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Skoog: CHM 414: Analytical Chemistry

This document contains chemistry problems and questions from chapters 19-20 of textbooks by Skoog and Chang and Overby. The problems involve calculating potentials of galvanic cells, generating equilibrium expressions, determining molar concentrations via titration with various oxidizing agents such as K2Cr2O7, and calculating percentages of substances such as iron and oxalic acid in samples.

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218 views

Skoog: CHM 414: Analytical Chemistry

This document contains chemistry problems and questions from chapters 19-20 of textbooks by Skoog and Chang and Overby. The problems involve calculating potentials of galvanic cells, generating equilibrium expressions, determining molar concentrations via titration with various oxidizing agents such as K2Cr2O7, and calculating percentages of substances such as iron and oxalic acid in samples.

Uploaded by

Capsanne
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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NAME ASSIGNMENT 3 FINALS

CHM 414: Analytical Chemistry

Skoog
Chapter 19
9. Calculate the potential of the following two half-cells that are connected by a salt bridge:
b.) a galvanic cell with two platinum electrodes, the one on the left immersed in a solution
that is 0.0445 M in Fe3+ and 0.0890 M in Fe2+, the one on the right in a solution that is 0.00300
M in Fe(CN)64- and 0.1564 M in Fe(CN)63-.

11. Generate equilibrium constant expressions for the following reactions. Calculate numerical
values for Keq.
b.) Fe(CN)63- + Cr2+ ⇌ Fe(CN)64- + Cr3+

d.) Tl3+ + 2Fe2+ ⇌ Ti+ +2Fe3+

Chapter 20
13. A solution prepared by dissolving a 0.2541 g sample of electrolytic iron wire in acid was
passed through a Jones reductor. The iron (II) in the resulting solution required a 36.76 mL
titration. Calculate the molar oxidant concentration if the titrant used was
b.) Cr2O7 2- (product: Cr3+)

c.) MnO4- (product: Mn2+)

17. A 0.1298 g sample of KBrO3 was dissolved in dilute HCl and treated with an unmeasured
excess of KI. The liberated iodine required 41.32 mL of a sodium thiosulfate solution. Calculate
the molar concentration of the Na2S2O3.

19. A 0.7120 g specimen of iron ore was dissolved and passed through a Jones reductor.
Titration of the Fe(II) produced required 41.63 mL of 0.01926 M KMnO4. Express the results of
this analysis in terms of
(a) percent Fe

(b) percent Fe2O3

Chang and Overby


Chapter 4
NAME ASSIGNMENT 3 FINALS

95. Iron (II) can be oxidized by an acidic K2Cr2O7 solution according to the net ionic equation
Cr2O72- + 6Fe2+ + 14H+ → 2Cr3+ + 6Fe3+ + 7H2O
If it takes 26.0 mL of 0.0250 M K2Cr2O7 to titrate 25.0 mL of a solution containing Fe2+, what is
the molar concentration of Fe2+?

97. A sample of iron ore (containing only Fe2+ ions) weighing 0.2792 g was dissolved in dilute
acid solution, and all the Fe(II) was converted to Fe(II) ions. The solution required 23.30 mL of
0.0194 M K2Cr2O7 for titration. Calculate the percent by mass or iron in the ore.

99. Oxalic acid (H2C2O4) is present in many plants and vegetables. If 24.0 mL of 0.0100 M
KMnO4 solution is needed to titrate 1.00 g of a sample of H2C2O4 to the equivalence point, what
is the percent by mass of H2C2O4 in the sample? The net ionic equation is
2MnO4- + 16H+ + 5C2O42- → 2Mn2+ + 10CO2 + 8H2O

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