REVISION DATE: 11-Nov-10 - Rev 01: 0721

SAFETY DATA SHEET

Xylene

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME Xylene

PRODUCT NO. XYLFBUL
APPLICATION Industrial solvent.
SUPPLIER Barrettine
Barrettine Works
St Ivel Way
Warmley, Bristol
BS30 8TY
0117 960 0060
0117 935 2437
[email protected]
EMERGENCY TELEPHONE 0870 190 6777
REACH Registration number 01-2119488216-32-0007

2 HAZARDS IDENTIFICATION

CLASSIFICATION (1999/45) Xn;R20/21. Xi;R38. R10.

CLASSIFICATION (EC 1272/2008)
Physical Flam. Liq. 3 - H226
Health Acute Tox. 4 - H312;Acute Tox. 4 - H332;Skin Irrit. 2 - H315
Environmental Not classified.
LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008

SIGNAL WORD Warning

CONTAINS XYLENE
HAZARD STATEMENTS
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.
PRECAUTIONARY STATEMENTS
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P261e Avoid breathing vapours.
P264a Wash contaminated skin thoroughly after handling.
P280a Wear protective gloves.
P403/235 Store in a well-ventilated place. Keep cool.
P501D Empty containers may contain residual product and vapours.
Do not cut or weld on or near empty containers.
Disposal should only be by means of a licensed waste disposal contractor.
SUPPLEMENTARY PRECAUTIONARY STATEMENTS
P302/352 IF ON SKIN: Wash with plenty of soap and water.
P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.

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Xylene
P301/P331/P315 If SWALLOWED: Do NOT induce vomiting. Get immediate medical
advice/attention.

3 COMPOSITION/INFORMATION ON INGREDIENTS

XYLENE 80-95%

CAS-No.: 1330-20-7 EC No.: 215-535-7

CLASSIFICATION (EC 1272/2008) CLASSIFICATION (67/548)

Flam. Liq. 3 - H226 R10
Acute Tox. 4 - H312 Xn;R20/21
Acute Tox. 4 - H332 Xi;R38
Skin Irrit. 2 - H315

ETHYLBENZENE 5-20%

CAS-No.: 100-41-4 EC No.: 202-849-4

CLASSIFICATION (EC 1272/2008) CLASSIFICATION (67/548)

Flam. Liq. 2 - H225 F;R11
Acute Tox. 4 - H332 Xn;R20

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16

4 FIRST-AID MEASURES

GENERAL INFORMATION
Remove affected person from source of exposure. Provide fresh air, first-aid, warmth and rest.
Do not give victim anything to drink if they are unconscious. Get medical attention if any discomfort continues.
INHALATION
If unconscious place patient on their side in the recovery position and ensure they are breathing. Clean nose and mouth
with water.
Artificial respiration may be administered by suitably qualified first-aiders.
Get medical attention if symptoms persist.
INGESTION
If swallowed do NOT induce vomiting.
Never give anything by mouth to an unconscious person. Rinse mouth thoroughly and seek medical attention if discomfort
persists. Keep patient under observation.
SKIN CONTACT
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and running water. Take especial care to clean
folds, crevices, creases and groin.
Get medical attention if irritation persists or develops.
Launder clothing and clean shoes thoroughly before re-use.
EYE CONTACT
Check for contact lenses which must be removed from the eyes before rinsing.
Promptly rinse eyes with plenty of clean water while lifting the eyelids.
Continue to rinse for at least 15 minutes. Continue until the eyes are free of all traces of contamination.
Get medical attention if any discomfort or irritation persists.

5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA
Use CO2, dry powder, foam, or water fog, mist or spray, Do not use high pressure water jet as this may spread burning
material.
UNUSUAL FIRE & EXPLOSION HAZARDS
Fire causes formation of toxic gases.
SPECIFIC HAZARDS
The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures.

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Xylene
PROTECTIVE MEASURES IN FIRE
Wear self-contained breathing apparatus and full protective clothing. Keep all unnecessary people away. Fire water run-off
must not be allowed to contaminate ground or enter drains, sewers or water courses. Provide bunding against fire water
run-off.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Ventilate to dispel residual vapour. Clean-up personnel should use respiratory protection, gloves, goggles and protective
clothing and footwear. (see section 8)
ENVIRONMENTAL PRECAUTIONS
Do not allow spilled material to enter drains or water courses.
Cover all drains and sewers. Avoid spreading spilled material. Contain spillages with sand, earth or suitable absorbent
material. Prevent further spillage if safe to do so.
In the event of contamination of watercourses or sewers advise the Environment Agency, fire brigade and police.
SPILL CLEAN UP METHODS
Absorb in vermiculite, sand, diatomaceous earth or other absorbent inert material. Place into clearly labelled container for
recovery or disposal (see section 13). Rinse site with copious amounts of water, which should not be allowed into drains,
sewers or water courses.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS
Eye wash facilities and emergency shower must be available when handling this product. Use only in well ventilated areas.
Avoid spilling, skin and eye contact. Do not breathe vapour or fumes.
Use suitable protective clothing. (see section 8). Wash thoroughly after handling.
STORAGE PRECAUTIONS
Keep away from all possible sources of ignition.
Store in tightly closed containers in segregated, cool, dry, ventilated storage.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name Std TWA - 8 hrs STEL - 15 min Notes

ETHYLBENZENE WEL 100 ppm 441 mg/m3 125 ppm 552 mg/m3 Sk

XYLENE WEL 50 ppm 220 mg/m3 100 ppm 441 mg/m3 Sk

WEL = Workplace Exposure Limit.

Sk = Can be absorbed through skin.
INGREDIENT COMMENTS
WEL = Workplace Exposure Limits
PROCESS CONDITIONS
Provide eyewash station.
ENGINEERING MEASURES
Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.
RESPIRATORY EQUIPMENT
If ventilation is insufficient suitable respiratory protection must be provided.
Seek recommendations and advice from equipment manufacturer or supplier.
HAND PROTECTION
Wear suitable protective gloves conforming to EN 374. Seek recommendations from manufacturer or supplier. After using
gloves the hands should be washed and dried thoroughly and a suitable moisturiser applied.
EYE PROTECTION
Wear tightly fitting safety goggles conforming to EN166
OTHER PROTECTION
Minimise all forms of skin contact. Overalls and footwear with oil and chemical resistant soles should be worn. Launder
overalls and undergarments regularly.
HYGIENE MEASURES
Wash promptly if skin becomes contaminated. When using do not eat, drink or smoke. Contaminated work clothes should
be removed and laundered before re-use.

9 PHYSICAL AND CHEMICAL PROPERTIES

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Xylene
APPEARANCE Liquid
COLOUR Colourless
ODOUR Aromatic.
SOLUBILITY Immiscible with water
BOILING POINT (°C) 137 to 143°C MELTING POINT (°C) -24°C
RELATIVE DENSITY 0.86 @ 20°C VAPOUR DENSITY (air=1) 3.7
VAPOUR PRESSURE 1.3 mbar 20°C EVAPORATION RATE 0.7 (BAC=1)
VOLATILE BY VOL. (%) 100 VISCOSITY 0.6 mPas 25°C
FLASH POINT (°C) 25°C CC (Closed cup). AUTO IGNITION 480°C
TEMPERATURE (°C)
FLAMMABILITY LIMIT - 1% FLAMMABILITY LIMIT - 9%
LOWER(%) UPPER(%)

10 STABILITY AND REACTIVITY

STABILITY
Stable under normal conditions of storage and use. See section 7.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.
MATERIALS TO AVOID
Strong acids. Strong oxidising substances.
HAZARDOUS DECOMPOSITION PRODUCTS
In fires or in conditions of excessive heat may give off toxic fumes and gases.

11 TOXICOLOGICAL INFORMATION

TOXIC DOSE 1 - LD 50 4300 mg/kg (oral rat)

INHALATION
In high concentrations, vapours may irritate throat and respiratory system and cause coughing. Vapours have a narcotic
effect and may cause headache, fatigue, dizziness and nausea.
INGESTION
Gastrointestinal symptoms, including upset stomach.
SKIN CONTACT
Irritating to skin. May be absorbed through the skin.
EYE CONTACT
Irritating and may cause redness and pain.

12 ECOLOGICAL INFORMATION

ECOTOXICITY
The product is not expected to be hazardous to the environment.
MOBILITY
Contamination will evaporate from the surface of water and soils.

13 DISPOSAL CONSIDERATIONS

GENERAL INFORMATION
Empty containers may contain residual flammable vapours and product residue. Keep away from sparks, heat and sources
of ignition. Labels should not be removed. Product is hazardous waste. Do not allow into drains, sewers or water courses.
Disposal must be by means of a licensed waste contractor.
DISPOSAL METHODS
Vent container thoroughly. Do not puncture, cut or weld on or near drums. Empty drums chould be sent for recovery or for
metal reclamation.

14 TRANSPORT INFORMATION

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UK ROAD CLASS 3
PROPER SHIPPING NAME XYLENES
PROPER SHIPPING NAME (XYLENE, ETHYLBENZENE)
UN NO. ROAD 1307 UK ROAD PACK GR. III
ADR CLASS NO. 3 ADR CLASS Class 3: Flammable liquids.
ADR PACK GROUP III TUNNEL RESTRICTION CODE (D/E)
HAZARD No. (ADR) 30 ADR LABEL NO. 3
HAZCHEM CODE 3Y CEFIC TEC(R) NO. 30GF1-III
RID CLASS NO. 3 RID PACK GROUP III
UN NO. SEA 1307 IMDG CLASS 3
IMDG PAGE NO. 3 IMDG PACK GR. III
EMS F-E, S-D MARINE POLLUTANT No.
UN NO. AIR 1307 AIR CLASS 3
AIR PACK GR. III

15 REGULATORY INFORMATION

EU DIRECTIVES
Regulation (EC) No 1272/2008: CLP (Classification, labelling and packaging of substances and mixtures).
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 SI No 716. (CHIP4).
Control of Substances Hazardous to Health Regulations (as amended). (COSHH)
Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2007. (CDG 2009)
GUIDANCE NOTES
Assessing and managing the risks at work from skin exposures to chemical agents. HSG 205.

16 OTHER INFORMATION

REVISION COMMENTS
Comprehensive revision.
GHS information added.
REVISION DATE 11-Nov-10 - Rev 01: 0721
RISK PHRASES IN FULL
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R20 Harmful by inhalation.
R11 Highly flammable.
R38 Irritating to skin.
HAZARD STATEMENTS IN FULL
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.

DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
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