Analytical Design of 1 KW Capacity Lithium Bromide/Water Absorption Refrigeration System
Analytical Design of 1 KW Capacity Lithium Bromide/Water Absorption Refrigeration System
Analytical Design of 1 KW Capacity Lithium Bromide/Water Absorption Refrigeration System
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Abstract
In current era, the energy scarcity is the key concern. In this context, new alternative
environment-friendly energy resources have to be explored. The researchers are focusing
more on effective and efficient use of energy. The difference in demand and production of
energy opens a new arena of heat recovery systems. Vapour absorption refrigeration systems
(VARS) are one of the prominent heat recovery systems powered by heat, and can be powered
by waste heat. This article presents the analytical design of aqueous lithium-bromide based
VARS. Operating parameters for all the parts are designed on the basis of evaporator
capacity, i.e. 1 kW. The thermodynamic simulation is done on the basis of empirical
correlations. The engineering equation solver (EES) codes are developed to determine
various working parameters of VARS with the different operating conditions. The coefficient
of performance (COP) for VARS is calculated with respect to different temperatures of the
generator, condenser, absorber and effectiveness of solution heat exchanger. The behaviour
of COP is studied with varying operating parameters. The obtained results prove that the
COP is highly responsive to operating temperature of generator and condenser. The optimum
value of COP and parameters are calculated by one factor at time (OFAT) technique.
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Design of LiBr/Water Absorption Refrigeration System Yadav and Berwal
directly affected by heat input. Akuart et al. absorbent fluid and heat is released. This
reviewed various technologies for waste heat solution of refrigerant and absorbent (strong
recovery and concluded that wasted heat can solution) is then pumped to generator through
be considerably recovered by heat exchangers solution heat exchanger. The heat from the
used to operate heat pipes, Rankin cycle and heat source separates refrigerant from solution
absorption heat pumps to enhance overall in generator. Refrigerant separated from the
efficiency of system [7]. Alam proposed solution left a weak solution in generator (low
theoretical model to utilize engine exhaust gas percentage of refrigerant). The weak solution
of engine to power air conditioner with passing through solution heat exchanger is
ammonia/water as a working fluid [8]. Waste sent to absorber through throttling valve. In
heat available in engine exhaust gases is 3.05 solution, heat exchanger heat is transferred
to 6.02 kJ/sec depending upon the load from weak solution to strong solution
applied. Engine exhaust gas can be used to (refrigerant-absorbent solution). Thus the
power VARS. The heat required to power solution heat exchanger helps to increase the
generator is 3.02 kJ/sec which is sufficiently COP of system. Pumps used in VARS run on
negligible pumping power as compared to
available in engine exhaust gas. Alexia et al.
compressors and thus this energy is usually
studied ammonia/water VARS powered by the
neglected in analysis. The sources of energy
engine exhaust gases heat [9]. VARS was
for VARS may come from the natural gas,
installed on market available automotive
waste process heat, solar energy etc. The
engine and tested on variable throttling
condenser, evaporator and throttling valve
conditions. VARS achieved a steady state in work as the conventional vapour compression
3 h for required temperatures. They studied refrigeration systems [11].
effect of VARS on performance of engine
power and exhaust emissions. VARS LiBr/Water Absorption System Model
installation on engine exhausts increases In the current study, LiBr/water absorbent and
hydrocarbon emissions but reduces carbon refrigeration pair is taken.
monoxide without altering the production of
carbon dioxide. The study implies that the Thermodynamic Analysis of the System
cooling capacity needs improvement for The mass balance is modelled using continuity
exhaust gases based VARS. Horuz used equation. Mass balance at any point in the
VARS for road transport vehicles [10]. system is shown by Eq. (1). Sum of mass
Internal combustion engine exhaust based entering at any point must be equal to the sum
VARS will reduce running cost and of mass exiting that point.
atmospheric pollution. However, further . .
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Journal of Alternate Energy Sources and Technologies
Volume 8, Issue 3
ISSN: 2230-7982 (Online), ISSN: 2321-5186 (Print)
Generator Evaporator
The mass entering in the generator is the The mass entering in the evaporator is the
solution pumped from absorber (m3) and the condensate from condenser (m9) after passing
mass exiting is the amount of steam generated the expansion device and the mass exiting is in
(m7) and the solution going to heat exchanger the form of evaporated condensate (m10) after
(m4). The mass balance is shown in Eq. (3). absorbing energy from fluid to be cooled. The
. . . mass balance at condenser is shown in Eq. (7).
m3 m7 m4 (3) . .
m9 m10 (7)
The energy required for generator is the The energy absorbed by refrigerant at
difference of energy supplied by solution evaporator is the difference of energy of
(𝑚3 ℎ3) pumped to generator from absorber condensate supplied (𝑚9 ℎ9) and energy used
and the energy used to generate vapour (𝑚7 ℎ7) to evaporate the condensate (𝑚10 ℎ10). The
and energy absorbed by solution (𝑚5 ℎ5) sent energy balance at condenser is shown in
to heat exchanger. The heat balance is shown Eq. (8).
in Eq. (4). .
Condenser Absorber
The mass entering in the condenser is the The mass entering in the absorber is the
steam from generator (m7) and the mass solution sent from heat exchanger (m6) and
exiting is the condensate (m8). The mass evaporated condensate (m10) from evaporator.
balance at condenser is shown in Eq. (5). The mass exiting from absorber is the strong
. . solution pumped to generator (m1). The mass
m7 m8 (5) balance at absorber is shown in Eq. (9).
𝑚1 = 𝑚6 + 𝑚10 (9)
The energy extracted from the condenser is the
difference of energy of vapour (𝑚7 ℎ7) The energy extracted from the absorber is the
supplied from generator and the condensate difference of energy supplied by solution
(𝑚8 ℎ8) exiting the condenser. The heat (𝑚6 ℎ6 ) sent from heat exchanger and
balance is shown in Eq. (6). evaporated condensate (𝑚10 ℎ10) from
. evaporator and the energy absorbed (𝑚1 ℎ1 ) by
Qc m7 (h7 h8 ) (6) the strong solution pumped to generator. The
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Design of LiBr/Water Absorption Refrigeration System Yadav and Berwal
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Journal of Alternate Energy Sources and Technologies
Volume 8, Issue 3
ISSN: 2230-7982 (Online), ISSN: 2321-5186 (Print)
Point 3:
Heat released from Absorber:
X ws Qa m6 H 6 m10 H10 m1 H1
m3 m9 0.001904 kg / sec
X ws X ss 1.193 kW
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Design of LiBr/Water Absorption Refrigeration System Yadav and Berwal
1.0
Xss(%)
0.5
0.0
-0.5
80
82
84
86
88
90
92
94
96
98
100
102
104
106
108
110
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Journal of Alternate Energy Sources and Technologies
Volume 8, Issue 3
ISSN: 2230-7982 (Online), ISSN: 2321-5186 (Print)
0.74
0.72
0.70
Xws(%)
0.68
0.66
0.64
0.62
0.60
80
82
84
86
88
90
92
94
96
98
100
102
104
106
108
110
Generater temperature (Celcius)
0.86
0.85
0.84
0.83
COP
0.82
0.81
0.80
0.79
0.78
80
82
84
86
88
90
92
94
96
98
100
102
104
106
108
110
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Design of LiBr/Water Absorption Refrigeration System Yadav and Berwal
The effects of generator temperature on the Figure 8 shows that concentration of strong
various parameters are calculated by keeping solution is not affected by rise in condenser
the evaporator, absorber and condenser temperature. The concentration of weak
temperatures fixed at 7, 30 and 30ºC solution has a linear behavior with rise in
respectively. Figure 2 depicts that variation in condenser temperature as shown in Figure 9.
generator temperature does not affect the As we increase the temperature of condenser,
concentration of weak solution. Figure 3 the COP decreases linearly till 38ºC, and after
shows that the concentration of weak solution that, it rapidly falls to 0.25 from 0.75 as shown
increases linearly with increase in generator in Figure 10.
temperature. Figure 4 shows the behaviour of
COP with the rise in generator temperature. For the further optimization, the generator,
The COP increases rapidly till temperature
condenser and absorber temperatures are
reaches 90ºC, after that, COP is less affected
varied from 80–106ºC, 20–46ºC and 30–56ºC
by generator temperature.
respectively by an increment of 2ºC in each.
The effects of absorber temperature on the The evaporator temperature is fixed at 7ºC.
various parameters are calculated by keeping Figure 11 shows the linear variation in
the generator, condenser and evaporator concentration of strong solution with the rise
temperatures fixed at 80, 30 and 7ºC temperatures. The concentration of weak
respectively. Figure 5 shows that variation the solution has a linear behavior with rise
concentration of strong solution increases temperatures as shown in Figure 12. Figure 13
linearly with the rise in absorber temperature. depicts the behaviour of COP with the rise in
Figure 6 shows that the concentration of weak temperatures. The COP decreases slowly till
solution is not effected by increase in absorber generator, condenser and absorber
temperature. Figure 7 depicts the behaviour of temperatures reached 100, 40 and 50ºC
COP with the rise in absorber temperature. respectively, after that, there is rapid decrease
The COP decreases slowly till temperature of COP from 0.76 to 0.51 for the rise of 4ºC
reaches 40ºC, after that, there is rapid decrease generator, condenser and absorber
in COP with rise in absorber temperature. temperatures respectively.
0.60
0.59
0.58
0.57
Xss(%)
0.56
0.55
0.54
0.53
0.52
0.51
0.50
30
32
34
36
38
40
42
44
46
48
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Journal of Alternate Energy Sources and Technologies
Volume 8, Issue 3
ISSN: 2230-7982 (Online), ISSN: 2321-5186 (Print)
1.0
Xws(%)
0.5
0.0
30
32
34
36
38
40
42
44
46
48
Absorber temperature (Celcius)
0.75
0.70
0.65
0.60
COP
0.55
0.50
0.45
0.40
0.35
30
32
34
36
38
40
42
44
46
48
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Design of LiBr/Water Absorption Refrigeration System Yadav and Berwal
1.5
Concentartion of Strong solution
1.0
Xss(%)
0.5
0.0
-0.5
20
22
24
26
28
30
32
34
36
38
40
42
44
46
48
50
Condenser temperature (Celcius)
0.72
Concentartion of weak Solution
0.70
0.68
0.66
0.64
0.62
Xws(%)
0.60
0.58
0.56
0.54
0.52
0.50
20
22
24
26
28
30
32
34
36
38
40
42
44
46
48
50
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Journal of Alternate Energy Sources and Technologies
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ISSN: 2230-7982 (Online), ISSN: 2321-5186 (Print)
0.80
0.75
0.70
0.65
0.60
COP
0.55
0.50
0.45
0.40
0.35
0.30
0.25
0.20
20
22
24
26
28
30
32
34
36
38
40
42
44
46
48
50
Condenser temperature (Celcius)
0.695
Concentartion of weak Solution (%)
0.690
0.685
0.680
Xws(%)
0.675
0.670
0.665
0.660
100-40-7-50
102-42-7-52
104-44-7-54
106-46-7-56
80-20-7-30
82-22-7-32
84-24-7-34
86-26-7-36
88-28-7-38
90-30-7-40
92-32-7-42
94-34-7-44
96-36-7-46
98-38-7-48
--
Temperatures(Tg-Tc-Te-Ta) (Celcius)
Fig. 11: Variation of Xws with Generator, Absorber and Condenser Temperatures.
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Design of LiBr/Water Absorption Refrigeration System Yadav and Berwal
0.64
0.62
0.60
0.58
Xss(%)
0.56
0.54
0.52
0.50
0.48
100-40-7-50
102-42-7-52
104-44-7-54
106-46-7-56
80-20-7-30
82-22-7-32
84-24-7-34
86-26-7-36
88-28-7-38
90-30-7-40
92-32-7-42
94-34-7-44
96-36-7-46
98-38-7-48
--
Temperatures(Tg-Tc-Te-Ta) (Celcius)
Fig. 12: Variation of Xss with Generator, Absorber and Condenser Temperatures.
0.90
Coefficient of Performance
0.85
0.80
0.75
0.70
COP
0.65
0.60
0.55
0.50
100-40-7-50
102-42-7-52
104-44-7-54
106-46-7-56
80-20-7-30
82-22-7-32
84-24-7-34
86-26-7-36
88-28-7-38
90-30-7-40
92-32-7-42
94-34-7-44
96-36-7-46
98-38-7-48
--
Temperatures(Tg-Tc-Te-Ta) (Celcius)
Fig. 13: Variation of COP with Generator, Absorber and Condenser Temperatures.
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Volume 8, Issue 3
ISSN: 2230-7982 (Online), ISSN: 2321-5186 (Print)
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