Research Progress in The Development of Natural Gas As Fuel For Road Vehicles: A Bibliographic Review (1991-2016)
Research Progress in The Development of Natural Gas As Fuel For Road Vehicles: A Bibliographic Review (1991-2016)
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Research progress in the development of natural gas as fuel for road vehicles:
A bibliographic review (1991–2016)
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art ic l e i nf o a b s t r a c t
Article history: Among all alternative fuels, compressed natural gas (CNG) has been considered as one the best solutions
Received 8 November 2015 for fossil fuel substitution because of its availability throughout the world, inherent clean burning,
Received in revised form economical as a fuel and adaptability to the gasoline and diesel engines.
19 August 2016
This bibliography reviews the potential of CNG as a transportation fuel. The added bibliography at the
Accepted 23 August 2016
end of this article contains 1102 references to papers, conference proceedings and theses/dissertations on
the subject that were published between 1991 and 2016. These references have been retrieved from 137
Keywords: scientific journals. The references are classified in the following categories: Regional Experience with
Vehicle CNG Vehicles; Economic Aspect of CNG Vehicles; CNG Engine's Design, Control and Performance;
CNG
Combustion and Fuel Injection Characteristics of CNG Engines; CNG/ Diesel Dual Fuel Operations; Hy-
Emission
drogen Enriched CNG Vehicles; Environmental Aspect of CNG Vehicles; Safety Aspect of CNG Vehicles.
Natural gas
Transportation & 2016 Elsevier Ltd. All rights reserved.
Contents
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 702
2. Regional experience with CNG vehicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 703
3. Economic aspect of CNG vehicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 703
4. CNG engine's design, control, and performance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 704
5. Combustion and fuel injection characteristics of CNG engines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 704
6. CNG/diesel dual fuel operations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 705
7. Hydrogen enriched CNG vehicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 705
8. Environmental aspect of CNG vehicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 705
9. Safety aspect of CNG vehicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 705
9.1. Concluding remarks and future directions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 705
Acknowledgment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 707
Annexure-A. (Journal's List) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 707
Annexure-B. (Bibliography). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 708
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 740
n
Corresponding author.
E-mail address: [email protected] (M.I. Khan).
http://dx.doi.org/10.1016/j.rser.2016.08.041
1364-0321/& 2016 Elsevier Ltd. All rights reserved.
M.I. Khan et al. / Renewable and Sustainable Energy Reviews 66 (2016) 702–741 703
1. Introduction Beijing (China), New York (USA), Brussels (Belgium), São Paulo
(Brazil), Salvador (Brazil), Rio de Janeiro (Brazil).
The yield of scientific articles is generally rising fast and pro-
fessionals are no longer able to be fully abreast with all pertinent
information. The rising specialization in various scientific arenas 3. Economic aspect of CNG vehicles
has triggered the dissemination of subject-oriented journals and
conference proceedings focused to specialist audiences. The One of the major advantages of CNG is that it offers a cheap
scholars have now more options for sharing the results of their source of energy. As the world continues to run with expensive
scientific work, but on the other hand exploring the relevant in- fuels such as and gasoline and diesel, the low-cost CNG offers a
formation may be a laborious and time-consuming process. glimmer of hope. Although emission reduction using natural gas
Moreover, sometimes the researchers are not willing to devote was the main focus of CNG application as a transportation fuel,
time to exploring the relevant information. It has been pointed out especially in metropolitan regions, in recent days, with a sharp rise
that in the field of engineering, informal knowledge channels are in oil prices, the increasingly considerable cost benefit of using
most frequently used for getting information [1]. natural gas has become a real major consideration for many new
With increasing government restriction of tailpipe emissions users. In most countries, natural gas is much cheaper than per
from vehicles powered by internal combustion engines and equivalent gallon of diesel and gasoline, even after accounting for
growing concern over the use and exhaustion of fossil fuel, alter- the costs linked with compression and even considering its lower
native fuels has gained popularity [2,3]. Natural gas has a widely thermal efficiency against diesel and gasoline, there are significant
used alternative fuel for a variety of reasons including ready economic benefits of using CNG as a transportation fuel. Gasoline
availability and its low cost and low emissions potential relative to and diesel must be passed through the complex refining process,
conventional fuel and its applicability in convention diesel and while natural gas needs very less processing from field to the
gasoline engines [4]. Natural gas is scattered in many regions of vehicle engine. It is also less prone to price fluctuations and as
the world so that it can stable supply. Therefore natural gas has compared to its resources are more evenly distributed around the
been subjected widely as a kind of clean alternative fuel for en- world.
gines [5–7]. One of the important factors for comparing the economic as-
The bibliography provided at Annexure-B contains 1102 refer- pect of automotive technology is the associated maintenance cost.
ences to journal's papers, conference proceedings and theses/dis- Although a review of the literature found no previous empirical
sertations on the subject that were published between 1991 and work that has examined the issue of maintenance cost competi-
2016. These references have been retrieved from 137 scientific tiveness of latest NGV or diesel technologies based on total life-
journals listed at Annexure-A. cycle costs. However, there are few studies which examined the
The bibliography is divided into the following parts and operating cost associated with natural gas vehicles. Based on
concerns: limited studies and research on comparative operating costs, evi-
dence supports both cost increases, cost decreases costs are
■ Regional Experience with CNG Vehicles equivalent [9–14].
■ Economic Aspect of CNG Vehicles However the association of high cost with the development of
■ CNG Engine's Design, Control and Performance refueling infrastructure (pipelines and filling stations for CNG ve-
■ Combustion and Fuel Injection Characteristics of CNG Engines hicles) remains the most significant barrier to the adaptation of
■ CNG/ Diesel Dual Fuel Operations CNG as an alternative fuel but with sufficient visibility on demand,
■ Hydrogen Enriched CNG Vehicles supportive economics, and government incentives these barriers
■ Environmental Aspect of CNG Vehicles appear surmountable. Nearly all of the countries where CNG in-
■ Safety Aspect of CNG Vehicles frastructure has been developed; incentive programs offered to
investors such as loans, subsidies, exemptions from import duties
It is difficult for the authors to recap the wide topics of this and the lowering or elimination of import tariffs on machinery,
article in a form of the state-of-the-art review article; therefore a equipment, and kits (price-supplier); and exemption from sales
bibliography is presented here. Hope, this bibliography will save taxes for the construction and operation of refueling stations. Once
time for researchers looking for information pertinent with the subsidies for fueling stations and NGV customers run out, the
subjects listed below, not having access to large databases or not expected profitability of new CNG filling facilities is no longer at-
willing to spend time on uncertain information retrieval. tractive enough. In e.g. Canada, reducing investments in fueling
stations caused the collapse of the whole NGV sector [15]. Costs of
installing CNG infrastructure can vary significant depending on
2. Regional experience with CNG vehicles size, capacity and the way natural gas is dispensed (fast-fill, time-
fill). Consequently, costs can vary widely from project to project
The word is turning towards substitute to gasoline and petro- and country to country. As the land is a significant component in
leum-based energy that is taking an upward trend in terms of building a CNG station so the cost depends on the decision to build
price. Across the globe, various countries have experienced that the station on a new site, or incorporate CNG fueling at an existing
CNG is good for the consumer and friendly to the environment site such as an existing diesel fuel station. Worldwide the average
while pushing the country into more independent state [8]. An costs identified in various studies to construct a CNG station ran-
increasing number of countries across the globe are jumping on ged between $600,000 and $1,000,000 per station excluding land
the bandwagon to make use of CNG, due to its various benefits. cost. In Pakistan the country having the highest number of CNG
This section of the bibliography covered the case studies of station after China, the average cost of constructing a CNG station
various countries and cities regarding their experience for using is comparatively much low and amounting to 150,000 US $. Ta-
the CNG as a transportation fuel. The case studies of the countries ble 1 provides estimates of total costs to construct a CNG station in
and cities listed: UK, USA, Pakistan, China, Japan, Germany, Ar- Pakistan.
gentina, Switzerland, Brazil, Qatar, Korea, Indonesia, Malaysia, In addition to short-term economics, there are several socio-
Sweden, Algeria, Nigeria, Ireland, Milan, Tokyo (Japan), Dhaka economic aspects associated with the development of natural gas
(Bangladesh), Delhi (India), Santiago (Chile), Madrid (Spain), as vehicular fuel. One of the significant impacts of the NGVs will be
704 M.I. Khan et al. / Renewable and Sustainable Energy Reviews 66 (2016) 702–741
the opportunities for local businesses. These opportunities in- 5. Combustion and fuel injection characteristics of CNG
clude new construction jobs associated with building new sta- engines
tions and supply infrastructure; employment associated with
retrofits of existing engines and jobs related to manufacturing or The natural gas used in natural gas vehicles is the same natural
supplying parts and equipment needed to expand the industry. In gas that is used in domestic sector for cooking and heats. CNG is
Pakistan, the 2nd largest user of CNG, the NGVs sector of the produced by compressing the conventional natural gas (which is
country has attracted more than one billion US $ investment have mainly composed of methane –CH4) to less than 1% of the volume
created more than 121,000 cumulative (direct and indirect) job it occupies at standard atmospheric pressure. It is stored and
opportunities [8]. Moreover, as the prices of natural gas com- distributed in a rigid container at a pressure of 200–248 bar
pared to gasoline or diesel fuel is significantly less and stable in (2900–3600 psi), usually in cylindrical shapes metallic cylinder.
most of NGVs user countries so it enhances the buying capacity of Table 2 represents the comparison between the physiochemical
customers. properties of CNG to that of diesel and gasoline.
The most observable social advantage associated with operat- The combustion properties of natural gas are significantly dif-
ing vehicles with CNG pertains to the environmental advantage of ferent from regular fuel i.e. diesel and gasoline. Natural gas can
natural gas. As previously discussed in Section 8, compared to oil, burn cleaner than gasoline. This is due main to more favorable
natural gas releases lower levels of carbon dioxide, sulfur, nitrogen thermodynamic properties of the mixture, lowered peak cylinder
oxides, and ash. By emitting fewer harmful chemicals into the air, temperatures reducing engine heat losses and reduced pumping
natural gas can help alleviate different environmental problems. losses through reduced throttling. As compared to diesel and ga-
Compared to oil, natural gas releases lower levels of carbon di- soline, CNG has a longer ignition delay time due to low flame
oxide, sulfur, nitrogen oxides, and ash. By emitting fewer harmful propagation speed. CNG has lower flame propagation speed as
chemicals into the air, natural gas can help alleviate different en- compared to conventional liquid fuels, such as gasoline and diesel
vironmental problems. Secondly, since natural gas combustion [16]. This lower flame propagation speed reduces the engine brake
produces a lower level of nitrogen oxides and particulate matter, it horsepower by 5–10%.
will contribute significantly less to smog formation and acid rain, The following topics are handled: combustion concepts for
preventing damages to crops, wildlife, and humans’ respiratory mono-fuel, bi-fuel and dual fuel operation of natural gas in IC
systems. engines; Homogeneous Charge Compression Ignition (HCCI), Pre-
Topics handled in this section: comparative economics of CNG; mixed Charge Compression Ignition (PCCI), Reactivity Controlled
cost-effectiveness evaluation of diesel vs. CNG for buses; com- Compression Ignition (RCCI); numerical simulation of CNG com-
mercializing CNG as a fuel; potential of CNG transport; policy bustion; Effect of EGR on CNG combustion; kinetic models of CNG
development for marketing CNG; CNG vehicles energy consump- combustion; the influence of fuel composition on the combustion;
tion life-cycle analyses; empirical analysis on the adoption of CNG; Different injection strategies; Sequential Port Injection, direct in-
global opportunities for CNG as a transportation fuel; fuel con- jection with homogeneous mixture, direct injection with stratified
sumption of CNG vehicles. mixture, partially-stratified natural gas injection; electronically
Table 2
4. CNG engine's design, control, and performance Physiochemical properties of CNG vs Gasoline & Diesel.
The octane number of natural gas is ranging from 120 to 130. Properties CNG Gasoline Diesel
Due to this high value of octane number, CNG has a higher knock Octane/Cetane number 120–130 85–95 45–55
resistance than gasoline which enables the use of higher com- Molar mass (kg/mol) 17.3 109 204
pression ratio and thus higher engine efficiency. The performance Stoichemetric (A/F)s mass 17.2 14.7 14.6
of CNG-fueled engine highly depended on the engine design and Stoichemetric mixture density (kg/m3) 1.25 1.42 1.46
L.H.V. (MJ/kg) 47.5 43.5 42.7
type i.e. mono-fuel, bi-fuel or dual fuel. However, the major per-
L.H.V. of stoichemetric mixture (MJ/kg) 2.62 2.85 2.75
formance draws back with natural gas vehicles is the 15–20% loss Combustion Energy (MJ/m3) 24.6 42.7 36
in brake horsepower of the engine. The major attributes for this Flammability limit in air (vol% in air) 4.3–15.2 1.4–7.6 1–6
power losses low flame propagation and lost in volumetric effi- Flame propagation speed (m/sec) 0.41 0.5 –
ciency. Due to the low densities, gaseous fuels occupy 4–15 of Adiabatic Flame Temp. °C 1890 2150 2054
Auto-ignition Temp. °C 540 258 316
intake passage volume resulting in significant reduction of volu- Wobbe Index (MJ/m3) 51–58 – –
metric efficiency when compared to liquid fuels. With its low
M.I. Khan et al. / Renewable and Sustainable Energy Reviews 66 (2016) 702–741 705
controlled gas injection system; spark ignited direct injection 8. Environmental aspect of CNG vehicles
(SIDI); spark plug fuel injector (SPFI) System;.
Exhaust gas emissions from transportation industries have
become one of the most prominent environment and social-eco-
6. CNG/diesel dual fuel operations nomic issue. The industry is moving toward alternative fuel due to
several reasons including climate change from an increase of
Diesel engines were traditionally preferred due to its lower greenhouse gas emissions, the increase of health problems in
running cost and better torque characteristics; however, during polluted cities and the political and social instability related to oil
the past decade, stringent emissions norms have mandated the supply and price. CNG is identified as a leading candidate for the
use of several advanced combustion and after-treatment technol- green transportation fuel among other alternative fuels. The main
ogies, which in turn have made the diesel engine power train constituent of CNG is methane, the simplest alkane with only one
expensive and complex. In recent years, a concern over the carbon atom and consequently no carbon-to-carbon bonds. The
emissions of a greenhouse gas like CO2 and particulate matter PM simple chemical structure of methane makes it an inherently clean
has further posed an additional challenge to the development of burning fuel. When used as motor fuels, this results in low parti-
diesel engines. One way to overcome these problems is by em- culate (PM) emissions and low toxicity of the exhaust gasses.
ploying dual fuel technology in which part of diesel fuel is sup- However, the nitrogen oxides (NOx) emissions of an engine are
plemented by natural gas which is fumigated in the intake first and foremost determined by the combustion scheme and
manifold. possible exhaust gas after- treatment. Tables 3,4 summarizes the
Existing diesel engines may be converted readily to operate major worldwide experiential studies conducted to evaluate the
primarily on CNG, using diesel as a spark plug to achieve ignition. comparative emission performance of NGVs.
Due to the high ignition temperature of natural gas, it needs very Topics handled in this section: experimental comparative
high compression ratio for auto ignition i.e. about 38:1. Owing to emission analysis of CNG in bi-fuel engines, impact of CNG on air
this, it should be ignited with another fuel (diesel)—pilot injection. quality; comparative life-cycle emissions analysis of CNG; regu-
The substitution rates vary depending on the engine load. A lated and unregulated exhaust emissions from CNG vehicles;
maximum substitution rate up to 90% can be obtained with the physical properties of the particle emissions from a CNG vehicles;
currently available dual-fuel engines. Substitution rate affects both evaluating carbon emissions reduction by use of CNG; on-road
engine performance and emission. When required the system al- measurement of regulated pollutants from diesel and CNG ve-
lows the engine to run on 100% diesel. The use of diesel fuel allows hicles; real-time NOx measurements from CNG and diesel transit
buses; Influence of CNG compositions on the regulated emissions;
the retention of the diesel compression ratio and its efficiency
well-to-wheels of CNG fuel; environmental benefits of CNG buses;
while the natural gas contributes to fuel economy and is re-
comparative ultrafine particle emissions from diesel and CNG
sponsible for lowering emissions. The peak combustion tempera-
buses.
ture reduces which reduces NOx emission. Drastic reduction in PM
Tables 3,4 summarize the major worldwide experiential studies
emission has been observed when the engine operates under dual
conducted to evaluate the comparative emission performance of
fuel mode.
NGVs.
Topic handled in this section: performance of a diesel/CNG
dual-fuel engine; effect of engine parameters on the performance
of dual-fuel engines; performance characteristics of a turbo-
9. Safety aspect of CNG vehicles
charged dual fuel engines; combustion simulation of dual fuel
engines; knock characteristics of dual-fuel combustion; NOx re-
Safety of CNG vehicle is a very important aspect. In terms of
duction from a dual-fuel engines; numerical study of the pollution
handling, CNG is much safer than gasoline in many respects [43].
formation in dual-fuel engine; after treatment system for dual-fuel
The physical properties of natural gas offer some safety advantages
operation; emission characteristic of dual-fuel engine; effects of
over gasoline and diesel fuel. For example, at the atmospheric
natural gas percentage on performance of dual-fuel engine.
condition, the natural gas has an auto-ignition temperature of
540 °C in contrast to 258 °C and 316 °C for gasoline and diesel
respectively. This high auto-ignition temperature of natural gas
7. Hydrogen enriched CNG vehicles hinders the possibility of ignition in an open environment. Simi-
larly as compared to diesel/gasoline natural has a narrow flamm-
As discussed 5–10% power loss occurs in CNG-fueled engines ability range i.e. 4.3–15.2% by volume in air, which lowers the
due to the low flame propagation speed of natural gas. One ef- chance of accidental fire of the fuel. Moreover due to gaseous fuel
fective method to address the problem of slow flame propagation and being lighter than air, CNG will dissipate into the air rapidly,
speed of the natural gas is to mix the CNG with the fuel having fast whereas diesel and gasoline will pool on the ground, increasing
burning speed e.g. hydrogen. Hydrogen (H2) is considered as the the risk of fire. Natural gas is also non-toxic and will not con-
best additive for CNG due to its fast flame propagation speed (265– taminate groundwater if leaked.
325 cm/s), much better lean-burn ability and small quenching Topics included in this section: safety issues associated with
distance. This gives the potentiality to develop engines with better the CNG vehicles; risk assessment of CNG buses; CNG cylinders
performance and lower environmental impact [17]. As hydrogen is failure causes; safety features implementation in CNG vehicles;
a carbon-free fuel, the reduction in CO2 emissions is a direct modeling of CNG vehicles refueling; FEA analysis of CNG cylinders;
function of H2 content in the blend. risk analysis of CNG cylinders; health monitoring of CNG cylinders;
Topic listed in this section: kinetic modeling HCNG engine; gas leakage analysis around CNG buses; behavior of a CNG tank
combustion analysis of SI HCNG engine; CO2 emissions from HCNG during fire.
engine; numerical evaluation of HCNG engine performance;
emission characteristics of HCNG engine; effect of H2 addition to 9.1. Concluding remarks and future directions
duel-fuel engine; effect of H2 addition on CNG HCCI combustion,
effect of compression ratio on HCNG engine performance; life The available literature shows that CNG has seen some sig-
cycle greenhouse emissions from HCNG engine. nificant success in terms of adoption as a transport fuel in various
706 M.I. Khan et al. / Renewable and Sustainable Energy Reviews 66 (2016) 702–741
Table 3
Emission summary of major worldwide experiential studies.
S.N. Study Study Test Method Vehicle Fuel Emission Factor (g/km)
Year
Type Disp. (cc) After CO2 CO NOx NMHC
treatment
1 Kelly et al.[18] 1996 Real world operation, Ded, CNG Van – – CNG 352 2.35 0.34 0.11
Washington DC, USA Gasoline Van – – Gasoline 416 3.64 0.49 0.18
2 Heidinger et al. 1996 Real world operation, Bi-Fuel Car 1968 TWC CNG – 1.79 0.26 1.4
[19] Vienna, Austria Gasoline – 2.41 0.41 0.31
3 Coroller et al 1998 CBD Cycle, Paris 3 CNG bus 9500 Nil CNG – 6 12.2 6.23
[20] 4 Diesel Bus 9800 Nil Diesel – 2.85 25.1 1.2
4 Clark et al.[21] 1999 Lab, USA 3 CNG Bus 6500 OC CNG – 1.9 5.4 –
3 Diesel Bus 5900 OC Diesel – 1.5 13.2 –
5 Frailey et al.[22] 2000 CBD cycle, USA 3 CNG Bus 5880 – CNG – 0.4 8.9 –
3 Diesel Bus 5880 – Diesel – 2.4 21 –
6 Chandler et al. 2000 CBD cycle, Hartford 13 CNG bus 5900 OC CNG 460 0.40 3.37 0.30
[23] 3 Diesel Bus 5900 – Diesel 495 1.61 6.65 0.31
7 Ayala et al.[24] 2002 CBD cycle, Los Angeles 3 CNG Bus 8500 Nil CNG – 6.84 11.81 7.40
2 Diesel Bus 8500 Nil Diesel – 0.84 18.77 0.05
NYBC 3 CNG Bus 8500 Nil CNG – 19.08 12.09 16.84
2 Diesel Bus 8500 Nil Diesel – 4.47 31.70 0.13
8 NREL Emission 2002 CBD cycle Washington 5 CNG bus 8300 OC CNG – 0.187 8.46 4.53
Tests[25] 4 Diesel Bus 8500 OC Diesel – 1.7 18 3.2
9 Lanni et al.[26] 2003 CBD cycle, New York 3 CNG Bus 8500 – CNG 1472 11.09 11.09 11.12
2 Diesel Bus 8500 DPF Diesel 1787 14.82 14.82 0.04
10 Pischinger et al. 2003 Dynamometer, Germany Bi-fuel car 1800 – CNG – 0.27 0.125 0.20
[27] 1800 – Gasoline – 0.70 0.130 0.27
11 Ullman et al. 2003 Dynamometer 1 CNG bus – Nil CNG – 7.7 26.1 15
[28] 2 Diesel Bus – DPF Diesel – 2.8 22.7 0.6
12 Nylund et al. 2004 OCTA, Finland 2 CNG Bus – OC CNG – – 7 –
[29] 1 Diesel Bus – OC Diesel – – 8 –
13 Ristovski et al 2004 Dynamometer, Australia Bi-Fuel Car 4000 None CNG 361 1.12 0.67 –
[30] Gasoline 561 28 0.94 –
14 Melendez et al. 2005 CBD cycle Washington 7 CNG bus 8300 OC CNG 1370 0.215 9.62 4.35
[31] 5 Diesel Bus 8500 OC Diesel 2034 0.174 12.8 2.92
15 Jayaratne et al. 2009 Real world operation, Ded, CNG Bus – TWC CNG 671 – 12 –
[32] Queensland, Australia Diesel Bus – None Diesel 834 – 10.5 –
16 Fontaras et al 2012 Real world operation, Dual-Fuel Bus 9500 DOC Diesel-CNG 2430 7.43 32.3 0.21
[33] Milan, Italy Ded, CNG Bus 7790 TWC CNG 3660 15.8 4.38 2.19
Ded, CNG Bus 7790 – CNG 2300 1.66 3.91 0.55
Ded, CNG Bus 6900 – CNG 3120 1.01 13.6 6.99
17 Hallquist[34] 2013 Road 7 CNG bus – Nil CNG – o3 21 o 4
28 Diesel Bus – DPF Diesel – 4.33 6.66 o 4
18 Guo J et al.[35] 2014 Real world operation, Euro-V, 4 Ded CNG 8400 OC, SCR CNG 894 5.72 3.42 7.9
Beijing, China Bus & 3 Diesel Bus
8400 OC Diesel 709 1.99 4.3 0.03
19 Arvind et al[36] 2015 UDDS Cycle, Los Angeles, US-EPA 2010, Ded 8900 TWC CNG – 4.72 0.358 0.0186
USA CNG Bus & Diesel
Bus
12,400 DPF Diesel – 2.82 3.42 0.0727
12,800 DPF, SCR 1 Diesel – 0.134 1.230 0.0006
12,800 DPF, SCR 2 Diesel – 0.0248 3.80 0.0093
11,900 DPF, SCR 3 Diesel – 0.0311 5.83 0.0434
20 Aslam et al.[37] 2005 Dynamometer, Malaysia Bi-Fuel Car 1468 TWC CNG 8.4 1.2 (vol%) 2000 ppm 300 ppm
(vol%)
Gasoline 12.8 9.2 (vol%) 875 ppm 1000 ppm
(vol%)
21 Geok et al.[38] 2009 Dynamometer, Malaysia Bi-Fuel Car 1468 None CNG 10.2 2 (vol%) – 110 ppm
(vol%)
Gasoline 12.8 3 (vol%) – 380 ppm
(vol%)
22 Jahirul et al[39] 2010 Dynamometer, Malaysia Bi-Fuel Car 1594 None CNG 7.82 5.4 (vol%) 619 ppm 313 ppm
(vol%)
Gasoline 11.68 10.5 (vol%) 442 ppm 419 ppm
(vol%)
countries around the world. Although worldwide, the environ- hurdle facing the NGVs right now is the price of oil, which has
mental benefits of CNG vehicle technologies are well established, halved in price in the last year. The questions the industry needs to
but according to the latest studies, putting together the short confront are firstly, how long we will have relatively lower oil
lifetime of methane and a high estimate for fugitive methane prices and what impact this will have on the development of
emissions can result in lifecycle emissions for CNG vehicles ex- NGVs. In the prevailing low oil prices, securing a return on in-
ceeding those of modern diesel engine technology equipped with vestment is pivotal to the success of NGVs and at present, this may
exhaust emission filter. Until this issue is settled, the environ- be a challenge. Governmental incentives, such as those offered in
mental benefits of natural gas vehicles are uncertain. Similarly, a most of the countries may help.
M.I. Khan et al. / Renewable and Sustainable Energy Reviews 66 (2016) 702–741 707
Table 4
Particle mass emission factor (PMEF) from comparative studies of diesel and CNG buses.
S.N Study Study Year Vehicles Test Method Fuel After treatment PMEF (g/km)
1 Wang et al.[40] 1997 Over 300 buses CBD transient cycle Diesel – 20
CNG – 1
2 Coroller et al[20] 1998 4 Diesel & 3 CNG buses CBD Cycle, Paris Diesel – 0.35
CNG – 0.04
3 Clark et al.[21] 1999 3 Diesel & 3 CNG buses CBD transient cycle Diesel OC 0.24
CNG OC 0.025
4 Frailey M. et al.[22] 2000 3 Diesel & 3 CNG buses CBD transient cycle Diesel – 0.38
CNG – 0.012
5 Chandler K. et al.[23] 2000 3 Diesel & 13 CNG buses CBD cycle, Hartford Diesel – 0.02
CNG OC 0.01
6 Ahlvik P. et al.[41] 2000 Diesel & 3 CNG buses CBD transient cycle Diesel None 0.16
Diesel OC 0.112
Diesel DPF 0.011
CNG None 0.017
CNG OC 0.012
7 NREL Emission Tests[25] 2002 4 Diesel & 5 CNG buses CBD cycle Washington Diesel OC 0.62
CNG OC 0.093
8 Ayala et al.[24] 2002 2 Diesel & 3 CNG buses CBD cycle, Los Angeles Diesel None 74.02
CNG None 22.81
NYBC Diesel None 392.17
CNG None 60.35
9 Lanni T. et al.[26] 2003 2 Diesel & 3 CNG buses CBD cycle, New York Diesel DPF 0.0267
CNG None 0.0197
10 Ullman TL. et al.[28] 2003 2 school buses CHSVC transient cycle Diesel None 0.115
Diesel PT 0.006
CNG None 0.033
11 Nylund N. et al.[29] 2004 2 Diesel & 3 CNG buses BSC & OCC transient cycle Diesel None 0.17
Diesel OC 0.12
Diesel PT 0.02
CNG None 0.02
CNG OC 0.01
12 Melendez M. et al.[31] 2005 5 Diesel & 7 CNG buses CBD cycle Washington Diesel OC 0.0081
CNG OC 0.0054
13 Kado N. et al.[42] 2005 2 Diesel & 3 CNG buses 3 transient cycles Diesel OC 0.056–0.074
Diesel PT 0.002–0.010
CNG None 0.014–0.058
1 steady state at 55 m/h @ 60% power Diesel OC 0.014
Diesel PT 0.002
CNG None 0.014
14 Jayaratne E. et al.[32] 2008 Diesel & dedicated CNG buses CBD Cycle, Queensland, Australia CNG TWC 0.163
Diesel None 96.5
15 Gua J et al.[35] 2014 Euro V- 3 Diesel & 4 dedicated CNG buses Real world operation, Beijing, China CNG OC, SCR 0.307
Diesel OC 1.09
16 Arvind et al[36] 2015 US-EPA 2010, Ded. CNG and Deisel Bus UDDS Cylce, Los Angeles, USA CNG TWC 1.68
Diesel DPF 2.367
Diesel DPF, SCR 1 6.03
Diesel DPF, SCR 2 4.58
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261. Kalam, M. A., Masjuki, H. H., Maleque, M. A., Amalina, M. A., Sized Two-Stroke SI Engines (No. 2001-01-1959). SAE Technical
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262. McTaggart-Cowan, G. P., Bushe, W. K., Rogak, S. N., Hill, P. G., & mulated results detailing the sensitivity of natural gas HCCI
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263. McMillian, M., Richardson, S., Woodruff, S. D., & McIntyre, D. Employing an ionization sensor for combustion diagnostics in a
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264. Lanni, T., Frank, B. P., Tang, S., Rosenblatt, D., & Lowell, D. haust Emissions_Characteristics in a Direct Injection Natural
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267. Yoshida, Y., Oguchi, M., & Sugiyama, G. (2003). Measuring Two-Wheeled Vehicle with Electronically Controlled Gas In-
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268. Kumarappa, S., & PrabhuKumar, G. P. (2004). Experimental in- control to optimize the efficiency of compression ignition en-
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269. Murakami, A., Toda, T., & Matsuki, M. (2002). Engine Control Application (No. 2003-26-0040). SAE Technical Paper.
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270. Dyntar, D., Onder, C., & Guzzella, L. (2002). Modeling and III CNG Engine for a Light Commercial Vehicle (No. 2007-26-
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277. Belchior, C. R., Barcellos, W. M., Pimentel, V. S. D. B., & Pereira, P. motored SI engine. SAE International Journal of Engines, 5
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298. Kaiadi, M., Tunestål, P., & Johansson, B. (2011). Reducing and Engineering, 21, 524-531.
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299. El-Din, H. A., Elkelawy, M., & Yu-Sheng, Z. (2010). HCCI engines compressed natural gas dual fuel operation with diesel and
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300. Feist, M. D., Landau, M., & Harte, E. (2010). The effect of fuel ignition) engine. Energy, 68, 495-509.
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301. Garg, M., & Ravikrishna, R. (2010). CFD Modeling of In-Cylinder reduction against base diesel engine. JSAE review, 22(2), 237-
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302. Shanmugam, P., Anbukarasu, A. S., Babu, Y. R., Harne, V., Rair- of a Spark Plug Fuel Injector (SPFI) for Compressed Natural Gas
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306. Pipitone, E., & Beccari, S. (2009). Performances improvement of opment of oxygen sensor for compressed natural gas engine.
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308. Abou-Arab, T. W., Mohamed, H. S., & Tayea, D. A. (2009). 325. Usmen, R.K., Subramanian, S., McCabe, R.W. and Kudla, R.J.,
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485. Ma, F., Liu, H., Wang, Y., Wang, J., Ding, S., & Zhao, S. (2008). A combustion and performance characteristics of a turbocharged
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488. Merkisz, J., Bajerlein, M., Kozak, W., & Markowski, J. (2008). The and a three way catalyst (No. 2005-01-0250). SAE Technical
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490. Obiols, J., Soleri, D., Dioc, N., & Moreau, M. (2011). Potential of lysis of combustion parameters and their relation to operating
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A comparison of engine emissions from heavy, medium, and hicles operating on gasoline, liquefied petroleum gas (LPG) and
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885. Papagiannakis, R. G., Rakopoulos, C. D., Hountalas, D. T., & Ra- 900. Taniguchi, S., Masubuchi, M., Kitano, K., & Mogi, K. (2012).
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dual fuel, compression ignition engine operating in a wide dual fuel (DDF) engine (No. 2012-01-1649). SAE Technical
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886. Thiruvengadam, A., Besch, M. C., Thiruvengadam, P., Pradhan, (OBD) Methods for Three-Way Catalysts Applicable to Various
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887. Majid, Z. A., Mohsin, R., & Nasri, N. S. (2015). Comparative study Regulated Emissions, Particle Number and Size Distribution
on exhaust emission and engine performance of single cylinder Emissions from a Refuse Hauler Truck. SAE International Jour-
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888. Kawasaki, K., Kubo, S., Yamane, K., & Kondo, C. (2014). The Ef- mented Large Bore Four-Stroke SI Engines (No. 2011-26-0005).
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7(2014-01-2697), 718-725. Bach, C. (2010). Unregulated emissions with TWC, gasoline &
889. Amirante, R., Distaso, E., Tamburrano, P., & Reitz, R. D. (2015). CNG (No. 2010-01-1286). SAE Technical Paper
Measured and Predicted Soot Particle Emissions from Natural 905. Shanmugam, R. M., Kankariya, N. M., Honvault, J., Srinivasan, L.,
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890. Besch, M. C., Israel, J., Thiruvengadam, A., Kappanna, H., & mance and emission characterization of 1.2 L MPI engine with
Carder, D. (2015). Emissions Characterization from Different multiple fuels (E10, LPG and CNG). SAE International Journal of
Technology Heavy-Duty Engines Retrofitted for CNG/Diesel Fuels and Lubricants, 3(2010-01-0740), 334-352.
Dual-Fuel Operation. SAE International Journal of Engines, 8 906. Pielecha, J., Merkisz, J., Markowski, J., & Gis, W. (2010). On-
(2015-01-1085). Board Emissions Measurement from Gasoline, Diesel and CNG
891. De Gennaro, M., Paffumi, E., Martini, G., Manfredi, U., Rossi, R., fueled Vehicles (No. 2010-01-1568). SAE Technical Paper.
Massari, P., & Roasio, R. (2015). Gaseous Emissions from Gaso- 907. Cachón, L., Tóth, D., Puchberger, G., & Pucher, E. (2009). Off-
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892. Karavalakis, G., Gysel, N., Hajbabaei, M., Durbin, T., Johnson, K., 908. Cachón, L., Tóth, D., & Pucher, E. (2009). Real-world Emission
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emissions from a transit bus (No. 2013-01-1137). SAE Technical 909. Cordiner, S., de Simone, G., & Mulone, V. (2009). Experimental-
Paper. Numerical Analysis of Nitric Oxide Formation in Partially
893. Zhou, L., Liu, Y., Sun, L., Hou, H., Zeng, K., & Huang, Z. (2013). Stratified Charge (PSC) Natural Gas Engines. SAE International
Effect of Hot Exhaust Gas Recirculation on the Combustion Journal of Engines, 2(2009-01-2783), 326-340.
Characteristics and Particles Emissions of a Pilot-Ignited Nat- 910. Cordiner, S., Mulone, V., Rocco, V., Scarcelli, R., Iannaccone, S., &
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894. Faghani, E., Patychuk, B., McTaggart-Cowan, G., & Rogak, S. Reduce Emissions of a Dual Fuel Diesel-Natural Gas Engine (No.
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in a High Pressure Direct-Injection Natural Gas Engine (No. 911. Tang, S., LaDuke, G., Whitby, R., Li, M., & Mazurek, M. A. (2008).
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895. Thipse, S. S., Kavathekar, K. P., Rairikar, S. D., Tyagi, A. A., & Light-Duty Gasoline, Diesel and CNG Vehicles over Different
Marathe, N. V. (2013). Development of Environment Friendly Driving Cycles. SAE International Journal of Fuels and Lu-
Diesel-CNG Dual Fuel Engine for Heavy Duty Vehicle Applica- bricants, 1(2008-01-1745), 1290–1306.
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896. Gautam, A. S., Garrick, R., Lee, J. H., Deminco, C. M., Hannum, P. (2008). Performance and Emissions of a Natural Gas Fueled
E., & Villasmil, L. A. (2012). A Comparison of the Emissions from Two-Stroke SI Engine(No. 2008-01-0318). SAE Technical Paper.
Gasoline vs. Compressed Natural Gas for an Electronic Fuel 913. Cachón, L., Tóth, D., & Pucher, E. (2009). Real-world Emission
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914. Baik, D. S., Lee, J. S., Cho, Y. S., & Lee, S. W. (2008). Combustion 932. McTaggart-Cowan, G. P., Bushe, W. K., Rogak, S. N., Hill, P. G., &
and Emission Characteristics of CNG Fuel inside CVC Chamber. Munshi, S. R. (2005). PM and NOx reduction by injection
SAE International Journal of Fuels and Lubricants, 1(2008-01- parameter alterations in a direct injected, pilot ignited, heavy
0322), 155-161. duty natural gas engine with EGR at various operating condi-
915. Choi, B., Jeong, J., & Lee, C. (2007). Effect of TiO2 on the Re- tions (No. 2005-01-1733). SAE Technical Paper.
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for Lean-burn Natural Gas Vehicle (No. 2007-01-1916). SAE Iannaccone, S. (2001). Influencing Parameters of the Exhaust
Technical Paper. Gas Emissions of a Stoichiometric Natural Gas Bus in Real Use
916. Chiu, J. P., Taylor, J. D., Tai, C., Reppert, T., & Christensen, L. (No. 2001-24-0038). SAE Technical Paper.
(2007). US 2010 Emissions Capable Camless Heavy-Duty On- 934. Catania, A. E., D'Ambrosio, S., Mittica, A., & Spessa, E. (2001).
Highway Natural Gas Engine (No. 2007-01-1930). SAE Techni- Experimental investigation of fuel consumption and exhaust
cal Paper. emissions of a 16V pent-roof engine fueled by gasoline and
917. Prieur, A., & Tilagone, R. (2007). A detailed Well to Wheel CNG (No. 2001-01-1191). SAE Technical Paper.
Analysis of CNG compared to diesel oil and gasoline for the 935. Stodart, A., Aitchison, I., & Lapetz, J. (2001). Emissions Perfor-
French and the European markets(No. 2007-01-0037). SAE mance of Bi-fuel CNG and Bi-fuel LPG Passenger Cars Using
Technical Paper. Sequential Multi-point Injection Systems (No. 2001-01-1195).
918. Hu, L. R., & Williams, S. (2007). Sulfur Poisoning and Re- SAE Technical Paper.
generation of Pd Catalyst under Simulated Emission Conditions 936. Louis, J. J. J. (2001). Well-to-wheel energy use and greenhouse
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919. Ha, D., Park, J., Yeom, J., Ha, J., & Chung, S. (2007). Study on 1343). SAE Technical Paper.
Combustion and Emission Characteristics of CNG Fueled RI- 937. Gambino, M., Iannaccone, S., Battistelli, C. L., Crebelli, R., Iami-
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920. Dalhuijsen, W., Bosma, H., Merts, M., & Buning, L. (2007). In- evaluation for heavy duty diesel and natural gas engines. Part I:
ternal Combustion Engine Vehicle: Emissions and Performance regulated and unregulated emissions with diesel fuel and a
Using Blends of Natural Gas and Hydrogen (No. 2007-32-0072). blend of diesel fuel and biodiesel (No. 2001-24-0044). SAE
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921. Cachón, L., & Pucher, E. (2007). Fuel consumption simulation 938. Tonegawa, Y., Oguchi, M., Tsuchiya, K., Sasaki, S., Ohashi, T., &
model of a CNG vehicle based on real-world emission mea- Goto, Y. (2006). Evaluation of Regulated Materials and Ultra
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922. Schreiber, D., Forss, A. M., Mohr, M., & Dimopoulos, P. (2007). CNG Engine (No. 2006-01-3397). SAE Technical Paper.
Particle characterization of modern CNG, gasoline and diesel 939. McTaggart-Cowan, G. P., Rogak, S. N., Hill, P. G., Bushe, W. K., &
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923. Pucher, E., & Mueller, J. (2005). Real-life Emission Measurement Emissions from a Heavy-Duty Direct Injection of Natural Gas
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924. Tilagone, R., Venturi, S., & Monnier, G. (2005). Natural gas-an Baronick, J. D. (2004). Clean Engine Vehicle A Natural Gas
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925. Tilagone, R., Venturi, S., & Monnier, G. (2006). Natural gas-an class 8 heavy-duty on-highway natural gas and gasoline engine
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