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SAFETY DATA SHEET

CEMAX 415

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CEMAX 415

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Cement Grinding Aid & Performance Enhancer.

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number

Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318 STOT RE 2 - H373

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H315 Causes skin irritation.

H318 Causes serious eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements P260 Do not breathe vapour/ spray.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.
P501 Dispose of contents/ container in accordance with national regulations.

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Contains TRIETHANOLAMINE (TEA), TRIISOPROPANOLAMINE, Diethylene Glycol Polyester Grade,

DIETHANOLAMINE

Supplementary precautionary P264 Wash contaminated skin thoroughly after handling.

statements P310 Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

TRIETHANOLAMINE (TEA) 10-30%

CAS number: 102-71-6 EC number: 203-049-8 REACH registration number: 01-
2119486482-31-XXXX

Classification
Eye Irrit. 2 - H319

TRIISOPROPANOLAMINE 10-30%
CAS number: 122-20-3

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319

Diethylene Glycol Polyester Grade 10-30%

CAS number: 111-46-6 EC number: 203-872-2

Classification
Acute Tox. 4 - H302
STOT RE 2 - H373

DIETHANOLAMINE 1-5%
CAS number: 111-42-2 EC number: 203-868-0 REACH registration number: 01-
2119488930-28-XXXX

Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
STOT RE 2 - H373
Aquatic Chronic 3 - H412

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

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General information Take off all contaminated clothing immediately. When symptoms persist or in all cases of
doubt seek medical advice.

Inhalation Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Ensure supply of fresh air.
Maintain an open airway. Get medical attention if any discomfort continues.

Ingestion Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person.
Do not induce vomiting. Remove affected person from source of contamination. Place
unconscious person on their side in the recovery position and ensure breathing can take
place. Keep affected person warm and at rest. Maintain an open airway. Obtain medical
attention.

Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water or use an
approved skin cleanser. Get medical attention promptly if symptoms occur after washing.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause discomfort.

Skin contact May cause skin irritation.

Eye contact Eye contact may cause serious and potentially irreversible injuries.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish fires using foam, dry powder, carbon dioxide, sand or earth.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards Water used for fire extinguishing, which has been in contact with the product, may be
corrosive. No unusual fire or explosion hazards noted.

Hazardous combustion No known hazardous decomposition products.

products

5.3. Advice for firefighters

Protective actions during No specific firefighting precautions known.
firefighting

Special protective equipment Use protective equipment appropriate for surrounding materials.
for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with eyes and prolonged skin contact. Do not touch or walk into spilled material.

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6.2. Environmental precautions

Environmental precautions Collect and dispose of spillage as indicated in Section 13. Do not discharge into drains or
watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Collect and dispose of
spillage as indicated in Section 13.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid contact with skin and eyes. Mechanical ventilation or local exhaust ventilation may be
required. Do not eat, drink or smoke when using this product.

Advice on general Wash hands and any other contaminated areas of the body with soap and water before
occupational hygiene leaving the work site.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
TRIETHANOLAMINE (TEA)
Long-term exposure limit (8-hour TWA): ACGIH/TLV:0.1 mg/m3 res
TLV - Threshold Limit Value 5 mg/m³
Diethylene Glycol Polyester Grade
Long-term exposure limit (8-hour TWA): WEL 23 ppm 101 mg/m³
Short-term exposure limit (15-minute): WEL
DIETHANOLAMINE
Long-term exposure limit (8-hour TWA): TWA 0,46 ppm 2 mg/m3
WEL = Workplace Exposure Limit

TRIISOPROPANOLAMINE (CAS: 122-20-3)

DNEL Workers - Inhalation; Long term systemic effects: 86 mg/m³

Workers - Dermal; Long term systemic effects: 50 mg/kg bw/day
General population - Inhalation; Long term systemic effects: 21 mg/m³
General population - Dermal; Long term systemic effects: 25 mg/kg bw/day
General population - Oral; Long term systemic effects: 9.7 mg/kg bw/day

PNEC Aqua - Fresh water; 0.71 mg/l

Aqua - marine water; 0.071 mg/l

DIETHANOLAMINE (CAS: 111-42-2)

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DNEL Workers - Inhalation; Long term local effects: 1 mg/m³

Workers - Dermal; Long term systemic effects: 0.13 mg/kg/day

PNEC - Fresh water; 0.0022 mg/l

- marine water; 0.00022 mg/l
- STP; 100 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Personal protection Wash hands and any other contaminated areas of the body with soap and water before
leaving the work site.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield. (conform EN 166)

Hand protection Nitrile gloves are recommended.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Do not eat, drink or smoke when using this product.

Respiratory protection No specific recommendations.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Colourless to light brown liquid

Odour Pungent.

Initial boiling point and range 100°C

Relative density ~ 1.08

Solubility(ies) Completely soluble in water.

Explosive properties Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information None known

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Reacts with: Strong alkalis.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

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Possibility of hazardous Reacts with alkalis and generates heat.

reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Alkali metals.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 3,846.15

Inhalation May cause coughing and difficulties in breathing.

Ingestion May be harmful if swallowed and enters airways.

Skin contact May cause serious chemical burns to the skin.

Eye contact Eye contact may cause serious and potentially irreversible injuries.

Toxicological information on ingredients.

TRIISOPROPANOLAMINE

Acute toxicity - oral

Notes (oral LD₅₀) LD₅₀ 6500 mg/kg bw, Oral, Rat

Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ > 5000 mg/kg bw, Dermal, Rabbit

Diethylene Glycol Polyester Grade

General information Contact physician if discomfort comtinues..

Inhalation Coughing. Difficulty in breathing.

Ingestion May cause chemical burns in mouth, oesophagus and stomach.

Skin contact Burning pain and severe corrosive skin damage.

Eye contact Severe irritation, burning and tearing.

Target organs Lungs Kidneys

DIETHANOLAMINE

Acute toxicity - oral

Notes (oral LD₅₀) LC50 ~1600 mg/kg, Oral, Rat

SECTION 12: Ecological information

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12.1. Toxicity
Toxicity Not considered toxic to fish.

Ecological information on ingredients.

DIETHANOLAMINE

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 1460 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic EC₅₀, 48 hours: 30.1 mg/l, Daphnia magna

invertebrates

12.2. Persistence and degradability

Persistence and degradability The product is not expected to be biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility Soluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

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14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information For professional use only. Only trained personnel should use this material.

Revision comments This is the first issue.

Revision date 10/07/2020

Revision 00

SDS number 28974

Hazard statements in full H302 Harmful if swallowed.

H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs (Gastro-intestinal tract, Kidneys) through prolonged or
repeated exposure if swallowed.
H373 May cause damage to organs (Blood, Kidneys, Liver) through prolonged or repeated
exposure if swallowed.
H412 Harmful to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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