadian DSL Inventory All components listed on inventory or are exempt.

Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

Germany, Water Endangering WGK 1: Low hazard to waters.

Classes (WGK)

15.2. Chemical Safety Assessment

No information available

SECTION 16: Other Information

Full text of R-phrases referred to under Sections 2 and 3
R34 Causes burns.
R22 Harmful if swallowed.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Key literature references and sources for data

www.ChemADVISOR.com/

Revision Date: 23-Oct-2014

Revision Note
Update to Format SECTION: 8

This safety data sheet complies with the requirements of Regulation (EC) No. 453/2010

Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is
obtained from various sources including the manufacturer and other third party sources. The information may not be valid
under all conditions nor if this material is used in combination with other materials or in any process. Final determination of
suitability of any material is the sole responsibility of the user.

End of Safety Data Sheet

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