Inter 2 Chemistry Companion Series 2021

AMBITIOUS ACADEMY LAHORE
Ph: +92-333-4082706 Website: www.ambitious.pk/
AMBITIOUS
ACADEMY LAHORE
INTERMEDIATE PART-II
CHEMISTRY
HOME BASED WORK
SHEETS
ALP SMART SYLLABUS
FOR REGULAR STUDENTS
By
Dr. Syed Sharafat Hussain

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248
AMBITIOUS INTER PART 2 CHEMISTRY HOME ASSIGNMENTS
Prepared By Dr. Sharafat Hussain (Lecturer Chemistry Ambitious Academy Lahore)
Page 1 of 17
AMBITIOUS MULTIPLE CHOICE QUESTIONS

UNIT#01+02
1. Keeping in view the size of atoms, which order is correct one:
A Mg > Sr B Ba > Mg C Lu > Ce D Cl > I
2. Mark the correct statement: -
A Na+ is smaller than Na atom B Na+ is larger than Na atom
-
C Cl is smaller than Cl atom D Cl- and Cl atom are equal in size
3. Period five in modern periodic table contains how many elements?
A 32 B 18 C 10 D 8
4. Smaller the size of an ion
A Lesser is degree of hydration B Lesser is polarizing power
C Greater is degree of hydration D Greater is electron affinity
5. Hydrogen can be placed with the elements of group IV-A because both
A Act as oxidizing agents B Act as reducing agents
C Possess the property of calcinations D Form neutral oxides
6. Which of the following element has highest ionization energy?
A N B P C Sb D Bi
nd
7. 2 value of electron Affinity is:
A negative B Positive C Both A and B D Zero
8. Hydration energy of Na+ ion:
A – 390 KJ/mole B – 490 KJ /mole C – 590 KJ /mole D – 690 KJ /mole
9. The elements of atomic number 15 is the member of:
A 2nd period B 3rd period C 4th period D 5th period
th
10. In the 7 period elements present of the p-block:
A 0 B 2 C 6 D 10
11. Which of the following Alkali metal is more reactive:
A Na B Lithium C Cesium D K
12. Ores of beryllium:
A Natron B Beryl C Asbestos D Talc
13. Which Ion will have maximum value of heat of hydration?
A Ba+2 B Mg+2 C Sr+2 D Ca+2
14. During electrolysis of brine which element is deposited at cathode:
A O2 B Cl2 C Na D H2
15. Chrysoberyl has formula:
A Al2O3. B2O3 B Al2BeO4 C Al2O3. 2H2O D Be2O3. H2O
16. Spodumene is the ore of:
A Na B K C Be D Li
17. Chile salt peter is:
A Na2SO4 B NaNO3 C Na2 (SO4)3 D NaNO2

Page 2 of 17
UNIT#03+04
1. Karoline is a mineral of:
A Beryllium B Carbon C Aluminium D Silicon
2. Tincal is a mineral of:
A Boron B Aluminium C Carbon D Silicon
3. Which of the following has highest melting point?
A Silicon B Phosphorous C Sulphur D Aluminium
4. Forms an ion with +3 Charge:
A Carbon B Magnesium C Silicon D Aluminium
5. Valence shell electronic configuration of the elements of group III-A is:
A ns1, np2 B ns2, np2 C ns0,np3 D ns2,np3
6. Chemical name of Borax is:
A Sodium B Sodium tetraborate C Sodium borate D Sodium
metaborate orthoborate
7. The nature of solution of Borax in water is:
A Basic B Neutral C Corrisive D Acidic
8. Which one is most stable:
A HBO2 B H2B2O2 C H3B2O3 D H3BO3
9. Chemical formula of laughing gas is:
A N2O B NO C N2O3 D N2O4
10. Which of the following is reddish brown gas?
A NO B N2O C NO2 D N2O5
11. The most reactive allotropic form of phosphorous is:
A White B Red C Black D None
12. S, Se, Te and Po are called:
A Chalcogens B Halogens C Alkali metals D Coin age metals
13. Following is used in making fire proof clothes:
A Water glass B Borax Glass C Asbestos D Kaolin
14. Gold dissolve in aqua regia to form:
A AuCl3 B AuCl2 C AuCl D None

Page 3 of 17
15. Which metal is rendered passive by HNO3 due to the formation of a film of metal oxide over the
metal?
A Al B Mn C Sn D Co
16. Which of the following metal reacts with HNO3?
A Titanium B Magnesium C Platinum D Iridium
17. Which of the following Catalyst is used in contact process?
A Fe2O3 B V2O5 C SO3 D Ag2O
UNIT#05+06
1. Which of the following hydrogen halide is the weakest acid in solution?
(a) HF (b) HBr (c) HI (d) HCl
2. Chlorine heptoxide (Cl2O7) reacts with water to form:
(a)Hypochlorous acid(b) chloric acid (c)perchloric acid (d) chlorine and oxygen
3. Hydrogen bond is the strongest between the molecules of:
(a) HF (b) HCl (c) HBr (d) HI
4. Which halogen will react spontaneously with Au (s) to produce Au3+?
(a) Br2 (b) F2 (c) I2 (d) Cl2
5. The anhydride of HClO4 is:
(a) ClO3 (b) ClO2 (c) Cl2O5 (d) Cl2O7
6. Bleaching powder may be produced by passing chlorine over:
(a) Calcium carbonate (b) hydrated calcium sulphate
(c) Anhydride calcium sulphate (d) calcium hydroxide
7. Which is the strongest acid?
(a) HClO (b) HClO2 (c) HClO3 (d) HClO4
8. Which halogen occurs naturally in a positive oxidation state?
(a) Fluorine (b) Chlorine (c) Bromine (d) Iodine
9. An element that has a high ionization energy and tends to be chemically inactive would most
likely to be:
(a) an alkali metal (b)a transition element (c) a noble gas (d) a halogen
10. Which of the following represents the correct electronic configuration of the outermost
energy level of an element of zero (VIIIA) group in the ground state?
(a) s2p2 (b) s2p4 (c) s2p5 (d) s2p6
11. Which of the following are non-stoichiometric compounds?
(a) Halogens (b) Halides (c) Interstitial Compounds (d) Oxides
12. The solution of [Ti(H2O)6]3+ ions looks:
(a) Brown (b) Yellow (c) Violet (d) Green
13. The paramagnetic behaviour is strongest for:

Page 4 of 17
(a) Fe3+ (b) Ni (c) Fe2+ (d) Sc2-

14. Number of unpaired electrons in Mn3+ are:
(a) 2 (b) 3 (c) 4 (d) 5
15. Melting point is maximum for:
(a) K (b) Mn (c) Zn (d) W
16. Oxidation state of HClO3 is:
(a) +1 (b) +2 (c) +3 (d) +5
17. I2O5 is……………crystalline solid.
(a) Green (b) White (c) Pink (d) Yellow
UNIT#07+08
1) A double bond consists of.
a) Two sigma bonds (b) One sigma and one pi-bond (c) One sigma and two pi-bonds (d) Two pi-bonds
2) The bond angle between any two sp2-hybridized orbitals is of.
a) 180o b) 109o c) 120o d) 107.5o
3) Formula of chloroform is.
a) CH3 – OH b) CH3 – Cl c) CH2Cl2 d) CHCl3
4) Which one is the heterocyclic compound of oxygen?
a) Pyridine b) Pyrrole c) Furan d) Thiophene
5) In t-butyl alcohol, the tertiary carbon is bonded to.
a) Three hydrogen atoms b) Two hydrogen atoms c) One hydrogen atom d) No hydrogen atom
6) Ethers shows the phenomenon of.
a) Position isomerism b) functional group isomerism c) Metamerism d) Chain isomerism
7) Which set represent the planer triangular shape?
a) sp3 b) sp2 c) sp d) dsp2
8) The chemist who synthesized urea from ammonium cyanate was.
a) Berzelius b) Kolbe c) Wohler d) Lavoisier
2
9) Carbon atom in following is sp -hybridized.
a) CH3CN b) CH ≡ CH c) HCOOH d) CH2Cl2
10) Raney Nickel is prepared by reacting an alloy with caustic soda:
(a) Ni − Cu (b) Ni − Fe (c) Ni − Al (d) Ni − Mg
11) Formula of marsh gas is.
(a) CH4 (b) C2H6 (c) C3H8 (d) C4H10
12) An alkene is treated with cold alkaline KMnO4. What will be of products?
(a) Glycerol (b) aldehyde (c) Glycol (d) ketone
13) An addition of water to ethene produces:
(a) alcohol (b) ketone (c) aldehyde (d) An alcohol and aldehye
14) The order of reactivity of halogen with Alkenes is:
(a)F>Cl>Br>I (b) l>Br>Cl>F (c) Cl>I>B>F (d) Cl>Br>l>F
Page 5 of 17
15) Addition of halogens to alkyne give?

(a)cis- product (b) trans- product (c) Both a & b (d) none
16) The heat of hydrogenation of most of Alkenes is about:
(a) 100KJ/mole (b) 120KJ/mole (c) 140KJ/mole (d) 103 KJ/mole
17) Ni-Al catalyst require pressure for hydrogenation of Alkenes
(a) 1 atm (b) 100 atm (c) 10 atm (d) 3 atm
UNIT#09+10
1. The end product obtained during the oxidation of benzene in the presence of V2O5 is
(a) glyoxal (b) oxalic acid (c) Maleic acid (d) Maleic anhydride
2. Which compound is most reactive one
(a) ethene (b) benzene (c) ethyne (d) all have equal reactivity
3. Among the following the compound that can be easily sulphonated
(a) toulene (b) benzene (c) nitrobenzene (d) Cholorobenzene
4. Actual halogenating agent during the halogenation of benzene is
(a) FeX3 (b) OX2 (c) X- (d) X+
5. Benzene is stable than hypothetic molecules (1,3,5-cyclohexatriene) by ______ energy in
kj/mol
(a) 208 (b) 358.5 (c) 150.5 (d) 239
6. Each carbon atom of benzene is ______ hybridized
(a) sp3 (b) sp2 (c) sp (d) none of these
7. Which one of following compound remain stable to KMnO4
(a) toluene (b) ethene (c) benzene (d) all of these
8. Which one is example of isolated polycyclic aromatic hydrocarbons
(a) Biphenyl (b) Diphenyl methane (c) Triphenyl methane (d) All
9. Benzene was discovered by Michacl Faraday in:
(a) 1925 (b) 1825 (c) 1725 (d) 1625
10. Which group is meta-director:
(a) –NH2 (b) –N2H (c) –NO2 (d) –OH
11. If the breakage of C – X bond and the formation of C – Nu bond take –place simultaneously then
known as.
a) SN1 b) SN2 c) E1 d) E2
12. Hybridization state of carbon atom in transition state of SN2 mechanism is.
a) Sp3 b) Sp2 c) Sp d) Sp2 – Sp2
13. In SN1 mechanism the rate depend upon the concentration of.
a) Alkyl halide b) nucleophile c) Both a & b d) None of these
14. In SN1 mechanism the configuration of product is form.
a) Mixture of configuration(b) Retention of configuration (c) Inversion of configuration (d) None of these
15. When ammonia reacts with excess of ethyl bromide the product is.
Page 6 of 17
a) Ethylamine b) Diethylamine c) Triethylamine d) tetra ammonium ion

16. Which one of the following is not a nucleophile?
a) H2O b) H2S c) BF3 d) NH3
17. For which mechanism, the first step involved in the same.
a) E1 and E2 b) E2 and SN2 c) SN1 and E2 d) E1 and SN1
UNIT#11+12
1- Which compound show maximum hydrogen bonding with water?
a) CH3OH b) C2H5OH c) CH3 – O – CH3 d) C6H5OH
2- Ethanol can be converted into ethanoic acid by.
a) Hydrogenation b) Hydration c) Oxidation d) Fermentation
3- Alcohol obtained by fermentation never exceeds.
a) 10% b) 16% c) 14% d) 95%
4- Which of the following is weakest acid?
a) Phenol b) Benzoic acid c) Ethyl alcohol d) Water
5- Ketones are prepared by Oxidation of.
a) Primary alcohol b) Tertiary alcohol c) Secondary alcohol d) Carboxylic acid
6- Which one is dihydric alcohol?
a) Ethanol b) Cyclohexanol c) Glycerol d) Glycol
7- The most reactive alcohol when O−H bond breaks is.
a) Tertiary alcohol b) Secondary alcohol c) Primary alcohol d) Methyl alcohol
8- Which one will show maximum repulsion with water?
a) C6H6 b) C2H5OH c) CH3CH2CH2OH d) CH3OCH3
9- Which compound is called universal solvent?
a) H2O b) CH3OH c) C2H5OH d) CH3 – O – CH3
10- Which is most acidic?
a) H2O b) CH3OH c) C2H5OH d) CH3 – CH2 – CH2OH
11- Phenol is also called.
a) Carbonic acid b) Carbolic acid c) Carboxylic acid d) Fatty acid
12- Aldehyde and small methyl ketones form crystalline ___________ ppts with saturated sodium
bisulphate solution
(a) White (b) Red (c) Yellow (d) None of these
13- Which of the following pairs of compounds can be distinguished by means of Tollen’s test?
(a) HCHO and CH3CHO (b) CH3CHO and CH3COCH3
(c) HCHO and CH3CH2CHO (d) CH3COCH3 and C6H5COCH3
14- A compound ‘X’ with general formula CnH2nO having three carbons forms brick red precipitated
upon heating with benedicts solution: The X could be:
(a) CH3COCH3 (b) CH3CH2CHO (c) CH2=CH-CH2OH(d) (CH3)2CHCHO
15- A diabetic patient is examined by asking him to bubble his breath through aqueous alkaline iodine
reagent: The exhaled breath of diabetes gives positive result as it contains:
Page 7 of 17
(a) Propanal (b) 1-Propanal (c) 1-butanol (d) Propanone

16- Which aldehyde follow Aldol reactions…………..contain.
(a) 𝛼 −hydrogen (b)𝛽 − hydrogen (c) No 𝛼 −hydrogen (d) None
17- Aldehyde and small methyl ketones form crystalline ppts with saturated sodium bisulphate
solution, the color of ppts is:
(a) White (b) red (c) yellow (d) Green
18. – CN cyano group on hydrolysis give:
(a) Ketone (b) Formaldehyde (c) Amin & Ketone (d) Carboxylic Acid
UNIT#13+15
1. Which is most difficult to oxidize:
A CH3COCH3 B CH3CHO C HCHO D C2H5CHO
2. Ester amylacetate has the flavour of:
A Raspberry B Banana C Orange D Apricot
3. Which compound is polyprotic acid?
A (COOH)2 B C6H4(OH)COOH C CH3COOH D C6H5OH
4. Organic compound having fruity smell are?
A Carboxylic acid B Ester C Ethers D Alcohols
5. Ester benzyl acetate has the flavour:
A Banana B Apricot C Jasmine D Orange
6. Banana flavour is given by the ester:
A Amyl acetate B Amyl butyrate C Oclyl acetate D Ethyl butyrate
7. Which one of the following acid is used to prepare synthetic fibre:
A Acetic acid B Formic acid C Carbonic acid D Butyric acid
8. The carbon atom of a carboxyl group is hybridized:
A Sp B Dsp2 C Sp3 D Sp2
9. Methyl cyanides, on boiling with mineral acids or alkalis yield:
A Formic acid B Propanoic acid C Acetic acid D Butanoic acid
10.Which one is a micro nutrient?
A Boron B Nitrogen C Phosphorous D Potassium
11. Macronutrient for soil is:

Page 8 of 17
A N B Cu C Zn D Fe
12. The fertilizer that contains largest nitrogen as nutrient is:
A Liquid nitrogen B Urea C Liquid D Ammonia gas
ammonia
13. Percentage of nitrogen in urea is:
A 76% B 56% C 46% D 86%
14. Which is not a calcareous material?
A Clay B Limestone C Marble D Chalk
15. The chemical formula of urea is:
A NH2-CO-NH2 B H2-CO-H2 C NH-CO-NH D NH2-SO-NH2
16. Which is the percentage alumina in Portland cement?
A 22% B 7.5% C 2.5% D None
17. Which one of the following elements is a trace element?
A Copper B Nitrogen C Sulphur D Calcium
AMBITIOUS SHORT QUESTIONS

UNIT#01+02
1. Define electron affinity and ionization energy. 2. Describe 6th period of the periodic table.
3. Why metallic character increases from top to 4. Why ionization energy decreases down the
bottom in a group of metals? group and increases along the period?
5. Why 1st electron affinity is negative and 2nd 6. Why melting and boiling points of elements
is positive? belonging to group VA-VIIA are lower?
7. Discuss variation of electrical conduction 8. How the classification of elements in
along period and groups. different blocks helps in understanding their
chemistry?
9. What is relation b/w non-metallic character 10. Why the ionic radii of negative ions are larger
and atomic size? than the size of their parent atoms?
11. Why diamond is non-Conductor and graphite 12. Why d and f block elements are called
is fairly good conductor? transition elements?
13. Discuss analogy of Hydrogen with Group IV-A. 14. Why the ionic character of halides decreases
from left to the right in a period?
15. Why the hydration energies of the ions are in 16. When the oxidation state of an element is
the following order: zero?
Al3+>Mg2+>Na+

Page 9 of 17
17. Give the formulas of: 18. Mention the properties of beryllium in which
(i) Sylvite (ii) Phosphorite. it does not resemble with its own family.
19. Why aqueous solution of Na2CO3 is alkaline 20. Write down reactions takes place at anode
in nature? and cathode during preparation of sodium in
Down’s cell.
21. What happens when Lithium hydroxide is 22. Write electronic configuration of s-block
heated to red hot? elements.
UNIT#03+04
1. What is Borax? 2. How HNO3 reacts with copper and lead?
3. Which basic radicals give response to borax 4. How does HNO3 acts as reducing agent?
bead test?
5. How the glassy bead is produced from borax? 6. How does nitrogen differ from other
elements of its group?
7. Discuss chemistry of Borax bead test. 8. How does oxygen differ from sulphur?
9. How H3BO3 can be prepared from Borax? 10. What is dehydrating agent? Give example.
11. How Borax is commercially prepared? Give 12. Write uses of H2SO4.
its two methods of preparation.
13. Give four uses of Borax. 14. How does dilute nitric acid reacts with Mn
and Cu?
15. Write uses of Boric acid. 16. How does nitrogen occurs in nature?
17. Why Boric acid cannot be titrated by NaOH? 18. What is Boric acid? Write its preparation.
19. Give reaction of aluminium with NaOH and 20. Define Aqua regia.
H2SO4
21. How Al finds its uses in metallurgy and 22. What is Ring test?
photoflash bulbs?
UNIT#05+06
1. What is bleaching powder?
2. How Bleaching powder is prepared commercially?
3. Give uses of bleaching powder.
4. What are disproportionation reaction? Explain your answer with an example.
5. How the halogen acids are ionized in water?
6. Why HF is weaker acid than HCl?
7. What happens when bleaching powder react with dil.H2SO4 and CO2?
8. Why Halogens are named as Halogens?
9. Give electronic configuration of halogens.
10. Discuss occurence of halogens.
11. On what factors oxidizing power of halogens depends?
12. Draw the structure of OF and O2F2.

Page 10 of 17
13. Discuss Hydrogen bonding in HF. Draw its structure as well.

14. How Bromine mono oxide is prepared?
15. What are oxyacids?
16. What is Corrosion? How prevention from corrosion is possible?
17. Give reactions of chlorine with Cold and Hot water.
18. Why transition metals have high melting and boiling points?
19. What are paramagnetic substances?
20. What are Diamagnetic substances?
21.Why transition elements exhibit variable oxidation state?
22. What is d-d transition?
UNIT#07+08
1) How was vital force theory rejected?
2) Define organic chemistry.
3) Why organic compounds do not give ionic reactions?
4) Why rates of organic reactions are slow?
5) What are aliphatic compounds?
6) Which hetero atoms are present in Pyridine and Thiophene?
7) What is zwitter ion?
8) Define functional group with two examples.
9) What is Geometric isomerism? Give an example
10) What are alicyclic compounds? Give two examples.
11) Define orbital hybridization and give its two types.
12) What is an octane number and how it is improved?
13) Why 1-butyne in acidic but 2-butyne is not?
14) Why ethyne is less reactive than ethene although it has two -bonds.
15) Why alkanes are least reactive at ordinary condition?
16) Give mechanism for reaction ethene with Bromine.
17) What is Raney Nickel, how it is prepare and give its uses?
18) Boiling point of n-butane is greater than iso-butane why?
19) Discuss free radical mechanism of halogenations of methane.
20) Prepare oxalic acid from alkyne.
21) Prepare acetaldehyde and acetone from alkynes.
22) Discuss catalytic oxidation of methane.
23) What is Lindlar’s catalyst?
24) Justify that the order of reactivity of alcohols for dehydration purposes is as follows Ter.
Alcohol > Sec. alcohol > Prime. Alcohol
UNIT#09+10
1) What is Markowniov’s rule?

Page 11 of 17
2) Why –OH attach on the Benzene them it is o, p-director?

3) What is Wurtz-Fitting Reaction?
4) Prepare Maleic Acid from Benzene?
5) Why Benzene gives sooty flame?
6) Draw Resonance structures of benzene?
7) Why Benzene is symbol of Aromatic compounds?
8) Differentiate monocyclic and polycyclic Aromatic Hydro carbons?
9) Give the mechanism of general pattern of Reactivity of benzene?
10) What is  –complex?
11) Give the structural formulas of? (i) Biphenyl (ii) P-dibenzylbenzene
12) Discuss x-ray analysis of benzene structure.
13) How will you convert 𝐶𝐻4 ⟶ 𝐶𝐻3 𝐶𝐻2 𝐶𝑂𝑂𝐻.
14) What do you understand by the term 𝛽 −elimination reaction?
15) Give the preparation of propanoic acid from eltyl bromide.
16) Give the IUPAC name of following compounds.
(i) (CH3)2CH Br (ii) (CH3)3C CH2Cl
17) What happen when alkyl halide react with sodium lead alloy?
18) Define leaving group with example.
19) Define the term molecularity with example.
20) What are mono alkyl halides and classify it.
21) Define electrophile with example.
22) What is substrate molecule?

Page 12 of 17
UNIT#11+12
1- How molasses is converted into ethyl alcohol?
2- What do you mean by denaturing of alcohol?
3- Why absolute alcohol cannot be prepared by fermentation?
4- Discuss the acidic character of phenol.
5- How can we distinguish between methanol and ethanol?
6- Give reaction of alcohols in which C – O bond breaks.
7- Write two uses of each of methanol and ethanol.
8- Give the reaction of phenol with conc. H2SO4 and acetyl chloride.
9- How will you distinguish between 1-propanol and 2-propanol?
10- How phenol is prepared by Dow’s method.
11-Give three applications of formaldehyde?
12-What is 2, 4 – DNPH test?
13-Define condensation Reaction?
14-Why Aldehyde do not show cannizaro Reaction which have  –hydrogen?
15-Give the general mechanism of derivative of Ammonia with carbonyl compounds?
16-How can you distinguish b/w methanal& Ethanal?
17-Which Reducing agents are used for the reduction of Aldehyde give name & formula?
18-Distinguish b/w 2 – pentanone & 3 – pentanone?
19-Give three applications of Acetaldehyde?
20-What sodium Nitro prusside test and give its formula?

Page 13 of 17
21-What is Formaline?
22-Can aldehydes and ketones show oxidation? If yes, then what agents are used for it?
UNIT#13 +15
(i) Name two aromatic carboxylic acids along with names.
(ii) How do carboxylic acids are prepared from aldehydes?
(iii) Write down structural formulas of:
(a) Isobutyric acid (b) Oxalic acid
(iv) How will you synthesize acetic acid from acetylene?

(v) Esters have characteristics smell. Write names of esters found in (a) Raspberry (b) Pineapple
(vi) How do carboxylic acids react with PCl5 and SOCl2?
(vii) What are fatty acids? Give an example.
(viii) Write structural formulas of: (a) Malonic acid (b) Phthalic acid
(ix) What is vinegar? How is it prepared from ethyl alcohol?
(x) What is glacial acetic acid.
(xi) How acetic acid are heated in presence of P2O5.
(xii) What are the requirements of a good fertilizer?
(xiii) What are fertilizers? Differentiate between micronutrients and macronutrients.
(xiv) Give an idea about clinker? How are they converted to cement?
(xv) What is manure?
(xvi) How urea is prepared from ammonia?
(xvii) Write is the importance of potassium fertilizer.
(xviii) What do you mean by setting of cement?
(xix) Write five stages involved in the manufacturing of Portland cement.
(xx) Write the importance of Phosphorus of the plants.
(xxi) Mention three important raw materials for the manufacture of cement.
(xxii) Ammonium nitrate cannot be used as a fertilizer for paddy rice. Summarize with reason.
(xxiii) Convert acetic acid into (a) methane (b) acetyl chloride
(xxiv) Give four uses of acetic acid.
(xxv) How are acetic acids manufactured?
(xxvi) Write uses of fertilizers.
(xxvii) Write classification of fertilizers.
(xxviii) What is meant by setting of cement?

Page 14 of 17
AMBITIOUS LONG QUESTION

UNIT#01+02
. 1. Justify Position of Hydrogen at the top of Group IA and VIIA.
2. Give Brief reason for the following: (2+2=4)
a) Lanthanide contraction controls the atomic sizes of elements of 6th and 7th periods.
b) The oxidation states vary in period but remain almost constant in group.
3. Discuss modern periodic table.
4. Explain the variation in melting points along short periods.
5. Discuss the peculiar behavior of lithium with respect to other members of alkali metals.
6. Describe the manufacturing of NaOH by diaphragm cell & give its problems.
UNIT-04+06
1. Give the advantages of contact process for the manufacture of sulphuric acid.
2. Explain the Brikeland and Eyde’s process for the manufacture of nitric acid.
3. Explain the action of sulphuric acid on metals along with chemical equation.
4. Discuss the trends in physical properties of group VI-A elements.
5. Discuss the binding energies of first and third transition series.
6. Give the resemblance of d-block elements.
7. Give systematic name of following complexes.
(i) [Cr(OH)3(H2O)3] (ii) [Pt(OH)2(NH3)4]SO4
(iii) [Co(NH3)6]Cl3 (iv) Na3[CoF6)
8. Discuss Electrochemical theory.
9. Discuss Tin Plating in detail.
10. What is Galvanizing? Explain it.
UNIT#07+08
1. Define hybridization. Discuss the structure of ethyne on its basis.
2. Define cracking and explain its type with examples.
3. Define isomerism Explain four types of Structural isomerism with one example each.
4. Explain reforming of petroleum with the help of suitable example.
Page 15 of 17
5. (i) Convert CH4 into Formic acid:

(ii) Convert CH2=CH2 into Ethane:
(iii) Convert R-C≡C-R into Tran’s alkenes:
(iv) Ethene into ethylene glycol
( v) Acetylene into acetaldehyde
6. What’s Kolbe’s Electrolysis Process (alkane Prep)?
7. Give IUPAC name of the following.
(i) CH3C(CH3)2CH2CH(Br)CH3
(ii) (ii) CH3-CH2-CH(CH3-CH-CH3)CH2-CH3
(iii) CH3-CH = CH – CH2-CH(CH3)-C  CH
(iv) (iv) CH  C-HC = CH2
8. Give structural formula of the following.
(i) neo-pentane (ii) Vinyl acetylene
(iii) Divinyl acetylene (iv) Iso-butylene
(v) Triphenyl methane (vi) Mustard gas
UNIT#09+10
1. Discuss the Molecular Orbital Treatment of benzene & stability of benzene?
2. What is sulphonation & give with mechanism?
3. Describe Friedel craft Alkylation’s & Acylation?
4. Give the orientation of benzene with o, p-director and m-director?
5. Write a note on SN1 and SN2 mechanism.
6. Differentiate b/w E1 and E2 elimination.
7. Describe the best methods of preparation of alkyl halide.
UNIT#11+12
1. How will you distinguish between primary, secondary and tertiary alcohol?
2. Describe any four chemical properties of phenol due to benzene ring.

Page 16 of 17
3. Describe the commercial preparation of methyl alcohol.
4. How will you convert: (i) Methanol into Ethanol (ii) Acetone into Ethyl alcohol?
5. Describes Aldol condensation with mechanism
6. Describes Cannizaro’s Reactions with mechanism.
7. Prepare formaldehyde & Acetaldehyde by Industrial method?
8. What are Halo form Reactions?
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AMBITIOUS ACADEMY LAHORE

Ph: +92-333-4082706 Website: www.ambitious.pk/

Dr. Syed Sharafat Hussain

AMBITIOUS MULTIPLE CHOICE QUESTIONS

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

(a) Fe3+ (b) Ni (c) Fe2+ (d) Sc2-

15) Addition of halogens to alkyne give?

a) Ethylamine b) Diethylamine c) Triethylamine d) tetra ammonium ion

(a) Propanal (b) 1-Propanal (c) 1-butanol (d) Propanone

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

AMBITIOUS SHORT QUESTIONS

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

13. Discuss Hydrogen bonding in HF. Draw its structure as well.

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

2) Why –OH attach on the Benzene them it is o, p-director?

14) What do you understand by the term 𝛽 −elimination reaction?

15) Give the preparation of propanoic acid from eltyl bromide.

16) Give the IUPAC name of following compounds.

(i) (CH3)2CH Br (ii) (CH3)3C CH2Cl

18) Define leaving group with example.

19) Define the term molecularity with example.

20) What are mono alkyl halides and classify it.

21) Define electrophile with example.

22) What is substrate molecule?

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2- What do you mean by denaturing of alcohol?

3- Why absolute alcohol cannot be prepared by fermentation?

4- Discuss the acidic character of phenol.

5- How can we distinguish between methanol and ethanol?

6- Give reaction of alcohols in which C – O bond breaks.

7- Write two uses of each of methanol and ethanol.

9- How will you distinguish between 1-propanol and 2-propanol?

10- How phenol is prepared by Dow’s method.

11-Give three applications of formaldehyde?

12-What is 2, 4 – DNPH test?

13-Define condensation Reaction?

14-Why Aldehyde do not show cannizaro Reaction which have  –hydrogen?

15-Give the general mechanism of derivative of Ammonia with carbonyl compounds?

16-How can you distinguish b/w methanal& Ethanal?

18-Distinguish b/w 2 – pentanone & 3 – pentanone?

19-Give three applications of Acetaldehyde?

20-What sodium Nitro prusside test and give its formula?

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

(iv) How will you synthesize acetic acid from acetylene?

Main Stop Jia Musa Shahdara Lahore Ph: 0333-4082706/ 0300-0040248

AMBITIOUS LONG QUESTION

5. (i) Convert CH4 into Formic acid:

7. Describe the best methods of preparation of alkyl halide.

2. Describe any four chemical properties of phenol due to benzene ring.

3. Describe the commercial preparation of methyl alcohol.

5. Describes Aldol condensation with mechanism

6. Describes Cannizaro’s Reactions with mechanism.

7. Prepare formaldehyde & Acetaldehyde by Industrial method?

8. What are Halo form Reactions?

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