SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Sikaflex®-221
Revision Date 01.05.2019 Version 0.0 Print Date 01.05.2019

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : Sikaflex®-221
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use : Sealant/adhesive

1.3 Details of the supplier of the safety data sheet

Company name of supplier : Sika Limited
Watchmead Welwyn Garden City
Hertfordshire. AL7 1BQ
Telephone : +44 (0)1707 394444
Telefax : +44 (0)1707 329129
E-mail address of person : [email protected]
responsible for the SDS

1.4 Emergency telephone number

+44 (0)1707 363899 (available during office hours).

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Respiratory sensitisation, Category 1 H334: May cause allergy or asthma symptoms or
breathing difficulties if inhaled.

Specific target organ toxicity - repeated H373: May cause damage to organs through pro-
exposure, Category 2, Central nervous longed or repeated exposure if inhaled.
system

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal word : Danger

Hazard statements : H334 May cause allergy or asthma symptoms or

breathing difficulties if inhaled.
H373 May cause damage to organs (Central nerv-
ous system) through prolonged or repeated
exposure if inhaled.
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Precautionary statements :
Prevention:
P260 Do not breathe dust/ fume/ gas/ mist/ va-
pours/ spray.
P284 In case of inadequate ventilation wear respir-
atory protection.
Response:
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P342 + P311 If experiencing respiratory symptoms: Call a
POISON CENTER/doctor.
Disposal:
P501 Dispose of contents/container in accordance
with local regulation.

Hazardous components which must be listed on the label:

 Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
 4,4'-methylenediphenyl diisocyanate
Additional Labelling
EUH204 Contains isocyanates. May produce an allergic reaction.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative
and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Registration number
Urea,N,N''-(methylenedi-4,1- 77703-56-1 Aquatic Chronic 4; >= 2,5 - < 5
phenylene)bis[N'-butyl- 416-600-4 H413
01-0000016345-72-
XXXX
xylene 1330-20-7 Flam. Liq. 3; H226 >= 1 - < 2,5
Contains: 215-535-7 Acute Tox. 4; H332
ethylbenzene <= 25 % 01-2119488216-32- Acute Tox. 4; H312
XXXX Skin Irrit. 2; H315
Eye Irrit. 2; H319
STOT SE 3; H335
STOT RE 2; H373
Asp. Tox. 1; H304

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Hydrocarbons, C9-C12, n- Not Assigned Flam. Liq. 3; H226 >= 1 - < 2,5
alkanes, isoalkanes, cyclics, aro- 919-446-0 STOT SE 3; H336
matics (2-25%) 265-185-4 STOT RE 1; H372
01-2119458049-33- Asp. Tox. 1; H304
XXXX [corresponding Aquatic Chronic 2;
group CAS 64742-82- H411
1]
4,4'-methylenediphenyl diisocya- 101-68-8 Acute Tox. 4; H332 >= 0,1 - < 1
nate 202-966-0 Eye Irrit. 2; H319
01-2119457014-47- STOT SE 3; H335
XXXX Skin Irrit. 2; H315
Resp. Sens. 1; H334
Skin Sens. 1; H317
Carc. 2; H351
STOT RE 2; H373

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Remove contact lenses.

Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Do not induce vomiting without medical advice.

Rinse mouth with water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Asthmatic appearance
Allergic reactions
See Section 11 for more detailed information on health effects
and symptoms.

Risks : sensitising effects

May cause allergy or asthma symptoms or breathing difficul-

ties if inhaled.
May cause damage to organs through prolonged or repeated
exposure if inhaled.
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4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : In case of fire, use water/water spray/water jet/carbon diox-
ide/sand/foam/alcohol resistant foam/chemical powder for
extinction.

5.2 Special hazards arising from the substance or mixture

Hazardous combustion prod- : No hazardous combustion products are known
ucts

5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Further information : Standard procedure for chemical fires.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment.
Deny access to unprotected persons.

6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For personal protection see section 8.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Avoid exceeding the given occupational exposure limits (see

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section 8).
For personal protection see section 8.
Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. When using do not eat or drink. When using do not
smoke. Wash hands before breaks and at the end of workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep container tightly closed in a dry and well-ventilated
areas and containers place. Store in accordance with local regulations.

Further information on stor- : No decomposition if stored and applied as directed.

age stability

7.3 Specific end use(s)

Specific use(s) : Consult most current local Product Data Sheet prior to any
use.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form Control parame- Basis *
of exposure) ters *
xylene 1330-20-7 STEL 100 ppm GB EH40
441 mg/m3
Further information Can be absorbed through skin. The assigned substances are those for
which there are concerns that dermal absorption will lead to systemic
toxicity.
TWA 50 ppm GB EH40
220 mg/m3
Further information Can be absorbed through skin. The assigned substances are those for
which there are concerns that dermal absorption will lead to systemic
toxicity.
TWA 50 ppm 2000/39/EC
221 mg/m3
Further information Identifies the possibility of significant uptake through the skin, Indicative
STEL 100 ppm 2000/39/EC
442 mg/m3
Further information Identifies the possibility of significant uptake through the skin, Indicative

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4,4'-methylenediphenyl diisocyanate 101-68-8 TWA 0,02 mg/m3 GB EH40

(NCO)
Further information Substances that can cause occupational asthma (also known as
asthmagens and respiratory sensitisers) can induce a state of specific
airway hyper-responsiveness via an immunological, irritant or other
mechanism. Once the airways have become hyper-responsive, further
exposure to the substance, sometimes even to tiny quantities, may cause
respiratory symptoms. These symptoms can range in severity from a
runny nose to asthma. Not all workers who are exposed to a sensitiser
will become hyper-responsive and it is impossible to identify in advance
those who are likely to become hyper-responsive. 54 Substances that
can cause occupational asthma should be distinguished from substances
which may trigger the symptoms of asthma in people with pre-existing
airway hyper-responsiveness, but which do not include the disease them-
selves. The latter substances are not classified asthmagens or respiratory
sensitisers., Wherever it is reasonably practicable, exposure to substanc-
es that can cause occupational asthma should be prevented. Where this
is not possible, the primary aim is to apply adequate standards of control
to prevent workers from becoming hyper-responsive. For substances that
can cause occupational asthma, COSHH requires that exposure be re-
duced as low as is reasonably practicable. Activities giving rise to short-
term peak concentrations should receive particular attention when risk
management is being considered. Health surveillance is appropriate for
all employees exposed or liable to be exposed to a substance which may
cause occupational asthma and there should be appropriate consultation
with an occupational health professional over the degree of risk and level
of surveillance., Capable of causing occupational asthma., The 'Sen'
notation in the list of WELs has been assigned only to those substances
which may cause occupational asthma.
STEL 0,07 mg/m3 GB EH40
(NCO)
Further information Substances that can cause occupational asthma (also known as
asthmagens and respiratory sensitisers) can induce a state of specific
airway hyper-responsiveness via an immunological, irritant or other
mechanism. Once the airways have become hyper-responsive, further
exposure to the substance, sometimes even to tiny quantities, may cause
respiratory symptoms. These symptoms can range in severity from a
runny nose to asthma. Not all workers who are exposed to a sensitiser
will become hyper-responsive and it is impossible to identify in advance
those who are likely to become hyper-responsive. 54 Substances that
can cause occupational asthma should be distinguished from substances
which may trigger the symptoms of asthma in people with pre-existing
airway hyper-responsiveness, but which do not include the disease them-
selves. The latter substances are not classified asthmagens or respiratory
sensitisers., Wherever it is reasonably practicable, exposure to substanc-
es that can cause occupational asthma should be prevented. Where this
is not possible, the primary aim is to apply adequate standards of control
to prevent workers from becoming hyper-responsive. For substances that
can cause occupational asthma, COSHH requires that exposure be re-
duced as low as is reasonably practicable. Activities giving rise to short-
term peak concentrations should receive particular attention when risk
management is being considered. Health surveillance is appropriate for
all employees exposed or liable to be exposed to a substance which may
cause occupational asthma and there should be appropriate consultation
with an occupational health professional over the degree of risk and level
of surveillance., Capable of causing occupational asthma., The 'Sen'
notation in the list of WELs has been assigned only to those substances
which may cause occupational asthma.

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*The above mentioned values are in accordance with the legislation in effect at the date of the re-
lease of this safety data sheet.
Biological occupational exposure limits
Substance name CAS-No. Control parame- Sampling time Basis
ters
xylene 1330-20-7 methyl hippuric After shift GB EH40 BAT
acid: 650 Millimo-
les per mole Cre-
atinine
(Urine)
4,4'-methylenediphenyl diisocyanate 101-68-8 urinary diamine Post task GB EH40 BAT
(Isocyanates): 1
µmol/mol creati-
nine
(Urine)
8.2 Exposure controls

Personal protective equipment

Eye protection : Safety glasses with side-shields conforming to EN166
Eye wash bottle with pure water

Hand protection : Chemical-resistant, impervious gloves complying with an ap-

proved standard must be worn at all times when handling
chemical products. Reference number EN 374. Follow manu-
facturer specifications.

Suitable for short time use or protection against splashes:

Butyl rubber/nitrile rubber gloves (0,4 mm)
Contaminated gloves should be removed.
Suitable for permanent exposure:
Viton gloves (0.4 mm),
breakthrough time >30 min.

Skin and body protection : Protective clothing (e.g. Safety shoes acc. to EN ISO 20345,
long-sleeved working clothing, long trousers). Rubber aprons
and protective boots are additionaly recommended for mixing
and stirring work.

Respiratory protection : Respirator selection must be based on known or anticipated

exposure levels, the hazards of the product and the safe work-
ing limits of the selected respirator.
Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.
organic vapor filter (Type A)
A1: < 1000 ppm; A2: < 5000 ppm; A3: < 10000 ppm
Ensure adequate ventilation. This can be achieved by local
exhaust extraction or by general ventilation. (EN 689 - Meth-
ods for determining inhalation exposure). This applies in par-
ticular to the mixing / stirring area. In case this is not sufficent
to keep the concentrations under the occupational exposure
limits then respiration protection measures must be used.

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Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : paste

Colour : various

Odour : characteristic

Odour Threshold : No data available

pH : No data available

Melting point/range / Freezing : No data available

point

Boiling point/boiling range : No data available

Flash point : 76 °C
Method: closed cup

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : 0,01 hPa

Relative vapour density : No data available

Density : ca. 1,26 g/cm3 (20 °C)

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Auto-ignition temperature : No data available

Decomposition temperature : No data available

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Viscosity
Viscosity, dynamic : Not applicable

Viscosity, kinematic : > 20,5 mm2/s (40 °C)

Explosive properties : No data available

Oxidizing properties : No data available

9.2 Other information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
Hazardous reactions : Stable under recommended storage conditions.

10.4 Conditions to avoid

Conditions to avoid : Avoid moisture.

10.5 Incompatible materials

Materials to avoid : No data available

10.6 Hazardous decomposition products

No decomposition if stored and applied as directed.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity
Not classified based on available information.
Components:

xylene:
Acute oral toxicity : LD50 Oral (Rat): 3.523 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): 1.700 mg/kg

4,4'-methylenediphenyl diisocyanate:

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Acute inhalation toxicity : Acute toxicity estimate: 1,5 mg/l

Test atmosphere: dust/mist
Method: Expert judgement

Skin corrosion/irritation
Not classified based on available information.
Components:

Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%):

Assessment : Repeated exposure may cause skin dryness or cracking.

Serious eye damage/eye irritation

Not classified based on available information.
Respiratory or skin sensitisation

Skin sensitisation
Not classified based on available information.
Respiratory sensitisation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
May cause damage to organs (Central nervous system) through prolonged or repeated exposure if
inhaled.
Aspiration toxicity
Not classified based on available information.

SECTION 12: Ecological information

12.1 Toxicity

Components:

Urea,N,N''-(methylenedi-4,1-phenylene)bis[N'-butyl-:
Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): > 250 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
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Toxicity to algae : EC50 (Raphidocelis subcapitata (freshwater green alga)): >

100 mg/l
Exposure time: 72 h

xylene:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 3,3 mg/l
Exposure time: 96 h

12.2 Persistence and degradability

No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..

12.6 Other adverse effects

Product:
Additional ecological infor- : There is no data available for this product.
mation

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : The generation of waste should be avoided or minimized
wherever possible.
Empty containers or liners may retain some product residues.
This material and its container must be disposed of in a safe
way.
Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor.
Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

European Waste Catalogue : 08 04 09* waste adhesives and sealants containing organic
solvents or other dangerous substances

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Contaminated packaging : 15 01 10* packaging containing residues of or contaminated

by dangerous substances

SECTION 14: Transport information

14.1 UN number
Not regulated as a dangerous good
14.2 UN proper shipping name
Not regulated as a dangerous good
14.3 Transport hazard class(es)
Not regulated as a dangerous good
14.4 Packing group
Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Not applicable
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
International Chemical Weapons Convention (CWC) : Not applicable
Schedules of Toxic Chemicals and Precursors

REACH - Candidate List of Substances of Very High : None of the components are listed
Concern for Authorisation (Article 59). (=> 0.1 %).

REACH - List of substances subject to authorisation : Not applicable

(Annex XIV)

Regulation (EC) No 1005/2009 on substances that de- : Not applicable

plete the ozone layer

Regulation (EC) No 850/2004 on persistent organic pol- : Not applicable

lutants

Regulation (EC) No 649/2012 of the European Parlia- : Not applicable

ment and the Council concerning the export and import
of dangerous chemicals

REACH Information: All substances contained in our Products are

- registered by our upstream suppliers, and/or
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- registered by us, and/or

- excluded from the regulation, and/or
- exempted from the registration.

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of ma-
jor-accident hazards involving dangerous substances.
Not applicable

Volatile organic compounds : Law on the incentive tax for volatile organic compounds
(VOCV)
Volatile organic compounds (VOC) content: 3,42 %

Directive 2010/75/EU of 24 November 2010 on industrial

emissions (integrated pollution prevention and control)
Volatile organic compounds (VOC) content:
3,42 %, 43,04 g/l
VOC content excluding water

If other regulatory information applies that is not already provided elsewhere in the Safety Data
Sheet, then it is described in this subsection.

Health, safety and environ- : Environmental Protection Act 1990 & Subsidiary Regulations
mental regulation/legislation Health and Safety at Work Act 1974 & Subsidiary Regulations
specific for the substance or Control of Substances Hazardous to Health Regulations
mixture: (COSHH)
May be subject to the Control of Major Accident Hazards
Regulations (COMAH), and amendments.

Other regulations:
Take note of Directive 92/85/EEC regarding maternity protection or stricter national regulations,
where applicable.

15.2 Chemical safety assessment

No Chemical Safety Assessment has been carried out for this mixture by the supplier.

SECTION 16: Other information

Full text of H-Statements

H226 : Flammable liquid and vapour.
H304 : May be fatal if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H332 : Harmful if inhaled.
H334 : May cause allergy or asthma symptoms or breathing difficul-
ties if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
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H351 : Suspected of causing cancer.

H372 : Causes damage to organs through prolonged or repeated
exposure if inhaled.
H373 : May cause damage to organs through prolonged or repeated
exposure.
H373 : May cause damage to organs through prolonged or repeated
exposure if inhaled.
H411 : Toxic to aquatic life with long lasting effects.
H413 : May cause long lasting harmful effects to aquatic life.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Chronic : Long-term (chronic) aquatic hazard
Asp. Tox. : Aspiration hazard
Carc. : Carcinogenicity
Eye Irrit. : Eye irritation
Flam. Liq. : Flammable liquids
Resp. Sens. : Respiratory sensitisation
Skin Irrit. : Skin irritation
Skin Sens. : Skin sensitisation
STOT RE : Specific target organ toxicity - repeated exposure
STOT SE : Specific target organ toxicity - single exposure
2000/39/EC : Europe. Commission Directive 2000/39/EC establishing a first
list of indicative occupational exposure limit values
GB EH40 : UK. EH40 WEL - Workplace Exposure Limits
GB EH40 BAT : UK. Biological monitoring guidance values
2000/39/EC / TWA : Limit Value - eight hours
2000/39/EC / STEL : Short term exposure limit
GB EH40 / TWA : Long-term exposure limit (8-hour TWA reference period)
GB EH40 / STEL : Short-term exposure limit (15-minute reference period)
ADR : European Agreement concerning the International Carriage of
Dangerous Goods by Road
CAS : Chemical Abstracts Service
DNEL : Derived no-effect level
EC50 : Half maximal effective concentration
GHS : Globally Harmonized System
IATA : International Air Transport Association
IMDG : International Maritime Code for Dangerous Goods
LD50 : Median lethal dosis (the amount of a material, given all at
once, which causes the death of 50% (one half) of a group of
test animals)
LC50 : Median lethal concentration (concentrations of the chemical in
air that kills 50% of the test animals during the observation
period)
MARPOL : International Convention for the Prevention of Pollution from
Ships, 1973 as modified by the Protocol of 1978
OEL : Occupational Exposure Limit
PBT : Persistent, bioaccumulative and toxic
PNEC : Predicted no effect concentration
REACH : Regulation (EC) No 1907/2006 of the European Parliament
and of the Council of 18 December 2006 concerning the Reg-
istration, Evaluation, Authorisation and Restriction of Chemi-
cals (REACH), establishing a European Chemicals Agency
SVHC : Substances of Very High Concern
vPvB : Very persistent and very bioaccumulative
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Further information
Classification of the mixture: Classification procedure:
Resp. Sens. 1 H334 Calculation method
STOT RE 2 H373 Calculation method

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the
time of publication. All warranties are excluded. Our most current General Sales Conditions shall
apply. Please consult the product data sheet prior to any use and processing.

Changes as compared to previous version !

GB / EN

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