MATERIAL SAFETY DATA SHEET

Print date: 04/09/2012 Version: 4 Revision date: 04/09/2012

1. COMPANY AND PRODUCT IDENTIFICATION

Product name: QUAKERCLEAN 68 RAH
Product code: 011876-02

Supplier: Emergency telephone number:

Quaker Chemical Corporation * 24 HOUR TRANSPORTATION:
Quaker Park One **CHEMTREC: 1-800-424-9300

MSDS SHEET 101116503 Rev. AA

901 Hector Street 703-527-3887 (Call collect outside of US)
Conshohocken, PA 19428 * 24 HOUR EMERGENCY HEALTH & SAFETY:
610-832-4000 **QUAKER CHEMICAL CORPORATION: (800) 523-7010
E-mail: [email protected] (Within US only) Outside of US call (703) 527-3887

3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS

Components CAS No. Weight % OSHA OSHA TWA ACGIH ACGIH Vendor
Ceiling (final) Ceiling Exposure Exposure
Limits Limits Limits Limits
Naphtha (petroleum), 64742-48-9 90 - 100%
hydrotreated heavy
D-limonene 5989-27-5 1 - 5%

2. HAZARDS IDENTIFICATION
Emergency Overview
Combustible material
Irritating to eyes.
May cause skin irritation and/or dermatitis.
Harmful by inhalation and if swallowed.

Signal word: WARNING

Principle routes of exposure: Eyes, skin and inhalation.

Eye contact: Irritating to eyes.

Skin contact: Prolonged skin contact may defat the skin and produce dermatitis.

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Inhalation: May cause irritation of respiratory tract. A component may cause central nervous
system depression characterized by the following progressive steps: headache,
dizziness, nausea, staggering gait, confusion and unconsciousness. Intentional
misuse by deliberately concentrating and inhaling the contents may be harmful or
fatal.

Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Risk of
product entering the lungs on vomiting after ingestion.

Physico-chemical properties: Combustible material.

4. FIRST AID MEASURES

General advice: Show this safety data sheet to the doctor in attendance. Remove contaminated
clothing and shoes. Wash contaminated clothing before re-use. Wash off with soap
and water. If symptoms persist, call a physician.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes.

Skin contact: Remove contaminated clothing and shoes. Wash contaminated clothing before re-
use.. Rinse immediately with plenty of water for at least 15 minutes.

MSDS SHEET 101116503 Rev. AA

Ingestion: If swallowed, seek medical advice immediately and show this container or label. Do
not induce vomiting without medical advice. Never give anything by mouth to an
unconscious person.

Inhalation: Move to fresh air in case of accidental inhalation of vapors. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Consult a physician.

Note to physician: This product contains petroleum ditillates Aspiration may cause pulmonary oedema
and pneumonitis

Medical condition Dermatitis and asthma

aggravated by exposure:

5. FIRE-FIGHTING MEASURES
Flash Point (°C): 79 Flash Point (°F): 174.2 Flash Point Method: COC

Flammable limits in air - lower (%): Not determined Flammable limits in air - upper (%): Not determined

Suitable extinguishing media: Carbon dioxide (CO2), Dry chemical, Foam.

Specific hazards: Do not allow material to contaminate ground water system.

Combustible material.

Unusual hazards: Keep away from open flames, hot surfaces and sources of
ignition Vapors are heavier than air and may spread along
floors Containers exposed to intense heat from fires should
be cooled with water to prevent vapor pressure buildup
which could result in container rupture

Special protective equipment for fire-fighters: As in any fire, wear self-contained breathing apparatus
pressure-demand, MSHA/NIOSH (approved or equivalent)
and full protective gear.

Specific methods: Use spark-proof tools and explosion-proof equipment. Cool

containers / tanks with spray water.

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 6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Ensure adequate ventilation. Use personal protective equipment. Avoid contact with
skin, eyes and clothing. Do not breathe vapour/dust. Wash thoroughly after handling

Environmental precautions: Do not flush into surface water or sanitary sewer system. Prevent further leakage or
spillage if safe to do so.

Methods for cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal
binder, sawdust). Sweep up and shovel into suitable containers for disposal.

7. HANDLING AND STORAGE

Handling

Technical Use only in area provided with appropriate exhaust ventilation..

measures/precautions:

Safe handling advice: Do not breathe vapors or spray mist. In case of insufficient ventilation, wear suitable
respiratory equipment. Wear personal protective equipment. Avoid contact with skin

MSDS SHEET 101116503 Rev. AA

and eyes. Wash thoroughly after handling.

Storage

Technical measures/storage Keep away from open flames, hot surfaces and sources of ignition. Store at room
conditions: temperature in the original container.

Incompatible products: Strong oxidizing agents

Safe storage temperature: 10 - 30 °C

Shelf life: 12 months

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components OSHA OSHA TWA ACGIH ACGIH NIOSH - Vendor
Ceiling (final) Ceiling Exposure Pocket Guide Exposure Limits
Limits Limits Limits
Naphtha (petroleum), None None None None None None
hydrotreated heavy
D-limonene None None None None None None

Engineering measures: Provide adequate ventilation. In case of insufficient ventilation, wear suitable
respiratory equipment.

Personal Protective Equipment:

General: Eye Wash and Safety Shower

Respiratory protection: If engineering controls do not maintain airborne concentrations to a level which is
adequate to protect worker health, a NIOSH-certified respirator with organic
vapor/P100 filter should be worn.

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 Eye protection: Safety glasses with side-shields. If splashes are likely to occur, wear: Tightly fitting
safety goggles.

Hand protection: Neoprene gloves

Skin and body protection: Long sleeved clothing

Hygiene measures: Avoid contact with skin, eyes and clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color Clear Colorless
Odor Citrus
Vapour density: Not determined
Vapor pressure (kPa): Not determined
Solubility in water Insoluble
Evaporation rate: Not determined
pH: NA

MSDS SHEET 101116503 Rev. AA

Flash Point (°C): 79
Flash Point (°F): 174.2
Decomposition temperature (°C): Not determined
Auto-ignition temperature (°C): Not determined
Density @ 15.5 °C (g/cc): 0.769
Bulk density @ 60 ° F (lb/gal): 6.41
Partition coefficient (n- Not determined
octanol/water):
Explosive Limits:
- upper limit: No data available
- lower limit: No data available

10. STABILITY AND REACTIVITY

Stability:
Stable under recommended storage conditions.

Conditions to avoid:
Heat, flames and sparks.

Materials to avoid:
Strong oxidizing agents

Hazardous decomposition products:

Carbon oxides.

Hazardous Polymerization:
None under normal processing.

11. TOXICOLOGICAL INFORMATION

Reports of animal studies using both sexes of several species have shown that kidney effects can occur in male rats after
prolonged and repeated inhalation exposures to light hydrocarbon vapors of the general type represented by this product.
While the effects are of low order of severity in animals, the implications of these results have not yet been determined.

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No toxicological information is available on the product. Data obtained on components are summarized below.

Components IARC Carcinogens NTP: OSHA - Acute Toxicity

Select Carcinogens
Naphtha (petroleum), Not listed as Not listed as known Not listed as a select Rabbit Dermal LD50 >
hydrotreated heavy carcinogenic or or reasonably carcinogen 3160 mg/kg
possibly carcinogenic anticipated to be a Rat Oral LD50 > 5000
to humans human carcinogen mg/kg
D-limonene Not listed as Not listed as known Not listed as a select Rat Oral LD50 = 4400
carcinogenic or or reasonably carcinogen mg/kg
possibly carcinogenic anticipated to be a Rabbit Dermal LD50 >
to humans human carcinogen 2000 mg/kg

12. ECOLOGICAL INFORMATION

Persistence and degradability: No information available

Mobility: No data available

Bioaccumulation: Not available

Ecotoxicity effects: No data available

MSDS SHEET 101116503 Rev. AA

Aquatic toxicity: Not Determined

Component Information

Components Ecotoxicity - Fish Species Ecotoxicity - Freshwater Ecotoxicity - Water Flea

Data: Algae Data: Data:
Naphtha (petroleum), 2200 =2.6mg/L LC50 (Chaetogammarus
hydrotreated heavy marinus - 96h) = 2.6 mg/L
D-limonene 0.619 No data No data
35

13. DISPOSAL CONSIDERATIONS

Waste from residues/unused Waste disposal must be in accordance with appropriate Federal, State, and local
products: regulations. This product, if unaltered by use, may be disposed of by treatment at a
permitted facility or as advised by your local hazardous waste regulatory authority.

Contaminated packaging: Do not re-use empty containers

Methods for cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal
binder, sawdust). Sweep up and shovel into suitable containers for disposal.

14. TRANSPORT INFORMATION

U. S. DEPARTMENT OF TRANSPORTATION:
UN/NA ID Number: NA 1993
Proper shipping name: Combustible Liquid, N.O.S. (Contains hydrotreated heavy
petroleum naptha and d-limonene)
Hazard class: Combustible
Packing group: III
Emergency Response Guide Number: ERG 128
Dot (bulk): When in individual containers of less than 119 gallons, this
material ships as non-regulated.

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 14. TRANSPORT INFORMATION
TDG (CANADA):
Proper shipping name: Combustible Liquid, N.O.S. (Contains hydrotreated heavy
petroleum naptha and d-limonene)
TDG Hazard Classification: Combustible
Subsidary class: III

IMDG/IMO:
Proper shipping name: Not Regulated

IATA/ICAO:
Proper shipping name: Not Regulated

15. REGULATORY INFORMATION

CANADIAN REGULATIONS:

Canada - WHMIS Classification This product has been classified according to the hazard criteria of the CPR and the
Information: MSDS contains all the information required by the CPR.

MSDS SHEET 101116503 Rev. AA

Canadian Product Classification: B3 = combustible (flash 100 - 200F)

Product Classification
Graphic(s):

Component Classification Data:

Components WHMIS hazard class CEPA Schedule I Challenge Substances

Naphtha (petroleum), B3 Not listed Not listed
hydrotreated heavy
D-limonene B3 D2B Listed Not listed

U.S. FEDERAL REGULATIONS:

OSHA Hazard Communication This product is considered to be hazardous under the OSHA Hazard Communication
Standard: Standard.

CERCLA/SARA Information:

SARA (311, 312) hazard class: This product possesses the following SARA Hazard Categories:
Immediate Health (Acute): Yes
Delayed Health (Chronic): No
Flammability: Yes
Pressure: No
Reactivity: No

Components Hazardous Substances and Extremely Hazardous SARA 313 Emission

RQs Substances and TPQs Reporting
Naphtha (petroleum), Not listed Not listed Not listed
hydrotreated heavy

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D-limonene Not listed Not listed Not listed

Clean Air and Clean Water Acts:

Components Hazardous Air CWA - Hazardous CWA - Toxic CWA - Priority

Pollutants Substances Pollutants Pollutants
Naphtha (petroleum), Not listed Not listed Not listed Not listed
hydrotreated heavy
D-limonene Not listed Not listed Not listed Not listed

RCRA Status: Not regulated

U.S. STATE REGULATIONS (RTK):

Components California PARTK MI Critical NJRTK MARTK

Proposition 65 Materials
Naphtha (petroleum), Not Listed Not Listed Not Listed Not Listed Not Listed
hydrotreated heavy
D-limonene Not Listed Not Listed Not Listed 0792 Not Listed

California Proposition 65 Status: No components are listed

MSDS SHEET 101116503 Rev. AA

INVENTORY STATUS:

United States TSCA - Sect. 8(b) Inventory: This product complies with TSCA

Canada DSL/NDSL Inventory List This product complies with DSL

16. OTHER INFORMATION

Sources of key data used to compile the data sheet: Material safety data sheets of the ingredients.

Prepared by: Quaker Chemical Corporation -Safety, Health and Environmental Affairs Group - US

Reason for revision: MSDS review

HMIS classification: HMIS Use Dilution NFPA rating:

Health: Health Health:

2 -- 2

Flammability: Flammability Flammability:

2 -- 2

Reactivity: Reactivity Reactivity:

0 -- 0

Personal Protection: Personal Protection Special:

G -- NA

* Indicates possible chronic heath effect

Personal protection recommendations should be reviewed by purchasers. Workplace conditions are important factors in
specifying adequate protection.

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Disclaimer
This product's safety information is provided to assist our customers in assessing compliance with
safety/health/environmental regulations. The information contained herein is based on data available to us and is
believed to be accurate. However, no warranty of merchantability, fitness for any use, or any other warranty is expressed
or implied regarding the accuracy of this data, the results to be obtained from the use thereof, or the hazards connected
with the use of the product. Since the use of this product is within the exclusive control of the user, it is the user's
obligation to determine the conditions for safe use of the product. Such conditions should comply with all regulations
concerning the product. Quaker Chemical Corporation ("Quaker") assumes no liability for any injury or damage, direct or
consequential, resulting from the use of this product unless such injury or damage is attributable to the gross negligence
of Quaker.

End of Safety Data Sheet

MSDS SHEET 101116503 Rev. AA

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