Silver Nitrate Fingerprint Development: Chemical Reaction

Download as docx, pdf, or txt
Download as docx, pdf, or txt
You are on page 1of 3

Silver Nitrate Fingerprint Development

Chemical Reaction
Silver nitrate (AgNO3) can react with the salt (NaCl) left from the perspiration on the friction
ridge skin to form solid silver chloride (AgCl) and sodium nitrate. The silver chloride can then
be converted to silver oxide (Ag2O), which is dark in color and can be more easily seen.

Materials
 Silver Nitrate Solution, 3% (0.75 g AgNO3 in 25 mL water; contained in a spray
bottle)
 Copy Paper (1 sheet per student)
 Newspaper (or other covering to collect overspray)
 Pencils

Preparation
 Cover the lab surface with newspaper to collect overspray.
 Arrange for students to be able to expose their prints to direct sunlight, either by
opening a window or by taking the paper outside.

Student instructions

Materials
 Silver Nitrate Solution, 3% (contained in a spray bottle)
 Copy Paper (1 sheet per student)
 Pencil
 Personal Protective Equipment (PPE)
 Work Surface (covered with newspaper or similar material)

Procedure
1. Set up your evidence.

a. Draw a horizontal line dividing a piece of paper in half. Write your initials
or name in both pencil and pen in both the top half and the bottom half of the
paper.
b. With your left hand, place several random fingerprints in the top half of
the paper.
2. Allow the paper to dry and to absorb the prints for 5 minutes. Wear gloves for the
remainder of the procedure.
3. Place your paper on the work surface.
4. Hold the spray bottle containing the silver nitrate solution approximately 2 to 3 inches
from the surface of the paper. Remember, this chemical reacts with skin, so avoid
contact.
5. Spray from the upper left corner across the page and then move down the page,
spraying until the sheet is saturated.
6. Allow the paper to dry for 1 minute.
7. Expose the paper to sunlight for 1 to 2 minutes. Once the prints begin to develop,
remove the paper from the sunlight. Further exposure will continue to darken the prints
and background.

Iodine Vapor Method Fingerprint Development

Reagents
Copper (II) sulfate
Potassium iodide

Safety
Put on protective gloves and eyewear.
Conduct the experiment on the plastic tray.

Step-by-step instructions
Potassium iodide KI contains iodine ions I−, which we can turn into iodine molecules I 2 using
CuSO4.
Iodine is quite volatile. This means that its molecules leave the solution easily and disperse as a
gas.

Iodine sticks to fats really well, and our fingerprints are mostly made of fats.

Expe
cted result
Iodine vapors are absorbed by fats contained in the fingerprints left on the paper. Iodine reveals
the fingerprints by coloring them characteristic brown.

You might also like