Chemistry–FUNGAT/ECAT

(Chapter 6+7 B-I)

1. Which of following best describes the change in the bond angle in water when the ion
H3O+ is formed:
(a) Decreases to approximately 107o (b) Decreases to approximately 109o
(c) Increases to approximately 1070 (d) Increases to approximately 120o
2. CCl4 has no net dipole moment because of:
(a) Regular tetrahedral structure (b) Planar structure
(c) Same E.N values (d) Same E.A values
3. __________ pair of molecules will have similar shape:
(a) SO3 and PCl3 (b) CdCl2 and SnCl2 (c) CO2 and SO2 (d) BF3 and AlCl3
4. Which one of the following is a linear molecule?
(a) H2O (b) Cl2O (c) HCN (d) SO2
5. The property which shows descending trend across the periods (left to right):
(a) Ionization energy (b) Hydration energy (cations)
(c) Electronegativity (d) Atomic radius
6. O2+2 has a bond order of:
(a) 1 (b) 2 (c) 3 (d) 4
7. Which one of the following is the correct set with reference to molecular formula,
hybridization of central atom and shape of the molecule?
(a) CO2, sp2, bent (b) H2O, sp2, bent (c) BeCl2, sp, linear (d) H2O, sp3, linear
8. The number of lone pairs of electrons present in central atom of CIF3 is:
(a) 0 (b) 1 (c) 2 (d) 3
9. Bond energy is increased by increase in all of following except:
(a) % of s character (b) Bond order
(c) Difference of E.N value (d) Bond length
10. Both ionic and covalent bonds are present in:
(a) CH4 (b) KCl (c) SO2 (d) NaOH
11. Which of the following has highest bond dissociation energy?
(a) N2 (b) N2–1 (c) N2–2 (d) N2+1
12. In which molecule, the bond angle between bond pair and bond pair is minimum:
(a) nitrogen trifluoride (b) ammonia
(c) water (d) boron trifluoride
13. Which substance has multiple bonds in a molecule?
(a) ethylene glycol (b) ammonium chloride
(c) hydrogen sulphide (d) carbon monoxide
14. The angle between lone pair and bond pair in NH3 molecule is:
(a) 107.5o (b) <107.5o
o
(c) < 102 (d) > 107.5o
15. The enthalpy change of a reaction does not depend on:
(a) Initial and final enthalpy change of reaction (b) State of reactants and products
(c) Different intermediate reactions (d) Nature of reactant and product
16. The correct equation for enthalpy change of formation of ammonia gas is
(a) N2(g) + 3H2(g)  2NH3(g) (b) 𝑁 + 3𝐻  𝑁𝐻
(c) 𝑁 + 𝐻  𝑁𝐻 (d) NH4Cl + NaOH  𝑁𝐻 + H2O(l) + HCl (g)
17. In exothermic reactions, the heat contents of the:
(a) products is more than that of reactants
(b) reactants is more than that of products
(c) both (a) and (b)
(d) reactants and products are equal

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18. Which one of the following enthalpy terms could be Exo as well as Endo in nature?
(a) Enthalpy of atomization (b) Enthalpy of neutralization
(c) Enthalpy of combustion (d) Enthalpy of solution
19. Which of the following changes is spontaneous as well as endothermic?
(a) H 2O(l)   H 2O(g) (b) H 2 O g   H 2 O l 
(c) H 2 Ol   H 2O ( s ) (d) All of these
20. The heat of formation of a compound is equal in magnitude to its:
(a) Heat of reaction
(b) Heat of decomposition into its elements
(c) Heat of combustion
(d) Heat of hydrogenation
21. At the standard condition i.e. 25°C and at 1 atmospheric pressure, the enthalpy value
of all elements is taken as:
(a) Zero (b) One (c) Positive (d) Negative
22. In Born-Haber cycle for KBr the total enthalpy change for the formation of ions comprises
following four reactions. Out of these largest enthalpy change takes place in:

K   K (g) K   K (g)  e
(a) (s) (b) (g)
1
Br2(g)   Br(g) Br  e    Br(g)
(c) 2 (d) (g)
23. Spontaneous reaction is such in which the system decreases its ________
(a) Energy (b) free energy (c) Entropy (d) All
24. Specific heat is defined as:
(a) heat capacity/mole (b) heat capacity at constant volume
(c) heat capacity/g (d) both a and c
25. The enthalpy of formation of ammonia is -46.0 kJ mol-1. The enthalpy for the reaction
N 2 g   3H 2 g    2 NH 3 g  is equal to:
(a) -46.0 kJ (b) 46.0 kJ (c) 92.0kJ (d) 92.0 kJ
26. Standard enthalpies of formation of O3, CO2, NH3 and HI are 142.2, -393.3, -46.2 and
+25.9 kJ mol-1respectively the order of their increasing stabilities will be:
(a) O3 , CO2 , NH 3 , HI (b) CO2 , NH 3, Hl , O3 (c) O3 , Hl , NH 3 , CO2 (d) NH 3 , Hl , CO2 , O3
27. The heats of neutralization of four acids A,B,C and D are 13.7, 9.4, 11.2 and 12.4
k-Cal respectively. When they are neutralized by a common base. The acidic character
obeys the order:
(a) A>B>C>D (b) A>D>C>B (c) D>C>B>A (d) D>B>C>A
28. The enthalpy of neutralization evolved when one mole of H2SO4 reacts with two
moles of NaOH is:
(a) 13.7 K-Cal (b) less than 13.7 k-Cal
(c) More than 13.7 k-Cal (d) 57.4 k-Cal
29. When enthalpy and entropy change for a chemical reaction are -2.5 x 103 cals and
7.4 cals-deg-1 respectively the predicted reaction at 298 K is
(a) irreversible (b) reversible (c) spontaneous (d) non-spontaneous
30. The difference between H and E at constant volume is equal to:
(a) R (b) PV (c) nRT (d) 3/2 R

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