Note : Encircle the alphabet which corresponds to the

A graph is
single best response.
plotted by taking time on x axis and concentration of reactant on y
axis for a reaction following a pseudo first order. The pattern of the graph is:
Acurve B. hyperbola
C. parabola
D. straight line
2. In the
photochemical degradation of multisulpha preparation, the order that a
reaction does follow is:
A. first
B. pseudo first
n 0 . 0 3

C. second
D. zero
3. The integral equation for a reaction (in common notation) is written as
rate
log c =
log c.- (kt/2.303). When a graph is drawn log c vs. the
be: t, slope will
nA
ideo
A negative B. one
C. positive D. zero

:4S
 C integral equation (in common notation) k = Wat(a-x) is concerned with
V t o the order:
A. first
B. pseudo first
ho O
(124C second D. zero
. When a series of steps are involved in a reaction, the 'overall rate of a
reaction depends upon the rate(s)
A. all steps
of
B. all
steps which follow the slowest step RDS.
Batk Sicle dmwey

C.all steps which

precede the slowest step maype uvune
LB. the slowest step
ne solid state
decomposition of aspirin in presence of moisture follows the
order:
A. first B. pseudofirst
C. second D. zero
7. The reaction rate constant (k) is 2. 0x10- min- for aspirin hydrolysis in
0.1 Nhydrochloric acid solution at 1 mg/mL concentration. Under same
conditions, if the product contains aspirin 4 mg/mL of the initial concentration,
the k value in minutes will be:
A. 0.5 x 10-3 VB. 2.0 x 10-3
C. 4.0 x 103 D. 8.0 x 10-3
8. A second order reaction follows pseudo-first order reaction, when the
concentrations of:
A. two reactants are high
B. two reactants are low

C. o n e reactant is far higher than the other reactant.

D. two reactants are equal
9. In the study of the rate of a reaction, 100 mL of 0.l N hydrochloric acid
solution is added to 10 mL methyl acetate for the reaction to occur. The

reason making such a proportion is

for to make:

A. analysis of degradation is easy

B. reaction to follow first order

C. reaction to proceed slowly

D. reaction to undergo a pseudo first order

of trans-stilbene to cis-stilbene follows the molecularity:

10. The conversion
A. bimolecular B. termolecular
C. unimolecular D. zeromolecular
in hydrochloric acid solution, the change in the
11. In the hydrolysis of sucrose
rotation follows the order:
optical
A. pseudofirst
B. pseudo zero
D. zerro
C. second
 12. In the degradation studies of aspirin suspension, the orders observed initially
and at the end, respectively,
are
A. first, second B. first, zero
C. second, first D. zero, first
13. A prescription
of liquid aspirin preparation contained 6. 5 g/100 mL. The
solubility of aspirin at 25°C is 0. 33 g/100 mL. The order of reaction in the
kinetic study is:
A. apparent first B. apparent zero
C. first D. second
14. The time required for the complete degradation of in solution is
a drug a
finite value. The order of that reaction is:
A. first B. pseudo first
C. second D. zero
D. Normally, ethyl acetate undergoes hydrolysis in presence of H* and (OH)"

ions. The order of the reaction observed in the acidic and alkaline solutions,
respectively, are:
A. first and second B. pseudo first and second
C. second and first D. second and pseudo first
16. In reactions that follow first order kinetics, half life is expressed by equation:
A. 0.693/k, B. 0.301k,
C. 0.105/k, D. k,/0.693
17. The units for the specific rate constant for a second order reaction are:
A. liter/moles. sec B. liter. sec/moles
C. moles/liter. sec D. moles. sec/liter
18. The half life of a first order reaction is 4 years. What is its shelf life (in
years)?
A. 0.02 B. 0.03
C. 0.17 D. 0.61
19. The general rate expression for a first order reaction (in common notation) is:
2.303
A. dc/dt = -kC B. k log Se
C

C. k= D. dcldt =k
at (d-x)
20. Which one of the following dosage forms exhibit faster rate of reaction under
normal conditions?

A. Emulsions B. Ointments
C. Solutions D. Suspensions
of a reaction is expressed (-dc/dt), where de
21. In chemical kinetics, the rate as
refers to the concentration. Whose concentration does it refer to?

A. Catalyst B. Product
C. Reactant D. Solvent medium
. Which one of the following be designated
can as the molecularity of a
reaction?
A. Half
B. One
C. One and half D. Zero
23. Which one of
them is refered as a general rate equation (-dc/dt) for
order? a second
A. AOB
B. AB
C. A'B?
D. A2B2
24. Which one of the
following orders have abundant
applications in
processes? biological
A. First
B. Second
C. Third
D. Zeroo
25. In a chemical reaction, the rate constant is
concentration. Which one of them is the order? independent of the initial
A. First
B. Second
C. Third
D. Zero
1. Chemical Kinetics
. A 2. D 3. A 4. C 5. C
6. D 7. B 8. C 9. D 10. C
11. A 12. D 13. B 14. D 15. B
6. A 17. A 18. D 19. A 20. C
22. B 23. B 24. A 25. D
21. C