Sample MCQ Organic Chemistry Sem IV PSCHO401 Regular

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Type-MCQ

Q1. The Grunwald-Winstein equation is


1. log(KX/KH)=ρσ
2. log(Kt-BuCl, sol)/Kt-BuCl, 80%EtOH, 20%H2O)=ϓ
3. log(KX/KH)=ρ[σ+r(σ+- σ)]
4. log(KNucx/KH2O)=α.En+β.H

Q2. The Hammett equation is


1. log(KX/KH)=ρσ
2. log(Kt-BuCl, sol)/Kt-BuCl, 80%EtOH, 20%H2O)=ϓ
3. log(KX/KH)=ρ[σ+r(σ+- σ)
4. log(KNucx/KH2O)=α.En+β.H

Q3. In Hammett substituent constant σ is negative the substituted benzoic acid is ------than
benzoic acid itself.
1. more acidic
2. neutral
3. more basic
4. less acidic

Q4. In Hammett substituent constant σ is positive the substituted benzoic acid is ------than
benzoic acid itself.
1. more acidic
2. neutral
3. more basic
4. less acidic

Q5. In Hammett equation, the substituted benzoic acid have electron donating group for this σ
value is
1. negative
2. positive
3. zero
4. infinity

Q6. When a linearly polarised light beam passes through a dissymmetric medium, its two
circularly polarized components show different indices and different absorption coefficients
giving rise to two chirotopical properties of a chiral medium, known as
1. Circular dichroism
2. Circular birefringence
3. Electromagnetic transition
4. Electronic transition

Q7. 2- and 3-oxocholestanone exhibit a


1. positive cotton effect
2. negative cotton effect
3. zero cotton effect
4. infinity

OH OH

H H

Li/NH3
A B A B

O O
H
X Y
Q8.

Y has an ORD resembling that of an A/B trans 3-oxosteroid with


1. positive cotton effect
2. negative cotton effect
3. zero cotton effect
4. infinity cotton effect
OH OH

H H

H2-Ru
A B A B

O O
H
X Y
Q9.

Y has an ORD resembling that of an A/B trans 3-oxosteroid with


1. positive cotton effect
2. negative cotton effect
3. zero cotton effect
4. infinity cotton effect

Q10. (-)-mentthone which exists as two conformers in water gives


1. positive cotton effect
2. negative cotton effect
3. zero cotton effect
4. infinity cotton effect

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