Hydrolysis of Sucrose Into Glucose and Fructose Is Known As

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NEET

REVISION SERIES

BIOMOLECULES

Revise Most Important Questions to Crack NEET 2020

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Q-1 - 14535250

Hydrolysis of sucrose into ( + ) glucose and ( − ) fructose is

known as.

(A) Muta rotation

(B) Inversion

(C) Pyrolysis

(D) None of these

CORRECT ANSWER: B

SOLUTION:

Hydrolysis of sucrose (dextrorotatory) into ( + ) glucose


and ( − ) fructose gives overall levorotatory mixture of

products, hence the process is known as "inversion of

surgar".

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Q-2 - 19094680

Chiral C-atoms in glucose and fructose are :

(A) 4 in each

(B) 3 in each

(C) 4 in glucose

(D) 3 in glucose and 4 in fructose

CORRECT ANSWER: C

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Q-3 - 13168617

The enzyme that converts cane sugar into invert sugar (a mixture of

glucose and fructose) is

(A) maltase

(B) diastase

(C) invertase

(D) zymase

CORRECT ANSWER: C

SOLUTION:

The sugar in mlasses , sugarcane or fruits such as

grapes is converted to glucose and fructose (both of

which have the formula C6 H12 O6 ) in the presence of

an enzyme, invertase.
C12 H22 O11 + H2 O
Sucrose
Invertase
−−−−→ C6 H12 O6
Glucose
+ C6 H12 O6
Fructose

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Q-4 - 19124593

How many of the following are used as atificial sweetners?

Sucrose, Sucrolose, D fructose, D glucose, Aspartame, Alitame

CORRECT ANSWER: 4

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Q-5 - 11486976

The correct statement(s) about the following sugars (X) and


(Y )is / are:

(A) (X) is a reducing sugar and (Y ) is a non-reducing

sugar.

(B) (X) is a non-reducing sugar and (Y ) is a reducing

sugar.

(C) The glucosidic linkage in (X) and (Y ) are α and β ,

respectively.
(D) The glucosidic linkages in (X) and (Y ) are β and α,

respectively.

CORRECT ANSWER: B::C

SOLUTION:

In ' X' the glycosidic linkage is between two anomeric

C atoms, while in Y it is only with one anomic carbon,

the other one is free. So, ' X' will be non-reducing while

' Y ' will be reducing. Again the glycosidic linkage in X

is between α − fuctose, in Y , one of the glucose units is

α.

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Q-6 - 14535370
The correct statement about the sugars given above are

(A) I and II are L-Sugars

(B) II and III above D-Sugar

(C) I and II and D-sugars

(D) I is L-sugar

CORRECT ANSWER: B::D

SOLUTION:

I is L-sugar whereas II & III is D-sugar.

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Q-7 - 11486862
Which of the statements are correct about D, L of sugars and amino

acids.

(A) In sugars, symbols D and L refer to the relative

configuration of the OH groups at the penultimate C

atom w.r.t. to glyceraldehyde taken as standard. D refers

to ( − OH) group on R.H.S. and L refres to OH group

on L.H.S.

(B) In amino acids, symbols D and L refer to the relative

configuration of the (NH2 ) group w.r.t. D (+) serine

taken as standard [D (+) Serine].

(C) D refers to NH2 group on R.H.S. and L refers to

( − NH 2 ) group on L.H.S.
(D) In sugars, d refers to dextrorotatory and L refers to

laevoratotory.

CORRECT ANSWER: A::B

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Q-8 - 19103341

Which set of terms correctly identifies the carbohydrate shown ?

(1) Pentose , (2) Pentulose, (3) Hexulose , (4) Hexose

(5) Aldose, (6) Ketose, (7) Pyranose , (8) Furanose


(A) 2,6,8

(B) 2,6,7

(C) 1,5,8

(D) A set of terms other than these

CORRECT ANSWER: A

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Q-9 - 11486877

Which carbohydrate is an essential contituent of plant cells?

(A) Starch

(B) Cellulose

(C) Sucrose

(D) Vitamins
CORRECT ANSWER: B

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Q-10 - 12580727

To become a carbohydrate, a compound must contain at least:

(A) 6 carbons

(B) 3 carbons

(C) 4 carbons

(D) 2 carbons

CORRECT ANSWER: B

SOLUTION:

Monosaccharides of 3 to 9 carbon atom are known.

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Q-11 - 15202312

The two function groups present in a typical carbohydrate are

(A) − OH and − COOH

(B) − CHO and − COOH

(C) > C = O and − OH

(D) − OH and − CHO

CORRECT ANSWER: D

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Q-12 - 12580678

The two forms of `D-glucopyranose obtained from solution of D-

glucose are known as:

(A) anomers
(B) epumers

(C) enantiomers

(D) geometrical isomers

CORRECT ANSWER: A

SOLUTION:

The D-glucose exists as α − D( + )-glucose and

β − D( + )- glucose which differ only at C1 position of

OH and called anomers.

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Q-13 - 12979673

In an aqueous solutions of D − glucose the percentages of α and β

anomers at the equilibrium condition are respectively

(A) 64 % and 36 %
(B) 20 % and 80 %

(C) 36 % and 64 %

(D) 80 % and 20 %

CORRECT ANSWER: C

SOLUTION:

The α and β − D − glucose have different specific

rotations. When either anomer is dissolved in water their

rotation change until the same fixed value results. This

rotation change is called mutarotation.

The α and β − D − glucose are each in equilibrium

with the open chain aldehyde form and therefore with

each other.
α − D − Glucose
⇔ aldehyde ⇔ β
form
− D − Glucose
As each anomer begins to establish this equilibrium, its

specific rotation changes. When equilibrium is reached,

the experimentaly determined rotation remains constant.

A base such as NaOH catalyzes the attainment of the

equilibrium. Assuming that the concentration of the

open-chain form is negligible, one can, by use of the

specific rotations, calculate the precentage of the α and

β anomers, respectively Let a and b be the mole

fractions of the α − and β − anomers, respectively.

Solving the simultaneous equations

a + b = 1

112a + 18.7b = 52.7

gives

a × 100 % = 36 %

b × 100 % = 64 %

Note that these percentages, 36 % α anomer and

64 % β − another are in accord with a greater stability


for β − D − ( + ) − glucopyranose. The preference

is (what we might expect) on the basis of its having only

equatorial groups.

However the β- anomer of a pyranose is not always the

more stabel. With D- mannose, the equilibrium favours

the α − anomer, and this result is called an anomeric

effect.

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Q-14 - 15603091

Which of the following bases is not present in DNA ?

(A) Quinoline

(B) Adenine

(C) Cytosine

(D) Thymine
CORRECT ANSWER: A

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Q-15 - 15603096

Which of the following pairs give positive Tollen's test ?

(A) Glucose, sucrose

(B) Glucose, fructose

(C) Hexanal, acetophenone

(D) Fructose, sucrose

CORRECT ANSWER: B

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Q-16 - 15603105
The total number of basic groups in the following form of lysine is

CORRECT ANSWER: 2

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Q-17 - 12581050

How many amino acids are present in the following polypeptide

chain ?

(A) 2
(B) 4

(C) 7

(D) 9

CORRECT ANSWER: B

SOLUTION:

Leucine, cysteine , tyrosine and glutamic acid total 4

amino acids form the given polypeptide chain.

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Q-18 - 11486897

Among the following the achiral amino acid is:

(A) Ethylalanine

(B) Methylglycine
(C) 2-Hydroxymethylserine

(D) Tryptophan

CORRECT ANSWER: C

SOLUTION:

It does not contain a chiral centre


CH2 OH

HOH2 C − C

NH2
− COOH
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Q-19 - 11486969

Statement I: Thymine occures in RN A.

Statement II: RNA controls the synthesis of proteins.

(A) Statement I is true, Statement II is true, Statements


II is the correct explanation of Statement I .

(B) Statement I is true, Statement II is true, Statement

II is not the correct explanation of Statement I .

(C) Statement I is true, Statement II is false.

(D) Statement I is false, Statement II is true.

CORRECT ANSWER: D

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Q-20 - 12580730

Which of the following α-amino acids is not optically active?

CORRECT ANSWER: B

SOLUTION:

Glycine H2 N − CH2 − COOH is optically inactive.


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Q-21 - 11486932

One of the different amino acids which can be synthesised in the

body is:

(A) lysine

(B) Histidine

(C) Valine

(D) Alanine

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Q-22 - 11486964

Statement I: All enzymes are protiens but all proteins are not

enzymes.
Statement II: Enzymes are biocatalysts and have stable

configuration having an active site.

(A) Statement I is true, Statement II is true, Statements

II is the correct explanation of Statement I .

(B) Statement I is true, Statement II is true, Statement

II is not the correct explanation of Statement I .

(C) Statement I is true, Statement II is false.

(D) Statement I is false, Statement II is true.

CORRECT ANSWER: A

SOLUTION:

Both the statements are correct and statement II is the

correct explantion of Statement I .

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Q-23 - 12580747

Peptides are formed by the joining of amino acids through amide

linage. Which of the following statement is not true in this respect?

(A) Amide groups do not contribute in the hydrogen

bonding interactions

(B) pπ resonance stabilizes the amide linkages

(C) Amide groups are more resistant to hydrolysis than

similar ester groups

(D) Stable conformations of peptides are restricted to

those having planar amide groups

CORRECT ANSWER: A

SOLUTION:

Hydrogen bonding plays an important role in the


secondary structure of proteins. These are formed

between amide groups of two chains.

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Q-24 - 19094685

Which of the following is an amino acid?

(A) H2 N − COOH

(B)
CH 3 − C H

CONH2
− COOH
O
∣∣
(C) NH2 − C − COOH

(D)
CORRECT ANSWER: D

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Q-25 - 12003319

Isoelectric point is defined as the pH at which:

(A) an amino acid becomes acidic

(B) an amino acid becomes basic

(C) zwitterio has positive charge

(D) zwitterion has zero charge

CORRECT ANSWER: D

SOLUTION:

Isoelectric point is the condition, where zwitterions or sol

particles do not move under the influence of electric


field, i.e., they lose their charge.

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Q-26 - 11486949

The pH value of the solution in which a particular amino acid does

not migrate under the influence of electric field is called the:

(A) Eutectic point

(B) Neutralisation point

(C) Effusion point

(D) Isoelectric point

CORRECT ANSWER: D

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Q-27 - 19103315
The pKa values for the three ionizable groups X, Y and Z of

glutamic acid are 4.3, 9.7 and 2.2 respectively


H O2 C − CH2 − CH
X ∣
+ NH 3
− CO2 H
Z

The isoelectric point for the amino acid is :

(A) 7.00

(B) 3.25

(C) 4.95

(D) 5.95

CORRECT ANSWER: B

SOLUTION:

4.3 + 2.2
In acidic medium = 3.25
2
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Q-28 - 14535331

The specific rotation of two glucose anomers are α = + 110 and

β = 19 and for the constant equilibrium mixtures is +52.7 .

Calculate the percentage compositions of the anomers in the

equilibrium mixture.

CORRECT ANSWER: ALP HA − ANOMER

= 37.2 % , BET A − ANOMER = 62.8 % .

SOLUTION:

Suppose % composition of α = x %

Suppose, % composition of β = 100 − x

∴ Optical rotation of equimixture


(x × 110)
+ (110 − x)19
=
100
= 52.7

∴ x = 37.2 %

∴ % for α = 37.2

∴ % for β = 62.8.

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Q-29 - 12580726

The change in optical rotation with time of freshly prepared solution

of sugar is known as :

(A) specific rotation

(B) inversion

(C) rotatory motion


(D) mutarotation

CORRECT ANSWER: B

SOLUTION:

Sugar undergoes hydrolysis, rotation `prop amount of

sugar. Thus,rotation decreases with time.

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Q-30 - 19103355

Stereoisomers of aldoheptose is (a) and stereoisomers of

ketoheptose is (b). Ratio of a/b is :

1
(A)
2
2
(B)
1
4
(C)
1
1
(D)
4

CORRECT ANSWER: B

SOLUTION:
5
2
4
2
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Q-31 - 14535498

Draw fisher projections for the two D-aldoheptose whose

stereorientation at C2 , C3 , C4 , C 5 is same as that of D − glucose at

C2 , C3 , C4 and C5 .

CORRECT ANSWER:
(#
#RESO RGC HMV 02X IIC 04E 01253 _ A01##)

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Q-32 - 19103235

Which of the following pair is C2 -epimer?

(A) D-Glucose, D-Maltose

(B) D-Glucose,D-Mannose

(C) D-Allose,D-Ribose

(D) D-Glucose,D-Arabinose

CORRECT ANSWER: B

SOLUTION:

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Q-33 - 11486890

Which statement is incorrect about the peptide bond?

(A) (C − N) bond length in proteins is longer than the

usual bond length of (C − N) bond,

(B) Spectroscopic analysis shows planar structure of

(CO − NH) group.

(C) (C − N) bond length in proteins is smaller than

usual bond length of (C − N) bond.

(D) None of the above.\

CORRECT ANSWER: A

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Q-34 - 19103373
Which of the following carbohydrate (s) would not undergo

mutarotation in aqueous solution ?

(A) II only

(B) I, III and IV only (c)

(C) II and IV only

(D) I and III only

CORRECT ANSWER: C

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Q-35 - 12660162

Which one of the following statements is incorrect about enzyme

catalysis?
(A) Enzymes are denatured by ultraviolet rays and at

high tempetaure.

(B) Enzymes are least reactive at optimum temperature.

(C) Enzymes are mostly proteinous in nature.

(D) Enzyme action is specific.

CORRECT ANSWER: B

SOLUTION:

Enzymes are least reactive at optimum temperature.

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Q-36 - 11486894

The reason for double helical structure of DNA is the operation of:

(A) Electrostatic attractions


(B) van der Waals forces

(C) Dipole-dipole interactions

(D) Hydrogen bonding

CORRECT ANSWER: D

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Q-37 - 12580758

DNA multiplication is called:

(A) translation

(B) transduction

(C) replication

(D) transcrption

CORRECT ANSWER: C
SOLUTION:

The genetic information of the cell is contained in the

sequance of the base, AT , G and C in DNA molecule.

When a cell divides DN A molecules replicate and

make exact copies of themselves so that each daughter

cell will have DN A identical to that of the parent cell.

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Q-38 - 11486919

Thymine is:

(A) 5 − Methyluracil

(B) 4 − Methyluracil

(C) 3 − Methyluracil

(D) 1 − Methyluracil
CORRECT ANSWER: A

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Q-39 - 12979765

The number of hydrogen bonds formed between adenine and

thymine and that formed between guanine and cytosine are

respectively

(A) 3 and 2

(B) 2 and 3

(C) 2 and 2

(D) 3 and 3

CORRECT ANSWER: B

SOLUTION:
DNA consists of two polynucleotide stands coiled

aroung each other in a helix. The sugar - phosphate

backbone is on the outside of the helix, and the amine

bases are on the inside, so that a base on one strand

points directly in towards a base on the second strand.

The two strands run in opposite directions and are held

together by hydrogen bond between pairs bases.

Adenine (A) and thymine (T ) form two strong hydrogen

bonds to each other, but not to G or C while G and C

form three strong hydrogen bonds to each other, but not

to A or T . As a result, sample of DNA having more

GC content has higher melting temperature (Tm ).

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Q-40 - 12979850

In DN A, the complementary bases are:


(A) Uracil and adenine, cytosine and guanine

(B) Adenine and thymine, guanine and cytosine

(C) Adenine and thymine, guanine and uracil

(D) Adenine and guanine, thymine and cytosine

CORRECT ANSWER: B

SOLUTION:

DNA is a dimeric polymer, in which two polynucleotide

chains are entwined in a double helix On hydrolysis, it is

found that although the ratio of bases vary from on

DNA to another, the ratios of C : G and A : T are

always 1 : 1 (or C = G and A = T ) because the C and

A in one strand always matches the G and T

respectively in the other strand. This matching is called

base-pairing which occurs by H-conding with maximum


efficiency between a pyrimidine and a purine base,

specifically between A and T and between C and G.

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Q-41 - 11486909

An alteration in the base sequence of nucleic acid molecule is:

(A) Relication

(B) Mutation

(C) Duplication

(D) Dislocation

CORRECT ANSWER: B

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Q-42 - 11486837
Which of the following statements are correct about α-amino acids.

(A) All the amino acids which constitute proteins have D-

configuration.

(B) Isoelectric point of glycine is 6.1.

(C) Valine is an essential amino acid

(D) In α-amino acids, the basic group is ( − COO Θ )



and acidic groups is ( − N H3 ).

CORRECT ANSWER: B::C::D

SOLUTION:

All statements are self-explanatory.

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Q-43 - 12581122
α − amino acids are

(A) acidic due to − COOH group and basic due to

− NH2 group

+
(B) acidic due to − NH3 group and basic due to

− COO − group.

(C) neither acidic nor basic

(D) none is true.

CORRECT ANSWER: B

SOLUTION:

Amino acis exist as Zwitterions in which acidic character


+ −
is due to − NH3 and basic due to − COO group.
R
+ ∣
H3 N C HCOOH
R
acid + ∣
−−→ H3 N C CHCOO −
R
acid ∣
−−→ H2 N C HCOO −
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Q-44 - 11486849

Which statements(s)is / are correct about sucrose?

(A) (C1 − α)(OH) of glucopyranose is linked with

(C2 ( − β ) ( OH ) of fructofuranose.

(B) (C1 − α)(OH) of glucopyranose is linked with

(C 2 − β)(OH) of fructopyranose.

(C) It reduces Fehling's solution.

(D) It exhibits mutarotation.


CORRECT ANSWER: A

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Q-45 - 15202390

Glycosidic linkage is present in

(A) sucrose

(B) Starch

(C) glucose

(D) fractose

CORRECT ANSWER: A::B

SOLUTION:

Glycosidic linkage is used to connect two monomer unit

(monosaccharide) in a linear polymer.

Glucose and fructose are mono saccharide so in which

no glysidic linkage is/are present. Sucrose is

disaccharide while starch is a linear polymer of glucose

so in both glycosidic linkage is present

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Q-46 - 12979838

Which one of the following sets of monosaccharides forms sucrose

?
(A) α − D − Galactopyranose and α − D −

Glucopyranose

(B) α − D − Glucopyranose and β − D −

fructofuranose

(C) β − D − Glucopyranose and β − D

fructofuranose

(D) α − D − Glucopyranose and β − D −

fructopyranose

CORRECT ANSWER: B

SOLUTION:

Acid-catalysed hydrolysis of 1 mol of surose

(C 12 H22 O11 ) yields 1 mol of D-glucose and 1 mol of an

osazone and does not undergo nonreducing sugar, it

does not form mean that neither the glucose nor the
fructose portion of sucrose has a hemiacetal group.

Thus, two hexoses must have a glycoside linkage that

involes C1 of glucose and C2 of fructose, because only

in this way will both carbonyl groups be present as full

acetals (i.e., as glycodies).

Surcose is hydrolysed by an α-glucosidase obtained

from yeast but not by β − glycosidase enzymes. This

hydrolysis indicates and α configuration at the

glycosides portion. Sucrose is aslo hydrolysed by

sucrase, and enzymes known to hydrolysis β-

fructofuranosides yields an octamethyl derivative that, on

hydrolysis, yields 2.,3,4,5,6-tetra − O − methyl-D-

fructose. The identities of these two products

demonstrate that the glucose portion is a pyranoside and

that the fructose portion is a furanoside.

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Q-47 - 14535249

Sucrose on hydrolysis yields a mixture which is.

(A) optically inactive

(B) dextrorotatory

(C) laevorotatory

(D) racemic

CORRECT ANSWER: C

SOLUTION:

(Sucrose, → , Gulose,
+ , Fructose),
( + 65 , , + 52.5 , ,

− 90 □ )
the products mixture is overall laevorotatary.

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Q-48 - 15202330

Naturally occuring (+)- sucrose

(A) α − D − glucopyronoside-β − D −

fructofuranoside

(B) α − D − glucopyronoside− α − D −

fructofuranoside

(C) β − D − glucopyronoside− α − D −

fructofuranoside

(D) β − D − glucopyronoside− β − D −

fructofuranoside

CORRECT ANSWER: A
SOLUTION:

( + ) − sucrose is

α − D glucopyronoside − β − D fructofuranoside

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Q-49 - 11486860

Globular proteins are present in:

(A) Eggs

(B) Muscles

(C) Keratin

(D) Blood
CORRECT ANSWER: A::D

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Q-50 - 11486870

Glucose reacts wih acetic anhydride to form:

(A) Monoacetate

(B) Tetra-acetate

(C) Penta-acetate

(D) Hexa-acetate

CORRECT ANSWER: C

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Q-51 - 11486876
Vitamin A is called:

(A) Ascorbic acid

(B) Retinol

(C) Calciferol

(D) Tocopherol

CORRECT ANSWER: B

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Q-52 - 11486908

Carbohydrates are stored in human body as the polysaccharide:

(A) Starch

(B) Glucose

(C) Glycogen
(D) Galactose

CORRECT ANSWER: C

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Q-53 - 11486912

In both DNA and RNA, the heterocyclic base and phosphate ester

linkages are at:

(A) C5 and C2 , respectively, of the sugar molecule.

(B) C2 and C5 , respectively, of the sugar molecule.

(C) C1 and C5 , respectively, of the sugar molecule.

(D) C5 and C1 , respectively, of the sugar molecule.

CORRECT ANSWER: C

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Q-54 - 14535283

The pentose sugar in DN A and RNA has the :

(A) Open chain structure

(B) Pyranose structure

(C) Furanose structure

(D) None of the above

CORRECT ANSWER: C

SOLUTION:

The pentose sugar in DNA and RNA has the

furanose structure.

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Q-55 - 12580744
Which of the following statements is true for protein synthesis

(translation)?

(A) Amino acids are directly recognize by m − RNA

(B) The third base of the codon is less specific

(C) Only one condon codes or an amino acid

(D) Every t − RNA molecules has more than one

amino acid attachment

CORRECT ANSWER: A

SOLUTION:

Protien synthesis or translation is the process by which

the genetic message in DNA that has been passed to

m RNA is decoded analysed for build proteins (i.e.,

amino acids)

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Q-56 - 11486928

The pyrimidine bases present in DN A are:

(A) Cytosine and adenine

(B) Cytosine and gunine

(C) Cytosine and thymine

(D) Cytosine and uracil

CORRECT ANSWER: C

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Q-57 - 11486935

Which of the following is a female sex hormone?

(A) Adrenaline
(B) Esterone

(C) Cortisone

(D) Testosterone

CORRECT ANSWER: B

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Q-58 - 11486939

To separate a mixture of monosacharides, you would use

(A) Centrifuge

(B) Chromatograph

(C) Mass spectometer

(D) Electrolytic cell

CORRECT ANSWER: B
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Q-59 - 11486952

If the sequence of bases in one strand of DNA is ATGACT GTC

then the sequence of bases in its complementary strands is:

(A) T ACT GACAG

(B) T UCT GUCCUG

(C) GUAGT UAUG

(D) None of the above

CORRECT ANSWER: A

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Q-60 - 11486925

The efficiency of an enzyme to catalyse a reacrtion is due to its


capacity to:

(A) Reduced the activation energy of the reaction.

(B) Form strong enzyme-substrate complex.

(C) Decrease the bond energies of all the substrate

molecules.

(D) Increase the free energy of the catalyst-substrate

reaction.

CORRECT ANSWER: A

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