CHEMISTRY

DPP
Momentum Topic : Atomic Structure DPP : 1

1. Complete the following table:

2. The mass-charge ratio for A+ ions is 1.97 × 10–7 kg C–1. Calculate the mass of A atom.
3. Calculate the charge in coulomb on Fe3+ ion.
4. An oil drop has 6.4 × 10–19 coulomb charge. How many electrons does this oil drop has?
5. The total number of electrons in a nitrate ion [NO3– ]is :
(A) 31 (B) 62 (C) 32 (D) 63
6. The mass of a neutron is .................... than the mass of a proton.
(A) slightly less (B) slightly more
(C) exactly equal (D) their masses cannot be compared
7. Which of the following are isoelectronic ?
(I) CH3+ (II) H3O+ (III) NH3 (IV) CH3–
(A) I and III (B) III and IV (C) I and II (D) II, III and IV
8. Atom consist of electrons, protons and neutrons. If the mass attributed to neutron were halved and that
attributed to the electrons were doubled, the atomic mass of 6C12 would be approximately :
(A) Same (B) Doubled (C) Halved (D) Reduced by 25%
9. Proton is -
(A) Nucleus of deuterium (B) Ionised hydrogen molecule
(C) Ionised hydrogen atom (D) An -particle
10. There are 11 protons and 12 neutrons in the nucleus of an atom. Find the atomic number (Z), mass number (A),
number of electrons and the symbol of the element.
11. According to Dalton's atomic theory, an atom can -
(A) Be created (B) Be destroyed
(C) take part in a chemical reaction (D) None of these
12. Which has highest e/m ratio ?
(A) He2+ (B) H+ (C) He+ (D) H

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 13. As an electron is brought from an infinite distance close to the nucleus of the atom, the energy of the
electron-nucleus system :
(A) Increases to a greater positive value (B) Decreases to a smaller positive value
(C) Decrease to a greater negative value (D) Increases to a smaller negative value
14. Arrange -particle(), electron (e–), proton(p) and neutron (n) in increasing order of their e/m value (specific
charge, consider magnitude only not sign) -
(A) < e– < p < n (B) n <  < p < e- (C) n < p <  < e- (D) e- < p < n < 

CHEMISTRY
DPP
Momentum Topic : Atomic Structure DPP : 2

1. For a broadcasted electromagnetic wave having frequency of 1200 KHz, calculate number of waves that will
be formed in 1 km distance (wave number per km).
_
2. Find the radius of nucleus of an atom having atomic mass number equal to 125.(R0 = 1.2 × 10 13 cm)
3. With what velocity should an -particle travel towards the nucleus of a copper atom so as to arrive at a
distance of 10–13 m from the nucleus of copper atom. (At. No. of Cu = 29)
4. If the radius of the first Bohr orbit of the H atom is r, then for the Li2+ ion it will be :

(A) 3r (B) 9r (C) r/3 (D) r/9

5. The radii of two of the first four Bohr’s orbits of the hydrogen atom are in the ratio 1 : 4. The energy difference
between them may be:

(A) Either 12.09 eV or 3.4 eV (B) Either 2.55eV or 10.2 eV

(C) Either 13.6 eV or 3.4 eV (D) Either 3.4eV or 0.85 eV

6. The ratio of radius of two different orbits in a H-atom is 4 : 9, then the ratio of the frequency of revolution of
electron in these orbits is :

(A) 2 : 3 (B) 27 : 8 (C) 3 : 2 (D) 8 : 27

7. The kinetic energy of an electron in a particular orbit in H atom is 3.4 eV. The angular momentum of electron in
this orbit is :
h h 3h 2h
(A) 2
(B) 
(C) 2
(D) 

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 8. The potential energy of the electron present in the ground state of Li2+ ion is represented by:
3e 2 3e 3e 2 3e 2
(A)  4   r (B)  4  r (C)  4   r 2 (D)  4   r
0 0 0 0

2h
9. If the angular momentum of an electron in a Bohr orbit is , then the value of potential energy of electron


present in He+ ion is :

(A) – 13.6 eV (B) – 3.4 eV (C) – 6.8 eV (D) – 27.2 eV.
10. In a certain electronic transition in the hydrogen atom from an initial state i to a final state f, the difference in the
orbit radius (ri  rf) is seven times the Bohr radius. Identify the transition.
(A) 4  1 (B) 4  2 (C) 4  3 (D) 3  1
8
11. The velocity of electron in the ground state of H atom is 2.185 × 10 cm/sec. The velocity of electron in the
second orbit of Li2+ ion in cm/sec would be
(A) 3.276 × 108 (B) 2.185 × 108 (C) 4.91 × 108 (D) 1.638 × 108
12. The ratio of the difference in energy between the first and second Bohr orbit to that between the second and
third Bohr orbit in a H-like species is
1 1 4 27
(A) (B) (C) (D)
2 3 9 5
13. For which of the following species, Bohr model is not valid :

(A) He+ (B) H (C) Li2+ (D) H+

14. The ratio of (E2 – E1) to (E4 – E3) for He+ ion is approximately equal to (where En is the energy of nth orbit)
(A) 10 (B) 15 (C) 17 (D) 12

15. Energy of H- atom in the ground state is -13.6 eV. Hence energy in the second excited state is -

(A) –6.8 eV (B) –3.4 eV (C) –1.51 eV (D) –4.3 eV

16. Calculate the following :

(a) the kinetic energy (in eV) of an electron in the ground state of hydrogen atom.

(b) the potential energy (in eV) of an electron in the ground state of hydrogen atom.

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 CHEMISTRY
DPP
Momentum Topic : Atomic Structure DPP : 3

1. The difference between the wave number of 1st line of Balmer series and last line of Paschen series for

Li2+ ion is
R 5R R
(A) (B) (C) 4R (D)
36 36 4

2. In a hydrogen like sample, electrons are in a particular excited state. If electrons make transition
upto 1 st excited state, then it produces maximum 15 different types of spectral lines, then electrons were
in

(A) 5th state (B) 6th state (C) 7th state (D) 8th state

3. Wave number of a spectral line for a given transition is x cm–1 for He+, then its value for Be3+ (isoelectronic of

He+) for same transition is :

x
(A) x cm–1 (B) 4x cm–1 (C) cm–1 (D) 2x cm–1
4
4. What would be the maximum number of emission lines for atomic hydrogen that you would expect to see

with the naked eye if the only electronic energy levels involved are those as shown in the Figure?

(A) 4 (B) 6 (C) 5 (D) 15

5. STATEMENT-1 : In Li2+ sample, an electron make transition from higher state to n = 2. Then the photon

observed will fall in the visible range.

STATEMENT-2 : Line falling in n = 2 is Balmer series line, which may belong to visible range in H-atom.

(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1

(C) Statement-1 is True, Statement-2 is False

(D) Statement-1 is False, Statement-2 is True

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 6. An electron in a H–like atom jumps from a higher energy level ‘n’ to ground state by emitting two successive

photons of wave numbers 5.25 x 108 m–1 and 7.25 x 108 m–1 . If the same electron undergoes the same

transition by emitting a single photon, then the wavelength of this photon is :

(A) 32.84 Å (B) 8Å (C) 0.125 Å (D) 0.03Å

7. An energy of 40.8 eV is required to excite a hydrogen like specie from 1st Bohr orbit to second. Which is/are

correct statement(s) :

(A) Atomic number of H-like specie is 2 (B) Ionisation energy of H-like specie is 122.4 eV

(C) Kinetic energy of electron in 1st orbit is – 54.4 eV (D) Energy of second orbit is –13.6 eV

8. In He+ ion sample electrons make transition from 5th excited state to 2nd state only, all different types of

photons are observed. Then change in angular momentum of electrons producing 3rd highest energy photon is

how much times of angular momentum of electron in first orbit.

9. Match the following :

Column () Column ()

(A) Binding energy of 5th excited state Li++ sample (p) 10.2 V

(B) st excitation potential of H-atom (q) 3.4 eV

(C) 2nd excitation potential of He+ (r) 13.6 eV

(D) I.E. of H-atom (s) 48.4 V

10. Match the following :

En = total energy n = angular momentum

Kn = K.E. , Vn = P.E.

Tn = time period, rn = radius of nth orbit

Column () Column ()

–y 1
(A) En  rn /z, then y is (p)
2

(B) n  nx ,then x is (q) – 2

En
(C) V (r) – 3
n

zt
(D) Tn  , t & m are respectively (s) 1
nm

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 CHEMISTRY
DPP
Momentum Topic : Atomic Structure DPP : 4
16 x
1. The largest wavelength in Paschen series of Li+2 is 9
. The largest wavelength of Balmer series in He+ is :
5x
(A) x (B) 1.2 x (C) 1.4 x (D) 9

2. Determine the de-Broglie wavelength associated with an electron in the 3rd Bohr's orbit of He+ ion?

(A) 10 Å (B) 2 A (C) 5 Å (D) 1 Å

3. Uncertainity in the position of an electron (mass 9.1  10–31 kg) moving with a velocity 300 ms–1, accurate upto

0.01% will be : ( 2m = 5.8  10–5)
e

(A) 1.92 cm (B) 0.576 cm (C) 0.384 cm (D) 0.192 cm

4. A small ball of mass 6.62 gm is moving with the velocity 100 m/s then the wavelength associated with the ball
is :

(A) 10–36 m (B) 10–33 m (C) 10–31 m (D) can't be calculated

Paragraph for Question No. 5 to 7

The French physicist Louis de Broglie in 1924 postulated that matter, like radiation, should exhibit a dual

behaviour. He proposed the following relationship between the wavelength  of a material particle, its linear
momentum p and planck constant h.
h h
= p =
m
The de Broglie relation implies that the wavelength of a particle should decrease as its velocity increases. It also

implies that for a given velocity heavier particles should have shorter wavelength than lighter particles.

The waves associated with particles in motion are called matter waves or de Broglie waves. These waves differ

from the electromagnetic waves as they

(i) have lower velocities

(ii) have no electrical and magnetic fields and

(iii) are not emitted by the particle under consideration.

The experimental confirmation of the de Broglies relation was obtained when Davisson and Germer, in 1927,

observed that a beam of electrons is diffracted by a nickel crystal. As diffraction is a characteristic property of

waves, hence the beam of electron behaves as a wave, as proposed by de broglie.

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 5. If proton, electron and -particle are moving with same kinetic energy then the order of their de-Broglie’s

wavelength.

(A)P > e >  (B)  > P > e (C)  < P < e (D) e = P < 

6. For the same value of de-broglie wavelength of electron as in second orbit of H, the value of orbit number for

He+ ion will be :

(A) 4 (B) 3 (C) 2 (D) 1

7. De-Broglie wavelength of an electron travelling with speed equal to 1% of the speed of light

(A) 400 pm (B) 120 pm (C) 242 pm (D) 375 pm

–5 –1
8. Uncertainty in position a particle of 25g in space is 10 m. Hence uncertainty in velocity (ms ) is
–34
(Planck's constant h = 6.6 × 10 Js)
–28 –34 –34 –24
(A) 2.1 × 10 (B) 2.1 × 10 (C) 0.5 × 10 (D) 5.0 × 20
9. In a hydrogen like sample, electron is in 2nd excited state. The binding energy of 4th state of this sample is

13.6 eV, then :

(A) A 25 eV photon can set free the electron from the second excited state of this sample.

(B) 3 different types of photon will be observed if electrons make transition up to ground state from the

second excited state

(C) If 23 eV photon is used, then K.E. of the ejected electron is 1 eV.

(D) 2nd line of Balmer series of this sample has same energy value as that of 1st excitation energy of H-

atom.

10. Calculate ratio of de-Broglie wavelength for a proton and -particle if their K.E. are same.

11. Calculate ratio of wavelength for an proton and -particle if they are accelerated through same potential V

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 CHEMISTRY
DPP
Momentum Topic : Atomic Structure DPP : 5

1. For s-orbitals, since ( orbital wave function) is independent of angles, the probability density (2) is -

(A) also independent of angles (B) spherically symmetric

(C) both (A) and (B) are correct (D) both (A) and (B) are incorrect

2. Which of the following statements is incorrect?

(A) Probabilities are found by solving Schrodinger wave equation

(B) Energy of the electron in an atom at infinite distance is zero and yet it is maximum

(C) Some spectral lines of an element may have the same wave number

(D) The position and momentum of a rolling ball can be measured accurately

3. Which d -orbital does not have four lobes?

(A) d x 2 – y 2 (B) dxy (C) dyz (D) dz 2

Passage for Questions Q.4 to Q.6

Orbital wave function  can

be given as

(r, , ) = R (r) . () . ()

For various orbitals of H-atom and H-like atoms values of R (radial wave function) are
3/2
 z 
For 1s-orbital : R1s = 2   e  zr/a 0
 a0 
For 2s-orbital :
3/ 2
 z   zr   zr / 2a 0
R2s =   2  e
 2a 0   a0 
For 1p-orbital
3/2
1  z   zr   zr / 2a 0
R2p =    e
3  2a 0   a0 
For 3s-orbital
3/ 2
2 z   2zr 2z 2 r 2  zr / 3 a0
R3s = 3  3a  3    e
 a0 9a 20 
 0 

40 
h2
etc. Here a0 = bohr radius =
e2
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 z = atomic number
Similarly angular functions  and  can also be given
For s-orbital  and  can be given as
1 1
() = and () =
2 2
So for 1s-orbital  can be given as -
1s = R1s.1s.1s
3/2
1  z 
=   e  zr/a 0
  a0 
4. Probability density of finding an electron at distance r from nucleus in H-atom (in ground state) is -
3
1  z  2zr/a 0
(A)  (B) R2 (C)   e (D) None of these
  a0 
5. Value of r at which radial node is found for 2s-orbital in H–atom is –
(A) a0 (B) 2a0 (C) 3a0 (D) 4a0
6. Radial nodes for 3s-orbital of H–atom is/are at
(A) r = 1.9 a0 (B) r = 7.1 a0 (C) r = 2a0 (D) Both (A) and (B)
7. Which of the following statements about nodal planes is/are not true -

(A) A plane on which there is zero probability of finding an electron

(B) A plane on which there is maximum probability that the electron will be found

(C) 2 is non zero at nodal plane

(D) None of these

8. How many of these orbitals have maximum orbital angular probability distribution at an angle of 45° to the axial
direction.
dxy, d x 2  y 2 , dyz, dxz, dz 2 , Px, Py, Pz, s
9. Any p-orbital can accommodate up to :
(A) four electrons (B) two electrons with parallel spin
(C) six electrons (D) two electrons with opposite spin.
10. The maximum number of electrons in s, p and d-subshells are :
(A) 2 in each (B) 2, 6 and 6 (C) 2, 6 and 10 (D) 2, 6 and 12.
11. Which of the following orbital does not make sense?
(A) 3d (B) 3f (C) 5p (D) 7s.
12 The total number of subshells in nth main energy level are :
(A) n2 (B) 2n2 (C) (n–1) (D) n.

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 CHEMISTRY
DPP
Momentum Topic : Atomic Structure DPP : 6
h
1. Orbital angular momentum of an electron is 3 , then the number of orientations of this orbital in space

are
(A) 3 (B) 5 (C) 7 (D) 9
2. Which of the following sets of quantum numbers can be correct for an electron in 4f-orbitals ?
1 1
(A) n = 3,  = 2, m = –2, s = + (B) n = 4,  = 4, m = –4, s = –
2 2
1 1
(C) n = 4,  = 3, m = +1, s = + (D) n = 4,  = 3, m = +4, s = +
2 2
3. In the following electronic configuration, some rules have been violated :

I : Hund II : Pauli's exclusion III : Aufbau

(A) I and II (B) I and III (C) II and III (D) I, II and III
n+
4. Magnetic moment of X (Z = 26) is 24 B.M. Hence number of unpaired electrons and value of n respectively
are -
(A) 4, 2 (B) 2, 4 (C) 3, 1 (D) 0, 2
5. How many maximum electrons can be described by the quantum numbers n = 5,  = 2 in a particular atom?
(A) 2 (B) 6 (C) 10 (D) 14
6. The total number of electrons in Cr atom for which m = 0
(A) 1 (B) 8 (C) 12 (D) 16
7. The Pauli exclusion principle states that
(A) no two electrons in an atom can have the same four quantum numbers
(B) electrons can have either ±1/2 spins
(C) electrons with opposing spins are attracted to each other
(D) no two electrons in an atom can have the same spin
8. Which of the following has two unpaired electrons ?
(A) Si, Mg (B) S, Mg (C) S, Si (D) S, Fe.
9. Which of the following statements is not correct ?
(A) The shape of an atomic orbital depends on the azimuthal quantum number
(B) The orientation of an atomic is given by magnetic quantum number
(C) The energy of an electron in an atomic orbital of multi electron atom depends on the principal quantum
number only
(D) The number of degenerate atomic orbitals of one type depends on the values of azimuthal quantum numbers
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 10. Column-I Column-II
(A) No. of electrons in Na(11) having m = 0 (P) 7
(B) No. of electrons in S(16) having (n + ) = 3 (Q) 15
(C) No. of maximum possible electrons having S = +1/2 spin in Cr(24) (R) 8
(S) 12
11. The ground state energy of hydrogen atom is –13.6 eV. Consider an electronic state  of He+ whose energy,
azimuthal quantum number and magnetic quantum number are –3.4 eV, 2 and 0, respectively.
Which of the following statement(s) is(are) true for the state  ? [JEE ADV. 2019]
(A) It is a 4d state
(B) The nuclear charge experienced by the electron in this state is less than 2e, where e is the magnitude of the
electronic charge
(C) It has 3 radial nodes
(D) It has 2 angular nodes
MATCH THE COLUMN
Answer the following by appropriately matching the lists based on the information given in the
paragraph.
Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the
following List-I contains some quantities for the nth orbit of the atom and List-II contains options showing how
they depend on n. [JEE ADV. 2019]
List-I List-II
(I) Radius of the nth orbit (P)  n–2
(II) Angular momentum of the electron in the nth orbit (Q)  n–1
(III) Kinetic energy of the electron in the nth orbit (R)  n0
(IV) Potential energy of the electron in the nth orbit (S)  n1
(T)  n2
(U)  n1/2
12. Which of the following options has the correct combination considering List–I and List–II?
(A) (III), (P) (B) (IV), (Q) (C) (IV), (U) (D) (III), (S)
13. Which of the following options has the correct combination considering List–I and List–II?
(A) (I), (T) (B) (II), (Q) (C) (I), (P) (D) (II), (R)
14. The mole fraction of urea in an aqueous urea solution containing 900 g of water is 0.05. If the density of the
solution is 1.2 g cm–3, the molarity of urea solution is_____ [JEE ADV. 2019]
(Given data : Molar masses of urea and water are 60 g mol–1 and 18 g mol–1, respectively)

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 ANSWER KEY DPP _ 01
1.
Particle Atomic No. Mass No. No. of Elecrrons No. of Protons No. of neutrons
Sodium atom 11 23 11 11 12

Aluminium ion 13 27 10 13 14

Chloride ion 17 35 18 17 18
Phosphorus atom 15 31 15 15 16

Cuprous ion 29 64 28 29 35

2. 3.16 × 10–26 kg 3. 4.80 × 10–19 C 4. 4 5. C 6. B

23
7. D 8. D 9. C 10. Z = 11,A=23, no. of electron = 11, 11 Na
11. C 12. B 13. C 14. B
ANSWER KEY DPP _ 02
C 3  10 8 m / s 1 1 km
1. = = 1200  10 3 s 1 =250 m = 0.25 km.  = Wave no. = = 0.25 km = 4 wave per km
 
2. –15
6 ×10 m 3. 6.34 × 106 m/s.

4. C 5. B 6. B 7. B 8. D 9. C 10. C

11. A 12. D 13. D 14. B 15. C

16. Ground state energy = –13.6 eV
K.E. = +13.6 eV  P.E. = –27.2 eV
ANSWER KEY DPP _ 03

1. D 2. C 3. B 4. A 5. D 6. B 7. AD

8. 2 9. [A – q] ; [B – p] ; [C – s] ; [D – r] 10. (A – s ; B – s ; C – p ; D – q, r)

ANSWER KEY DPP _ 04

1. C 2. C 3. D 4. B 5. C 6. A 7. C
p 2 p 2 2
8. A 9. AB 10.  11. 
 1  1

ANSWER KEY DPP _ 05

1. C 2. C 3. D 4. C 5. B 6. D 7. BC

8. 3 9. D 10. C 11. B 12 D
ANSWER KEY DPP _ 06
1. C 2. C 3. C 4. A 5. C 6. C 7. A

8. C 9. C 10. (A) P (B) R (C) Q 11. AD 12. A 13. A

14. 2.985

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