FLP-1 (Full Book-I) - 27-07-2021

Roll No__________ (To be filled in by the candidate) (Academic Session 2020 – 2021)
CHEMISTRY Class 1st year

PAPER –II (Objective Type) PAPER CODE = 270721
Time Allowed: 20 Minutes (Group - I) Maximum Marks: 17
Q.1 Four possible answers A, B, C and D to each question are given. The choice which you think
is correct fill that circle in front of that question with marker or pen ink. Cutting or filling two
or more circles will result in zero mark in that question.
1. A very dilute solution of glucose in water has ________.
(a) Free ions in the solution (b) Free atoms in the solution
(c) Free molecules of solute (d) Free atoms and molecules both
2. Strength of a base can be determine by
(a) PKa (b) pKb (c) P[OH] (d) pKw
3. If a solution has zero pH. The hydrogen ion concentration will be
(a) 10-4 (b) 10-3 (c) 10-7 (d) 1
4. The strong reducing agent is
)a) Cl2 (b) F2 (c) Br2 (d) I2
5. The component which rises at maximum has
(a) Highest Rf value (b) Slowest Rf value (c) Rf = 1 (d) Rf > 1
6. Ether extraction is most suitable for…
(a) Volatile or thermally unstable product. (b) Volatile or thermally stable product.
(c) Non-volatile or thermally unstable product. (d) Non-volatile or thermally stable product.
7. Identify the highest heat change of any type
(a) Breaking of Covalent bond (b) Bond formation of ionic bond
(c) Evaporation of 1 mole of water (d) No comparison
8. Standard enthalpies of reaction be easily measured by using
(a) Bomb calorimeter (b) Glass calorimeter (c) Polarimeter (d) Glucometer
9. Kinetic gas equation was derived by...
(a) Clausius (b) Boltzmann (c) Bernoulli (d) Maxwell
10. Minimum temperature attained so far is...
(a) 0 K. (b) 0 °C. (c) – 273°C. (d) None of the above.
11. The limiting line of Balmer series lie in.
(a) UV-region (b) IR-Region (c) Visible region (d) Microwave region
12. Beta rays consist of
(a) Electrons (b) Protons (c) Neutrons (d) Helium Nuclei
13. Isotopes differ in
(a) properties which depend upon mass (b) arrangement of electrons in orbitals
(c) chemical properties (d) the extent to which they may be affected in electromagnetic field
14. 27 g of Al will react completely with how much mass of O2 to produce Al2O3
(a) 8 g of oxygen (b) 16 g of oxygen (c) 32 g of oxygen (d) 24 g of oxygen
15. Actual yield is always ______ the theoretical yield.
(a) Greater than (b) Less than (c) Equal to (d) Less or Equal to
16. Example of unit cell with crystallographic dimensions a =b  c, α = β =  = 90,
(a)Diamond (b) Graphite (c) Rhombic (d)Monoclinic
17. Which pair of molecules have Debye force?
(a) Ne and Ne (b) Argon and water (c) Na+ ion and water (d) Water and water
CHEMISTRY Class 1st year
Time Allowed: 2.40 Hours Maximum Marks: 68
SECTION I
Q2. Attempt any eight (8) questions? (8×2=16)
1. Calculate the pH of 1.0 mole dm−3 of H2X which is only 50% dissociated
2. What are ideal solutions? Give their properties.
3. What are Colligative properties? Why are they called so?
4. Explain the difference between ionization and electrolysis.
5. The reaction rate decreases every moment but rate constant “k” of the reaction is a constant quantity under
the given condition. Justify it.
6. The rate of a chemical reaction with respect to products in written with positive sign, but with respect to
reactants is written with a negative sign. Explain it with reference to the following hypothetical reaction
A ⎯⎯→ B
7. What is meant by Common ion effect? Apply it to the purification of commercial sodium chloride.
8. What is meant by optimum conditions to prepare SO3(g)?
9. What is the function of a salt bridge?
10. How is electrochemical series be helpful in predicting feasibility of chemical reaction?
11. What is State and State Function?
12. Prove that qv = ΔE
Q3. Attempt any eight (8) questions? (8×2=16)
1. Why in case of N2 ‘σ2px’ orbital is higher in energy than ‘π2py’ and ‘π2pz’ as compared to O2?
2. Why is the sigma bond stronger than pi-bond?
3. Why the size of a cation is smaller than their parent atom?
4. Why the value of second electron affinity is always positive for both metals and non-metals?
5. Draw the Lewis structures of HNO2 and HNO3?
6. The e/m value for positive rays obtained from hydrogen gas is 1836 times less than that of cathode
rays. Justify it.
7. Compare line emission and line absorption spectra
8. Write electronic configuration of Cr24 and Cu29.
9. Calculate the mass of electron from e/m value of electron. (e/m=1/758x10 11CKg-1)
10. In very cold winter fish in garden ponds owe their lives to hydrogen bonding.
11. Explain anisotropy with example.
12. Why water has a higher boiling point than HF although F is more electronegative Oxygen.
Q4. Attempt any six (6) questions? (6×2=12)
1. Give the two important uses and characteristics of Plasma.
2. Derive Boyle’s Law from Kinetic gas equation
3. How pressure of a dry gas is computed when it is collected over water?
4. Write two assumptions of Stoichiometry.
5. What is meant by average atomic mass?
6. Write uses of Chromatography.
7. Differentiate b/w Stationary and Mobile phase.
8. Briefly explain ether extraction.
9. One milligram of K2CrO4 when completely ionized in water has twice the number of positive ions than
the number of negative ions.
SECTION II
NOTE: Attempt any three questions. (3×8=24)
Q5 (a) Draw the energy diagram of N2 and O2 according to MOT. (4)
(b) Explain the Hess’s Law of constant heat summation. (4)
Q6 (a) What is the percentage ionization of acetic acid in a solution in which 0.1 moles of it has been dissolved
per dm3 of the solution. (Dissociation constant ka of acetic acid is 1.85 x 10–5) (4)
(b) Explain construction and Working of Standard Hydrogen Electrode. (4)
Q7 (a) Explain Millikan Oil droplet experiment for the charge on electron. (4)
(b) Write the postulates of KMT. (4)
Q8 (a) what are London dispersion forces. Describe the polarizabilty. (4)
(b) Mg metal reacts with HCl to give hydrogen gas. What is the minimum volume of HCl solution (27% by
weight) required to produce 12.1g of H2. The density of HCl solution is 1.14gcm–3. (4)
Mg ( s )  2 HCl( aq ) 
 MgCl2( aq )  H 2( g )
Q9 (a) Write a note on Roults law for a nonvolatile solute. (4)
(b) Write a detailed note on Order of reaction. (4)

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Roll No__________ (To be filled in by the candidate) (Academic Session 2020 – 2021)

CHEMISTRY Class 1st year

2. What are ideal solutions? Give their properties.

3. What are Colligative properties? Why are they called so?

4. Explain the difference between ionization and electrolysis.

the given condition. Justify it.

8. What is meant by optimum conditions to prepare SO3(g)?

9. What is the function of a salt bridge?

10. How is electrochemical series be helpful in predicting feasibility of chemical reaction?

11. What is State and State Function?

12. Prove that qv = ΔE

Q3. Attempt any eight (8) questions? (8×2=16)

2. Why is the sigma bond stronger than pi-bond?

3. Why the size of a cation is smaller than their parent atom?

5. Draw the Lewis structures of HNO2 and HNO3?

rays. Justify it.

7. Compare line emission and line absorption spectra

8. Write electronic configuration of Cr24 and Cu29.

11. Explain anisotropy with example.

Q4. Attempt any six (6) questions? (6×2=12)

1. Give the two important uses and characteristics of Plasma.

2. Derive Boyle’s Law from Kinetic gas equation

3. How pressure of a dry gas is computed when it is collected over water?

4. Write two assumptions of Stoichiometry.

5. What is meant by average atomic mass?

6. Write uses of Chromatography.

7. Differentiate b/w Stationary and Mobile phase.

8. Briefly explain ether extraction.

the number of negative ions.

NOTE: Attempt any three questions. (3×8=24)

Q5 (a) Draw the energy diagram of N2 and O2 according to MOT. (4)

(b) Explain the Hess’s Law of constant heat summation. (4)

(b) Explain construction and Working of Standard Hydrogen Electrode. (4)

(b) Write the postulates of KMT. (4)

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