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    CSEC Chem P2 2018 June Ans (1) BKJNBNJKK

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    Sanjeev Deodath
    The document is a summary of questions from a CSEC Chemistry exam paper. It includes questions on: 1) Rates of reaction and calculations involving moles and volumes of gases. 2) Isotopes and uses of radioisotopes in medicine, power, and dating. 3) Balanced equations for chemical reactions including those involving chlorine and iodine. 4) Equations and conditions for reactions involving sulfur, esters, and alkenes. 5) Processes of electrolysis, fermentation, soap making, and polymerization. 6) Effects of deficiencies in magnesium and other metal ions on plant growth.

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    CSEC Chem P2 2018 June Ans (1) BKJNBNJKK

    Uploaded by

    Sanjeev Deodath
    52 views4 pages
    The document is a summary of questions from a CSEC Chemistry exam paper. It includes questions on: 1) Rates of reaction and calculations involving moles and volumes of gases. 2) Isotopes and uses of radioisotopes in medicine, power, and dating. 3) Balanced equations for chemical reactions including those involving chlorine and iodine. 4) Equations and conditions for reactions involving sulfur, esters, and alkenes. 5) Processes of electrolysis, fermentation, soap making, and polymerization. 6) Effects of deficiencies in magnesium and other metal ions on plant growth.

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    CSEC Chem P2 2018 June Ans (1)bkjnbnjkk

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    The document is a summary of questions from a CSEC Chemistry exam paper. It includes questions on: 1) Rates of reaction and calculations involving moles and volumes of gases. 2) Isotopes and uses of radioisotopes in medicine, power, and dating. 3) Balanced equations for chemical reactions including those involving chlorine and iodine. 4) Equations and conditions for reactions involving sulfur, esters, and alkenes. 5) Processes of electrolysis, fermentation, soap making, and polymerization. 6) Effects of deficiencies in magnesium and other metal ions on plant growth.

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    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    52 views4 pages

    CSEC Chem P2 2018 June Ans (1) BKJNBNJKK

    Uploaded by

    Sanjeev Deodath
    The document is a summary of questions from a CSEC Chemistry exam paper. It includes questions on: 1) Rates of reaction and calculations involving moles and volumes of gases. 2) Isotopes and uses of radioisotopes in medicine, power, and dating. 3) Balanced equations for chemical reactions including those involving chlorine and iodine. 4) Equations and conditions for reactions involving sulfur, esters, and alkenes. 5) Processes of electrolysis, fermentation, soap making, and polymerization. 6) Effects of deficiencies in magnesium and other metal ions on plant growth.

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    of 4

    CSEC Chem 2018 June Paper 2

    Q1
    a) Rate of Rxn: change in concentration of reactant or product
    in unit time OR divided by time taken (1K)
    b) (i) Ca CO3 (s) + 2HCl (aq) → CaCl2 (aq) + H2O (l) + CO2 (g) (1U) balanced (1U) formulae
    (ii) 100g Ca CO3 = 1 mol
    1.0 g = (1/ 100) x 1.0 mol = 0.01 mol (1U)
    1 mol Ca CO3 → 1 mol CO2 (g) (1U) (mole ratio) = 24 000 cm3
    0.01 mol Ca CO3 → (24 000/1) x 0.01 cm3 (1U) = 240 m3
    c) (i) 5 = (3X) (ii) 5 = (3U) ALL 3 dp = (1U)
    4 = (2X) 3 – 4 = (2U)
    Test Temp. / °C Time taken / s 1/t / s – 1
    1 18 51.5 0.019
    2 23 31.5 0.032
    3 28 19.0 0.053
    4 32 13.0 0.077
    5 37 8.5 0.118
    6 43 5.0 0.200

    (iii) 4 points plotted = (4X), line of best fit = (1X)


    d) (i) As temperature increases rate of reaction increases. (1U)
    (ii) Increase in temperature increases the energy of the particles so they move faster (1K) and
    get into more frequent collisions. (1K)
    OR Increase in temperature means that more particles have activation energy
    (the minimum amount of energy necessary to cause bonds to break and reaction to occur) (1K)
    e) At 40 °C 1/t = 0.16 (1U) s – 1 Accept from graph: 0.15 correct interpolation (lines) (1U)
    f) CO2 (g) bubbled through lime water (calcium hydroxide solution) (1X)
    forms a white precipitate. (1X) Accept: cloudy milky Only if lime water named
    Q2
    a) (i) Isotopes are atoms of the same element with the same atomic number (1K)
    but different mass numbers. (1K)
    OR atoms of the same element with the same number of protons (1K)
    but different numbers of neutrons. (1K)
    (ii) A = p + n 35 = 17 + n1 n1 = 35 – 17 (1U) n1 = 18
    37 = 17 + n2 n2 = 37 – 17 (1U) n2 = 20
    b) Uses of radioisotopes: radiotherapy / treatment of cancer
    AND/OR dating ancient artifacts / carbon-14 dating
    AND/OR power supply in pacemakers
    AND/OR generation of electricity in nuclear power plants
    AND/OR sterilization of medical equipment
    AND/OR irradiation of food as a means of preservation / food safety
    AND/OR as tracer Any 2 = (1K) each = (2K)
    c) (i) Cl2 (g) + 2 I – (aq) → 2 Cl – (aq) + I2 (aq) (1U) balanced (1U) formulae
    Cl2 (g) + 2KI (aq) → 2KCl (aq) + I2 (aq) Award: (1U) only
    (ii) Colour change: colourless (1K) to red-brown (1K) Accept: yellow
    d) (i) S (s) + O2 (g) → SO2 (g) (1) formulae (1) state symbols
    (ii) Use of sulphur: matches / gunpowder OR vulcanizing rubber OR antibiotic drugs
    OR sulphur dioxide in food preservation OR whitening pulp in paper-making
    OR manufacture of sulphuric acid (1K)
    (iii) Mg (s) + S (s) → MgS2 (s) (1) balanced (1) state symbols

    Q3
    a) X: alkane (1K) Y: alkene (1K)
    b) Use of X: fuel OR solvent (1K) Accept: propellant in aerosol OR refrigerant
    Use of Y: to make plastic / polymer OR to make alcohol OR to make petrochemicals (1K)
    c) X: (2U) Any H missing = (1U) Y: (2U) Any H missing = (1U)
    H H H H H H H
    | | | | | | |
    H–C–C–C–C –H H–C – C = C–H
    | | | | |
    H H H H H
    d) (i) (2U) Any H missing = (1U)
    H H H OR H H H
    | | | | | |
    H–C–C–C–O–H H–C–C – C–H
    | | | | | |
    H H H H O-H H
    (ii) Reagent: conc sulphuric acid (H2SO4) (1K), water
    Conditions: 170 °C (1K), atmospheric pressure
    OR Reagent: phosphoric (V) acid (H3PO4) (1K), steam
    Conditions: 300 °C (1K), 60-70 atm pressure
    e) Name of ester: ethyl ethanoate (1K)
    f) C2H5OH (l) + CH3COOH (l) → CH3COOC2H5 (aq) + H2O (l) (1U) formula of ester (1U) all products
    Q4
    a) Electrolysis: the passage of electricity through a substance / electrolyte (1K)
    which results in its decomposition. (1K)

    b) (i) solid NaCl : Effect : Bulb will not light (1U)


    Reason : No free, mobile ions (1K) / Ions are held in lattice by strong ionic bonds / strong forces
    (ii) 1 mol dm3 HCl : Effect : Bulb will light (1U)
    Reason : Free, mobile ions in aqueous solution (1K)
    / HCl is an acid and (strong) electrolyte, dissociates to form mobile ions.
    (iii) Ethanol : Effect : Bulb will not light (1U)
    Reason : No free, mobile ions, nor free, mobile electrons (1K)
    Ethanol is a covalent substance, does not dissociate to form mobile ions.
    (iv) Lead : Effect : Bulb will light (1U)
    Reason : Free, mobile electrons (1K) Lead is a metal made up of cations and a sea of mobile electrons

    c) time = 3 min x 60 s = 180 s (1U)


    Q = I x t = 6 A x 180 s = 1080 C (1U)
    mol e: 1080 / 96500 = 0.0112 mol (1U)
    2 mol e – → 1 mol Pb mol Pb (1080 / 96500) / 2 (1U) = 0.0056 mol Pb
    1 mol Pb = 207 g mass Pb: = 207 x (1080 / 96500) / 2 g (1U) = 1.16 g

    Q5
    a) Fermentation: Materials: Fruit juice / solution containing sugar or starch (carbohydrate) (1K)
    yeast / enzyme zymase (1K) is added. Left in a cool place / at room temperature, anaerobic conditions
    with neutral pH, Campden tablets (potassium or sodium metabisulfite) added.
    Products are ethanol (1K) and carbon dioxide
    C6H12O6 (aq) → 2 C2H5OH (aq) + 2 CO2 (g) (1U) formulae (1U) balanced
    b) Soap making: Animal fat or vegetable oil mixed with Reagent: sodium (or potassium) hydroxide. (1K)
    Condition: Heated / boiled. (1K) Sodium chloride added after prolonged heating. Filter and press dry.
    Product, soap, is sodium / potassium salt of fatty acid (1K) with glycerol.
    O
    ||
    R – CH2 – C – O – Na + (1U)
    c) (i) BB: Type of Polymer: polyamide (1U)
    Type of Polymerization: condensation polymerization (1U)
    CC: Type of Polymer: polyalkene (1U)
    Type of Polymerization: addition polymerization (1U)
    (ii) Monomer:
    H H H H H
    | | | | |
    H–C=C–C–H OR H – C = C – CH3 (2U) (any H missing = 1U)
    |
    H
    Q6
    a) (i) Magnesium is necessary to make the green pigment / chlorophyll (1K)
    which is necessary (catalyst) for the process by which plants make food / photosynthesis (1K)
    Deficiency of magnesium means less chlorophyll / yellow leaves / less photosynthesis (1U)
    So less food / glucose / carbohydrates will be made (1U)
    / there will be less food to be stored in the tomato fruit
    So less tomatoes will be made / fruit will be smaller / lower yield (1U)
    (ii) Other metal ion: iron (1K) Deficiency: yellowing of (young) leaves (between veins) (1U)
    OR Other metal ion: potassium (1K) Deficiency: stunted growth / early leaf death / (1U)
    yellow spots on (older) leaf (including veins) / yellow or brown leaf edges / (purple spots)
    OR Other metal ion: calcium (1K) Deficiency: abnormal shoot tip / shoot tip dies (1U)
    (abnormal root tip) / curling of leaves / young leaves curl and die
    OR Other metal ion: zinc (1K) Deficiency: yellow (middle) leaves / stunted growth (1U)
    OR Other metal ion: manganese (1K) Deficiency: yellow (young) leaves / stunted growth (1U)
    b) Metal: lead (1K)
    Effect: toxic /damage to nervous system / mental retardation / reduced IQ level (1U)
    / damage to kidney
    Accept: Metal: mercury (1K) Effect: toxic (1U)
    Non-metal: Sulphur (1K)
    Effect: sulphur dioxide dissolves in rain water and forms acid rain (1U)
    causing corrosion of metal structures/bridges OR degrading limestone structures/statues (1U)
    OR causing death of plants or crops / death of fish
    OR Non-metal: Nitrogen (1K)
    Effect: oxides of nitrogen dissolves in rain water and forms acid rain (1U)
    causing corrosion of metal structures/bridges OR degrading limestone structures/statues (1U)
    OR causing death of plants or crops / death of fish
    NOT: carbon / carbon dioxide / carbon monoxide (0)
    Greenhouse Effect/ Global Warming / gas poisoning (0)
    c) Green Chemistry: The use of principles and processes that reduce or eliminate the use of or the production
    of toxic/harmful chemicals (1K) in the design, manufacture use or disposal of chemical products.
    Greener fuel: Eliminate lead in gasoline / unleaded gasoline
    so eliminate emission of lead compounds into atmosphere (1U)
    Reduce sulphur in gasoline / low sulphur fuel / low sulphur diesel
    so reduce emission of sulphur dioxide into atmopshere (1U)
    NOT: alternative fuels: ethanol / gasohol / biodiesel NOR: solar power / electric vehicles

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