Organic Chemistry Test-1 On Total Syllabus: Single Correct

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Organic chemistry test-1 on total syllabus

Single Correct

1. Which product is not obtained when propanoicacid is subjected to HVZ


reaction?
HO O
HO O HO O
HO O
H Cl
H Cl Cl H Cl Cl

A) CH3 B) CH3 C) CH3 D) Cl

2. Ethyl acetate is commercially made by treating acetaldehyde with


aluminiumethoxide. This reaction is known as
A) Cannizzaro reaction B) Baeyer – villiger oxidation
B) Oppenauer oxidation D) Tischenko reaction

3. Identify the compound [A], by using differential extraction, as shown in the given
scheme.
NH2 OH COOH

F CH3

10% HCl

Ether layer Aqueous layer

Aq.NaHCO 3 NaOH

Aqueous layer
Ether layer

[C]

[A]

HCl

[B]

4. The missing reagents P and Q respectively in the following sequential


reactions is
P Q
Acetamide   Ethanenitrile  Ethanamine
A) P2O5 and SnCl2  HCl  aq  B) Br2 / KOH and LiAlH4
C) SOCl2 and Na  Hg  /EtOH D) POCl3 and NaBH4
5. The ratio of tertiary, secondary and primary hydrogens in the simplest acyclic
alkane that contains primary, secondary, tertiary and quartenary carbon atoms in
it is

A) 15:2:1 B) 12:2:1 C) 9:2:1 D) 18:2:1

6. The major product of the following reaction is

O
Cl Mg
H3C Et2O
Br

O O
MgCl Cl
H3C H3C
A) Br B) MgBr

O
O
H3C H3C
C) D)

7. The following structures represent a pair of

(A) identical molecules (B) diastereomers

(C) enantiomers (D) anomers

8. Arrange the following in decreasing order of basicity

p-nitroaniline
Aniline
 I (II)

N,N-dimethyl aniline N,N,2,6-tetra methyl aniline


 III  IV 

(A) I > II > IV > III (B) III >IV > I > II

(C) III > I > IV > II (D) IV > III > I > II
Multi Correct

9. Which reagent(s) is (are) used to convert nitrobenzene to aniline?

(A) H2/Pd-C (B) NaBH4 (C) LiAlH4 (D) (NH4)2S

10. Which of the carbohydrate(s) has/have at least one   glycosidic linkage?


A) Sucrose B) Maltose C) Lactose D) Cellulose

11. How many of following reactions doesn’t produce methane?

A) Wurtz reaction B) Kolbes reaction

C) Corey-House synthesis D) Readuction of bromo methane by NaBH4

12. Which of the following on treatment with CHCH produce gas(es)?


 
(A) NH2  (C) OH 

(B) C H3 (D) Na in liq NH3

13. The intermediate(s) involved in the following reaction is/are


Br

HBr CH3
H3 C CH2
CH3
CH3
H3 C + CH2 (B) +
(A) CH2

CH3 CH3

CH3
(C) + (D) CH3
H3 C CH2
+ CH
3
CH3
CH3

Numerical Model

14. The number of networked polymers among the following is

Melamine- formaldehyde resin, Bakelite, LDPE, HDPE, Nylon 66,


Cellulose, Amylase, Amylopectin
NaOH
15. NH2CONH2  Br2   N2
Hint: The intermediate product is NH2NH2

The stoichiometric coefficient of Br2 in the above conversion is

16. The number of moles of CO2 formed when 1 mol of


PhCCCH=CHCH=CH2 is treated with excess of hot
alkaline KMnO4 is
HINT:  -electrons of benzene are not involved in reaction
17. How many of them will form atleast one enantiomeric pair during monochlorination ?

i) 2-methylbutane ii) isobutane iii) neopentane

CH3

H3C

iv) CH3 ( Optically pure ) v) 2,2-di methyl butane vi)

CH3 H3C
CH3
H3C

vii) viii) CH3 ix)

18. Find the total number of structural isomers of C 9H18 containing cyclohexane
ring is

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