AP Chemistry: Solution Stoichiometry Practice Problems

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AP Chemistry: Solution Stoichiometry Practice Problems

Directions: Write your answers to the following questions in the space provided. For problem solving, show all of
your work. Make sure that your answers show proper units, notation, and significant digits.

1. A solution is made by dissolving 13.5 g of glucose (C6H12O6) in 0.100 kg of water. What is the mass
percentage of solute in this solution?

2. What is the molality of a solution made by dissolving 36.5 g of naphthalene (C10H8) in 425 g of toluene
(C7H8)?

3. What is the molarity of a solution that contains 4.50 g of sodium chloride in 40.0 mL of solution?

4. Commercial concentrated hydrochloric acid is 12.0 M HCl. What volume of concentrated hydrochloric
acid is required to prepare 4.50 L of 2.25 M HCl solution?

5. How many grams of Na2SO4 are required to make 0.350 L of 0.500 M Na2SO4?

6. A solution contains 36% HCl by mass.


a. Calculate the mole fraction of HCl in the solution.

b. Calculate the molality of HCl in the solution.

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6. A solution contains 5.0 g of toluene (C7H8) and 225 g of benzene (C6H6) and has a density of 0.876 g/mL.
Calculate the molarity of the solution.

7. If 10.0 mL of a 10.0 M stock solution of NaOH is diluted to 250 mL, what is the concentration of the
resulting solution?

8. A solution containing equal masses of glycerol (C3H8O3) and water has a density of 1.10 g/mL.
a. Calculate the molality of glycerol.

b. Calculate the mole fraction of glycerol.

c. Calculate the molarity of glycerol in the solution.

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9. The density of an 18.0% solution of ammonium sulfate is 1.10 g/mL. What mass of ammonium sulfate is
required to prepare 275 mL of this solution?

10. A solution is made by dissolving 16.0 g of CaCl2 in 64.0 g of water and has a density of 1.180 g/mL at
20°C.
a. What is the percent by mass of CaCl2 in the solution?

b. What is the molarity of CaCl2 in the solution?

11. Calculate the volume of a 0.225 M solution of potassium hydroxide required to react with 0.215 g of acetic
acid according to the following reaction.

KOH + CH3COOH KCH3COO + H2O

12. What volume of 0.246 M HNO3 solution is required to react completely with 38.6 mL of 0.0515 M
Ba(OH)2?
Ba(OH)2 + 2HNO3 Ba(NO3)2 + 2H2O

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13. An excess of AgNO3 reacts with 185.5 mL of an AlCl3 solution to give 0.325 g of AgCl. What is the
concentration, in moles per liter, of the AlCl3 solution?

AlCl3 + 3AgNO3 3AgCl + Al(NO3)3

14. How many grams of Ca(OH)2 are needed to neutralize 25.0 mL of 0.100 M HNO3?

Ca(OH)2 + 2HNO3 Ca(NO3)2 + 2H2O

15. One commercial method used to peel potatoes is to soak them in a solution of NaOH for a short time,
remove them from the NaOH, and spray off the peel. The concentration of NaOH is normally in the range
of 3 to 6 M. The NaOH is analyzed periodically. In one such analysis, 45.7 mL of 0.500 M H2SO4 is
required to neutralize a 20.0 mL sample of NaOH solution. What is the concentration of the NaOH
solution?

H2SO4 + 2NaOH 2H2O + Na2SO4

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