Section C Ideal Gas and Liquid Heat Capacities. C ⬚p / R ⫽ a0 ⫹ a1T ⫹ a2T 2 ⫹ a3T 3 ⫹ a4T 4.

CpIG and Cpliq at 298.15 K, J mol⫺1 K⫺1.

No. Formula Name CAS # Trange, K a0 a1 ⫻ 103 a2 ⫻ 105 a3 ⫻ 108 a4 ⫻ 1011 CpIG Cpliq
1 Ar argon 7440-37-1 — 2.500 0.000 0.000 0.000 0.000 20.79
2 Br2 bromine 7726-95-6 50-1000 3.212 7.160 ⫺1.528 1.445 ⫺0.499 36.05 75.67
3 BrD deuterium bromide 13536-59-9 50-1000 3.716 ⫺2.318 0.738 ⫺0.717 0.250 29.23
6 BrH hydrogen bromide 10035-10-6 50-1000 3.842 ⫺3.098 0.917 ⫺1.032 0.426 29.14
7 CBrClF2 bromochlorodifluoromethane 353-59-3 100-1000 1.968 36.592 ⫺5.489 4.036 ⫺1.170 74.65
8 CBrF3 bromotrifluoromethane 75-63-8 100-1000 1.959 30.789 ⫺3.782 2.236 ⫺0.515 69.24
9 CBr2F2 dibromodifluoromethane 75-61-6 100-1000 2.476 36.115 ⫺5.666 4.368 ⫺1.324 77.02
10 CClF3 chlorotrifluoromethane 75-72-9 50-1000 2.369 23.861 ⫺1.579 ⫺0.366 0.528 66.87
11 CCl2F2 dichlorodifluoromethane (R-12) 75-71-8 50-1000 2.185 31.251 ⫺3.724 1.930 ⫺0.323 72.28 119.00
12 CCl3F trichlorofluoromethane (R-11) 75-69-4 50-1000 2.090 38.890 ⫺6.079 4.542 ⫺1.316 78.09 121.80
13 CCl4 tetrachloromethane 56-23-5 200-1000 2.518 41.882 ⫺7.160 5.739 ⫺1.756 83.43 131.60
14 CF4 tetrafluoromethane 75-73-0 50-1000 2.643 15.383 0.850 ⫺2.940 1.469 61.05
15 CHBrF2 bromodifluoromethane 1511-62-2 100-1000 3.254 13.871 ⫺0.070 ⫺1.130 0.606 58.76

A.35
16 CHClF2 chlorodifluoromethane (R-22) 75-45-6 50-1000 3.164 10.422 1.179 ⫺2.650 1.222 55.85 110
17 CHCl2F dichlorofluoromethane 75-43-4 50-1000 2.949 17.130 ⫺0.629 ⫺0.821 0.573 60.94 108
18 CHCl3 trichloromethane 67-66-3 200-1000 2.389 26.218 ⫺3.145 1.857 ⫺0.423 65.40 113.80
19 CHF3 trifluoromethane (R-23) 75-46-7 50-1000 3.450 3.480 3.012 ⫺4.452 1.834 50.98
20 CH2Cl2 dichloromethane 75-09-2 200-1000 2.710 11.561 0.324 ⫺1.370 0.662 50.88 100.00
21 CH2F2 difluoromethane 75-10-5 50-1000 4.150 ⫺5.584 4.384 ⫺5.160 1.920 42.88
22 CH2O2 methanoic acid (formic acid) 64-18-6 50-1000 3.809 1.568 3.587 ⫺4.410 1.672 53.45 99.17
23 CH3Cl chloromethane 74-87-3 200-1000 3.578 ⫺1.750 3.071 ⫺3.714 1.408 40.74 81.84
24 CH3F fluoromethane 593-53-3 50-1000 4.561 ⫺10.437 4.813 ⫺5.069 1.769 37.51
25 CH3NO2 nitromethane 75-52-5 50-1000 4.196 ⫺1.102 5.158 ⫺6.721 2.660 57.22 106.80
26 CH4 methane 74-82-8 50-1000 4.568 ⫺8.975 3.631 ⫺3.407 1.091 35.69
27 CH4O methanol 67-56-1 50-1000 4.714 ⫺6.986 4.211 ⫺4.443 1.535 44.06 81.08
28 CH4S methanethiol (methyl mercaptan) 74-93-1 50-1000 4.119 1.313 2.591 ⫺3.212 1.208 50.26 90.50
29 CH5N methanamine (methyl amine) 74-89-5 50-1000 4.193 ⫺2.122 4.039 ⫺4.738 1.751 50.05 102.09
30 CO carbon monoxide 630-08-0 50-1000 3.912 ⫺3.913 1.182 ⫺1.302 0.515 29.14
31 CO2 carbon dioxide 124-38-9 50-1000 3.259 1.356 1.502 ⫺2.374 1.056 37.13
33 C2ClF5 1-chloro-1,1,2,2,2- 76-15-3 50-1000 2.355 50.469 ⫺5.156 2.041 ⫺0.139 111.10
pentafluoroethane
 Section C Ideal Gas and Liquid Heat Capacities. C ⬚p / R ⫽ a0 ⫹ a1T ⫹ a2T 2 ⫹ a3T 3 ⫹ a4T 4.
CpIG and Cpliq at 298.15 K, J mol⫺1 K⫺1 (Continued )

No. Formula Name CAS # Trange, K a0 a1 ⫻ 103 a2 ⫻ 105 a3 ⫻ 108 a4 ⫻ 1011 CpIG Cpliq
34 C2Cl2F4 1,1-dichloro-1,2,2,2- 374-07-2 50-1000 2.268 56.415 ⫺6.908 3.953 ⫺0.861 115.80
tetrafluoroethane
35 C2Cl2F4 1,2-dichloro-1,1,2,2- 76-14-2 50-1000 2.525 53.644 ⫺5.771 2.417 ⫺0.199 116.60
tetrafluoroethane
36 C2Cl3F3 1,1,2-trichloro-1,2,2- 76-13-1 50-1000 2.133 63.238 ⫺8.916 6.140 ⫺1.683 121.00
trifluoroethane
37 C2F4 tetrafluoroethene 116-14-3 200-1000 2.223 36.551 ⫺4.776 3.283 ⫺0.931 80.41
38 C2F6 hexafluoroethane 76-16-4 50-1000 2.525 43.543 ⫺2.948 ⫺0.630 0.967 106.54
41 C2HClF4 1-chloro-1,1,2,2-tetrafluoroethane 354-25-6 50-1000 2.888 38.360 ⫺2.468 ⫺0.397 0.677 100.40
42 C2HClF4 1-chloro-1,2,2,2-tetrafluoroethane 2837-89-0 50-1000 3.022 35.834 ⫺1.744 ⫺1.211 0.994 99.06
43 C2HCl2F3 1,1-dichloro-2,2,2-trifluoroethane 306-83-2 50-1000 2.996 39.490 ⫺2.743 ⫺0.122 0.572 102.60
(R-123)
44 C2HCl2F3 1,2-dichloro-1,2,2-trifluoroethane 354-23-4 50-1000 2.699 43.299 ⫺3.663 0.697 0.322 104.45

A.36
(R-123a)
45 C2HF5 pentafluoroethane 354-33-6 50-1000 3.146 29.937 ⫺0.056 ⫺3.019 1.669 94.40
47 C2H2 ethyne (acetylene) 74-86-2 50-1000 2.410 10.926 ⫺0.255 ⫺0.790 0.524 59.03
48 C2H2F2 1,1-difluoroethene 75-38-7 200-1000 0.749 26.756 ⫺1.905 0.245 0.204 59.08
49 C2H2F4 1,1,1,2-tetrafluoroethane (R-134a) 811-97-2 50-1000 3.064 25.420 0.586 ⫺3.339 1.716 86.64
50 C2H2F4 1,1,2,2-tetrafluoroethane (R-134) 359-35-3 50-1000 3.084 32.841 ⫺2.425 0.488 0.162 90.32
51 C2H3ClF2 1-chloro-1,1-difluoroethane 75-68-3 50-1000 2.338 29.791 ⫺1.048 ⫺1.336 0.927 83.26 130
52 C2H3Cl2F 1,1-dichloro-1-fluoroethane 1717-00-6 50-1000 2.140 36.934 ⫺3.121 0.927 0.068 88.37
(R-141b)
53 C2H3F3 1,1,1-trifluoroethane (R-143a) 420-46-2 50-1000 2.577 23.727 0.480 ⫺2.824 1.439 78.61
54 C2H3F3 1,1,2-trifluoroethane (R-143) 430-66-0 50-1000 3.531 16.450 2.074 ⫺4.217 1.869 77.34
55 C2H4 ethene (ethylene) 74-85-1 50-1000 4.221 ⫺8.782 5.795 ⫺6.729 2.511 42.90
56 C2H4Br2 1,2-dibromoethane 106-93-4 298-1000 3.784 24.587 ⫺0.750 ⫺0.886 0.601 85.31 135.6
57 C2H4Cl2 1,1-dichloroethane 75-34-3 200-1000 2.610 24.853 ⫺0.675 ⫺1.035 0.643 76.32 126.4
58 C2H4Cl2 1,2-dichloroethane 107-06-2 298-1000 2.990 23.197 ⫺0.404 ⫺1.133 0.617 77.32 126.30
59 C2H4F2 1,1-difluoroethane (R-152a) 75-37-6 50-1000 3.292 11.749 2.835 ⫺4.645 1.941 68.49 118.00
60 C2H4O2 ethanoic acid (acetic acid) 64-19-7 50-1000 4.375 ⫺2.397 6.757 ⫺8.764 3.478 63.44 123.10
61 C2H4O2 methyl methanoate (methyl 107-31-3 298-1000 2.277 18.013 1.160 ⫺2.921 1.342 66.50 119.70
formate)
62 C2H5Br bromoethane 74-96-4 100-1000 3.636 6.861 3.749 ⫺5.446 2.231 64.23 99.8
63 C2H5Cl chloroethane 75-00-3 200-1000 3.029 9.885 2.967 ⫺4.550 1.871 62.64 106
64 C2H5F fluoroethane 353-36-6 50-1000 3.881 1.616 4.799 ⫺6.161 2.364 59.61
 65 C2H6 ethane 74-84-0 50-1000 4.178 ⫺4.427 5.660 ⫺6.651 2.487 52.47 231.50
66 C2H6O ethanol 64-17-5 50-1000 4.396 0.628 5.546 ⫺7.024 2.685 65.21 112.25
67 C2H6O dimethyl ether 115-10-6 100-1000 4.361 6.070 2.899 ⫺3.581 1.282 65.57
68 C2H6S ethanethiol (ethyl mercaptan) 75-08-1 50-1000 3.894 12.951 2.052 ⫺3.287 1.312 73.01 117.80
69 C2H6S 2-thiapropane (dimethylsulfide) 75-18-3 273-1000 3.535 17.530 0.596 ⫺1.632 0.696 74.06 118.10
70 C2H7N ethanamine (ethyl amine) 75-04-7 50-1000 4.640 2.069 5.797 ⫺7.659 3.043 71.54 129.70
71 C2H7N N-methylmethanamine (dimethyl 124-40-3 273-1000 2.469 15.462 2.642 ⫺4.025 1.564 70.50
amine)
72 C3F8 octafluoropropane (R-218) 76-19-7 200-1000 1.605 76.488 ⫺8.707 4.540 ⫺0.856 147.95
73 C3HF7 1,1,1,2,3,3,3-heptafluoropropane 431-89-0 137.00
(R-227ea)
82 C3H3NO 1,2-oxazole (isoxazole) 288-14-2 50-1000 3.911 ⫺9.705 10.380 ⫺13.472 5.359 59.01 96.48
83 C3H4 1-propyne (methyl acetylene) 74-99-7 50-1000 3.158 12.210 1.167 ⫺2.316 1.002 60.73
84 C3H4 1,2-propadiene 463-49-0 50-1000 3.403 6.271 3.388 ⫺5.113 2.161 81.82
85 C3H6 propene (propylene) 115-07-1 50-1000 3.834 3.893 4.688 ⫺6.013 2.283 64.32 112.00
86 C3H6 cyclopropane 75-19-4 50-1000 4.493 ⫺18.097 12.744 ⫺16.049 6.426 55.57
87 C3H6Cl2 1,2-dichloropropane 78-87-5 298-1000 1.697 40.582 ⫺2.247 ⫺0.038 0.377 98.27

A.37
88 C3H6O 2-propen-1-ol (allyl alcohol) 107-18-6 298-1000 0.248 34.938 ⫺1.685 ⫺0.192 0.324 76.01 138.90
89 C3H6O propanone (acetone) 67-64-1 200-1000 5.126 1.511 5.731 ⫺7.177 2.728 74.52 126.60
90 C3H6O2 propanoic acid 79-09-4 152.80
91 C3H6O2 methyl ethanoate (methyl acetate) 79-20-9 298-1000 4.242 14.388 3.338 ⫺4.930 1.931 85.30 143.90
92 C3H6O2 ethyl methanoate (ethyl formate) 109-94-4 89.00 146.60
94 C3H7Cl 1-chloropropane 540-54-5 200-1000 4.365 9.895 5.366 ⫺7.708 3.120 85.30 131
95 C3H8 propane 74-98-6 50-1000 3.847 5.131 6.011 ⫺7.893 3.079 73.60 120.00
96 C3H8O 1-propanol 71-23-8 50-1000 4.712 6.565 6.310 ⫺8.341 3.216 85.56 143.73
97 C3H8O 2-propanol 67-63-0 50-1000 3.334 18.853 3.644 ⫺6.115 2.543 89.32 154.40
98 C3H8O methyl ethyl ether 540-67-0 100-1000 4.008 21.493 1.803 ⫺3.333 1.331 93.30
99 C3H8S 2-thiabutane (methyl ethyl sulfide) 624-89-5 273-1000 2.816 29.186 0.807 ⫺2.888 1.325 95.06 144.60
100 C3H9N 1-propanamine (propyl amine) 107-10-8 50-1000 4.142 12.606 5.471 ⫺7.524 2.918 91.80 136.20
101 C3H9N 2-propanamine (methyl ethyl 75-31-0 50-1000 3.633 22.221 3.094 ⫺5.375 2.236 97.55 163.88
amine)
102 C3H9N N, N-dimethylmethanamine 75-50-3 298-1000 1.660 27.899 2.517 ⫺5.097 2.190 91.80 136.20
(trimethyl amine)
104 C4F8 octafluorocyclobutane 115-25-3 298-1000 0.949 80.942 ⫺7.976 2.970 ⫺0.087 79.48
105 C4F10 decafluoro-2-methylpropane 355-25-9 200-1000 1.965 99.798 ⫺11.830 6.680 ⫺1.457 78.02
106 C4H4O furan 110-00-9 50-1000 3.816 ⫺10.453 12.446 ⫺16.907 7.020 65.40 114.64
 Section C Ideal Gas and Liquid Heat Capacities. C ⬚p / R ⫽ a0 ⫹ a1T ⫹ a2T 2 ⫹ a3T 3 ⫹ a4T 4.
CpIG and Cpliq at 298.15 K, J mol⫺1 K⫺1 (Continued )

No. Formula Name CAS # Trange, K a0 a1 ⫻ 103 a2 ⫻ 105 a3 ⫻ 108 a4 ⫻ 1011 CpIG Cpliq
107 C4H4S thiophene 110-02-1 50-1000 3.063 1.520 9.514 ⫺14.129 6.088 72.78 123.88
108 C4H5N pyrrole 109-97-7 50-1000 3.554 ⫺6.426 12.231 ⫺16.957 7.095 71.60 127.74
109 C4H6 1-butyne 107-00-6 50-1000 2.995 20.800 1.560 ⫺3.462 1.524 81.42 122.80
110 C4H6 1,3-butadiene 106-99-0 50-1000 3.607 5.085 8.253 ⫺12.371 5.321 79.54 125.20
111 C4H6O3 acetic anhydride 108-24-7 298-1000 ⫺1.274 50.172 ⫺1.459 ⫺1.951 1.244 99.51 124.10
112 C4H8 cyclobutane 287-23-0 50-1000 4.739 ⫺16.423 14.488 ⫺18.041 7.089 70.56 109.3
113 C4H8 1-butene 106-98-9 50-1000 4.389 7.984 6.143 ⫺8.197 3.165 85.56 124.90
114 C4H8 trans-2-butene 624-64-6 50-1000 5.584 ⫺4.890 9.133 ⫺10.975 4.085 87.67
115 C4H8 cis-2-butene 590-18-1 50-1000 3.689 19.184 2.230 ⫺3.426 1.256 80.15 127.00
116 C4H8 2-methylpropene 115-11-7 50-1000 3.231 20.949 2.313 ⫺3.949 1.566 88.09
117 C4H8O butanone (methyl ethyl ketone) 78-93-3 200-1000 6.349 11.062 4.851 ⫺6.484 2.469 103.26 158.90
118 C4H8O tetrahydrofuran 109-99-9 50-1000 5.171 ⫺19.464 16.460 ⫺20.420 8.000 76.53 124.10
119 C4H8O2 butanoic acid 107-92-6 177.70

A.38
120 C4H8O2 2-methylpropanoic acid 79-31-2 173.00
121 C4H8O2 1,3-dioxane 505-22-6 50-1000 3.834 ⫺0.249 11.985 ⫺15.494 6.047 89.47 143.90
122 C4H8O2 1,4-dioxane 123-91-1 50-1000 3.730 1.851 11.781 ⫺15.602 6.177 92.18 154.50
124 C4H8O2 ethyl ethanoate (ethyl acetate) 141-78-6 298-1000 10.228 ⫺14.948 13.033 ⫺15.736 5.999 113.64 170.60
125 C4H8O2 propyl methanoate (propyl 110-74-7 110.10 178.10
formate)
126 C4H9Cl 2-chlorobutane 78-86-4 200-1000 4.450 22.285 4.350 ⫺7.215 3.015 110.22
127 C4H10 butane 106-97-8 200-1000 5.547 5.536 8.057 ⫺10.571 4.134 98.49 142.89
128 C4H10 2-methylpropane (isobutane) 75-28-5 50-1000 3.351 17.883 5.477 ⫺8.099 3.243 96.65 142.50
130 C4H10O 1-butanol 71-36-3 50-1000 4.467 16.395 6.688 ⫺9.690 3.864 108.03 177.06
131 C4H10O 2-methyl-1-propanol (isobutanol) 78-83-1 113.00 183.00
132 C4H10O 2-methyl-2-propanol (tert-butanol) 75-65-0 50-1000 2.611 36.052 1.517 ⫺4.360 1.947 113.63 220.10
133 C4H10O 2-butanol (sec-butanol) 78-92-2 50-1000 3.860 28.561 2.728 ⫺5.140 2.117 112.74 199.00
134 C4H10O diethyl ether 60-29-7 100-1000 4.612 37.492 ⫺1.870 1.316 ⫺0.698 119.46 172.60
138 C4H10S 3-thiapentane (diethyl sulfide) 352-93-2 273-1000 4.335 26.082 3.959 ⫺6.881 2.900 116.57 171.50
139 C4H11N 1-butanamine (butyl amine) 109-73-9 298-1000 2.668 38.366 1.150 ⫺3.817 1.712 113.90 294.30
140 C4H11N n-ethylethanamine (diethyl amine) 109-89-7 298-1000 3.028 32.373 2.828 ⫺5.501 2.300 116.00 178.10
141 C4H11N 2-methyl-1-propanamine (isobutyl 78-81-9 298-1000 0.380 53.027 ⫺2.436 0.207 0.038 117.09 194.0
amine)
 142 C5F12 dodecafluoropentane 678-26-2 200-1000 2.315 123.238 ⫺14.997 8.875 ⫺2.081 231.95
143 C5H5N pyridine 110-86-1 298-1000 ⫺3.505 49.389 ⫺1.746 ⫺1.595 1.097 78.23 132.70
144 C5H6O 2-methylfuran 534-22-5 50-1000 3.952 5.535 9.252 ⫺13.046 5.353 89.66 143.7
145 C5H8 1-pentyne 627-19-0 50-1000 3.382 31.688 0.790 ⫺3.109 1.417 106.69 167.00
146 C5H8 cyclopentene 142-29-0 50-1000 4.555 ⫺12.408 15.195 ⫺19.676 7.900 81.25 122.4
147 C5H8O cyclopentanone 120-92-3 50-1000 4.294 ⫺1.236 13.080 ⫺17.531 7.071 95.32 154.5
148 C5H10 cyclopentane 287-92-3 50-1000 5.019 ⫺19.734 17.917 ⫺21.696 8.215 82.76 126.80
149 C5H10 1-pentene 109-67-1 200-1000 5.079 11.919 7.838 ⫺10.962 4.381 108.20 154.00
150 C5H10 cis-2-pentene 627-20-3 298-1000 2.901 31.785 1.842 ⫺3.953 1.609 108.87 151.80
151 C5H10 2-methyl-2-butene 513-35-9 298-1000 1.240 39.303 0.270 ⫺2.500 1.120 105.00 152.80
152 C5H10 3-methyl-1-butene 563-45-1 298-1000 2.108 41.912 ⫺0.416 ⫺1.937 0.954 115.00 156.10
153 C5H10O cyclopentanol 96-41-3 50-1000 4.370 5.723 13.357 ⫺18.752 7.733 113.00 184.5
154 C5H10O 2-pentanone (methyl propyl 107-87-9 200-1000 7.836 9.051 8.063 ⫺10.847 4.283 125.90 184.30
ketone)
155 C5H10O 3-pentanone (diethyl ketone) 96-22-0 200-1000 8.071 13.654 6.120 ⫺8.337 3.253 129.87 191.00
156 C5H10O 3-methyl-2-butanone (methyl 563-80-4 124.10 180.10
isopropyl ketone)

A.39
158 C5H10O2 pentanoic acid 109-52-4 210.30
159 C5H10O2 3-methylbutanoic acid 503-74-2 197.10
160 C5H10O2 methyl butanoate 623-42-7 133.10 200.80
161 C5H10O2 ethyl propanoate 105-37-3 131.90 197.60
162 C5H10O2 methyl 2-methylpropanoate 547-63-7 132.00 191.00
163 C5H10O2 propyl ethanoate (propyl acetate) 109-60-4 134.90 202.20
164 C5H10O2 2-methylpropyl methanoate 542-55-2 136.60 217.00
(isobutyl formate)
165 C5H11Cl 1-chloropentane 543-59-9 200-1000 7.052 9.759 10.210 ⫺14.077 5.640 130.58
166 C5H12 pentane 109-66-0 200-1000 7.554 ⫺0.368 11.846 ⫺14.939 5.753 120.04 167.19
167 C5H12 2-methylbutane 78-78-4 200-1000 1.959 38.191 2.434 ⫺5.175 2.165 118.97 164.80
168 C5H12 2,2-dimethylpropane (neopentane) 463-82-1 200-1000 ⫺11.428 156.037 ⫺33.383 40.127 ⫺17.806 120.80 172.00
169 C5H12O 1-pentanol 71-41-0 200-1000 5.530 16.887 9.430 ⫺13.725 5.607 130.70 208.10
172 C5H12O 2-methyl-2-butanol 75-85-4 298-1000 4.282 27.248 6.649 ⫺10.683 4.474 131.69 247.9
173 C5H12O 3-methyl-1-butanol 123-51-3 211.00
174 C5H12O 3-methyl-2-butanol 598-75-4 245.90
175 C5H12O ethyl propyl ether 628-32-0 140.00 197.40
 Section C Ideal Gas and Liquid Heat Capacities. C ⬚p / R ⫽ a0 ⫹ a1T ⫹ a2T 2 ⫹ a3T 3 ⫹ a4T 4.
CpIG and Cpliq at 298.15 K, J mol⫺1 K⫺1 (Continued )

No. Formula Name CAS # Trange, K a0 a1 ⫻ 103 a2 ⫻ 105 a3 ⫻ 108 a4 ⫻ 1011 CpIG Cpliq
176 C5H12S 3-methyl-1-butanethiol (isopentyl 541-31-1 142.30 200.30
mercaptan)
177 C6Cl5F chloropentafluorobenzene 344-07-0 200-1000 2.994 74.969 ⫺8.448 4.889 ⫺1.177 158.30
178 C6F6 hexafluorobenzene 392-56-3 200-1000 2.531 75.268 ⫺8.410 4.845 ⫺1.166 155.38
180 C6F14 tetradecafluorohexane 355-42-0 200-1000 2.660 146.733 ⫺18.179 11.086 ⫺2.710 273.99
184 C6HF5 pentafluorobenzene 363-72-4 200-1000 1.197 72.572 ⫺7.369 3.676 ⫺0.718 143.02
185 C6H2F4 1,2,4,5-tetrafluorobenzene 327-54-8 200-1000 0.007 69.341 ⫺6.192 2.343 ⫺0.202 131.21
186 C6H5Cl chlorobenzene 108-90-7 200-1000 0.104 38.288 1.808 ⫺5.732 2.718 97.99 150.80
187 C6H6 benzene 71-43-2 50-1000 3.551 ⫺6.184 14.365 ⫺19.807 8.234 82.43 135.95
188 C6H6O phenol 108-95-2 50-1000 2.582 17.501 8.894 ⫺14.435 6.317 103.22
189 C6H7N benzeneamine (aniline) 62-53-3 50-1000 2.598 19.936 8.438 ⫺13.368 5.630 107.90 191.90
190 C6H7N 2-methylpyridine (2-picoline) 109-06-8 50-1000 4.156 2.699 12.517 ⫺17.424 7.163 100.17 158.40
191 C6H7N 3-methylpyridine (3-picoline) 108-99-6 50-1000 4.140 2.780 12.458 ⫺17.328 7.118 99.99 158.70

A.40
192 C6H7N 4-methylpyridine (4-picoline) 1108-89-4 50-1000 3.904 4.296 12.062 ⫺16.884 6.942 99.70 159.00
194 C6H10 cyclohexene 110-83-8 50-1000 3.874 ⫺0.909 14.902 ⫺19.907 8.011 101.49
195 C6H10O cyclohexanone 108-94-1 50-1000 4.416 ⫺1.248 17.367 ⫺23.640 9.595 116.19
197 C6H12 cyclohexane 110-82-7 100-1000 4.035 ⫺4.433 16.834 ⫺20.775 7.746 106.10 156.20
198 C6H12 methylcyclopentane 96-37-7 50-1000 5.379 ⫺8.258 17.293 ⫺21.646 8.263 109.50 158.70
199 C6H12 1-hexene 592-41-6 200-1000 6.303 12.352 10.258 ⫺14.272 5.708 130.83 183.30
200 C6H12 4-methylpent-1-ene 691-37-2 298-1000 ⫺1.326 65.625 ⫺3.560 0.514 0.176 126.59
201 C6H12O cyclohexanol 108-93-0 50-1000 3.239 21.585 10.322 ⫺14.762 5.885 128.06
202 C6H12O 2-hexanone (methyl butyl ketone) 591-78-6 200-1000 9.146 8.701 10.736 ⫺14.496 5.768 148.53 213.40
203 C6H12O 3-hexanone (ethyl propyl ketone) 589-38-8 200-1000 9.357 13.505 8.735 ⫺11.918 4.710 152.51 216.80
206 C6H12O 4-methyl-2-pentanone (methyl 108-10-1 147.40 209.60
isobutyl ketone)
207 C6H12O2 methyl pentanoate 624-24-8 155.80 229.30
208 C6H12O2 ethyl butanoate 105-54-4 154.60 255.70
209 C6H12O2 propyl propanoate 106-36-5 153.10 229.10
210 C6H12O2 ethyl 2-methylpropanoate 97-62-1 154.00 222.00
211 C6H12O2 butyl ethanoate (butyl acetate) 123-86-4 151.50 228.40
212 C6H12O2 2-methylpropyl ethanoate 110-19-0 154.30 241.10
(isobutyl acetate)
 213 C6H12O2 pentyl methanoate (pentyl 638-49-3 156.20 243.00
formate)
214 C6H12O2 3-methylbutyl methanoate 110-45-2 155.80 241.30
(isopentyl formate)
216 C6H14 hexane 110-54-3 200-1000 8.831 ⫺0.166 14.302 ⫺18.314 7.124 142.59 195.43
217 C6H14 2-methylpentane 107-83-5 200-1000 2.096 46.419 3.124 ⫺6.829 2.902 142.21 193.93
218 C6H14 3-methylpentane 96-14-0 200-1000 0.433 11.143 0.730 ⫺1.612 0.690 140.10 190.66
219 C6H14 2,2-dimethylbutane 75-83-2 200-1000 3.007 39.059 4.851 ⫺8.243 3.367 141.50 188.70
220 C6H14 2,3-dimethylbutane 79-29-8 200-1000 ⫺2.214 74.352 ⫺3.697 0.273 0.308 139.41 188.66
221 C6H14O 1-hexanol 111-27-3 200-1000 6.784 17.060 11.935 ⫺17.147 6.985 153.30 232.50
223 C6H14O 3-hexanol 623-37-0 269.30
224 C6H14O 2-methyl-1-pentanol 105-30-6 249.20
229 C6H15N N, N-diethylethanamine (triethyl 121-44-8 298-1000 4.581 40.089 5.793 ⫺10.032 4.193 161.00
amine)
231 C7F16 hexadecafluoroheptane 335-57-9 200-1000 3.002 170.245 ⫺21.365 13.301 ⫺3.341 316.03
232 C7H3F5 pentafluorotoluene 771-56-2 298-1000 6.079 48.333 0.158 ⫺3.861 1.948 164.30
234 C7H8 toluene 108-88-3 50-1000 3.866 3.558 13.356 ⫺18.659 7.690 103.75 157.29

A.41
235 C7H8O 2-methylphenol (o-cresol) 95-48-7 50-1000 3.123 31.032 6.152 ⫺10.805 4.642 127.30
236 C7H8O 3-methylphenol (m-cresol) 108-39-4 50-1000 2.876 26.142 8.544 ⫺14.238 6.189 124.68 225.02
237 C7H8O 4-methylphenol (p-cresol) 106-44-5 50-1000 2.881 27.407 7.943 ⫺13.423 5.843 124.97
238 C7H9N 2,3-dimethylpyridine (2,3 lutidine) 583-61-9 129.74 189.30
239 C7H9N 2,3-dimethylpyridine (2,3 lutidine) 108-47-4 50-1000 4.225 13.393 11.364 ⫺16.169 6.585 120.97 186.00
240 C7H9N 2,4-dimethylpyridine (2,4 lutidine) 589-93-5 50-1000 4.247 13.487 11.535 ⫺16.564 6.803 122.01 183.40
241 C7H9N 2,5-dimethylpyridine (2,5 lutidine) 108-48-5 50-1000 4.183 14.253 11.226 ⫺16.133 6.610 121.86 184.30
242 C7H9N 2,6-dimethylpyridine (2,6 lutidine) 583-58-4 50-1000 3.413 31.807 5.284 ⫺8.851 3.610 128.75 189.60
243 C7H9N 3,4-dimethylpyridine (3,4 lutidine) 591-22-0 50-1000 4.135 15.216 10.792 ⫺15.509 6.324 121.78 186.30
244 C7H14 3,5-dimethylpyridine (3,5 lutidine) 291-64-5 50-1000 3.995 5.299 17.971 ⫺24.179 9.665 132.01 200.00
247 C7H14 methylcyclohexane 108-87-2 50-1000 3.148 18.438 13.624 ⫺18.793 7.364 135.80 184.50
248 C7H14 ethylcyclopentane 1640-89-7 50-1000 5.847 ⫺0.048 17.507 ⫺22.495 8.656 133.60 186.60
249 C7H14 cis-1,3-dimethylcyclopentane 2532-58-3 298-1000 ⫺2.522 60.538 2.703 ⫺7.572 3.361 134.50 190.00
250 C7H14 trans-1,3-dimethylcyclopentane 1759-58-6 298-1000 ⫺2.522 60.538 2.703 ⫺7.572 3.361 134.50 190.90
251 C7H14 1-heptene 592-76-7 200-1000 7.520 12.824 12.670 ⫺17.578 7.035 153.46 211.8
253 C7H14O2 ethyl pentanoate 539-82-2 177.30 257.50
254 C7H14O2 ethyl 3-methylbutanoate 108-64-5 176.00 253.00
255 C7H14O2 propyl butanoate 105-66-8 175.80 257.20
 Section C Ideal Gas and Liquid Heat Capacities. C ⬚p / R ⫽ a0 ⫹ a1T ⫹ a2T 2 ⫹ a3T 3 ⫹ a4T 4.
CpIG and Cpliq at 298.15 K, J mol⫺1 K⫺1 (Continued )

No. Formula Name CAS # Trange, K a0 a1 ⫻ 103 a2 ⫻ 105 a3 ⫻ 108 a4 ⫻ 1011 CpIG Cpliq
256 C7H14O2 2-methylpropyl propanoate 540-42-1 179.50 268.00
257 C7H14O2 propyl 2-methylpropanoate 644-49-5 175.00 254.00
258 C7H14O2 3-methylbutyl ethanoate 123-92-2 173.50 265.40
(isopentyl acetate)
259 C7H16 heptane 142-82-5 200-1000 9.634 4.156 15.494 ⫺20.066 7.770 165.20 224.98
260 C7H16 2-methylhexane 591-76-4 200-1000 3.452 46.373 5.446 ⫺9.875 4.089 164.50 222.97
261 C7H16 3-methylhexane 589-34-4 163.60 221.25
262 C7H16 3-ethylpentane 617-78-7 200-1000 7.598 19.547 11.641 ⫺16.107 6.378 166.00 219.58
263 C7H16 2,2-dimethylpentane 590-35-2 200-1000 1.315 60.462 2.813 ⫺7.620 3.434 166.70 221.20
264 C7H16 2,3-dimethylpentane 565-59-3 200-1000 ⫺4.314 96.708 ⫺6.454 2.227 ⫺0.313 160.83 218.28
265 C7H16 2,4-dimethylpentane 108-08-7 200-1000 ⫺3.133 97.923 ⫺6.912 2.424 ⫺0.250 170.75 224.22
266 C7H16 3,3-dimethylpentane 562-49-2 200-1000 ⫺0.480 73.415 ⫺0.740 ⫺3.562 1.822 165.80 214.76
267 C7H16 2,2,3-trimethylbutane 464-06-2 200-1000 ⫺0.711 73.562 ⫺1.007 ⫺3.018 1.583 163.30 213.51

A.42
268 C7H16O 1-heptanol 111-70-6 200-1000 7.935 18.023 14.223 ⫺20.320 8.262 175.90 270.60
270 C7H16O 4-heptanol 589-55-9 317.60
271 C8F18 octadecafluorooctane 307-34-6 200-1000 3.352 193.679 ⫺24.528 15.491 ⫺3.962 358.07 429
273 C8H10 ethylbenzene 100-41-4 50-1000 4.544 10.578 13.644 ⫺19.276 7.885 127.40 185.96
274 C8H10 1,2-dimethylbenzene (o-xylene) 95-47-6 50-1000 3.289 34.144 4.989 ⫺8.335 3.338 132.31 188.07
275 C8H10 1,3-dimethylbenzene (m-xylene) 108-38-3 50-1000 4.002 17.537 10.590 ⫺15.037 6.008 125.71 188.44
276 C8H10 1,4-dimethylbenzene (p-xylene) 106-42-3 50-1000 4.113 14.909 11.810 ⫺16.724 6.736 126.02 181.66
277 C8H10O 2-ethylphenol 90-00-6 298-1000 ⫺2.392 82.472 ⫺4.476 ⫺0.434 0.890 151.16
278 C8H10O 3-ethylphenol 620-17-7 298-1000 ⫺4.029 90.167 ⫺5.877 0.702 0.546 148.54
279 C8H10O 4-ethyl-phenol 123-07-9 298-1000 ⫺3.628 88.368 ⫺5.660 0.616 0.548 148.83
280 C8H10O 2,3-dimethylphenol (2,3 xylenol) 526-75-0 164.10
281 C8H10O 2,4-dimethylphenol (2,4 xylenol) 105-67-9 50-1000 3.752 41.738 5.814 ⫺11.112 4.855 156.10
282 C8H10O 2,5-dimethylphenol (2,5 xylenol) 95-87-4 50-1000 3.008 50.507 2.960 ⫺7.548 3.351 157.09
283 C8H10O 2,6-dimethylphenol (2,6 xylenol) 576-26-1 50-1000 2.604 51.990 2.683 ⫺7.380 3.340 155.97
284 C8H10O 3,4-dimethylphenol (3,4 xylenol) 95-65-8 50-1000 1.407 67.846 ⫺1.345 ⫺3.401 1.952 163.52
285 C8H10O 3,5-dimethylphenol (3,5 xylenol) 108-68-9 50-1000 2.869 43.266 5.901 ⫺11.468 5.053 152.70
286 C8H16 cyclooctane 292-64-8 50-1000 4.236 13.119 16.313 ⫺21.072 7.987 146.19 215.50
287 C8H16 t-1,4-dimethylcyclohexane 2207-04-7 50-1000 3.902 20.058 15.345 ⫺20.707 7.974 155.19 210.3
288 C8H16 1-octene 111-66-0 200-1000 8.745 13.240 15.096 ⫺20.895 8.366 176.10 241.40
289 C8H16O2 octanoic acid 124-07-02 298
 296 C8H18 octane 111-65-9 200-1000 10.824 4.983 17.751 ⫺23.137 8.980 187.78 254.15
297 C8H18 2-methylheptane 592-27-8 200-1000 5.257 41.188 9.739 ⫺15.692 6.570 187.23 251.99
298 C8H18 3-methylheptane 589-81-1 185.80 250.20
299 C8H18 4-methylheptane 589-53-7 200-1000 2.182 62.828 4.419 ⫺10.021 4.358 187.02 251.08
300 C8H18 3-ethylhexane 619-99-8 200-1000 7.178 33.720 10.365 ⫺15.312 6.088 189.62 250.29
301 C8H18 2,2-dimethylhexane 590-73-8 200-1000 3.452 55.222 6.066 ⫺11.271 4.732 188.30 249.20
302 C8H18 2,3-dimethylhexane 584-94-1 200-1000 ⫺3.594 100.983 ⫺4.880 ⫺0.342 0.789 184.10 248.78
303 C8H18 2,4-dimethylhexane 589-43-5 200-1000 ⫺3.372 108.645 ⫺7.267 2.176 ⫺0.103 192.30 250.08
304 C8H18 2,5-dimethylhexane 592-13-2 200-1000 ⫺1.367 87.285 ⫺1.799 ⫺3.343 1.857 185.48 249.20
305 C8H18 3,3-dimethylhexane 563-16-6 200-1000 ⫺2.093 94.480 ⫺2.808 ⫺2.811 1.816 190.87 246.60
306 C8H18 3,4-dimethylhexane 583-48-2 200-1000 ⫺6.148 116.522 ⫺8.351 2.961 ⫺0.344 182.34 246.90
307 C8H18 3-ethyl-2-methylpentane 609-26-7 200-1000 ⫺0.873 95.193 ⫺5.319 1.180 0.000 192.05 248.91
308 C8H18 3-ethyl-3-methylpentane 1067-08-9 200-1000 ⫺1.350 88.584 ⫺1.961 ⫺3.139 1.789 187.99 245.89
309 C8H18 2,2,3-trimethylpentane 564-02-3 200-1000 ⫺4.490 108.022 ⫺6.486 1.441 0.142 185.64 245.39
310 C8H18 2,2,4-trimethylpentane (isooctane) 540-84-1 200-1000 0.384 77.059 0.665 ⫺5.565 2.619 188.41 238.55
311 C8H18 2,3,3-trimethylpentane 560-21-4 200-1000 ⫺5.726 117.939 ⫺8.940 4.012 ⫺0.816 187.02 245.56
312 C8H18 2,3,4-trimethylpentane 565-75-3 191.59 248.61

A.43
313 C8H18 2,2,3,3-tetramethylbutane 594-82-1 200-1000 0.768 72.950 1.659 ⫺6.322 2.886 187.19 279.10
314 C8H18O 1-octanol 111-87-5 200-1000 9.193 18.228 16.682 ⫺23.641 9.580 198.60 302.40
316 C8H18O 3-octanol 589-98-0 338.50
317 C8H18O 4-octanol 589-62-8 337.60
321 C9F20 eicosafluorononane 375-96-2 200-1000 3.697 217.163 ⫺27.706 17.697 ⫺4.589 400.11
322 C9H7N quinoline 91-22-5 194.90
324 C9H10 indan 496-11-7 190.30
325 C9H12 propylbenzene 103-65-1 50-1000 4.759 23.956 11.859 ⫺17.393 7.064 152.30 214.71
326 C9H12 1-methylethylbenzene (cumene) 98-82-8 50-1000 2.985 34.196 11.938 ⫺20.152 8.923 159.69 213.30
327 C9H12 1-ethyl-4-methylbenzene 622-96-8 50-1000 5.097 17.385 13.600 ⫺19.299 7.817 148.25 210.30
328 C9H12 1,2,3-trimethylbenzene 526-73-8 50-1000 4.042 31.152 10.185 ⫺16.262 6.922 155.07 216.10
329 C9H12 1,2,4-trimethylbenzene 95-63-6 50-1000 5.319 20.074 12.034 ⫺16.873 6.687 149.71 215.00
330 C9H12 1,3,5-trimethylbenzene 108-67-8 50-1000 5.305 20.039 11.606 ⫺16.317 6.503 147.63 209.10
(mesitylene)
331 C9H18 1-nonene 124-11-8 200-1000 9.963 13.704 17.511 ⫺24.203 9.694 198.74 271.20
333 C9H18O2 3-methylbutyl butanoate 106-27-4 221.40 320.40
334 C9H20 nonane 111-84-2 200-1000 12.152 4.575 20.416 ⫺26.777 10.465 210.41 284.45
335 C9H20 2-methyloctane 3221-61-2 200-1000 5.914 47.039 10.387 ⫺16.686 6.852 212.05 271.50
336 C9H20 2,2-dimethylheptane 1071-26-7 211.30 283.40
337 C9H20 2,2,5-trimethylhexane 3522-94-9 200-1000 ⫺0.880 92.152 ⫺0.423 ⫺5.261 2.601 208.11
338 C9H20 2,2,3,3-tetramethylpentane 7154-79-2 200-1000 ⫺6.019 131.511 ⫺9.916 4.520 ⫺0.934 209.80 284.20
 Section C Ideal Gas and Liquid Heat Capacities. C ⬚p / R ⫽ a0 ⫹ a1T ⫹ a2T 2 ⫹ a3T 3 ⫹ a4T 4.
CpIG and Cpliq at 298.15 K, J mol⫺1 K⫺1 (Continued )

No. Formula Name CAS # Trange, K a0 a1 ⫻ 103 a2 ⫻ 105 a3 ⫻ 108 a4 ⫻ 1011 CpIG Cpliq
339 C9H20 2,2,3,4-tetramethylpentane 1186-53-4 200-1000 ⫺5.422 123.507 ⫺8.031 2.590 ⫺0.261 207.30 252.70
340 C9H20 2,2,4,4-tetramethylpentane 1070-87-7 200-1000 3.621 67.875 4.875 ⫺10.109 4.292 214.94
341 C9H20 2,3,3,4-tetramethylpentane 16747-38-9 200-1000 ⫺9.189 161.921 ⫺17.927 12.689 ⫺3.869 218.30 275.70
342 C9H20O 1-nonanol 143-08-8 200-1000 10.350 19.105 19.007 ⫺26.878 10.891 221.20 334.20
344 C10F22 docosafluorodecane 307-45-9 200-1000 4.042 240.657 ⫺30.888 19.907 ⫺5.219 442.15
345 C10H8 naphthalene 91-20-3 50-1000 2.889 14.306 15.978 ⫺23.930 10.173 132.55
351 C10H14 butylbenzene 104-51-8 200-1000 6.490 19.080 15.665 ⫺22.059 8.887 173.86 243.39
352 C10H14 2-methylpropylbenzene 538-93-2 173.90 241.00
(isobutylbenzene)
353 C10H14 1,4-diethylbenzene 105-05-5 298-1000 ⫺0.359 75.371 0.442 ⫺5.736 2.783 176.15 239.10
354 C10H14 1-(1-methylethyl)-4- 99-87-6 173.70 237.70
methylbenzene ( p-cymene)
355 C10H14 1,2,4,5-tetramethylbenzene 95-93-2 298-1000 3.352 67.376 0.527 ⫺4.883 2.290 186.50

A.44
356 C10H18 cis-bicyclo[4.4.0]decane 493-01-6 298-1000 ⫺5.445 80.068 5.065 ⫺11.756 5.088 168.10 232.00
(cis-decalin)
357 C10H18 trans-bicyclo[4.4.0]decane 493-02-7 298-1000 ⫺2.155 53.852 12.610 ⫺20.981 9.066 168.60 228.50
(trans-decalin)
358 C10H20 1-decene 872-05-9 200-1000 11.175 14.222 19.908 ⫺27.488 11.012 221.97 300.3
360 C10H22 decane 124-18-5 200-1000 13.467 4.139 23.127 ⫺30.477 11.970 233.05 314.54
361 C10H22 2,2,5-trimethylheptane 20291-95-6 200-1000 ⫺0.961 100.294 0.237 ⫺6.883 3.357 229.20 306.40
362 C10H22 3,3,5-trimethylheptane 7154-80-5 200-1000 ⫺2.999 118.108 ⫺4.182 ⫺2.362 1.717 232.80 295.30
363 C10H22 2,2,3,3-tetramethylhexane 13475-81-5 200-1000 ⫺7.678 153.766 ⫺12.616 6.171 ⫺1.323 236.82
364 C10H22 2,2,5,5-tetramethylhexane 1071-81-4 200-1000 0.8 87.376 3.168 ⫺9.35 4.141 228.78
365 C10H22O 1-decanol 112-30-1 200-1000 11.637 19.130 21.517 ⫺30.271 12.247 243.80 366.00
367 C11H10 1-methylnaphthalene 90-12-0 298-1000 ⫺5.637 98.625 ⫺4.956 ⫺1.033 1.281 159.30 224.40
368 C11H10 2-methylnaphthalene 91-57-6 298-1000 ⫺4.671 93.882 ⫺4.334 ⫺1.331 1.317 154.60
369 C11H24 undecane 1120-21-4 255.69 345.05
370 C11H24O 1-undecanol 112-42-5 200-1000 12.923 18.973 24.124 ⫺33.816 13.675 267.24
371 C12H10 1,1⬘-biphenyl 92-52-4 200-1000 ⫺0.843 61.392 6.352 ⫺13.754 6.169 165.28 250.95
372 C12H12 1,6-dimethylnaphthalene 575-43-9 298-1000 ⫺4.332 103.947 ⫺4.556 ⫺1.769 1.571 185.10
373 C12H12 2,7-dimethylnaphthalene 582-16-1 298-1000 ⫺3.288 101.288 ⫺4.748 ⫺1.079 1.219 187.08
374 C12H18 1,3,5-triethylbenzene 102-25-0 298-1000 1.319 87.791 1.406 ⫺7.682 3.595 224.42
 376 C12H24 1-dodecene 112-41-4 200-1000 13.617 15.108 24.747 ⫺34.111 13.669 267.38 360.70
377 C12H26 dodecane 112-40-3 200-1000 17.229 ⫺7.242 31.922 ⫺42.322 17.022 278.33 375.47
378 C12H26O 1-dodecanol 112-53-8 200-1000 14.073 19.938 26.412 ⫺36.989 14.951 289.95
379 C13H12 diphenylmethane 101-81-5 266.10
380 C13H28 tridecane 629-50-5 200-1000 18.546 ⫺7.636 34.604 ⫺45.978 18.509 300.97 406.89
382 C14H10 phenanthrene 85-01-8 50-1000 2.374 38.372 16.471 ⫺26.813 11.640 185.16
383 C14H10 anthracene 120-12-7 50-1000 2.577 31.826 18.811 ⫺29.722 12.840 182.29
385 C14H30 tetradecane 629-59-4 200-1000 18.375 6.585 32.307 ⫺42.663 16.590 323.61 438.48
387 C15H32 pentadecane 629-62-9 200-1000 21.180 ⫺8.424 39.969 ⫺53.290 21.482 346.25 469.95
389 C16H34 hexadecane 544-76-3 200-1000 39.747 ⫺206.152 114.814 ⫺155.548 67.534 368.89 501.45
392 C17H36 heptadecane 629-78-7 200-1000 23.813 ⫺9.210 45.333 ⫺60.601 24.455 391.53 534.34
397 C18H38 octadecane 593-45-3 200-1000 25.130 ⫺9.603 48.015 ⫺64.256 25.942 414.17 564.45
399 C19H40 nonadecane 629-92-5 200-1000 26.447 ⫺9.998 50.697 ⫺67.912 27.428 436.81 595.94
401 C20H42 eicosane 112-95-8 200-1000 27.764 ⫺10.389 53.379 ⫺71.567 28.914 459.45 627.45
407 ClD deuterium chloride 7698-05-7 50-1000 3.917 ⫺3.965 1.205 ⫺1.323 0.521 29.17
408 ClFO3 perchloryl fluoride 7616-94-6 298-1000 0.470 36.338 ⫺4.796 3.147 ⫺0.83 64.93
410 ClH hydrogen chloride 7647-01-0 50-1000 3.827 ⫺2.936 0.879 ⫺1.031 0.439 29.17

A.45
413 Cl2 chlorine 7782-50-5 50-1000 3.0560 5.3708 ⫺0.8098 0.5693 ⫺0.15256 29.14
414 DH deuterium hydride 13983-20-5 50-1000 3.893 ⫺3.508 1.083 ⫺1.337 0.580 29.20
415 DI deuterium iodide 14104-45-1 50-1000 3.741 ⫺2.862 1.000 ⫺1.051 0.382 29.36
416 D2 deuterium 7782-39-0 50-1000 3.590 ⫺0.462 0.057 0.036 ⫺0.026 29.19
417 D2 deuterium, normal 800000-54-8 29.20
418 D2O deuterium oxide 7789-20-0 50-1000 4.274 ⫺3.465 1.376 ⫺1.482 0.568 34.26 84.35
419 D2S deuterium sulfide 13536-94-2 50-1000 4.290 ⫺3.944 1.974 ⫺2.268 0.872 36.13
420 D3N trideuteroammonia 13550-49-7 50-1000 4.090 ⫺3.243 2.367 ⫺0.264 0.961 38.23
422 FH hydrogen fluoride 7664-39-3 50-1000 3.901 ⫺3.708 1.165 ⫺1.465 0.639 29.14 52.00
423 FNO2 nitrogen dioxyfluoride 10022-50-1 298-1000 1.620 20.883 ⫺2.512 1.586 ⫺0.420 49.89
424 F2 Fluorine 7782-41-4 50-1000 3.347 0.467 0.526 ⫺0.794 0.330 31.30
428 F2O oxygen difluoride 7783-41-7 50-1000 3.437 5.527 0.502 ⫺1.453 0.735 43.31
433 F4S sulfur tetrafluoride 7783-60-0 298-1000 ⫺0.808 51.235 ⫺8.251 6.335 ⫺1.887 72.03
437 HI hydrogen iodide 10034-85-2 50-1000 3.648 ⫺1.392 0.389 ⫺0.326 0.110 29.16
438 H2 hydrogen 1333-74-0 50-1000 2.883 3.681 ⫺0.772 0.692 ⫺0.213 28.84
439 H2 hydrogen, normal 800000-51-5 28.83
440 H2O water 7732-18-5 50-1000 4.395 ⫺4.186 1.405 ⫺1.564 0.632 33.58 75.29
441 H2S hydrogen sulfide 7783-06-4 50-1000 4.266 ⫺3.438 1.319 ⫺1.331 0.488 34.12 74.68
 Section C Ideal Gas and Liquid Heat Capacities. C ⬚p / R ⫽ a0 ⫹ a1T ⫹ a2T 2 ⫹ a3T 3 ⫹ a4T 4.
CpIG and Cpliq at 298.15 K, J mol⫺1 K⫺1 (Continued )

No. Formula Name CAS # Trange, K a0 a1 ⫻ 103 a2 ⫻ 105 a3 ⫻ 108 a4 ⫻ 1011 CpIG Cpliq
442 H2S2 dihydrogen disulfide 13465-07-1 50-1000 3.364 8.093 0.636 ⫺1.991 1.048 49.21 92.74
443 H2S3 dihydrogen trisulfide 13845-23-3 123.42
444 H2S4 dihydrogen tetrasulfide 13845-25-5 154.10
445 H2S5 dihydrogen pentasulfide 13845-24-4 184.78
447 H3N ammonia 7664-41-7 50-1000 4.238 ⫺4.215 2.041 ⫺2.126 0.761 35.65 83
449 H4N2 hydrazine 302-01-2 50-1000 3.627 2.239 2.876 ⫺4.060 1.690 49.12 96.8
450 He helium 9440-59-7 — 2.500 0.000 0.000 0.000 0.000 20.79
451 He helium-3 14762-55-1 — 2.500 0.000 0.000 0.000 0.000 20.79
452 I2 iodine 7553-56-2 50-1000 3.508 6.303 ⫺1.461 1.470 ⫺0.531 36.88

A.46
453 Kr krypton 7439-90-9 — 2.500 0.000 0.000 0.000 0.000 20.79
454 NO nitrogen monoxide (nitric oxide) 10102-43-9 50-1000 4.534 ⫺7.644 2.066 ⫺2.156 0.806 29.87
455 N2 nitrogen 7727-37-9 50-1000 3.539 ⫺0.261 0.007 0.157 ⫺0.099 29.12
456 N2O dinitrogen oxide (nitrous oxide) 10024-97-2 50-1000 3.165 3.401 0.989 ⫺1.880 0.890 38.64
457 N2O4 dinitrogen tetroxide (nitrogen 10544-72-6 50-1000 3.374 27.257 ⫺1.917 ⫺0.616 0.859 81.07 142.2
dioxide)
458 Ne neon 7440-01-9 — 2.500 0.000 0.000 0.000 0.000 20.79
459 OT2 tritium oxide 14940-65-9 34.96
460 O2 oxygen 7782-44-7 50-1000 3.630 ⫺1.794 0.658 ⫺0.601 0.179 29.38
461 O2S sulfur dioxide 7446-09-5 50-1000 4.417 ⫺2.234 2.344 ⫺3.271 1.393 40.05
462 O3 ozone 10028-15-6 50-1000 4.106 ⫺3.809 3.131 ⫺4.300 1.813 39.60
463 O3S sulfur trioxide 7446-11-9 50-1000 3.426 6.479 1.691 ⫺3.356 1.590 50.86 226.8
464 Rn radon 10043-92-2 — 2.500 0.000 0.000 0.000 0.000 20.79
465 S sulfur 7704-34-9 50-1000 2.803 ⫺0.036 0.143 ⫺0.435 0.268 23.67
467 T2 tritium 10028-17-8 29.20
468 Xe xenon 7440-63-3 — 2.500 0.000 0.000 0.000 0.000 20.79