Safety Data Sheet: Not For Sale in California

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Safety Data Sheet

1 - Chemical Product and Company Identification

Trade Name: WD-40 Multi-Use Product Bulk Liquid Manufacturer: WD-40 Company
NOT FOR SALE IN CALIFORNIA Address: 1061 Cudahy Place (92110)
P.O. Box 80607
Product Use: Lubricant, Penetrant, Drives Out San Diego, California, USA
Moisture, Removes and Protects Surfaces From 92138 –0607
Corrosion Telephone:
Restrictions on Use: None identified Emergency only: 1-888-324-7596 (PROSAR)
Information: 1-888-324-7596
MSDS Date Of Preparation: 8/25/15 Chemical Spills: 1-800-424-9300 (Chemtrec)
1-703-527-3887 (International Calls)

2 – Hazards Identification
Hazcom 2012/GHS Classification:
Flammable Liquid Category 3
Aspiration Toxicity Category 1

Note: The 1 gallon size product is a consumer product and is labeled in accordance with the US
Consumer Product Safety Commission regulations which take precedence over OSHA Hazard
Communication labeling. The actual container label will not include the label elements below. The
labeling below applies to larger containers sold for industrial/professional use.

Label Elements:

DANGER!
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Prevention
Keep away from heat, sparks, open flames, hot surfaces – No smoking.
Keep container tightly closed.
Ground and bond containers and receiving equipment.
Use explosion-proof electrical equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear eye protection.
Response
IF SWALLOWED: Immediately call a POISON CENTER or physician.
Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
In case of fire: Use water fog, dry chemical, carbon dioxide or foam to extinguish.
Storage
Store locked up.
Store in a well-ventilated place. Keep cool.
Disposal
Dispose of contents and container in accordance with local and national regulations.

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3 - Composition/Information on Ingredients
Ingredient CAS # Weight Percent GHS Classification
Aliphatic Hydrocarbon 64742-47-8 45-50 Flammable Liquid Category 3
Aspiration Toxicity Category 1
Petroleum Base Oil 64742-56-9 <35 Not Hazardous
64742-65-0
64742-53-6
64742-54-7
64742-71-8
LVP Aliphatic Hydrocarbon 64742-47-8 12-18 Aspiration Toxicity Category 1
Note: The specific chemical identity and exact percentages are a trade secret.

4 – First Aid Measures


Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center
or the WD-40 Safety Hotline at 1-888-324-7596 immediately.
Eye Contact: Flush thoroughly with water. Remove contact lenses if present after the first 5 minutes and
continue flushing for several more minutes. Get medical attention if irritation persists.
Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention.
Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if irritation or other
symptoms develop and persist.
Signs and Symptoms of Exposure: May cause eye and respiratory irritation. Inhalation may cause
coughing, headache and dizziness. Skin contact may cause drying of the skin.
Indication of Immediate Medical Attention/Special Treatment Needed: Immediate medical attention is
needed for ingestion.

5 – Fire Fighting Measures


Suitable (and unsuitable) Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do
not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire.
Specific Hazards Arising from the Chemical: Combustible liquid and vapor. Vapors are heavier than air
and may travel along surfaces to remote ignition sources and flash back. Combustion will produce oxides of
carbon and hydrocarbons.
Special Protective Equipment and Precautions for Fire-Fighters: Firefighters should always wear positive
pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with
water.

6 – Accidental Release Measures


Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective
clothing (see Section 8). Eliminate all sources of ignition and ventilate area.
Methods and Materials for Containment/Cleanup: Contain and collect liquid with an inert absorbent and
place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required.

7 – Handling and Storage


Precautions for Safe Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing
vapors or aerosols. Use with adequate ventilation. Keep away from heat, sparks, hot surfaces and open
flames. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep
out of the reach of children.
Conditions for Safe Storage: Store in a cool, well-ventilated area, away from incompatible materials. NFPA
30 Class II Liquid.

8 – Exposure Controls/Personal Protection


Chemical Occupational Exposure Limits
Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended)
Petroleum Base Oil 5 mg/m3 (inhalable) TWA ACGIH TLV

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5 mg/m3 TWA OSHA PEL
LVP Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended)

The Following Controls are Recommended for Normal Consumer Use of this Product
Engineering Controls: Use in a well-ventilated area.
Personal Protection:
Eye Protection: Avoid eye contact. Safety glasses or goggles recommended.
Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations
where skin contact is likely.
Respiratory Protection: None needed for normal use with adequate ventilation.

For Bulk Processing or Workplace Use the Following Controls are Recommended
Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels
below that occupational exposure limits.
Personal Protection:
Eye Protection: Safety goggles recommended where eye contact is possible.
Skin Protection: Wear chemical resistant gloves.
Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are
exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant
type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice.
Work/Hygiene Practices: Wash with soap and water after handling.

9 – Physical and Chemical Properties

Appearance: Light amber liquid Flammable Limits: LEL: 0.6% UEL: 8.0%
(Solvent Portion)
Odor: Mild petroleum odor Vapor Pressure: 1 psi @38C (100F)
ASTM D323
Odor Threshold: Not established Vapor Density: Greater than 1 (air=1)
pH: Not Applicable Relative Density: 0.8 – 0.82 @ 60F
Melting/Freezing Point Not established Solubilities: Insoluble in water
Boiling Point/Range: 361 - 369F (183 - Partition Coefficient; n- Not established
187°C) octanol/water:
Flash Point: 122F (49°C) Tag Open Autoignition Not established
Cup Temperature:
Evaporation Rate: Not established Decomposition Not established
Temperature:
Flammability (solid, gas) Not Applicable Viscosity: 2.79-2.96 cSt @
100F
VOC: 412 grams/liter (49.5%) Pour Point: -63C (-81.4F ) ASTM
D-97

10 – Stability and Reactivity


Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition.
Incompatibilities: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide.

11 – Toxicological Information
Symptoms of Overexposure:
Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects
such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal.

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Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible
dermatitis.
Eye Contact: Contact may be irritating to eyes. May cause redness and tearing.
Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea,
vomiting and diarrhea. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause
chemical pneumonitis, severe lung damage and death.
Chronic Effects: None expected.
Carcinogen Status: None of the components are listed as a carcinogen or suspect carcinogen by IARC,
NTP, ACGIH or OSHA.
Reproductive Toxicity: None of the components is considered a reproductive hazard.

Numerical Measures of Toxicity:


Acute Toxicity Estimates: Oral > 5,000 mg/kg; Dermal >2,000 mg/kg based on an assessment of the
ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard.

12 – Ecological Information
Ecotoxicity: No specific aquatic toxicity data is currently available, however components of this product are
not expected to be harmful to aquatic organisms
Persistence and Degradability: Component are readily biodegradable.
Bioaccumulative Potential: Bioaccumulation is not expected based on an assessment of the ingredients.
Mobility in Soil: No data available
Other Adverse Effects: None known

13 - Disposal Considerations
If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous
waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper
classification and method of disposal. Dispose in accordance with federal, state, and local regulations.

14 – Transportation Information_
DOT Surface Shipping Description: Excepted from Hazmat (49CFR 173.150 (F)) in non-bulk packagings. Bulk
Packagings: UN1268, Petroleum Distillates, n.o.s., Combustible Liquid, PG III
IMDG Shipping Description: UN1268, Petroleum Distillates, n.o.s. 3, PG III
ICAO Shipping Description: UN1268, Petroleum Distillates, n.o.s. 3, PG III NOTE: WD-40 does not test
containers to assure that they meet the pressure differential and other requirements for transport by air. We
do not recommend that our products be transported by air.

15 – Regulatory Information
U.S. Federal Regulations:
CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements,
however, oil spills are reportable to the National Response Center under the Clean Water Act and many
states have more stringent release reporting requirements. Report spills required under federal, state and
local regulations.
SARA TITLE III:
Hazard Category For Section 311/312: Acute Health, Fire Hazard
Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III
Section 313 Reporting requirements: None
Section 302 Extremely Hazardous Substances (TPQ): None
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the
TSCA inventory
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not
contain chemicals regulated under California Proposition 65.
VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and
states adopting the OTC VOC rules.

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Canadian Environmental Protection Act: One of the components is listed on the NDSL. All of the other
ingredients are listed on the Canadian Domestic Substances List or exempt from notification.
Canadian WHMIS Classification: Class B-3 (Combustible Liquid)
This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the
MSDS contains all of the information required by the CPR.

16 – Other Information:
HMIS Hazard Rating:
Health – 1 (slight hazard), Fire Hazard – 2 (moderate hazard), Reactivity – 0 (minimal hazard)

Revision Date: August 2015 Supersedes: July 2014

Prepared by: Industrial Health & Safety Consultants, Inc. Shelton, CT, USA

Reviewed by: I. Kowalski Regulatory Affairs Department

3069000/No.0015106

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