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Chapter 4. Gas Dehydration

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12/28/2020 Dr. Mai Cao Lan, Dept.

of Drilling & Production Engineering, GEOPET, HCMUT 147


Chapter Outline

Why Gas Dehydration?

Overview of Dehydration Methods

Gas Dehydration by Absorption with Glycol Process

Gas Dehydration by Adsorption with Solid Desiccants

12/28/2020 Dr. Mai Cao Lan, Dept. of Drilling & Production Engineering, GEOPET, HCMUT 148
Why Gas Dehydration?

• Gas dehydration removes water from the gas stream to


avoid hydrate formation in surface facilities or in gas
pipelines
• Hydrate formation conditions: high pressure + low
temperature + liquid water

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Overview of Dehydration Methods

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Overview of Dehydration Methods
Absorption
• Removing water from gas streams using solvents
• Popular solvents:
– MEG: Monoethylene Glycol
– DEG: Diethylene Glycol
– TEG: Triethylene Glycol

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Overview of Dehydration Methods
Adsorption

• Removing water from gas streams using solid surfaces, known


as solid beds

• Chemisorption (chemical or electrovalent bonding) vs


Physisorption (van der Waals forces between gas molecules
and solid surface)
• Popular solid desiccants:
– Alumina
– Molecular sieves (microporous media with or nm pore
size)
– Silicon gel
– CaCl2

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Overview of Dehydration Methods
Condensation
• Removing water from gas streams by cooling below dew
points
• Popular cooling methods for condensation:
– External cooling or refrigeration: Using ammonia
liquid or liquid propane
– Turbo expansion: Generating work in an adiabatic
process

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Gas Dehydration by Absorption
Glycol Process
Advantages:

• Continuous rather than batch process


• Lower pressure drop
• High performance: Up to 0.5 lb H2O/MMscf of gas can be
achieved
• Glycol can be effectively regenerated
• Low installation cost

12/28/2020 Lan Mai-Cao, HCM University of Technology, Vietnam 154


Gas Dehydration by Absorption
Glycol Process
Advantages:

• Continuous rather than batch process


• Lower pressure drop
• High performance: Up to 0.5 lb H2O/MMscf of gas can be
achieved
• Glycol can be effectively regenerated
• Low installation cost

12/28/2020 Lan Mai-Cao, HCM University of Technology, Vietnam 155


Gas Dehydration by Absorption
Glycol Process
Disadvantages:

• Glycol is susceptive to contamination

• Glycol is corrosive when contanminated or decomposed

• Water dew points below -25oF requires special gas stripper


columns

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Typical Glycol Process Flow

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Glycol Process Description

• Wet gas enters the absorption column from near its bottom

• Gas flows upward through six to eight trays and passes


through mist extractor at the outlet

• Lean glycol flows downward, absorbing water vapor from


the natural gas

• Rich glycol leaves from the bottom of the column to the


regeneration unit.

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Glycol Process Description (cont’d)

• Reboiler generates steam from the water in the rich glycol

• Steam is circulated through the packed section to strip the


water from the glycol

• Stripped water and any lost hydrocarbon are vented at the


top of the stripper

• Hot lean glycol exchange its heat to the rich glycol in the
heat exchanger and thus saves the energy

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Design of Gas Dehydration by Absorption
in TEG
Three main factors that affect on the amount of water
removal in glycol processes:
- Lean TEG purity
- TEG circulation rate
- Number of stages in the glycol contactor/absorber

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Lean TEG Purity
- The purity of lean TEG controls the dry gas water dew point
- Equilibrium water dew point depends on the contactor
temperature at various lean TEG concentrations (wt %)

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TEG Circulation Rate
- Actual water removal depends on circulation rate and the number of
stages N
- Typical TEG rate: 15-40 liters TEG/kg H2O absorbed

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Tray Efficiency – Number of Trays
Overall tray efficiency is defined as the ratio between the number of
equilibrium stages and the number of actual trays

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