Safety Data Sheet

EPORIP comp.B
Safety Data Sheet dated: 4/24/2019 - version 2
Date of first edition: 6/7/2018

1. Identification
GHS Product identifier
Mixture identification:
Trade name: EPORIP comp.B
Trade code: 901531
Recommended use of the chemical and restrictions on use
Recommended use: Hardener for epoxy products
Uses advised against: Data not available
Supplier's details
Company: MAPEI AUSTRALIA Pty Ltd
180 Viking Drive Wacol QLD 4076 Australia
Emergency phone number
Australian Poisons Information Centre 24 Hour Service 13 11 26
Police or Fire Brigade 000

2. Hazard identification

Classification of the Hazardous chemical

Skin Corr. 1B Causes severe skin burns and eye damage.

Eye Dam. 1 Causes serious eye damage.
Skin Sens. 1A May cause an allergic skin reaction.
Aquatic Acute 1 Very toxic to aquatic life.
Aquatic Chronic 1 Very toxic to aquatic life with long lasting effects.
Adverse physicochemical, human health and environmental effects:
No other hazards
GHS label elements, including precautionary statements
Pictograms and Signal Words

Danger

Hazard statements:
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.

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P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see supplementary instructions on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with applicable regulations.
Other hazards which do not result in a classification
Other Hazards: No other hazards

3. Composition/information on ingredients
Substances
no data available
Mixtures

Hazardous components within the meaning of the "Australian Work Health and Safety (WHS)" regulation and related
classification:
Concentration Name Ident. Numb. Classification Registration Number
(% w/w)
≥75 - <100 % Fatty acids, C18-unsaturated, dimers, CAS:68410-23-1 Eye Dam. 1, H318; Aquatic
reaction products with Chronic 1, H410; Skin Corr. 1C,
Polyethylenepolyamines H314; Skin Sens. 1A, H317;
Aquatic Acute 1, H400

≥5 - <10 % Amines, polyethylenepoly-, CAS:112-24-3 Acute Tox. 4, H312; Acute Tox. 4, 01-2119487919-13-XXXX
triethylenetetramine fraction (TETA) H302; Skin Corr. 1B, H314; Eye
Dam. 1, H318; Skin Sens. 1,
H317; Aquatic Chronic 3, H412

≥2.5 - <5 % 2,4,6- CAS:90-72-2 Skin Corr. 1C, H314; Eye Dam. 1, 01-2119560597-27-XXXX
tris(dimethylaminomethyl)phenol EC:202-013-9 H318; Skin Sens. 1B, H317

≥2.5 - <5 % 3-Aminopropyldimethylamine CAS:109-55-7 Flam. Liq. 3, H226; Acute Tox. 4, 01-2119486842-27-xxxx
EC:203-680-9 H302; Skin Corr. 1B, H314; Skin
Index:612-061- Sens. 1, H317; Eye Dam. 1, H318
00-6

≥0.25 - <0.49 bis[(dimethylamino)methyl]phenol CAS:71074-89-0 Skin Corr. 1C, H314; Skin Sens.
% EC:275-162-0 1B, H317

4. First-aid measures
Description of necessary first-aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
OBTAIN IMMEDIATE MEDICAL ATTENTION.
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and the hazard label.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
Symptoms caused by exposure
Eye irritation
Eye damages
Skin Irritation
Erythema
Medical attention and special treatment
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

5. Fire-fighting measures
Suitable extinguishing media
None in particular.
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 None in particular.
Water.
Carbon dioxide (CO2).
Specific hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products: no data available
Explosive properties: ==
Oxidizing properties: no data available
Special protective equipment and precautions for fire-fighters
Use suitable breathing apparatus.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.

7. Handling and storage

Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.

8. Exposure controls/personal protection

Control parameters – exposure standards, biological monitoring

Predicted No Effect Concentration (PNEC) values

Component CAS-No. PNEC Exposure Route Exposure Frequency Remark
Limit
Amines, 112-24-3 0,19 mg/l Fresh Water
polyethylenepoly-,
triethylenetetramine
fraction (TETA)

0,038 mg/l Marine water

95,5 mg/kg Freshwater
sediments

19,2 mg/kg Marine water

sediments

19,1 mg/kg Soil

2,4,6- 90-72-2 0,084 mg/l Fresh Water
tris
(dimethylaminomethyl)
phenol
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phenol

0,0084 Marine water

mg/l

0,2 mg/l Microorganisms in

sewage treatments

3- 109-55-7 0,0535 Fresh Water

Aminopropyldimethylamin mg/l
e

0,00535 Marine water

mg/l

Derived No Effect Level. (DNEL)

Component CAS-No. Worker Worker Consu Exposure Route Exposure Frequency Remark
Industr Profess mer
y ional
Amines, 112-24-3 0,57 0,25 Human Dermal Long Term, systemic
polyethylenepoly-, mg/kg mg/kg effects
triethylenetetramine
fraction (TETA)

0,001 0,00029 Human Inhalation Long Term, systemic

mg/l mg/l effects

8 Human Dermal Short Term, systemic

mg/kg effects

0,41 Human Oral Long Term, systemic

mg/kg effects

0, 0, Human Dermal Short Term, local

028000 430000 effects
mg/cm2

2,4,6- 90-72-2 4,9 Human Inhalation Long Term, local

tris mg/m3 effects
(dimethylaminomethyl)
phenol

0,31 Human Inhalation Long Term, systemic

mg/m3 effects

3- 109-55-7 9,8 Human Inhalation

Aminopropyldimethylamin mg/m3
e

Appropriate engineering controls

no data available
Individual protection measures, such as personal protective equipment (PPE)
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Use adequate protective respiratory equipment.

9. Physical and chemical properties

Color: white
Appearance: Liquid
Odour: ammonia
Odour threshold: no data available
pH: 10.00
Melting point / freezing point: no data available
Initial boiling point and boiling range: no data available
Flash point: 100 °C (212 °F)
Evaporation rate: no data available
Flammability (Solid, Gas): no data available
Upper/lower flammability or explosive limits: no data available
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 Upper/lower flammability or explosive limits: no data available
Vapour pressure: 0.01
Vapour density: no data available
Relative density: 1.02 g/cm3
Solubility in water: partly soluble
Solubility in oil: soluble
Partition coefficient (n-octanol/water): no data available
Auto-ignition temperature: no data available
Decomposition temperature: no data available
Viscosity: 1,500.00 cPs
Specific heat value: no data available
Saturated vapour concentration: no data available
Release of invisible flammable vapours and gases: no data available
Particle size: no data available
Particle size distribution: no data available
Shape and aspect ratio: no data available
Crystallinity: no data available
Dustiness: no data available
Specific surface area: no data available
Degree of aggregation or agglomeration, and dispersibility: no data available
Biodurability or biopersistence: no data available
Surface coating or chemistry: no data available
VOC (Volatile Organic Compound) : 9,1 (A+B) (Rule 1168) g/l

10. Stability and reactivity

Reactivity
Stable under normal conditions
Chemical stability
no data available
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products

SECTION 11: Toxicological information

Information on toxicological effects

Toxicological information of the mixture:

There is no toxicological data available on the mixture. Consider the individual concentration of
each component to assess toxicological effects resulting from exposure to the mixture.

Toxicological information on main components of the mixture:

Amines, a) acute toxicity LD50 Oral Rat = 1760 mg/kg
polyethylenepoly-,
triethylenetetramine
fraction (TETA)

LD50 Skin Rabbit = 1465 mg/kg

b) skin corrosion/irritation Skin Irritant Positive

2,4,6- a) acute toxicity LD50 Oral Rat = 2169 mg/kg

tris
(dimethylaminomethyl)
phenol

3- a) acute toxicity LD50 Oral Rat = 410 mg/kg

Aminopropyldimethylamin
e

LD50 Skin Rat = 1200 mg/kg

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 LD50 Skin Rat = 2139 mg/kg
LC50 Inhalation Rat = 24,8 mg/l 4h

If not differently specified, the information required in the regulation and listed below must be considered as N.A.
a) acute toxicity
b) skin corrosion/irritation
c) serious eye damage/irritation
d) respiratory or skin sensitisation
e) germ cell mutagenicity
f) carcinogenicity
g) reproductive toxicity
h) STOT-single exposure
i) STOT-repeated exposure
j) aspiration hazard

12. Ecological information

Ecotoxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:
Very toxic to aquatic organisms.
Very toxic to aquatic life with long lasting effects.

List of components with eco-toxicological properties

Component Ident. Numb. Ecotox Infos
Amines, polyethylenepoly-, CAS: 112-24-3 a) Aquatic acute toxicity : LC50 Fish = 330 mg/L 96
triethylenetetramine fraction
(TETA)

a) Aquatic acute toxicity : EC50 Daphnia = 31,1 mg/L 48

a) Aquatic acute toxicity : EC50 Algae = 20 mg/L 72
2,4,6- CAS: 90-72-2 - a) Aquatic acute toxicity : LC50 Fish = 222 mg/L 24
tris(dimethylaminomethyl)phenol EINECS: 202-013-9

a) Aquatic acute toxicity : LC50 Fish = 249 mg/L 24

a) Aquatic acute toxicity : LC50 Fish = 175 mg/L 96
a) Aquatic acute toxicity : EC50 Daphnia = 718 mg/L 96
a) Aquatic acute toxicity : EC50 Algae = 84 mg/L 72
b) Aquatic chronic toxicity : NOEC Algae = 6,25 mg/L
3-Aminopropyldimethylamine CAS: 109-55-7 - a) Aquatic acute toxicity : LC50 Algae = 53,5 mg/L 72
EINECS: 203-680-9
- INDEX: 612-061-
00-6

a) Aquatic acute toxicity : EC50 Bacteria > 1000 mg/L 0.5

a) Aquatic acute toxicity : EC50 Bacteria = 95 mg/L 17
a) Aquatic acute toxicity : EC50 Daphnia = 59,5 mg/L 48
a) Aquatic acute toxicity : LC50 Fish = 122 mg/L 96
Persistence and degradability

no data available
Bioaccumulative potential

no data available
Mobility in soil

no data available
Other adverse effects
no data available

13. Disposal considerations

Disposal methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and
national
Date regulations
3/23/2021 currently in force.Name
Production EPORIP comp.B Page n. 6 of 9
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and
national regulations currently in force.

14. Transport information

UN number
2735
UN proper shipping name
ADG-Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (ADDUCTED POLYAMIDE)
ADR-Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (ADDUCTED
POLYAMIDE)
IATA-Technical name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (ADDUCTED
POLYAMIDE)
IMDG-Technical name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (ADDUCTED
POLYAMIDE)
Transport hazard class(es)
ADG-Class: 8
ADR-Class: 8
IATA-Class: 8
IMDG-Class: 8
Packing group, if applicable
ADG-Packing Group: II
ADR-Packing Group: II
IATA-Packing group: II
IMDG-Packing group: II
Environmental hazards
ADG-Environmental Pollutant: Yes
Marine pollutant: Yes
no data available
Special precautions for user
no data available
Additional Information
no data available
HazChem Code/Emergency Action code
no data available

15. Regulatory information

Safety, health and environmental regulations specific for the product in question
This Safety Data Sheet has been prepared according to the Australian Work Health and Safety (WHS) act and the Code of Practice
on preparation of safety data sheets for Hazardous Chemicals.
AICS: all components are listed

16. Other information

Code Description
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European
Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality.
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The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
BCF: Biological Concentration Factor
BEI: Biological Exposure Index
BOD: Biochemical Oxygen Demand
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CAV: Poison Center
CE: European Community
CLP: Classification, Labeling, Packaging.
CMR: Carcinogenic, Mutagenic and Reprotoxic
COD: Chemical Oxygen Demand
COV: Volatile Organic Compound
CSA: Chemical Safety Assessment
CSR: Chemical Safety Report
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level.
DPD: Dangerous Preparations Directive
DSD: Dangerous Substances Directive
EC50: Half Maximal Effective Concentration
ECHA: European Chemicals Agency
EINECS: European Inventory of Existing Commercial Chemical Substances.
ES: Exposure Scenario
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
IC50: half maximal inhibitory concentration
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
IRCCS: Scientific Institute for Research, Hospitalization and Health Care
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LDLo: Leathal Dose Low
N.A.: Not Applicable
N/A: Not Applicable
N/D: Not defined/ Not available
NA: Not available
NIOSH: National Institute for Occupational Safety and Health
NOAEL: No Observed Adverse Effect Level
OSHA: Occupational Safety and Health Administration.
PBT: Persistent, Bioaccumulative and Toxic
PGK: Packaging Instruction
PNEC: Predicted No Effect Concentration.
PSG: Passengers
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
vPvB: Very Persistent, Very Bioaccumulative.
WGK: German Water Hazard Class.

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Paragraphs modified from the previous revision:
- 2. HAZARDS IDENTIFICATION

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