Introduction to the Theory
of Ferromagnetism
Exact solution of the Ising model in one
dimension. Antiferromagnetism
Neél temperature. Magnetic susceptibility of the
Ising antiferromagnet in the mean-field
approximation
Neél temperature
zJ x z J x
Denote 𝑥𝐴 = 𝑥, 𝑥𝐵 = −𝑥 x tanh tanh
T T
TN
Denote 𝑧 𝐽 ≡ 𝑇𝑁 x tanh x
T
The solution is already known θ → 𝑇𝑁
T
x 3 1 , T TN
TN
2TN T
x 1 2e , T 0
𝑇𝑁 is called the Neel temperature or transition temperature
into antiferromagnetic state
Antiferromagnetism
Total magnetization of antiferromagnetic
N N N N
ˆiA z iB z
ˆ B i A z
ˆ B iB z
ˆ
M 2 2 2 2
V V
N N N N
B x A B xB B x B x
2 2 2 2 0
V V
Magnetic susceptibility
M
0
H
Differential magnetic susceptibility
M
?
H H 0
Magnetic susceptibility of the
Ising antiferromagnet
Differential magnetic susceptibility
M M 2B N x A xB
B h h
H H 0 h h 0 2V h 0
Partial derivatives
h xBTN x A 1 tanh 2 h xBTN 1 TN xB
x A tanh h T T h
T T
x tanh h x ATN xB 2 h x ATN
1 tanh
1 TN x A
B T T h
T h T
x A 1 TN xB
h 1 x A T T h
2
x A xB 2 2 TN x A xB
1 x
xB 1 x 2 1 N x A
T h h T T h h
B
h T T h
Magnetic susceptibility of the
Ising antiferromagnet
x A xB 2 1 x 2
The sum of partial derivatives
h h T 1 x 2 TN
N
2
2
1 x 2
Differential magnetic susceptibility B
2V T 1 x 2 TN
h 0
TN
Analysis in the absence of magnetic field x tanh x
T
A. In the case 𝑇 > 𝑇𝑁 the order parameter 𝑥 = 0
2B N 1
V T TN
Magnetic susceptibility of the
Ising antiferromagnet
𝑇𝑁 −𝑇
B. In the case of ≪ 1, the order parameter squared is
𝑇𝑁
equal
T μ 2B N 3T 2TN μ 2B N
x 3 1
2
χ T TN χ
TN 2 V 2T TN 2V
C. If the temperature decreases below 𝑇𝑁 , differential
magnetic susceptibility decreases linearly
2B N 3T 2TN 2B N 2T TN T TN
2V 2T TN 2V 2T TN
2B N T TN 2B N T TN 2B N T
1 1
2V 2T TN 2V TN 2V TN
Magnetic susceptibility of the
Ising antiferromagnet
D. In the case of 𝑇 ≪ 𝑇𝑁 , the order parameter squared is
equal
2TN
2T
N μ N
2
4e T
4μ 2B N 2TTN
x 2 1 4e T
χ B
2TN
e
V VT
T 4TN e T
Summary
• Antiferromagnetic ordering is realized if the exchange
integral is less than zero for the nearest neighbors and is
equal to zero for other atom pairs
• Antiferromagnetic phase transition occurs at Neél
temperature. At Neél temperature spontaneous
magnetization appears in each sublattice, but atomic
magnetic moments of these sublattices have opposite
directions
• Total magnetization of the antiferrromagnet is equal to
zero, but differential magnetic susceptibility is not equal to
zero
• The temperature dependence of antiferromagnet
differential magnetic susceptibility does not have the
divergence as in the case of ferromagnetism