• Learn PVT behaviour of fluids, laws of thermodynamics • Understand the nature and role of the following thermodynamic properties of matter :internal energy, enthalpy, entropy, temperature, pressure and specific volume • Access thermodynamic property data from appropriate sources • Chart thermodynamic processes on appropriate thermodynamic diagrams, such as a temperature-entropy or pressure-volume diagram • Recognize and understand the different forms of energy and restrictions imposed by the first law of thermodynamics on conversion from one form to another
COURSE OUTCOMES
After completion of this course, students will be able to
• Apply thermodynamic concepts and the laws of thermodynamics to various systems and processes • Resolve thermodynamic competence of different energy associated processes • Gauge the properties of ideal and real mixtures based on thermodynamic ethics • Establish changes in the properties of fluids undergoing changes in temperature and volume • Explain the effects of Compression at different work environment
UNIT I LAWS OF THERMODYNAMICS
Laws of Thermodynamics Laws of Thermodynamics: Basic concepts; Zeroth l aw; First Law - applications to non-flow and flow processes; Second Law - heat engines, Carnot cycle and theorem, Entropy calculations; Third Law of thermodynamics.
UNIT II PROPERTIES OF REAL GASES AND THERMODYNAMICS
FORMULATIONS Properties of Real Gases and Thermodynamics Formulations: PVT behaviour of fluids - compressibility factor, two- and three-parameter theorems of corresponding states; Equation of states- Virial, Vander Waals, Redlich-Kwong and Peng-Robinson equations; Basic energy relations; Maxwell relations.
UNIT III PROPERTIES OF SOLUTIONS
Partial molar properties; chemical potential; fugacity and activity coefficients; Gibbs -Duhem equation; enthalpy , entropy and Gibbs free energy changes in mixing of ideal solution.
UNIT IV PHASE EQUILIBRIA
Phase equilibrium and stability; criteria for equilibrium between phases in single and multi - component non-reacting systems; vapor-liquid equilibrium of binary ideal and non-ideal solutions; azeotropes; Raoult‘s l aw and Henry‘s law; P-x- y and T-x- y diagrams using Antoine equations.
UNIT V CHEMICAL REACTION EQUILIBRIA 12
Criteria of equilibrium; standard free energy change and react ion equilibrium constant; effect of temperature and pressure on reaction equilibrium constant; homogeneous chemical reactions - thermodynamic analysis and prediction of equilibrium compositions. Total: 60
SUGGESTED READINGS
1. J.M. Smith, H.C. Van Ness and M.M. Abbott, “Introduction to Chemical Engineering Thermodynamics”, 8th edition, McGraw-Hill International Edition, 2019 2. S.Sandler, “Chemical, Biochemical and Engineering Thermodynamics”, 4th edition, Wiley, India. 2006 3. 4. K.V. Narayanan, A Textbook of Chemical Engineering Thermodynamics, Prentice Hall India, 2004 5. Y.V.C.Rao, “Chemical Engineering Thermodynamics”, University Press, Hyderabad, 2007. 6. Pradeep Ahuja, Chemical Engineering Thermodynamics, PHI Learning Ltd, 2009 7. Thermodynamics https://nptel.ac.in/courses/103/104/103104151/
