MOLE CONCEPT

LEVEL # 1
Determination of Number of Q.8 One atom of an element ‘X’ weighs 6.664 × 10–23
Questions
based on Different Types of Particles gm. The number of gram atoms in 40 kg of it
is -
(A) 10 (B) 100
Q.1 Mass of 1 atom of Hydrogen is - (C) 10000 (D) 1000
(A) 1.66 × 10–24 g (B) 10–22 g
(C) 10–23 g (D) 10–25 g Q.9 The number of oxygen atoms present in 14.6 g
of magnesium bicarbonate [Mg(HCO3)2] is
Q.2 Which of the following contains the largest
(A) 6NA (B) 0.6NA
number of atoms -
(C) NA (D) 0.5 NA
(A) 11g of CO2 (B) 4g of H2
(C) 5g of NH3 (D) 8g of SO 2
Q.10 One mole of P4 molecules contains -
Q.3 Four containers of 2L capacity contains (A) 1 molecule
dinitrogen as described below. Which one (B) 4 molecules
contains maximum number of molecules (C) 1/4 × 6.022 × 1023 atoms
under similar conditions. (D) 24.088 × 1023 atoms
(A) 2.5 gm-molecules of N2
(B) 4 gm-atom of nitrogen Q.11 The total number of protons , electrons and
(C) 3.01 × 1024 N atoms neutrons in 12gm of 6C12 is -
(D) 84 gm of dinitrogen (A) 1.084 × 1025
(B) 6.022 × 1023
Q.4 What is correct for 10 g of CaCO3 - (C) 6.022 × 1022
(A) It contains 1g-atom of carbon (D) 18
(B) It contains 0.3 g-atoms of oxygen
(C) It contains 12 g of calcium Q.12 The number of sodium atoms in 2 moles of
sodium ferrocyanide Na4[Fe(CN)6], is-
(D) None of these
(A) 2
Q.5 The total number of electrons present in 18 (B) 6.023 × 1023
mL water (density 1 g/mL) is - (C) 8 × 6.02 × 1023
(A) 6.023 × 1023 (B) 6.023 × 1024 (D) 4 × 6.02 × 1023
(C) 6.023 × 1025 (D) 6.023 × 1021
Q.13 Out of 1.0 g dioxygen, 1.0 g (atomic) oxygen
Q.6 4.0 g of caustic soda (mol mass 40) contains and 1.0 g of ozone, the maximum number of
same number of sodium ions as are present oxygen atoms are contained in -
in- (A) 1.0 g of atomic oxygen.
(A) 10.6 g of Na2CO 3 (mol. mass 106) (B) 1.0 g of ozone.
(B) 58.5 g of NaCl (Formula mass 58.5) (C) 1.0 g of oxygen gas.
(C) 100 ml of 0.5 M Na2SO4 (Formula mass 142) (D) All contain same number of atoms.
(D) 1mol of NaNO3 (mol. mass 85)
Q.14 Number of Ca+2 and Cl– ion in 111 g of
Q.7 No. of oxalic acid molecules in 100 ml of
anhydrous CaCl2 are -
0.02 N oxalic acid is -
(A) NA, 2NA
(A) 6.023 × 1020
(B) 2NA, NA
(B) 6.023 × 1021
(C) NA, NA
(C) 6.023 × 1022
(D) None
(D) 6.023 × 1023
 Q.24 The density of air is 0.001293 gm/ml at S.T.P.
Questions Vapour Density, Number of Moles It’s vapour density is -
based on and NTP & STP (A) 143 (B) 14.3
(C) 1.43 (D) 0.143
Q.15 2 moles of H2 at NTP occupy a volume of
(A) 11.2 litre (B) 44.8 litre
(C) 2 litre (D) 22.4 litre Questions Percentage and Weight Based
based on Calculation
Q.16 4.48 litres of methane at N.T.P. correspond
to- Q.25 The percentage of nitrogen in urea is about-
(A) 1.2 x 1022 molecules of methane (A) 38.4 (B) 46.6
(B) 0.5 mole of methane (C) 59.1 (D) 61.3
(C) 3.2 gm of methane
(D) 0.1 mole of methane
Q.26 The mass of carbon present in 0.5 mole of
K4[Fe(CN)6] is -
Q.17 The weight of a substance that displaces
(A) 1.8 gm (B) 18 gm
22.4 litre air at NTP is -
(A) Mol. wt. (B) At. wt. (C) 3.6 gm (D) 36 gm
(C) Eq. wt. (D) all
Q.27 1.2 gm of Mg (At. mass 24) will produce
Q.18 Mol. wt. = vapour density × 2, is valid for - MgO equal to -
(A) metals (B) non metals (A) 0.05 mol (B) 40 gm
(C) solids (D) gases (C) 40 mg (D) 4 gm

Q.19 5.6 litre of a gas at N.T.P. weighs equal to Q.28 Insulin contains 3.4% sulphur by mass.
8 gm the vapour density of gas is - What will be the minimum molecular weight
of insulin -
(A) 32 (B) 16
(A) 94.117 (B) 1884
(C) 8 (D) 40.
(C) 941 (D) 976

Q.20 The maximum volume at N.T.P. is occupied Q.29 The percent of N in 66% pure (NH4)2 SO4
by- sample is -
(A) 32 (B) 28
(A) 12.8 gm of SO2
(C) 14 (D) None of these
(B) 6.02 x 1022 molecules of CH4
(C) 0.5 mol of NO2 Q.30 The chloride of a metal contains 71% chlorine
(D) 1 gm-molecule of CO2 by weight and the vapour density of it is 50.
The atomic weight of the metal will be -
(A) 29 (B) 58
Q.21 Equal masses of O2 , H2 and CH4 are taken (C) 35.5 (D) 71
in a container. The respective mole ratio of
these gases in container is - Q.31 The haemoglobin of most mammals contains
(A) 1 : 16 : 2 (B) 16 : 1 : 2 approximately 0.33% of iron by mass. The
molecular mass of haemoglobin is 67200. The
(C) 1 : 2 : 16 (D) 16 : 2 : 1
number of iron atoms in each molecule of
Q.22 Number of moles of water in 488 gm of haemoglobin is-
BaCl2.2H2O are - (Ba = 137) (A) 3 (B) 4
(A) 2 moles (B) 4 moles (C) 2 (D) 6
(C) 3 moles (D) 5 moles
Q.32 A compound was found to contain 5.37%
Q.23 16 gm of SOx occupies 5.6 litre at STP. nitrogen by mass. What is the minimum
Assuming ideal gas nature, the value of x is - molecular weight of compound-
(A) 1 (B) 2 (A) 26.07 (B) 2.607
(C) 3 (D) None of these (C) 260.7 (D) None
 Q.39 14g of element X combine with 16g of oxygen.
Questions Empirical Formula & Molecular On the basis of this information, which of the
based on Formula
following is a correct statement :
(A) The element X could have an atomic
Q.33 An element (A) (at wt = 75) and another weight of 7 and its oxide formula XO
element (B) (at. wt. = 25) combine to form a
(B) The element X could have an atomic
compound. The compound contains 75% (A)
weight of 14 and its oxide the formula
by weight. The formula of the compound will
X2O
be -
(C) The element X could have an atomic
(A) A2B (B) A3B
weight of 7 and its oxide is X2O
(C) AB3 (D) AB
(D) The element X could have an atomic
weight of 14 and its oxide is XO2
Q.34 The empirical formula of a compound is CH.
Its molecular weight is 78. The molecular
formula of the compound will be - Limiting Reagent & Stoichiometry
(A) C2H2 (B) C3H3
(C) C4H4 (D) C6H6 Q.40 A mixture containing 100 gm H2 and 100 gm
O 2 is ignited so that water is formed
according to the reaction, 2H2 + O2  2H2O;
Q.35 An oxide of a metal (M) contains 40% by How much water will be formed -
mass of oxygen. Metal (M) has atomic mass (A) 113 gm (B) 50 gm
of 24. The empirical formula of the oxide is- (C) 25 gm (D) 200 gm
(A) M2O (B) MO
Q.41 0.5 mole of H2SO4 is mixed with 0.2 mole of
(C) M2O 3 (D) M3O 4 Ca (OH)2. The maximum number of moles of
CaSO4 formed is -
(A) 0.2 (B) 0.5
Q.36 Two oxides of Metal contain 27.6% and 30%
(C) 0.4 (D) 1.5
oxygen respectively. If the formula of first
oxide is M3O4 then formula of second oxide Q.42 How many mol Fe2+ ions are formed, when
is - excess of iron is treated with 50mL of 4.0M
HCl under inert atmosphere ? Assume no
(A) MO (B) M2O
change in volume -
(C) M2O 3 (D) MO 2 (A) 0.4 (B) 0.1
(C) 0.2 (D) 0.8
Q.37 The formula which represents the simple ratio
Q.43 12 litre of H2 and 11.2 litre of Cl2 are mixed
of atoms in a compound is called - and exploded. The composition by volume of
(A) molecular formula mixture is -
(B) structural formula (A) 24 litre of HCl
(C) empirical formula (B) 0.8 litre Cl2 and 20.8 lit HCl.
(D) rational formula (C) 0.8 litre H2 & 22.4 litre HCl
(D) 22.4 litre HCl

Q.38 On analysis, a certain compound was found Q.44 For the reaction : A + 2B  C
to contain 254 gm of iodine (at. mass 127) 5 mole of A and 8 mole of B will produce -
and 80 gm oxygen (at. mass 16). What is (A) 5 mole of C
(B) 4 mole of C
the formula of the compound -
(C) 8 mole of C
(A) IO (B) I2O (D) 13 mole of C
(C) I5O 3 (D) I2O 5
 Q.48 The law of multiple proportions is illustrated
Laws of Chemical Combination
by -

Q.45 Hydrogen and oxygen combine to form H2O2 (A) Carbon monoxide and carbon dioxide
and H 2 O containing 5.93% and 11.2% (B) Potassium bromide and potassium
Hydrogen respectively. The data illustrates- chloride
(A) Law of conservation of mass
(C) Water and heavy water
(B) Law of constant proportions
(C) Law of reciprocal proportions (D) Calcium hydroxide and barium hydroxide.
(D) Law of multiple proportions
Q.49 The law of conservation of mass holds good
Q.46 If water samples are taken from sea, rivers, for all of the following except -
clouds, lake or snow, they will be found to (A) All chemical reactions
contain H2 and O 2 in the fixed ratio of 1 : 8.
This indicates the law of - (B) Nuclear reactions
(A) Multiple proportion (C) Endothermic reactions.
(B) Definite proportion (D) Exothermic reactions.
(C) Reciprocal proportion
(D) None of these. Q.50 If law of conservation of mass was to hold
Q.47 One of the following combinations illustrate true, then 20.8 gm of BaCl2 on reaction with
law of reciprocal proportions- 9.8 gm of H2SO 4 will produce 7.3 gm of HCl
and BaSO4 equal to -
(A) N2O3, N2O4, N2O 5
(A) 11.65 gm (B) 23.3 gm
(B) NaCl, NaBr, NaI
(C) 25.5 gm (D) 30.6 gm
(C) CS2, CO2, SO 2
(D) PH3, P2O3, P2O 5
 LEVEL # 2
Q.1 Which one of the following properties of an Q.7 If one mole of ethanol (C2H5OH) completely
element is not variable ? burns to form carbon dioxide and water, the
(A) Valency (B) Equivalent mass weight of carbon dioxide formed is about -
(C) Atomic mass (D) All the three (A) 22 gm (B) 45 gm
(C) 66 gm (D) 88 gm
Q.2 An element A is tetravalent and another
element B is divalent. The formula of the Q.8 If LPG cylinder contains mixture of butane
compound formed from these elements will
and isobutane, then the amount of oxygen
be-
that would be required for combustion of 1kg
(A) A2B (B) AB of it will be-
(C) AB2 (D) A2B3
(A) 1.8 kg (B) 2.7 kg
(C) 4.5 kg (D) 3.58 kg
Q.3 The vapour density of gas A is four times that
of B. If molecular mass of B is M, then
molecular mass of A is - Q.9 1 gm - atom of nitrogen represents -
(A) M (B) 4M (A) 6.02 x 1023 N2 molecules
(B) 22.4 lit. of N2 at N.T.P.
M
(C) (D) 2M (C) 11.2 lit. of N2 at N.T.P.
4
(D) 28 gm of nitrogen.
Q.4 Percentage of copper and oxygen in sample Q.10 The moles of O2 required for reacting with
of CuO obtained by different methods were 6.8 gm of ammonia.
found to be same. This proves the law of -
(..... NH3 +..... O2  ..... NO + ..... H2O) is
(A) Constant proportion
(A) 5 (B) 2.5
(B) Multiple proportion
(C) 1 (D) 0.5
(C) Reciprocal proportion
(D) None of these
Q.11 If isotopic distribution of C–12 and C–14 is
98% and 2% respectively, then the number
Q.5 6 gm of carbon combines with 32 gm of of C–14 atoms in 12 gm of carbon is -
sulphur to form CS2. 12 gm of C also combine
(A) 1.032 × 1022 (B) 3.01 × 1022
with 32 gm of oxygen to form carbondioxide.
10 gm of sulphur combines with 10 gm of (C) 5.88 × 1023 (D) 6.02 × 1023
oxygen to form sulphur dioxide. Which law is
illustrated by them - Q.12 If 3.01 x 10 20 molecules are removed from
(A) Law of multiple proportions 98 mg of H2SO4, then the number of moles
(B) Law of constant composition of H2SO4 left are-
(C) Law of Reciprocal proportions (A) 0.1 × 10–3
(D) Gay Lussac's law. (B) 0.5 × 10–3
(C) 1.66 × 10–3
Q.6 Two elements X (at mass 16) and Y (at mass (D) 9.95 × 10–2
14) combine to form compounds A, B and C.
The ratio of different masses of Y which
Q.13 Total number of atoms of all elements present
combine with a fixed mass of X in A, B and C
in 1 mole of ammonium dichromate
is 1 : 3 : 5. If 32 parts by mass of X combines
with 84 parts by mass of Y in B, then in C, 16 [(NH4)2Cr2O 7] is
parts by mass of X will combine with- (A) 14
(A) 14 parts by mass of Y (B) 19
(B) 42 parts by mass of Y (C) 6 × 1023
(C) 70 parts by mass of Y (D) 114 × 1023
(D) 84 parts by mass of Y
Q.14 X gm of Ag was dissolved in HNO3 and the Q.23 Phosphine (PH3) decomposes to produce
solution was treated with excess of NaCl. vapours of phosphorus and H2 gas. What will
When 2.87 gm of AgCl was precipitated the be the change in volume when 100 mL of
value of x is - phosphine is decomposed ?
(A) 1.08 gm (B) 2.16 gm (A) + 50 mL (B) 500 mL
(C) 2.70 gm (D) 1.62 gm (C) + 75 mL (D) – 500 mL

Q.24 In the reaction 4A + 2B + 3C  A4B2C3 ,

Q.15 What mass of calcium chloride in grams
would be enough to produce 14.35 gm of what will be the number of moles of product
AgCl. formed, starting from one mole of A, 0.6 mole
of B and 0.72 mole of C ?
(At. mass Ca = 40, Ag = 108) -
(A) 0.25 (B) 0.3
(A) 5.55 gm (B) 8.295 gm
(C) 16.59 gm (D) 11.19 gm (C) 0.24 (D) 2.32

Q.16 Total no. of atoms in 44 gm of CO2 is - Q.25 8 gm of O 2 has the same number of
molecules as-
(A) 6.02 × 1023 (B) 6.02 × 1024
(A) 7 gm of CO (B) 14 gm of CO
(C) 1.806 × 1024 (D) 18.06 × 1022
(C) 14 gm of CO2 (D) 12 gm of CO2

Q.17 If the density of water is 1 gm/cm 3, then the Q.26 4.4 gm of CO2 and 2.24 litre of H2 at STP
volume occupied by one molecule of water is are mixed in a container. The total number of
approximately- molecules present in the container will be -
(A) 18 cm 3 (B) 22400 cm 3 (A) 6.022 × 1023 (B) 1.2044 × 1023
–23 cm (D) 3.0 × 10–23 cm 3
3
(C) 6.02 × 10 (C) 2 moles (D) 6.023 × 1024

Q.18 How many grams are contained in 1gm-atom Q.27 Find the volume of CO2 obtained at S.T.P. on
of Na - heating 200 gm of 50% pure CaCO3 -
(A) 13 gm (B) 23 gm (A) 11.2 litre (B) 22.4 litre
(C) 1 gm (D) 1/23 gm (C) 44.8 litre (D) None of these

Q.19 1.35 gm of pure Ca metal was quantitatively Q.28 2.76 gm of silver carbonate on being strongly
converted into 1.88 gm of pure CaO. What is heated yields a residue weighing -
atomic weight of Ca - (A) 2.16 gm (B) 2.48 gm
(A) 40.75 (B) 50 (C) 2.32 gm (D) 2.64 gm
(C) 60 (D) 70
Q.29 A sample of AlF3 contains 3.0 × 1024 F –
Q.20 The % loss in weight after heating a pure ions. The number of formula units in this
sample of potassium chlorate (M. wt. 122.5) sample are -
will be - (A) 9.0 × 1024
(A) 12.25 (B) 24.50 (B) 3.0 × 1024
(C) 39.17 (D) 49.00 (C) 0.75 × 1024
(D) 1.0 × 1024
Q.21 The minimum quantity in gram of H2S needed
to precipitate 63.5 gm of Cu+2 will be nearly
(A) 63.5 gm (B) 31.75 gm Q.30 Calculate the gm quantity of Na2CO 3 which
has same No. of atoms as the No. of protons
(C) 34 gm (D) 20 gm
present in 10 gm CaCO3 -
Q.22 Mass of H2O in 1000 kg CuSO4.5H2O is - (A) 20 gm
(Cu = 63.5) (B) 88.33 gm
(A) 360.5 kg (B) 36.05 kg (C) 44 gm
(C) 3605 kg (D) 3.605 kg (D) 60 gm
Q.31 The mass of CaCO3 produced when carbon Q.36 Avogadro's number of Rupees can be spent in
dioxide is passed in excess through 500 ml ..........years if 10 lac rupees per second are
of 0.5 M Ca(OH)2 will be- spent -
(A) 10 gm (B) 20 gm (A) 1.91 × 1010 year (B) 2.91 × 1010 year
(C) 50 gm (D) 25 gm. (C) 3.91 × 1010 year (D) 4.91 × 1010 year

Q.32 The mass of 70% pure H2SO 4 required for Q.37 The amount of sulphur required to produce 100
neutralisation of 1 mol of NaOH - moles of H2SO4 is -
(A) 49 gm (B) 98 gm (A) 3.2 × 103 gm (B) 32.65 gm
(C) 70 gm (D) 34.3 gm (C) 32 gm (D) 3.2 gm

Q.38 The vapour density of a mixture containing NO2

Q.33 A sample of hard water is found to contain
and N2O4 is 38.3 at 27º C. The moles of NO2 in
40 mg of Ca+2 ion per litre. The amount of
100 mole mixture is -
washing soda (Na2CO 3) required to soften
(A) 33.48 (B) 53.52
five litres of the sample would be -
(C) 28.3 (D) 76.6
(A) 1.06 gm (B) 5.3 gm
(C) 53 mg (D) 530 mg
Q.39 Assuming that petrol is iso-octane (C8H18) and
has density 0.8 gm/ml, 1.425 litre of petrol on
Q.34 The mass of oxygen that would be required complete combustion will consume oxygen -
to produce enough CO, which completely
(A) 50 L (B) 125 L
reduces 1.6 kg Fe2O3 (at. mass Fe = 56) is-
(C) 125 mol (D) 50 mol
(A) 240 gm (B) 480 gm
(C) 720 gm (D) 960 gm
Q.40 The conversion of oxygen to ozone occurs to
the extent of 15% only. The mass of ozone that
Q.35 1.5 gm of divalent metal displaced 4 gm of can be prepared from 67.2 L of oxygen at S.T.P.
copper (at. wt. = 64) from a solution of copper will be -
sulphate. The atomic weight of the metal is- (A) 14.4 gm (B) 96 gm
(A) 12 (B) 24 (C) 640 gm (D) 64 gm
(C) 48 (D) 6
 LEVEL # 3
Passage : Q.8 Nitrogen forms five oxides. It proves the law
of multiple proportions.
10 moles of SO 2 and 4 moles of O 2 are
mixed in a closed vessel of volume 2 litres.
The mixture is heated in presence of Pt Q.9 Empirical formula = (Molecular formula) × n
catalyst. Following reaction takes place :
2SO 2(g) + O 2(g)  2SO 3(g) Q.10 Mass of 3.01 × 1023 molecules of methane
Assuming the reaction proceeds to is 8 gm.
completion.
Q.11 Avogadro’s number varies with temperature
Q.1 Select the correct statement - and pressure.
(A) SO 2 is the limiting reagent
(B) O 2 is the limiting reagent Q.12 18 gm of water vapour and 18 gm of ice will
(C) both SO 2 and O 2 are limiting reagent not contain the same number of molecules.
(D) cannot be predicted
Each of the questions given below consists
Q.2 Number of moles of SO 3 formed in the of Statement-I and Statement-II. Use the
reaction will be - following Key to choose the appropriate
(A) 10 (B) 4 answer.
(C) 8 (D) 14
(A) If both statement-1 and statement-2 are
correct, and statement-2 is the correct
Q.3 Number of moles of excess reactant
explanation of statement-1
remaining -
(B) If both statement-1 and statement-2 are
(A) 4 (B) 2
correct, and statement-2 is not the correct
(C) 6 (D) 8
explanation of statement-1
(C) If statement-1 is correct and statement-2 is
Q.4 The calculation on the given reaction is
incorrect
based on -
(D) If statement-1 is incorrect and statement-2
(A) Boyle’s law
is correct
(B) Charle’s law
(C) Gay-Lussac’s law Q.13 Statement-1 : Molarity of pure water is
(D) Avogadro’s hypothesis 55.5 M.
Statement-2 : Molarity is temperature
Q.5 Total number of moles of gaseous component dependent parameter
will ...... after the reaction -
(A) increase
(B) decrease Q.14 Statement-1 : 1 g-atom of sulphur contains
(C) remain same Avogadro number of sulphur molecules
(D) may increase or decrease Statement-2 : Atomicity of sulphur is eight.

True or False :
Q.6 Equal volumes of different gases under similar Q.15 Statement-1 : The number of O atoms in
conditions of temperature and pressure 1 gm. of O 2, 1 gm O 3 and 1 gm of atomic
contain equal number of atoms. oxygen is same.
Statement-2 : Each of the species
Q.7 1 mole of C12H22O11 contains 22 hydrogen represents 1/16 gm-atom of oxygen.
atoms.
Q.16 Statement-1 : The ratio by volume of H 2 :
Cl2 : HCl in a reaction H2(g) + Cl2(g)  2HCl(g)
is 1 : 1 : 2.
Statement-2 : Substances always react in
such a way that their volume ratio is in
simple integers.

Q.17 Statement-1 : 0.2 N H2SO 4 solution has

molarity equal to 0.2 M.
Statement-2 : H2SO 4 is a diabasic acid.

Q.18 Column matching :

Column I Column II
A. CaC2 P. 106 gm
B. 2 g-equivalent of Q. 22.4 L at S.T.P.
Na2CO3
C. 6.02 × 1023 Ne R. Molarity of solution
atoms
D. Number of S. 0.01 moles of solute
gm-molecules in one lit. of solution
per litre of solution
E. Centimolar solution T. N0 formula units
Fe4[Fe(CN)6]3
F. Mohr’s salt U. Calcium carbide
G. Contain 18 gm-atom V. (NH4)2SO4.Fe(SO4).
of N 6H2O
 ANSWER KEY
LEVEL # 1
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. A B D B B C A D B D A C D A B C A D B D

Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

Ans. A B B B B D A C C A B C D D B C C D C A

Q.No. 41 42 43 44 45 46 47 48 49 50

Ans. A B C B D B C A B B

LEVEL # 2
Q .No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. C C B A C C D D C D A B D B A C D B A C

Q .No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

Ans. C A C C A B B A D B D C D B B B A A C A

LEVEL # 3

1. B 2. C 3. B 4. C 5. B 6. False 7. False

8. True 9. False 10. True 11. False 12. False 13. B 14. D

15. A 16. C 17. D 18. A  U; B  P; C  Q; D  R; E  S; F  V; G  T