SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : BEZAPRINT GREEN CC-M

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Pigment for the textile finishing
stance/Mixture

1.3 Details of the supplier of the safety data sheet

Manufacturer/Supplier

CHT Germany GmbH CHT Switzerland AG

Bismarckstraße 102 Kriessernstrasse 20
72072 Tübingen 9462 Montlingen
Germany Switzerland
Tel.: +49 7071 154 0 Tel.: +41 71 763 88 11
[email protected] [email protected]

Importer : -
-
-
-
-
-

Responsible Department : CHT Germany GmbH

CHT Switzerland AG
Product Safety
[email protected]
[email protected]

1.4 Emergency telephone number

Emergency telephone : +49 7071 154 0 (Germany, 24 hours)

number +41 71 763 88 11 (Switzerland, 24 hours)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

Precautionary statements :
Storage:
P404 Store in a closed container.

Additional Labelling
EUH208 Contains 2-methyl-2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, 2-octyl-
2H-isothiazol-3-one. May produce an allergic reaction.
2.3 Other hazards
According to our present knowledge the product does not contain persistent, bioaccumulative and
toxic substances (PBT substances) or very persistent and very bioaccumulative (vPvB substanc-
es) as defined in Annex XIII of the Regulation (EG) No 1907/2006 (REACH), respectively.

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Chemical nature : Organic pigment in an aqueous dispersion

Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Index-No.
Registration number
Sodium polynaphthalene sulpho- 9084-06-4 Aquatic Chronic 3; >= 2,5 - <= 5
nate Polymer H412

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Take off contaminated clothing and shoes immediately.

If inhaled : Move to fresh air.

If symptoms persist, call a physician.

In case of skin contact : Wash off immediately with soap and plenty of water.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 10 minutes.
If symptoms persist, call a physician.

If swallowed : Rinse mouth with water.

Immediately give plenty of water (if possible charcoal slurry).
If symptoms persist, call a physician or Poison Control Centre
immediately.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

4.2 Most important symptoms and effects, both acute and delayed
Risks : irritant effects

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Water spray
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing : none

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : Exposure to decomposition products may be a hazard to
fighting health.

5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Further information : In case of fire do not inhale smoke, conflagration gases and
steams.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear personal protective equipment.

6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Use mechanical handling equipment.
Contain spillage, and then collect with non-combustible ab-
sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

6.4 Reference to other sections

For personal protection see section 8.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Avoid formation of aerosol.

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
Keep away from food, drink and animal feedingstuffs.
When using do not eat or drink.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep containers tightly closed in a dry, cool and well-
areas and containers ventilated place.
Store in original container.

Advice on common storage : No special precautions required.

Storage class (TRGS 510) : 12, Non Combustible Liquids

7.3 Specific end use(s)

Specific use(s) : Consult the technical guidelines for the use of this sub-
stance/mixture.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Contains no substances with occupational exposure limit values.
8.2 Exposure controls

Engineering measures
Provide sufficient air exchange and/or exhaust in work rooms.
Personal protective equipment
Eye protection : Safety glasses with side-shields

Hand protection
Material : PVC or other plastic material gloves

Skin and body protection : Long sleeved clothing

Respiratory protection : Breathing apparatus with filter.

Combination filter A/P

Protective measures : Avoid contact with the skin and the eyes.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

Do not breathe spray.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : Dispersion

Colour : green

Odour : characteristic

pH : 8,5 - 10 (20 °C)

Concentration: 10 g/l

Boiling point/boiling range : 100 °C

Flash point : Not applicable

Flammability (solid, gas) : does not ignite

Solubility(ies)
Water solubility : dispersible

Decomposition temperature : No decomposition if stored and applied as directed.

9.2 Other information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

Conditions to avoid : Not applicable

10.5 Incompatible materials

Materials to avoid : Avoid contact with other chemicals.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Product:
Acute oral toxicity : LD50 Oral (Rat): > 2 000 mg/kg

Skin corrosion/irritation

Product:
: No skin irritation

Serious eye damage/eye irritation

Product:
: No eye irritation

Respiratory or skin sensitisation

Product:
: No known sensitising effect.

SECTION 12: Ecological information

12.1 Toxicity

Product:
Toxicity to fish : LC0 (Poecilia reticulata (guppy)): > 100 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 203

LC50 (Poecilia reticulata (guppy)): > 100 mg/l

Exposure time: 48 h
Method: OECD Test Guideline 203

Toxicity to microorganisms : EC50 : > 100 mg/l

Exposure time: 3 h
Test Type: Respiration inhibition of activated sludge
Method: Retarded respiration test (OECD 209)

Components:

Sodium polynaphthalene sulphonate:

Ecotoxicology Assessment
Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

12.2 Persistence and degradability

Product:
Biodegradability : Dyestuffs are, as indicated, very persistent and they are, un-
der the conditions of the sewage plant or water course, very
difficult to biodegrade.

Chemical Oxygen Demand : 660 mg/g

(COD)

Physico-chemical removabil- : 90 - 100 %

ity Method: static method (Photometry)
The product is slightly soluble in water. It can be eliminated
from water by abiotic processes.
Low waste water contamination is due to a very high level of
fixation.

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Bioaccumulation is unlikely.

12.4 Mobility in soil

Product:
Mobility : No data available

12.5 Results of PBT and vPvB assessment

Product:
Assessment : According to our present knowledge the product does not
contain persistent, bioaccumulative and toxic substances
(PBT substances) or very persistent and very bioaccumulative
(vPvB substances) as defined in Annex XIII of the Regulation
(EG) No 1907/2006 (REACH), respectively.

12.6 Other adverse effects

Product:
Adsorbed organic bound : < 0,1 %
halogens (AOX)

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Dispose of as special waste in compliance with local and na-
tional regulations.

Contaminated packaging : Dispose of as unused product.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

Waste Code European Union

unused product : dyestuffs and pigments other than those mentioned in 04 02
16

SECTION 14: Transport information

14.1 UN number
Not regulated as a dangerous good
14.2 UN proper shipping name
Not regulated as a dangerous good
14.3 Transport hazard class(es)
Not regulated as a dangerous good
14.4 Packing group
Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Remarks : see chapter 6 - 8

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Remarks : Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture

Other regulations:
Currently no information available.

15.2 Chemical safety assessment

A Chemical Safety Assess-
ment is not required for this
substance.

SECTION 16: Other information

Full text of H-Statements

H412 : Harmful to aquatic life with long lasting effects.
Full text of other abbreviations
Aquatic Chronic : Long-term (chronic) aquatic hazard

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

BEZAPRINT GREEN CC-M

Version Revision Date: Date of last issue: 19.12.2017

1.2 17.09.2019 Date of first issue: 25.10.2017

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regula-
tion; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN
- Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Cana-
da); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - In-
ternational Air Transport Association; IBC - International Code for the Construction and Equip-
ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra-
tion; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Mari-
time Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisa-
tion for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration
to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not
Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International
Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature;
SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical
Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Sub-
stances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioac-
cumulative

Further information
Other information : This data sheet contains changes from the previous version in
section(s):
3

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
This safety datasheet only contains information relating to safety and does not replace any prod-
uct information or product specification.

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