MEGA-XII INORGANIC CHEMISTRY : V.K.

JAISWAL(VKJ SIR)
Answers of DPP-2
I.U.P.A.C. name of the following complex Compounds :
1. K2[HgI4]  Potassium tetraiodidomercurate (II)
2. LiAlH4  Lithium tetrahydridoaluminate (III)
3. K3[Fe(CN)6]  Potassium hexacyanidoferrate (III)
4. K2[Pt Cl6]  Potassium hexachloridoplatinate (IV)
5. [PtCl2(NH3)2]  Diamminedichloridoplatinum (II)
6. [Co(NH3)6]Cl3  Hexaamminecobalt (III) chloride
7. [Fe(en)3]Cl3  Tris (ethylenediamine) iron (III) chloride
8. K3[Ir(C2O4)3]  Potassium trisoxalatoiridate (III)
9. [Co(NCS)(NH3)5]Cl2  Pentaammineisothiocyanato cobalt (III) chloride
Pentaamminethiocyanato–N–cobalt (III) chloride
+1
10. [CoBr(ONO)(en)2]  Bromidobis(ethylenediamine) nitrito-O cobalt (III) ion
11. K2[Mo(CN)6]  Potassium hexacyanidomolybdate (IV)
12. [CoI(NH3)5]SO4  Pentaammineiodidocobalt (III) sulphate

VIBRANT ACADEMY
13. [Co(NH3)6] [Co(ONO)6]  Hexaammine cobalt (III) hexanitrito–Ocobaltate (III)
14. (NH4)2[Pt(SCN)6]  Ammonium hexathiocyanato–S platinate (IV)
15. [Co(NO2)3(NH3)3]  Triamminetrinitrito-N-cobalt (III)
16. (NH4)3[Cr(NCS)6]  Ammonium hexaisothiocyanatochromate (III)
17. [Pt(NH3)4][PtCl4]  Tetraammine Platinum (II) tetrachloridoplatinate (II)
18. (NH4)4[Mo(CN)8]  Ammonium octacyanidomolybdate (IV)
3–
19. [FeF6]  Hexafluoridoferrate (III) ion
20. [CoCO3(NH3)5]Cl  Pentaamminecarbonatocobalt (III) chloride
21. K3[Fe(NH2)6]  Potassium hexaamidoferrate (III)
22.
23.
24.
[PtCl3(SnCl3)]2–
Na3[Co(NO2)6]
[PtCl4(NH3)2]
unacademy 


Trichlorido trichlorostannitoplatinate(II)ion
Sodium hexanitrito–N cobaltate(III)
Diamminetetrachloridoplatinum (IV)
25. [PtCl2(NH3)4] [PtCl4]  Tetraamminedichloridoplatinum (IV) tetrachloridoplatinate(II)
26. [PdI2(ONO)2(H2O)2]  Diaquadiiodidodinitrito–O palladium (IV)
27. [CoCl(ONO)(en)2]  Chlorobis(ethylenediamine) nitrito–O cobalt (II)
28. [CoCl2(en)2]2SO4  Dichloridobis (ethylenediamine) cobalt (III) sulphate
29. [Cr(CO)5(PPh3)]  Pentacarbonyltriphenylphosphinechromium (O)
30. Na2[Ni(EDTA)]  Sodium ethylenediaminetetraacetatonickelate (II)

31.  Tetraammine cobalt (III) –amido –superoxido tetraammine cobalt (III) ion

OR –amido –superoxido bis {tetraammine cobalt (III)} ion

32. [Be4O(CH3COO)6]  Hexa –– acetato–4 – oxido –tetra beryllium(II)
33. [CuCl(H2O)4]Cl  Tetraquachloridocopper (II) chloride
34. [CoBr(H2O)(NH3)4](NO3)2  Tetraammineaquabromocobalt (III) nitrate
35. Na[B(NO3)4]  Sodium tetranitratoborate (III)
[1]
36. [Zn4O(CH3COO)6]  Hexa--acetato-4-oxido-tetrazinc (II)
37. [(C6H5)3PCl Pd Cl2 PdCl(C6H5)3P]
 Chlorotriphenyl phosphene palladium (II) di--chloridochlorido triphenyl phosphene palladium (II)
 di--chloridodichloridobis (triphenylphosphene) di palladium (II)
 di--chloridobis{chloridotriphenyl phosphene palladium (II)}
 bis {–chlorido chloridotriphenyl phosphene palladium (II)}
38. H2[PtCl6]  Hexacloro platinic (IV) acid
39. [(Cl3Sn)2RhCl2Rh(SnCl3)2] 4— 
IV
SnCl2 + Cl–  SnCl3–
Stannous chloride trichlorostannito
 Bis(trichlorostannito) rhodate (I) di –chlorido bis(trichlorostannito) rhodate(I) ion
 Di––chloridotetrakis(trichlorostannito) dirhodate(I) ion
 Di––chlorido bis{bis(trichlorostannito) rhodate (I)}ion
40. Fe(CO)5  Pentacarbonyl iron (O)
41. Co2(CO)8  Octacarbonyl dicobalt (O)
42. K2[Cd(CN)4]  Potassium tetracyanidocadmate (II)
43. [CrCl2(H2O)4]Cl  Tetraaquodichloridochromium (III) chloride
44. Co[Hg(SCN)4]  Cobalt(II)tetrathiocyanato–S Mercurate(II)

VIBRANT ACADEMY
45.
46.
47.
[Ag(NH3)2]Cl
K[SbCl5(C6H5)]
[RuBr2(NH3)4]NO3



Diammine silver (I) chloride
Potassium pentachloridophenylantimonate (V)
Tetraamminedibromoruthenium (III) nitrate
48. [CoCl(NO3)(NH3)4] [Au(CN)2]  Tetraamminechloridonitratocobalt (III) dicyanidoaurate (I)
49. [PtCl(NO2)(en)(NH3)2] Cl2  Diamminechloridoethylenediaminenitrito–N platinum (IV) chloride
50. [Ni(CN)4]2—  Tetracyanidonickelate (II) ion
51. [(NH3)5Cr-OH-Cr(NH3)5]Cl5
 Pentaammine chromium (III) –hydroxo pentaammine chromium (III) chloride
 –hydroxo bis {pentaammine chromium (III)}chloride

52. [Br2Pt(SMe2)2PtBr2]
unacademy


(Me2O  dimethyl ether/ Me2S Dimethyl thioehter)

 Dibromoplatinum (II) bis(-dimethyl thioether) dibromoplatinum (II)
 Bis{-dimethylthioether dibromo platinum (II)}
 bis(-dimethyl thioether) tetrabromo diplatinum (II)
53. [PtCl2(Et3P)2]  Dichloridobis (triethylphosphine) platinum (II)
54. [CuCl2(Et2NH)2]  Dichloridobis (diethylamine) copper (II)
55. [CoCl2(en)2]Cl  Dichloridobis (ethylenediamine) cobalt (III) chloride
56. K[PtCl3(C2H4)]  Potassium trichlorido-2-ethylene platinate (II)
57. K2[OsCl5N]  Potassium pentachloridonitridoosmate (VI)
58. Na3[Ag(S2O3)2]  Sodium bis(thiosulphato)argentate (I)
59. Na2[Fe(CN)5(NO)]  Sodium pentacyanidonitrosonium ferrate (II)
[NO in +1 state proved by magnetic moment]
60. K3[Fe(CN)5(CO)]  Potassium carbonyl pentacyanidoferrate (II)

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MEGA-XII INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

Answers of DPP-3
I.U.P.A.C. name of the following complex Compounds :
1. [ Ni (CO ) 2 (PPh 3 ) 2 ]  Dicarbonyl bis(triphenylphosphine) nickel (O)
2. [(en)2Co(NH2)(OH)Co(en)2]4+  Bis(ethylenediamine) cobalt(III) –amido –hydroxo
bis(ethylenediamine) cobalt(III) ion
3. [(CO)3Fe(CO)3Fe(CO)3]  Tri--carbonyl–bis(tricarbonyl iron (O))
4. [(NH3)5CrOHCr(NH3)4(H2O)]5+  Pentaammine chromium (III) –hydroxotetraammine aquo
chromium(III) ion
5. [CoN3(NH3)5]SO4  Pentaammineazidocobalt (III) sulphate
6. [Co(NH2)2(NH3)4]OC2H5  Diamidotetraamminecobalt(III) ethoxide
7. [Pt(Cl)(NO2)(NH3)4]SO4  Tetraamminechloronitrito–N platinum (IV) sulphate
8. [CrCl2(H2O)4]Cl  Tetraaquodichlorochromium (III) chloride
9. [Ru(N3)(NH3)5]Cl2  Pentaammineazidoruthenium(III) chloride
10. [CoCl3(NH3)3]  Triamminetrichlorocobalt(III)

VIBRANT ACADEMY
11. [PtCl4(NH3)2]  Diamminetetrachloroplatinum (IV)
12. [CrCl(H2O)5]Cl2  Pentaaquachlorochromium(III) chloride
13. Ti(-c5H5)2(-C5H5)2  Bis(cyclopentadienyl) bis 5-cyclopentadienyl titanium (IV)

14. Mo(-C3H5)(-C5H5)(CO)3  Allyl tricarbonyl- 5 – cyclopentadienyl molybdum (II)

CH2=CH–CH2(–) allyl

15.

16.
Mn(-C5H5)(CO)3

Cr(C6H6)(CO)3
unacademy 


Tricarbonyl- 5 – cyclopentadienyl manganese (I)

6 –benzene tricarbonyl chromium (O)

17. Fe(CO)2(-C5H5)(-C5H5)  Dicarbonyl- 5 –cyclopentadienyl cyclopentadienyl iron (II)

18. Cr(C6H6)2  Bis ( 6 –benzene) chromium (O)

19. Fe(-C5H5)2  Bis ( 5 –cyclopentadienyl) iron (II)

20. Mn(CO)5(-C3H5) or Mn(CO)5(–CH2–CH=CH2)  Allyl pentacarbonyl manganese (I)

21. Co(CO)3(-C3H5)  3 –allyl tricarbonylcobalt (I)

22. Fe(   C4H4 )(CO)3  tricarbonyl-4-cyclobutadiene iron (O)
23. [PtCl2(NH3)(C2H4)]  Amminedichloro (2 – ethylene) platinum (II)
24. Ni(CO)4  Tetracarbonylnickel (O)
25. Mn2(CO)10  Decacarbonyl dimanganese (O)
26. [Cu(NH3)4][PtCl4]  Tetraaminecopper (II) tetrachloro platinate (II)
27. [W(en)3]Cl3  Tris (ethylenediamine) tungston (III)chloride
28. K3[Co(NCS)6]  Potassium hexathiocyanato–N cobaltate (III)

[3]
29. [Pt(NH3)4][Cr(NCS)(NO2)2(NH3)2Py]  Tetrammine platinum (II) diammine dinitrito-N
pyridine thiocyanato-N chromate (I)
30. K3[Co(C2O4)2Cl2]  Potassium dichlorobis(oxalato)cobaltate (III)

31.  Tetraamine cobalt (III) di––hydroxo bis (ethylenediamine) cobalt

(III) chloride {III way is not applicable}

32. Na2[Pt(CN)2I(NO2)]  Sodium dicyanidoiodidonitrito-N-platinate (II)
33. [Ru(PPh3)3Cl3]  Trichlorotris(triphenylphosphine)ruthenium(III)
34. K2[Co(N3)4]  Potassium tetraazidocobaltate (II)
35. [NiCl2(Ph3P)2]  Dichlorobis(triphenylphosphine) nickel (II)
36. [Cr(acac)3]  Tris(acetylacetanato) chromium (III)
37. [IrCl(CO)(Ph3P)2]  Carbonylchlorobis(triphenylphosphine) iridium (I)
38. [Co(NCS)(NH3)5]Cl2  Pentaammine thiocyanato–N cobalt (III) chloride
39. [Pt(C5H5N)4] [PtCl4]  Tetrapyridine platinum (II) tetrachloroplatinate (II)
40. [CrCl(ONO)(NH3)4] NO3  Tetraammine chloronitrito-O-chromium (III) nitrate
41. [Co(NH3)6][CuCl5]  Hexaamminecobalt (III) pentachlorocuprate (II)

VIBRANT ACADEMY
42.
43.
[Ca(EDTA)]2—
[Fe(H2O)5(NO)]SO4


Ethylenediaminetetraacetato calcate (II) ion
Pentaaquanitrosonium iron (I) sulphate
[brown ring complex is unstable]
44. K4[Ni(CN)4]  Potassium tetracyanidonickelate (O)
45. [Al(OH)(H2O)5]SO4  Pentaaquohydroxoaluminium (III) sulphate
46. [VBr2(H2O)(NH3)2]Br  Diammineaquodibromovanadium (III) bromide
47. Na[Co(CO)4]  Sodium tetracarbonylcobaltate (–I)

unacademy
48. Fe4[Fe(CN)6]3  Iron (III) hexacyanidoferrate (II)
49. Fe3[Fe(CN)6]2  Iron (II) hexacyanidoferrate (III)
50. [Cr(en)3] [Ni(CN)5]  Tris (ethylenediamine) chromium (III) pentacyanido nickelate (II)
51. [(NH3)4CoNH2NO2Co(NH3)4](NO3)4 –amido –nitro bis {tetraammine cobalt (III)} nitrate
 Tetraammine cobalt (III) –amido –nitro tetraammine
cobalt (III) nitrate
 –amido –nitro–octamminedicobalt (III) nitrate
52. K[B(C2H5)4]  Potassium tetraethyl borate (III)
53. [PtBr(NH3)3] NO3  Triamminebromoplatinum (II) nitrate
54. trans-[PtCl2(NH3)2]  Trans–diammine dichloroplatinum (II)
55. [RhCl(PPh3)3]  Chlorotris (triphenylphosphine) rhodium (I)
56. [Ni(dmg)2]  Bis (dimethylglyoximato) nickel (II)
57. [Co(NH3)6][Cr(CN)6]  Hexaamminecobalt (III) hexacyanidochromate (III)
58. Ni(–C4H4)2  bis (4- cyclobutadiene) nickel (0)
59. [CoCl(NCS)(NH3)4]+  Tetraamminechlorothiocyanato–N cobalt (III) ion
60. [PtCl4(en)]  Tetrachloroethylenediamine platinum (IV)
61. [CoBrCl(en)(NH3)2] NO3  Diamminebromochloroethylenediamine cobalt (III) nitrate

[4]