Unit - IV Semiconductor Physics: Prepared by Dr. T. KARTHICK, SASTRA Deemed University
Unit - IV Semiconductor Physics: Prepared by Dr. T. KARTHICK, SASTRA Deemed University
Unit - IV Semiconductor Physics: Prepared by Dr. T. KARTHICK, SASTRA Deemed University
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Introduction to Semiconductors
Semiconductors are the materials having electrical conductivity lies between the conductors and
insulating materials. Some of the semiconductors are of pure form (intrinsic) and some of them
are compound semiconductors (extrinsic). The resistivity of the semiconductor lies between the
conductors and insulators and the value of resistivity is about 106 – 107 𝜴.m.
The unique and interesting feature of semiconductors is that they are bipolar and two carrier
charges (electrons and holes) transport current in these materials. The electrical conductivity of
pure semiconductor is known as intrinsic conductivity. Intrinsic conductivity is significantly low
and are greatly influenced by the temperature.
Basic Definitions
Valance electrons
A valence electron is an outer shell electron that is associated with an atom, and that can
participate in the formation of a chemical bond.
The electrons in an atom exist in a particular shell or a subshell. The number of electrons in a
particular shell is 2n2 according to the Pauli’s exclusion principle.
Valance band
The valence band is the band of electron orbitals that electrons can jump into the conduction
band when excited. The valence band is simply the outermost electron orbital of an atom of any
Conduction band
The energy difference between the highest occupied energy state of the valence band and the
lowest unoccupied state of the conduction band is called the band gap and is indicative of
the electrical conductivity of a material. A large band gap means that a lot of energy is required to
excite valence electrons to the conduction band.
The Fermi Level is the energy level which is occupied by the electron orbital at temperature equals
to 0 K. The level of occupancy determines the conductivity of different materials.
Band theory demonstrates that the solids are classified into metals, insulators and
semiconductors
• Metals: valence band and conduction band overlap each other, thus electrons easily flow
from valence band to conduction band that leads to high electrical conductivity
The band gap represents the minimum energy difference between the top of the valence band and
the bottom of the conduction band. However, the top of the valence band and the bottom of the
conduction band are not generally at the same value of the electron momentum.
In a direct band gap semiconductor, the top of the valence band and the bottom of the conduction
band occur at the same value of momentum
In an indirect band gap semiconductor, the maximum energy of the valence band occurs at a
different value of momentum to the minimum in the conduction band energy.
The Fermi-Dirac statistics deals with the particles having half integral spin. The spin of the electron
is ½. Hence an electron is said to be a Fermi particle or fermions.
𝑓 (𝐸 ) =
Where f(E) represents the probability that a quantum state is occupied by an electron. k is the
Boltzmann constant, T is the temperature in Kelvin. E is the energy of an electron and EF is the
Fermi energy.
Case (i)
Case (ii)
Case (iii)
Thus from the above, the term Fermi level is defined as the energy level that has the probability
of ½ for the occupation of quantum states by the electrons when 𝑇 > 0 𝐾.
Density of states
Density of states is the number of states available per unit volume between the energy level E
and E+dE
𝐸 = --------------(1)
𝑛 =𝑛 +𝑛 +𝑛 --------------(2)
Let us consider every point in the space represents a state, i.e a unit cube contains exactly one
state. The number of states available in any volume is equal to the numerical value of the
volume. In a space of radius n, the number of states (z) available is,
𝑍= 𝜋𝑛 --------------(3)
Therefore, the number of quantum states with energy equal to or smaller than E is proportional to
the first octant of the sphere.
𝑍(𝐸) = × 𝜋𝑛 --------------(4)
Similarly, the number of energy states within one octant of a sphere of redius (n+dn)
corresponding to energy (E+dE)
Therefore, the number of energy states having energy values between E and E+dE is given by
1 4
𝑍(𝐸)𝑑𝐸 = × 𝜋[𝑛 + 𝑑𝑛 − 𝑛]
8 3
1 4 1 4
𝑍(𝐸 )𝑑𝐸 = × 𝜋 𝑑𝑛 = × 𝜋 × 3𝑛 𝑑𝑛
8 3 8 3
2𝑛 𝑑𝑛 = 𝑑𝐸
𝑛 𝑑𝑛 = 𝑑𝐸 -------------------------(8)
According to Pauli’s exclusion principle, a state can occupy two electrons, one with up-spin and
another with down-spin. Therefore, the density of states available per unit volume in an energy
interval dE is
⁄
2𝜋 8𝑚𝐿 ⁄
𝑍(𝐸 )𝑑𝐸 = 𝐸 𝑑𝐸
4 ℎ
Or
⁄ ⁄
𝑍(𝐸)𝑑𝐸 = ( 2𝑚) 𝐿 𝐸 𝑑𝐸 ---------------------------(10)
4𝜋 ⁄ ⁄
( 2𝑚) 𝐿 𝐸 𝑑𝐸
𝑍(𝐸)𝑑𝐸 = ℎ
𝐿
4𝜋 ⁄ ⁄
𝑍(𝐸 )𝑑𝐸 = ( 2𝑚) 𝐸 𝑑𝐸
ℎ
At 0 K temperature, the electrons in the valance band are engaged in covalent bond. With an
increase in temperature, covalent bonds are broken in an intrinsic semiconductor an electron-hole
pairs are generated. At this stage, a large number of electrons can be found in the conduction band
and similarly, a large number of holes can be found in the valance band. As electrons and holes
are charged particles, they are together called as charge carries. Intrinsic carrier concentration is
the number of electrons in the conduction band per unit volume or the number of holes in the
valence band per unit volume of the material.
Where n is the number of electrons in the conduction band per unit volume and
Let dn be the number of electrons whose energy lies in the energy interval E and E+dE in the
conduction band, then
𝑑𝑛 = 𝑍 (𝐸 ) 𝑓 (𝐸 ) 𝑑𝐸
Where 𝑍 (𝐸 )dE is the density of states in the energy interval E and E+dE and 𝑓(𝐸 ) probability that
a state of energy is occupied by an electron.
The electron density in the conduction band can be determined by integrating the above equation
between the limits Ec and .
𝑛 = ∫ 𝑍(𝐸 ) 𝑓 (𝐸 ) 𝑑𝐸 -----------(1)
(2𝑚∗ ) ⁄ ⁄
𝑍(𝐸 ) 𝑑𝐸 = 𝐸 𝑑𝐸 -----------------(2)
The bottom edge of the conduction band Ec corresponds to the potential energy of an electron at
rest. Therefore, (EEc) will be the kinetic energy of the conduction electron at higher energy levels.
(2𝑚∗ ) ⁄ ⁄
𝑍(𝐸 ) 𝑑𝐸 = (𝐸 − 𝐸 ) 𝑑𝐸 -------------------(3)
𝑓(𝐸 ) = -----------------------(4)
Since E >EF, the term 𝑒𝑥𝑝 > 1, therefore the above equation can be modified as,
𝑓(𝐸 ) = or 𝑒 ----------------------(5)
4𝜋 ⁄ ⁄
𝑛 = 𝑍(𝐸 ) 𝑓(𝐸 ) 𝑑𝐸 = (2𝑚∗ ) (𝐸 − 𝐸 ) 𝑑𝐸 × 𝑒
ℎ
(2𝑚∗ ) ⁄ ⁄
𝑛= 𝑒 ∫ (𝐸 − 𝐸 ) .𝑒 𝑑𝐸 --------------(6)
For mathematical simplification, put 𝑥 = (𝐸 − 𝐸 ), and 𝑎 = , the 𝑑𝐸 = 𝑑𝑥. The lower limit
of the integral becomes 0 and the upper limit is .
4𝜋 ⁄ ⁄
𝑛= (2𝑚∗ ) 𝑒 𝑥 .𝑒 𝑑𝑥
ℎ
4𝜋 ⁄ √𝜋
𝑛= (2𝑚∗ ) 𝑒
ℎ 2(𝑎) /
4𝜋 ⁄ √𝜋
𝑛= (2𝑚∗ ) 𝑒 /
ℎ 1
2
𝑘𝑇
∗
𝑛=2 𝑒 --------------(7)
or
𝑛=𝑁 𝑒
∗
Where 𝑁 = 2
Nc is temperature dependent material constant known as the effective density of states in the
conduction band. In silicon at 300 K, Nc= 2.8 x 1025 states/m3.
Let dp be the number of holes whose energy lies in the energy interval E and E+dE in the valence
band, then
𝑑𝑝 = 𝑍(𝐸 ) [1 − 𝑓(𝐸 )] 𝑑𝐸
Where 𝑍(𝐸 ) dE is the density of states in the energy interval E and E+dE and [1 − 𝑓(𝐸 )]
probability that a state of energy is vacant and not occupied by an electron.
The hole density in the valence band can be determined by integrating the above equation between
the limits and EV.
⁄ ⁄
𝑍(𝐸) 𝑑𝐸 = (2𝑚∗ ) 𝐸 𝑑𝐸 -----------------(2)
The top edge of the valence band Ev corresponds to the potential energy of a hole at rest. Therefore,
(EvE) will be the kinetic energy of the holes at lower energy levels.
(2𝑚∗ ) ⁄ ⁄
𝑍(𝐸 ) 𝑑𝐸 = (𝐸 − 𝐸) 𝑑𝐸 -------------------(3)
[1 − 𝑓(𝐸 )] = 1 −
𝐸−𝐸
1 + 𝑒𝑥𝑝 −1
[1 − 𝑓(𝐸 )] = 𝑘𝑇
𝐸−𝐸
1 + 𝑒𝑥𝑝
𝑘𝑇
𝐸−𝐸
𝑒𝑥𝑝
[1 − 𝑓(𝐸 )] = 𝑘𝑇
𝐸−𝐸
1 + 𝑒𝑥𝑝
𝑘𝑇
Since E <EF, the term 𝑒𝑥𝑝 in the denominator is less than 1. So, it is negligible when
compared to 1. Therefore the above equation can be modified as,
4𝜋 ⁄ ⁄
𝐸−𝐸
𝑝 = 𝑍 (𝐸 ) 𝑓(𝐸 ) 𝑑𝐸 = (2𝑚∗ ) (𝐸 − 𝐸) 𝑑𝐸 × 𝑒𝑥𝑝
ℎ 𝑘𝑇
4𝜋 ⁄ ⁄
𝑝 = (2𝑚∗ ) (𝐸 − 𝐸) .𝑒 𝑑𝐸
ℎ
𝑝= (2𝑚∗ ) ⁄
𝑒 ∫ (𝐸 − 𝐸) ⁄
.𝑒 𝑑𝐸 --------------(6)
For mathematical simplification, put 𝑥 = (𝐸 − 𝐸), and 𝑎 = , the 𝑑𝐸 = −𝑑𝑥. The lower
limit of the integral becomes and the upper limit is 0.
4𝜋 ⁄ ⁄
𝑝= (2𝑚∗ ) 𝑒 𝑥 .𝑒 (−𝑑𝑥)
ℎ
4𝜋 ⁄ ⁄
𝑝= (2𝑚∗ ) 𝑒 𝑥 .𝑒 𝑑𝑥
ℎ
4𝜋 ⁄ √𝜋
𝑝= (2𝑚∗ ) 𝑒
ℎ 2(𝑎) /
4𝜋 ⁄ √𝜋
𝑝= (2𝑚∗ ) 𝑒 /
ℎ 1
2
𝑘𝑇
𝑝=𝑁 𝑒 --------------(7)
∗
Where 𝑁 = 2
NV is temperature dependent material constant known as the effective density of states in the
valence band. In silicon at 300 K, Nc= 1025 states/m3.
In an intrinsic semiconductor, the concentration of hole in the valence band is equal to the
concentration of electron in the conduction band.
i.e n=p
𝑁 𝑒 =𝑁 𝑒
𝑁 𝑒
= =𝑒
𝑁
𝑒
𝑁
= 𝑒
𝑁
𝑁 𝐸 + 𝐸 − 2𝐸
ln =
𝑁 𝑘𝑇
𝑁
𝐸 + 𝐸 − 2𝐸 = 𝑘𝑇 ln
𝑁
𝐸 +𝐸 𝑘𝑇 𝑁
𝐸 = − ln
2 2 𝑁
𝐸 +𝐸 𝑘𝑇 𝑁
𝐸 = + ln
2 2 𝑁
The above figure shows the energy band diagram of an n-type semiconductor. When the
semiconductor is at 0K, the donor atoms are not ionized and are at the donor energy level (ED)
which is near to conduction band (EC). When the temperature is raised above 0K, the donor atoms
get ionized and free electrons appear in the conduction band. With increase in temperature, more
and more donor atoms get ionized and the electron concentration in the conduction band increases.
The number of electrons present in the conduction band (n) of the n-type semiconductor is given
by the sum of the number of holes in the valence band and the number of ionized donor impurities.
𝑖. 𝑒 𝑛 = 𝑁 +𝑁 .............(1)
Where 𝑁 is the number of holes in the valence band and 𝑁 is the number of ionized donor
impurities.
𝑁 = 𝑁 [1 − 𝑓(𝐸 )] .............(2)
Where 𝑁 is the number of unionized donor impurities and [1 − 𝑓(𝐸 )] is the probability of
finding a hole in the donor energy level.
1
[1 − 𝑓(𝐸 )] = 1 −
𝐸 −𝐸
1 + exp
𝑘𝑇
𝐸 −𝐸
1 + exp −1
= 𝑘𝑇
𝐸 −𝐸
1 + exp
𝑘𝑇
𝐸 −𝐸
exp
= 𝑘𝑇
𝐸 −𝐸
1 + exp
𝑘𝑇
Since 𝐸 < 𝐸 , exp < 1 , and hence the term exp in the denominator is
negligible. The value of [1 − 𝑓 (𝐸 )] is written as,
Therefore,
𝑁 = 𝑁 exp .............(4)
At T = 0 K, all the states in the valence band are occupied by the electrons and hence, 𝑁 is equal
to zero, therefore 𝑛 = 𝑁
𝑛 = 𝑁 exp .............(5)
𝑛 = 𝑁 exp .............(6)
𝐸 −𝐸 𝐸 −𝐸
𝑁 exp = 𝑁 exp
𝑘𝑇 𝑘𝑇
𝑁 𝐸 −𝐸 𝐸 −𝐸
= exp . exp
𝑁 𝑘𝑇 𝑘𝑇
𝑁 𝐸 + 𝐸 − 2𝐸
𝑙𝑛 =
𝑁 𝑘𝑇
𝐸 +𝐸 𝑘𝑇 𝑁
𝐸 = − 𝑙𝑛
2 2 𝑁
𝐸 = + 𝑙𝑛 .............(7)
Equation (7) gives the equation for the Fermi level in an n-type semiconductor.
𝐸 +𝐸 𝑘𝑇 𝑁
𝐸 −𝐸 + 𝑙𝑛 −𝐸
2 2 𝑁
𝑛 = 𝑁 exp = 𝑁 exp
𝑘𝑇 𝑘𝑇
or
𝐸 +𝐸 1 𝑁 𝐸
𝑛 = 𝑁 exp + 𝑙𝑛 −
2𝑘𝑇 2 𝑁 𝑘𝑇
or
𝐸 −𝐸 1 𝑁
𝑛 = 𝑁 exp + 𝑙𝑛
2𝑘𝑇 2 𝑁
𝐸 −𝐸 𝑁
𝑛 = 𝑁 exp .
2𝑘𝑇 𝑁
𝑛 = (𝑁 𝑁 ) exp .............(8)
∗
Substituting the value of 𝑁 = 2 in equation (8), we get,
The above equation gives the carrier concentration of electrons in an n-type semiconducting
material.
Intrinsic
E electrons
Conduction Band
Ec
EA
Intrinsic holes
The above figure shows the energy band diagram of a p-type semiconductor. When the
semiconductor is at 0K, the acceptor atoms are not ionized and are at the acceptor energy level
(EA) which is near to valence band (EV). When the temperature is raised above 0K, the acceptor
atoms get ionized and holes appear in the valence band. With increase in temperature, more and
more acceptor atoms get ionized and the hole concentration in the valance band increases. The
number of holes in the valence band (p) of a p-type semiconductor is given by the sum of the
number of electrons in the conduction band and the number of ionized acceptor impurities.
𝑖. 𝑒 𝑝 = 𝑁 +𝑁 .............(1)
𝑁 = 𝑁 . 𝑓(𝐸 ) .............(2)
Where 𝑁 is the number of unionized acceptor impurities and 𝑓(𝐸 ) is the probability of finding
an electron in the acceptor energy level.
1
𝑓 (𝐸 ) =
𝐸 −𝐸
1 + exp
𝑘𝑇
Therefore,
𝑁 = 𝑁 exp .............(4)
At T = 0 K, all the states in the conduction band are empty and hence, 𝑁 is equal to zero, therefore
𝑝=𝑁
𝑝 = 𝑁 exp .............(5)
𝑝 = 𝑁 exp .............(6)
𝐸 −𝐸 𝐸 −𝐸
𝑁 exp = 𝑁 exp
𝑘𝑇 𝑘𝑇
𝑁 𝐸 −𝐸 𝐸 −𝐸
= exp . exp
𝑁 𝑘𝑇 𝑘𝑇
𝑁 𝐸 + 𝐸 − 2𝐸
= exp
𝑁 𝑘𝑇
𝐸 = − 𝑙𝑛 .............(7)
Equation (7) gives the equation for the Fermi level in an p-type semiconductor.
𝐸 +𝐸 𝑘𝑇 𝑁
𝐸 − − 𝑙𝑛
𝐸 −𝐸 ⎛ 2 2 𝑁 ⎞
𝑝 = 𝑁 exp = 𝑁 exp ⎜ ⎟
𝑘𝑇 𝑘𝑇
⎝ ⎠
or
𝐸 −𝐸 1 𝑁
𝑝 = 𝑁 exp + 𝑙𝑛
2𝑘𝑇 2 𝑁
𝐸 −𝐸 𝑁
𝑝 = 𝑁 exp .
2𝑘𝑇 𝑁
𝑝 = (𝑁 𝑁 ) exp .............(8)
∗
Substituting the value of 𝑁 = 2 in equation (8), we get,
∗
𝑝 = (2𝑁 ) . . exp .............(9)
The above equation gives the carrier concentration of holes in a p-type semiconducting material.
direction normal to both the magnetic field and the current directions. This is known as Hall Effect.
The potential difference or an e.m.f developed across the material is known as Hall voltage.
insulating material. One of the opposite sides of the slab is connected to a constant current source
and the other pairs of the opposite sides of the slab is connected to a voltmeter in order to measure
the hall voltage. Now this rectangular semiconductor slab is placed in between the pole pieces of
an electron magnet in such a way that magnetic field acts perpendicular to the lateral faces of the
semiconductor slap.
Let Ix be the current applied along the x-direction and By be the magnetic field applied along the
y-direction, then the force due to the magnetic field is 𝐵 𝑒 𝑣 and the force due to the electric
Or
𝐸 = 𝐵 𝑣 (1)
𝐸 = 𝐵 (3)
∴ = 𝐵
×
∴ = 𝐵
×
𝐵 𝐼
𝑉 =
𝑡 × 𝑛𝑒
Or
𝐵 𝐼
𝑉 = 𝑅
𝑡
𝑛=−
Hall mobility is defined as the drift velocity acquired by the majority charge carrier (either
electron/hole) in the unit electric field intensity.
𝐽 = 𝑛𝑒𝑣
and
𝐽 = 𝜎𝐸
∴ 𝑛𝑒𝑣 = 𝜎𝐸
𝑣 𝜎
=
𝐸 𝑛𝑒
𝜇 =𝜎𝑅