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PHYSICS
SECTION – I
Straight Objective Type
This section contains 6 multiple choice questions numbered 1 to 6. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1. Two strings A and B of equal length but unequal linear mass density are tied together
with a knot and stretched between two supports. A particular frequency happens to
produce a standing wave on each part, with node at the knot as shown. If linear mass
density of the two strings A and B are µ1 and µ2 respectively, then :

String A String B
(A) µ1 = µ2 (B) µ1 < µ2

(C) µ1 > µ2 (D) can’t be decided.

2. Figure shows variation of magnetic field inside and outside two cylindrical wires P and Q
carrying currents that are uniformly distributed across the cross section of wires. If
current density for two wires are jP and jQ , then :
B

Wire Q
Wire P

r
(A) jP = jQ (B) jP < jQ
(C) jP > jQ (D) can’t be decided

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3. Radius of curvature of a concave spherical surface air

glass
separating air-glass medium is R. A point object is
placed on the principal axis in the glass (g = 1.5). For
object P
the image to be real, seen by observer in air, distance of
the object from P should be :
(A) 2R < u < 3R (B) u < 2R
(C) u = R (D) u > 3R

4. A parent radioactive nucleus A (decay constant a) converts into a radio-active nucleus B
of decay constant b, Initially, number of atoms of B is zero. At any time Na, Nb are
number of atoms of nuclei A and B respectively then maximum value of Nb is :
a Na  b Na
(A) (B)
b a
( a   b )N a b
(C) (D) Na
b ( a   b )

5. Liquid of density  is filled in the container of negligible

mass having area A. Area of hole ‘a’ very small (a << A) is
made near the bottom in the wall of container. Co-efficient of
a
friction between container and surface is equal to   . As
A
liquid is coming out of vessel, instantaneous acceleration of
the container is :
A 3g
(A)   g (B)
a 2

a
(C)   g (D) zero
A

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K
6. Initially spring is compressed by distance x0 from equilibrium
position. At this compression block is given velocity
Equilibrium x0
Position
3K
x0 , so that compression in the spring increases and
m
block start S.H.M. (Spring constant is K). Equation of motion
of the block is :
 k   K 
(A) y  3 x0 sin  (B) y  2 x0 sin 
 m t  3   m t  6 
   
 K   K 
(C) y  3 x0 sin  t   (D) y  2 x0 sin  t  
 m 6   12 3 
 

SECTION – II
Assertion – Reason Type
This section contains 3 multiple choice questions numbered 7 to 9. Each question has 4 choices (A), (B), (C) and
(D), out of which MORE THAN ONE IS/ARE CORRECT.

7. The trajectory of a particle in vertical plane is given by y = ax bx2 where a, b are

constants
(A) angle of projection is tan1 a
g(a 2  1)
(B) speed of projection is
2b
a2
(C) horizontal range for particle is
4b
a2
(D) maximum height attained by particle is
4b

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8. A semi-circular wire of radius r, carrying a current i, is placed in a uniform magnetic field

of magnitude B. The force acting on it
(A) Can be zero
(B) Can have the maximum magnitude 2 Bir
(C) Can have the maximum magnitude Bir
(D) Can have the maximum magnitude Bir

9. Which of the following functions represent a stationary wave ? Here a, b and c are
constants
(A) y = a cos (bx) sin (ct) (B) y = a sin (bx) cos (ct)
(C) y = a sin (bx + ct) (D) y = a sin (bx + ct) + a sin (bx  ct)

SECTION – III
Linked Comprehension Type
This section contain 1 paragraph P10-12. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

P10–12 : Paragraph for Question Nos. 10 to 12

m
An insulated cylinder contains nitrogen gas which is sealed on the top by a
heavy metal piston of mass m. Piston is free to move with negligible K h = .3 m
friction. Initial height of the piston is 0.3 m at temperature 27°C when it is E
given some heat with the help of an electrical circuit, piston slowly rises to
height 0.5 m above the bottom of the cylinder.

10. Expansion of gas in the cylinder is :

(A) Isothermal process (B) Adiabatic process
(C) Isobaric process (D) Isochoric process

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11. Final temperature of the nitrogen gas inside the cylinder is :

(A) 400 K (B) 300 K
(C) 200 K (D) 500 K

12. During expansion of the gas, net heat absorbed by the nitrogen gas is :
(A) Equal to work done by nitrogen gas on the piston
(B) Greater than work done by nitrogen gas on the piston
(C) Less than work done by nitrogen gas on the piston
(D) Will be always twice of the work done by the gas on the piston

SECTION – IV
Subjective Questions
This section contains 2 subjective questions numbered 13 to 14.

13. When a box ‘A’ is connected across an a.c. source of 200 V, 0.4 A of current flows in
circuit. When a capacitor of reactance 400  is connected in series with box and
connected across a.c. source, the power factor of circuit becomes 1. What is power factor
of box ‘A’. (Express your answer in the order of 101)

14. A ring of mass M is attached with spring of spring constant

10Mg
K . The other end of the spring is attached to fixed R
R 37°
horizontal rod. Ring is free to slide on fixed horizontal rod.
Ring is released from the condition shown in figure. Natural
length of the spring is R. Find ratio of maximum and minimum
normal reaction on ring. Initially ring is at rest

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SECTION – V
Matrix–Match Type
p q r s
This section contains 2 questions. Each question contains statements given in two
column which have to be matched. Statements (A, B, C, D) in Column I have to be A p q r s
matched with statements (p, q, r, s) in Column II. The answers to these questions p q r s
B
have to be appropriately bubbles as illustrated in the following example.
C p q r s
If the correct matches are A–p, A–s, B–q, B–r, C–p, C–q and D–s, then the correctly
bubbled 4 × 4 matrix should be as follows : D p q r s

15. In the circuit shown in figure plates of capacitor C2 are gradually pulled apart. Then
match the following :
C3

C1 C2

Column I Column II
A. Potential difference across C1 (p) Will remain same
B. Energy stored in C3 (q) Will increase
C. Potential difference across C2 (r) Will decrease
D. Electric field between the plates of capacitor C1 (s) Less than V

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16. Match the quantities having same dimensions :

Column I Column II
A. Coefficient of self induction L. (p) ohm  sec
B. Permittivity of the medium (q) sec
meter  ohm
C. Permeability of the medium (r) Joule
(Ampere) 2 metre
D. Co-efficient of mutual inductance M (s) Volt  sec
Ampere

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CHEMISTRY
SECTION – I
Straight Objective Type
This section contains 6 multiple choice questions numbered 17 to 22. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

17. Ammonium carbamate dissociates as NH2COONH4(s)   2NH3(g) + CO2(g). In a

closed vessel containing ammonium carbamate in equilibrium, ammonia is added such
that partial pressure of NH3 now equals to the original total pressure. Calculate the ratio
of total pressure now to the original pressure.
(A) 23/27 (B) 31/27
(C) 4/9 (D) 4/3
18. Enthalpy of neutralisaton of H3PO3 is –106.68 KJ mol–1 using NaOH. If enthalpy of
neutralization of HCl by NaOH is –55.84 KJ mol–1. Calculate the Hionisation of H3PO3
into its ions
(A) 50.84 KJ mol–1 (B) 5 KJ mol–1
(C) 2.5 KJ mol–1 (D) 7.5 KJ mol–1
19. Consider the hypothetical reaction
1 3
A2(g) + B2 (g)  AB3(g); H = –30 KJ
2 2
If the standard entropies of A2, B2 and AB3 are 80, 60 and 90 JK–1 respectively, the above
reaction will be in equilibrium at
(A) 450 K (B) 750 K
(C) 250 K (D) 1500 K
20. When 0.1 mole of NaOH is added to 1 L of solution containing 0.15 M CH3COOH and
0.15M CH3COONa. Assume no volume change. Given log 3 = 0.48, log 2 = 0.30, pKa of
acetic acid = 4.74. pOH of the resulting solution is
(A) 5.44 (B) 5.52
(C) 9.66 (D) none of these

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O
dil. HO- HSCH2CH2SH Raney Ni
21. + Ph CHO (A) (B) (C)
BF3 H2
Product (C) in the above reaction is:

(A) CH2 (B) CH Ph

CH CH Ph
(C) (D)

CO2H
OsO4 NaIO4 LiAlH4
22.. + (A) (B) (C) (D)
(excess)
CO2H
Product (D) in above reaction sequence is:
OH

OH
(A) OH OH
HO (B)
HO HO OH
OH
HO
(C) OH (D) OH

HO
OH OH OH

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SECTION – II
Assertion – Reason Type
This section contains 3 multiple choice questions numbered 23 to 25. Each question has 4 choices (A), (B), (C) and
(D), out of which MORE THAN ONE IS/ARE CORRECT.

23. When CO2 is passed into aqueous:

(A) Na2CrO4 solution, it’s yellow colour changes to orange.
(B) KMnO4 solution, it disproportionates to KMnO4 and MnO2.
(C) Na2Cr2O7 solution it’s orange colour changes to green
(D) KMnO4 solution, it’s pink colour changes to green

24. Choose the correct statement(s) from followings:

(A) Nascent hydrogen is a powerful reducing agent than molecular hydrogen.
(B) White phosphorous is more reactive than red phosphorous.
(C) The reactivity of K2O towards water is more than that of Na2O towards water
(D) Nitrate salt of silver is soluble in ammonia but insoluble in water.

25. Identify the correct statement(s) amongst the followings:

(A) Liquid nitrogen does not stick to the poles of magnet whereas liquid oxygen does
(B) NO2 is brown in colour at room temperature but colourless below 00C.
(C) Bond order of CN and N2 are equal but CN is more reactive
(D) NO+ is having lower bond strength than NO.

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SECTION – III
Linked Comprehension Type
This section contain 1 paragraph C26-28. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

C26–28 : Paragraph for Questions Nos. 26 to 28

When atoms are arranged in ABCABC type of packing or ABAB type of packing, some space is
left in between the atom which is known as voids. Depending upon the situation, voids can be
classified as triangular, tetrahedral, octahedral or cubic
For example;

void shown in the figure is triangular void because it is formed by touching 3 atoms.

26. In a compound AB, the ionic radii of A+ and B– are 88 pm and 200 pm respectively?
What is the coordination no. of A+ ?
(A) 6 (B) 8
(C) 2 (D) 4
27. In a compound XY2O4, oxide ions are arranged in ccp, X is present in octahedral voids
and Y is equally distributed between octahedral voids and tetrahedral voids. Calculate %
of octahedral voids occupied.
(A) 90% (B) 25%
(C) 50% (D) 75%
28. Determine the formula of a compound formed by A, B, C in which A is present in ccp
and B is present in 2/3 of octahedral void and C is present in 50% of the remaining of
octahedral void and 75% of tetrahedral void
(A) A2B3C2 (B) AB5C2
(C) A3B6C4 (D) A3B2C5

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SECTION – IV
Subjective Questions
This section contains 2 subjective questions numbered 29 to 30.

29. A weak base AOH with 42 ml (equivalence point) reacts with strong acid HCl, where 14
ml of weak base AOH is being consumed by acid, the pH of the solution is found to be
8.3, if the equivalence point is obtained by adding 10 meq. of HCl, then find pKb value
for AOH.

30. A gaseous mixture containing N2 and a unknown gas A2 (g) are present in a sealed vessel
at 700 mm of Hg. Gas A2 decomposes as A2(g)  2A(g) with progress of time and
decomposition follow first order kinetics. If the total pressure inside the flask measured
after 30 min and 60 min are 760 and 800 mm of Hg, Calculate the initial pressure of A2.

SECTION – V
Matrix-Match Type
p q r s
This section contains 2 questions. Each question contains statements given in two
column which have to be matched. Statements (A, B, C, D) in Column I have to be A p q r s
matched with statements (p, q, r, s) in Column II. The answers to these questions p q r s
B
have to be appropriately bubbles as illustrated in the following example.
C p q r s
If the correct matches are A–p, A–s, B–q, B–r, C–p, C–q and D–s, then the correctly
bubbled 4 × 4 matrix should be as follows : D p q r s

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31. Match the column I and column II

Column – I Column – II
2+
(A) Precipitate with KCN, which is soluble (p) Fe
in excess of reagent.
(B) Precipitate with NaOH and NH4OH, (q) Hg2+
which is insoluble in excess of both the
reagents separately.
(C) Coloured ppt. with KI which is soluble (r) Pb2+
in excess of reagent
(D) Black precipitate with H2S, which is (s) Ag+
soluble in hot and dilute HNO3

32. Match the column I and column II

Column – I Column – II
(Reaction) (Types of intermediate formed)

(A) HO
  (p) Carbocation
PhCHCl2  Product
O

C OEt
(B) CH2 + OH Product (q) Carbanion
C OEt

O
CH 2 CH CH 2
(C) (1) HBr (r) Free-Radical

(2) NBS/ h


OH
CH3
(D) H (s) Carbene

 Product

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MATHEMATICS
SECTION – I
Straight Objective Type
This section contains 6 multiple choice questions numbered 33 to 38. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

3 sin 2x  cos 2x  2
33. Value of x (, ) satisfying the equation  3 sin x  cos x   4 , is
 
(A) (B)
3 6
 2
(C)  (D)
3 3

34. If a, b, c, are in H.P. then the line acx + bcy + ab = 0, passes through
(A) (1, 2) (B) (1, 2)
(C) (2, 1) (D) (2, 1)

104 10
{ x}
35. Let I1   dx and I2   x{x 2 }dx where {.} denotes fractional part of x. Then
1 x 1

(A) I1 = I2 (B) I1 < I2

(C) I1 = 4I2 (D) I1 = 200

36. A married couple has decided not to have more than 5 children. Even if children of both
sex born before, they will stop. It is given that first two children are male. The probability
of less than 5 children is
1 1
(A) (B)
4 8
3 1
(C) (D)
4 2

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37. If [cot1x]2 + (cot 1x)2  2[cot1x]2 (cot1x)  2, where [.] denotes greatest integer  x
& (.) denotes least integer  x, the value of ‘x’ satisfying will be
 
(A) (B)
4 2
(C) cot 1 (D) cot 2
x
38. Let f(x) =   (a  1)(t 2  t  1) 2  (a  1)(t 4  t 2  1)  dt. Then the value of ‘a’ for which
0

f (x) = 0 has two distinct real roots are

(A) (, 2)  (2, ) (B) (2, )
(C) (2, 2) (D) (, 2)

SECTION – II
Assertion – Reason Type
This section contains 3 multiple choice questions numbered 39 to 41. Each question has 4 choices (A), (B), (C) and
(D), out of which MORE THAN ONE IS/ARE CORRECT.

39. If one of the lines of my2 + (1 – m2)xy – mx2 = 0 is a bisector of the angle between the
lines xy = 0 then m is
(A) 1 (B) 2
1
(C)  (D) – 1
2
  6
40. If |z – 3i| = 3 and amp z   0,  then cot(amp z)  is equal to
 2  z
(A) i (B) 1
1
(C) – 1 (D) 
i

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41. If in a ABC, r1 = 2r2 = 3r3, then

a 4 a 5
(A)  (B) 
b 5 b 4
a 3 a 5
(C)  (D) 
c 5 c 3

SECTION – III
Linked Comprehension Type
This section contain 1 paragraph M42-44. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

M42–44 : Paragraph for Question Nos. 42 to 44

Consider a hyperbola xy = 4 and a line y + 2x = 4. O is centre of hyperbola. Tangent at any point

P of hyperbola intersect the co-ordinate axis at A and B.

42. Area of OAB is

(A) Constant and equal to 16 (B) Constant and equal to 32
(C) Constant and equal to 64 (D) Variable

43. Locus of circumcentre of OAB is

1
(A) An ellipse with eccentricity
2
1
(B) an ellipse with eccentricity
3
(C) a hyperbola with eccentricity 2
(D) a circle of radius 2

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44. Shortest distance between the line and hyperbola is

2 4( 2  1)
(A) 8 (B)
5 5
2 2 4( 2  1)
(C) (D)
5 5

SECTION – IV
Subjective Questions

This section contains 2 subjective questions numbered 45 to 46.

45. If the greatest negative integer value of parameter a so that x3 – 12x + [a] = 0 has exactly
one real root, is – k, then find the value of ‘k’.

46. If f(x) is continuous and differentiable function such that f(x + y) = f(x) + f(y) + xy
f (h)
x, y  R and hlim
0  1, then find the area bounded by the curve y = 2f(x) and
h
y = 4 – x2.

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SECTION – V
Matrix–Match Type
p q r s
This section contains 2 questions. Each question contains statements given in two p q
A r s
column which have to be matched. Statements (A, B, C, D) in Column I have to be
matched with statements (p, q, r, s) in Column II. The answers to these questions B p q r s
have to be appropriately bubbles as illustrated in the following example.
C p q r s
If the correct matches are A–p, A–s, B–q, B–r, C–p, C–q and D–s, then the correctly
p q r s
bubbled 4 × 4 matrix should be as follows : D

47.
Column I Column II
(A) The number of non-differentiability points on the curve (p) 1
y = |e|x|  3| is/are
(B) Length of the latus-rectum of the parabola defined by x = (q)
0
cos t  sint and y = sin 2t
(C) The number of real solution of the equation x 2log x (x  3) = 16
(r) 3
is
 r  r  (s)
(D) If in a triangle 2R + r = r1, then 1  1   1  1  is equal to 2
 r2   r3 

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48.
Column I Column II
(A) Area of the rectangle formed by asymptotes of the (p) 32
hyperbola
xy – 3y – 2x = 0 and co-ordinate axes is
(B) Area bounded by min (|x|, |y|) = 1 and max (|x|, |y|) = 3 (q)
2
is,
(C) The number of common tangents of the two circles
x2 + y2 – 10x – 6y + 9 = 0 and x2 + y2 – 4x + 2y – 11 = (r) 5
0 are
(D) The greatest value of f(x) = 2cos(2xex + 7x4 – log (1 + (s)
6
x2))

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