Type IV Cracking Review
Type IV Cracking Review
EM12. This had a duplex microstructure containing d- retards the coarsening of M23C6 carbides (which
ferrite, giving poor impact toughness.6 At about the stabilise the martensite lath structure).14 However, at
same time a 12Cr–1Mo steel was developed in Germany concentrations in excess of 2 wt-%, the formation of
with the designation X20CrMoV12–1 and applied coarse laves phase (Fe2W) can lead to a deterioration of
throughout the world for tubes and pipes. While this creep properties.15 Tungsten also promotes the forma-
steel benefited from a fully martensitic microstructure, it tion of d-ferrite, so its use has to be balanced, either by
exhibited inferior creep strength to EM12 at tempera- reductions in the concentrations of other ferrite promot-
tures .520uC and was difficult to weld, primarily owing ing solutes such as molybdenum, or by adding austenite
to a high carbon content.6 stabilisers such as cobalt.16 The evolution of the 9–12 Cr
In the 1970s the Oak Ridge National Laboratory ferritic steels is illustrated in Fig. 1.17 Table 1 lists the
(USA) developed a modified 9Cr–1Mo steel,12 leading chemical compositions for various steels.6 It can be seen
ultimately to T91 for pressure tube applications and that many of the modern steels contain tungsten in the
alloy P91 for piping and headers; this superseded EM12 range 1–2 wt-%.
and X20CrMoV12–1. The alloy relies on a tempered Many of the new alloys which exhibited improved
martensitic microstructure stabilised by M23C6 carbides, creep rupture strength in short term tests have dis-
with further strengthening owing to molybdenum in appointed when 100 000 h data became available. As a
solid solution and a fine distribution of vanadium/ result, the focus of research has shifted to understanding
niobium rich carbonitride (MX) precipitates.10 the factors that affect the long term stability of M23C6
Reliable further improvements in creep strength have and MX precipitates. In creep tested steels a ‘modified
been achieved with the advent of steels such as NF616 Z-phase’, Cr(V,Nb)N (Ref. 18) seems to precipitate at
and HCM12A, where tungsten enhances the long term the expense of M23C6 and vitally, the MX precipi-
creep strength through solid solution hardening13 and tates.16,20 Recent studies have examined the effect of
Steels C N Si Mn Cr Mo V Nb W Co Cu
Hirata and Ogawa.42,43 They used induction heated this unusual HAZ microstructure have not been fully
HAZ simulated specimens with TP in the range 830 to clarified, but it is suggested22 that the low nitrogen
1200uC, subjecting them to creep at 650uC with a stress content reduces the content of MX, thus allowing the
of 98 MPa. The precipitates in the over tempered austenite grains to coarsen, eliminating the FGHAZ
regions did not dissolve as a consequence of the weld which is weak in creep. In any event, none of the welds
thermal cycle with TP5830uC, just above Ac1. In the studied exhibited type IV cracking, with fracture
coarse grained HAZ with TP51200uC, the precipitates occurring at the weld interface with rupture times
almost completely dissolved but were reprecipitated comparable to that of the parent metal. This is a system
during the post-weld heat treatment. In the fine grained which deserves further attention.
HAZ with TP51000uC (just above Ac3), carbides The mechanism of the boron effect is not clear; could
containing chromium or vanadium underwent partial it be that it influences austenite formation even at
dissolution with reprecipitation and relatively rapid such minute concentrations? Much may be attributable
coarsening during the post-weld heat treatment and to the absence of a fine grained HAZ, but it is also
subsequent creep, far more so than in the other zones. known that additions of boron have led to improved
After 5014 h there were indications of Z-phase in the creep performance for the parent material, through the
fine grained HAZ, a phase associated with reduced creep delayed coarsening of M23C6 carbides and a correspond-
properties.16,20,40 ing delay in the onset of tertiary creep.22
These observations are important because the partial
dissolution of M23C6 in the fine grained HAZ promotes Stress evolution
Z-phase which in turn destabilises MX. The resulting Watanabe et al.45 studied thermally aged 2.25Cr–1Mo,
deterioration of creep thus becomes localised to the type with and without an applied stress and found that
IV region. coarsening was accelerated in the presence of stress. It is
Some fascinating results have recently been reported expected therefore that residual stresses resulting from
on the influence of boron on type IV failure in 9–12 Cr welding are detrimental to creep properties, especially
steels.22,44 Albert et al.22 found that such failures were since coarse particles enhance the formation of
suppressed in a 9Cr–3W–3CoVNb steel containing voids.30,39
boron in the range 90–130 ppm, with nitrogen kept Although there are no specific data on residual
,0.002 wt-%. At stresses .100 MPa, fracture occurred stresses in 9–12 Cr steel weldments, the existence of
in the parent material, while for lower stresses the failure such stresses is well established in general.46–48
occurred at the fusion surface rather than in the usual Yaghi et al.49 recently made numerical predictions for
type IV region, which is the HAZ heated to near Ac3. the residual stresses that arise in P91 circumferential
There were reportedly no creep voids in the HAZ of pipe welds. Their results suggest that the location of the
fractured specimens. Curiously, the austenite grains peak tensile residual stresses will vary with the wall
remained large at a distance 1–2 mm from the fusion thickness. Nevertheless, as the wall thickness becomes
surface, the region where fine grained austenite is usually large, they consistently predict peak tensile residual
observed in the HAZ of welded joints. The reasons for stresses between 400 and 500 MPa near the outer surface
of the pipe; a result that becomes insensitive to further HAZ simulated specimens.53 Finally, they noted that
increases in wall thickness. There is a pressing need to once sliding was accommodated and constraint relaxed,
validate such numerical predictions with experimental the failure time for both cross-weld specimens and
data. Furthermore, studies specific to the power plant simulated type IV specimens was similar.
steels would be useful in assessing the importance of
parameters such as the preheat and post-weld heat Suggestions for future work
treatment in determining residual stress distributions
and the tendency for type IV cracking. As a result of this assessment of literature, we believe
Because of the gradients of microstructure in the that the following areas need particular attention in
HAZ, there are corresponding gradients in the creep future research:
properties. If the creep resistance reaches a minimum at (i) Controlled additions of boron: Evidence clearly
some location then complex constraint effects are suggests type IV cracking can be suppressed
expected during cross-weld loading, which may intensify using controlled additions of boron to 9–12 Cr
local damage. Using a two-dimensional finite element steels. Concentrations between 90 and 130 ppm
technique, Li et al.50 simulated creep in a P122 weldment result in the elimination of the conventional fine
by compiling a model consisting of four regions with grained HAZ; they stabilise M23C6 carbides,
different creep properties (weld metal, CGHAZ, apparently through the partial substitution of
FGHAZ and base metal). During creep, each zone carbon by boron. However, it is not clear which
within the weldment was assumed to obey Norton’s of these factors is responsible for the suppres-
creep law. The stress and strain distributions following sion of type IV failures, nor why it might be
1000 h of creep at 90 MPa and 650uC were thus counterproductive to exceed a boron level of
estimated. It was found that a high tensile first principal 130 ppm.
stress and high tensile hydrostatic stress were generated (ii) The stability of MX precipitates: MX precipi-
in the FGHAZ. It was argued that the strain focuses in tates are vital in determining the long term creep
the weaker FGHAZ during the early stages of creep, strength for 9–12 Cr steels. However, there are
leading to the nucleation of creep voids, which are then indications that the thermal cycles that are
experienced in the fine grained HAZ promote a
encouraged to grow by the strain mismatch and triaxial
chromium-rich ‘modified Z-phase’ of the form
stresses generated as creep progresses.
Cr(V,Nb)N during creep at the expense of MX
The triaxial stress state in the FGHAZ has been
precipitates. Further work is required to estab-
previously recognised to accelerate the growth of creep
lish how the fine grained HAZ is particularly
voids,28,50 but this may not necessarily lead to a
susceptible to this deleterious phase and
reduction in creep life. To illustrate this point, it is
whether its formation can be avoided.
worth considering the data in Fig. 7, for P122 steel.
(iii) Significance of welding parameters: There is a
Above 100 MPa, the creep performance of weldments is
dearth of studies relating welding parameters,
close to that for the parent material. Furthermore, as
particularly the preheat temperature and heat
the applied stress is reduced, the creep performance of
input, to the tendency for type IV cracking.
the weldments approaches (but still exceeds) that of the
(iv) Role of stress: The role of residual stresses
weakest zone within the weldment, i.e. the FGHAZ. If it arising from welding, on the creep performance
is assumed that the triaxial stress states that arise in the of 9–12 Cr steels, needs to be investigated with
FGHAZ accelerate the formation of creep voids, then it respect to their effect on the evolution of
is intriguing that the creep lives of the welded joints, microstructure in the HAZ. Further work is
which failed owing to type IV cracking, were still longer also necessary to clarify the extent to which
than those for the simulated FGHAZ specimens (these, grain-boundary sliding is responsible for the
after all, are mechanically homogeneous and will not formation of creep voids in longer-term creep
contain triaxial stresses). The data of Fig. 7 suggest that tests. In general, greater emphasis needs to be
the mechanical constraint resulting from the property placed on tests carried out at stresses below
gradients in the HAZ actually delays failure in the 100 MPa, as it is at these lower stress levels that
FGHAZ. type IV failures predominate.
An alternative approach to modelling type IV damage
is due to Kimmins and Smith,51 who used finite element
representations of Cr–Mo weldments, allowing for the Mechanism for type IV cracking
relaxation of constraint by the sliding of adjacent The focus on type IV cracking has in this review been on
elements during creep. It is known that models based the 9–12Cr steels which are leading the search for steels
on transverse strain compatibility give rise to significant useful in making ever more efficient power plants. For
constraint of creep deformation in the weak zone.52 these steels, it appears that the microstructure which is
However, it was pointed out that at lower service weakest in creep is that associated with the FGHAZ of
stresses grain boundaries are less resistant to sliding.53 a weld. This is the zone which reaches temperatures
Thus, in contrast to continuum models where damage just inside the austenite phase field, but not for long
accumulation is enhanced by multiaxial stresses, enough to allow carbide precipitates to completely
Kimmins and Smith suggested that constraint is relaxed dissolve. As a result, the austenite grains that form
by grain boundary sliding.51 They later presented remain relatively fine and transform to martensite on
evidence to suggest that grain boundary sliding in cooling. On post-weld heat treatment, the undissolved
cross-weld specimens gives rise to greater numbers of carbides coarsen with limited further precipitation.
cavities, consistent with their observation that greater The FGHAZ does not correspond to the heat affected
numbers of cavities are observed in welded joints than in region with the lowest hardness, which is the zone that is
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