DPP-19 PChe

PHYSICAL CHEMISTRY
(NURTURE)
DPP # 18
M.M. : 30 MAX. TIME : 20 Min.
ONLY ONE OPTION CORRECT TYPE
1. Two container each containing liquid water are connected as shown in diagram. [3]
Given that vapour pressure of H2O(l) at 300 K & 350 K are 22 mm of Hg and 40 mm of Hg. The
final pressure in each container if valve is opened while keeping the containers at the given
temperature is [3]
(A) 22 mm of Hg (B) 40 mm of Hg (C) 31 mm of Hg (D) 62 mm of Hg
2
2. A sample containing CaBr2 & NaI in mass ratio was dissolved in water and treated with
9
sufficient amount of aq. AgNO3 solution to form a mixed precipitate of AgI and AgBr. The weight
of mixed precipitate was found to be 1786 gm. [3]
Select the correct option.
(A) Moles of CaBr2 and NaI in the original sample was 1 and 6 respectively.
(B) Mass of original sample was 900 gm
(C) Mass of CaBr2 in the original sample was 400 gm
(D) Number of moles of AgBr produced is 1.
3. Which graph represent the correct -relationship between various velocities for ideal gas - [3]
(A) (B)
(C) (D)
C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Mob. 0744-2799900 Online Partner Unacademy 1
PHYSICAL CHEMISTRY
(NURTURE)
4. A vessel contains equal masses of three gases A,B,C and recorded a pressure of 3.5 bar at 25°C.
The molecular mass of C is twice that of B and molecular mass of A is half of B. Find the partial
pressure of B (in bar) in the vessel [3]
(A) 3 (B) 2 (C) 4 (D) 1
ONE OR MORE THAN ONE OPTION CORRECT TYPE
5. The graph below shows the distribution of molecular speed of two ideal gases X and Y at 200K.
on the basis of the below graph identify the correct statements - [3]
(A) If gas X is methane, then gas Y can be CO2

(B) Fraction of molecules of X must be greater than Y in a particular range of speed at 200K
(C) Under identical conditions rate of effusion of Y is greater than that of X
(D) The molar kinetic energy of gas X at 200K is equal to the molar kinetic energy of Y at 200K
INTEGER / SUBJECTIVE
6. Two bulbs A and B of equal capacity are filled with He and SO 2 respectively at same temperature.
[3]
(i) How will the URMS be affected if volume of B becomes 4 times that of A at constant
temperature.
(ii) How will the URMS be affected if half of the molecules of SO2 are removed at constant
temperature.
If URMS increases then fill 2 if it is decreases then fill 1 and if remains same then fill 0
7. What is the fraction of molecules possessing velocities [3]

(i) From Uavg to Uavg + 0.005 Uavg of a gas having molecular mass 100 g at 400 K.
(ii) From Uavg – 0.04 Uavg to Uavg + 0.04 Uavg.
Fill your answer by multiplying it with 104.
8. What is the fraction of molecules possessing energy [ E is average K.E.] [3]

(i) From E to E + 0.005 E of a gas having molecular mass 100 g at 400 K.
(ii) From E – 0.04 E to E + 0.04 E .
Fill your answer by multiplying it with 104.
PHYSICAL CHEMISTRY
(NURTURE)
9. The gas "A" decomposes as A  B + 5C [3]

A partially decomposed gaseous mixture is allowed to effuse through a pin hole and the gas
coming out initially was analysed. The mole fraction of C in effused gas was found to be 0.6.
Determine
(a) ratio of rate of effusion of "C" and "B".
If your simplest ratio is x/y then fill the value of x + y in OMR sheet till u get single digit answer.
(b) the degree of dissociation of ''A''.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
[Given: Molecular mass of A = 360,
Molecular mass of B = 160,
Molecular mass of C = 40]
10. 34 gm of a mixture containing N2 and H2 in 1 : 3 by mole is partially converted into NH3.

Calculate the vapour density of the mixture (containing remaining N 2, H2 and NH3 formed) after
reaction if it has been found that the NH3 formed required 0.5 moles of H3PO4 for complete
neutralization. [3]
3NH3 + H3PO4  (NH4)3 PO4
First multiply your answer with 10. Then fill your answer as sum of digits (excluding decimal
places) till you get the single digit answer.

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PHYSICAL CHEMISTRY

ONE OR MORE THAN ONE OPTION CORRECT TYPE

(A) If gas X is methane, then gas Y can be CO2

7. What is the fraction of molecules possessing velocities [3]

8. What is the fraction of molecules possessing energy [ E is average K.E.] [3]

9. The gas "A" decomposes as A  B + 5C [3]

10. 34 gm of a mixture containing N2 and H2 in 1 : 3 by mole is partially converted into NH3.

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