WO2019045261A1

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2 $31 B ASH so} SAM FAS a AA Ae es CAA A FAS ARS ay FANG Zz oy 2019 33.27 Z (07.03.2019) wipo| pct WO 2019/045261 Al Gh SAS OER a) Waa AR (KIM, din oy, 059 DE PA A Goss 2172 20n601)——_-Ho4N-977 2106 01 EE Roh & 1a 263, 906-305, Gyeonggi-do KR), Goss 2192 (20601) Gat a1 G07 01 APA CHA, Jae Ming 16975 BLE Be 7) Gash 25714200601) BOND S304 (200601 7) 23812 St, 166203, Gyeongsio (KR). 2 ow 78 2006.01) (KIM, Hyo ity: [7161 A7}s= BA) Le ab FASS PCTIER2O100790 ee a reomesie ee laa a2) Fazal: 2ows x17 12.9) (2072018) 32-1902, Gyeonggi-do (KR) a8 eae 50] 74) sfelel: SA VIAS1o}oL a (AMP PATENT & LAW ar FAR: 529 AA 2 te, Se on 88am: ay ABE (IS9| MAP Me BASE SS SHAS WW20170112732 2017 9-24 POsOH2017) KR ee tera ieanianases Win san Solan ae Sele LAE MIA: AE AG. AL AM, 80. A (hy 28a: RENSA FATA ANSTITUTE FOR CL, CN.CO,CR CU, C7, DE. DI DK, DM, DO. D7. EC, ADVANCED ENGINEERING) [KRIKR), 17180 EELEG, ES. 1, GB, GD, GE, GH, GM, GT, HN, HR HU, IS 2214 silt whe wekesniid 175.28, jndo (KR). BEAPWAL FA] 814} (KOREA WESTERN POWER CO., LTD.) [KR/KR]: 32140 2 Gycong YE Heke ele Sas (kp), Bae ORPORATION) [KR/KRI; 58322 2 55, Jeollanam-do (KR) 285, Chungcheongoan-do } (KOREA ELECTRIC POWER hs Ue a ID. IL, IN, IR, IS. JO, IP, KE, KG, KH, KN, KP. KW, KZ, LA, LC, LK, LR. LS, LU. LY, MA. MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT. QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK. SL, SM, ST, SV, SY, TH, TJ, 7M, TN, TR, TT. TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, 2W. wo 2019/045261 A1 lll (Ga) Title: POLLUTANT GAS REMOVAL DEVICE, MONITORING SYSTEM AND METHOD OF POLLUTANT GAS RE MOVAL DEVICE G64 SAS YA: Oaths a7] Ba (57) Astras B87) B72 7] BAI aA A288 SL he present invention relates to a pollutant gas removal device which continously supplies and discharges new adsorbent regardless of abreakthrouzla point, detects thzough color change ofa detection tube whether pollutant gas remains in gas discharged from the pollutant gas removal device which removes te pollutant gs con- tained in syngas, nd allows a state of an adsorption tower to be naified without field personnel, inorder to efficiently itoring system nove the pollutant gis contained in the syngas, and ind a method for the pollutant gas removal device. According 10 ‘one embodiment of the present invention, provided is a pollutant gas removal device ‘which comprises a body portion which isa pressure vessel: a syngas supply unit which is installed ata lower end ofthe body portion o supply the syngas to the body portion: a syngas discharge unit which is installed at an upper end of the body portion to dis- ‘chutge syagas from the body portion, an adsorption unit whicl is installed inside the body portion to be inclined and in which an impregnated activated carbon is placed a supply unit which supplies the impregnated activated carbon to the adsomption unt and a discharge unit which discharges the impregnated activated carbon that has re= acted and become permeated with the pollutant gas contained in the syngas, wherein Ue adsorption unit comprises a par of inclined plates, and a connection portion which ‘connec the pair of inclined plates and in which the impregnated activated carbon is collected. and the par of inclined plates are formed to be inclined downward ina direc- tion ofthe connection portion, and the syngas containing the pollutant gas reacts with the impregnated activated carbon to remove the pollutant gas, and th ough the syngas discharge unit, is dischamged [he a WO 2019/045261 AL ill 00 A h AAS CSS) WAVE ME F2] uy el 2] MB 9] 8}o}y: ARIPO (BW. 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BT wel] RW, 2) BARB VI ASTON al ASA AAA sy Vs ~ 2 om a Aon ee he Eg mk 2 ip AS =e a S WO 20191045261 PCT/KR2018/007890 [872 16] P8717] (BTS 18] 37S 19] P83 20] 9 WES Ages AAA VHS BA Holey AA LENZ AA BAS] BAL ALAA BFA 139] GLO], B71 93 NL PES] MIA] HE LVAD STS AATOS HASH FAB aOTS C] EMSS, ONS Al] AAS) BA AAW AFB ZAI LA, 27) 272: WA VUELY Bas B71 VA wa S| ebay, A BEY VA YY SH OLS Brel AAV YH oA as od BAL BY LAMA A BAS] SHES Spo] S SAA SHES SIE ABs, OYA Ald ale} 2 Aza PQA] BB LYLE ASH G.I 7bZ: a7] AA] ZA] AARNE 01.G4 27k BAL HOA, B7| BENS A BAMA WED Weel) 27TH heh BEANE BA] MAMF] AAS AY spo} YA cole] By 37) BS VS UVES AA YHAS We 37) WAM AA VPS VT Mole S ve] AVA ae Be egy} waste] 7] Arla Va ye wdole| S Foy sp] QF BOE] QAM Be USA Moule giz) oS Ue Eas} 437) deat ebao] Beh zp, Ab7] ZJo]R: Srpe] Yah ajo] ey 7} apy] QAASA PE USA BAe] Noa CAAA AAAVSS els dS RAE, OVS BAe BS 18] VHA, 2y7| WesRs HA AV) BAY wll Ss + ball; AP) FAM YA vlolELS HSV Ae] YA Model ew 437) ated HSV Bt soles Azalea Bayal eoreeer NSO AVA STAs Yass da: @ QV ABM GIA UY Aalae PTH YA Models ase GAS BAe, O71 WA BS. BYP 190] QA, 37) Weadshs ARS 237) AS AAW VPA BH oS 71Wwes aah eA HSV # S 4ols: B42] HSV go] 7] B72 Ba VS Aol) AAHOY US THAT SEA G AbOV OM QNS=7] OPE HY ait ELSES, yy) tehis das Br] Aol s B+] HSV ge] by] V7 BA WO 20191045261 PCT/KR2018/007890 (37821) [878 22] [878 23] 20 -S-Atol 41x10} glitz AL ghst sa] ak Aho oH gored 2.4774 Ale] Lok eel Aste] whe} BME els, 27h BAL WA. JF 199) Blo}, 7) aalaba eel alsa Wa ob Fel, 7) 158 ALM BAL eOleELEE -VAaE Yop YA ol e| 8 Ao) 21S RLASE C] APSR, 9.91 7b2: 2A wa BEB 18] DOA, ay) = Ea] ol-Fell, ay7) eae] ea spo] ChE OA A S PS e]Aa aol Fo] TEAL SHS CASE C] APSR, 291742 TAL WH. FA 1991 OVA, 27) BH: Wl OLN, BAF] AAW YS AOL gebe] QA Yoo Ay 2.97274 Bele a abl 2@lzizs i aalel Bae Babel Sele SAPS SS WEES aloyshs WE C Reon, V7 LA. & ee ee WO 20191045261 PCT/KR2018/007890 [21 ane 130 22 198-Q| 14444 140, 142, 143. WO 20191045261 PCT/KR2018/007890 [=2] [53] WO 20191045261 PCT/KR2018/007890 arr cs] 121 (e5] > 5 ‘y (Br 5 a) 7 @ G 500 LI ~300 (61 WO 20191045261 PCT/KR2018/007890 ar [=7] Bro et I 19 1 \ 1 I \ 1 \ 1 ; Se aol NaS 1 1 1 I 1 1 1 I 20 aa dole Wee —----------------4 200 203 206 dl Bale ea WS oe Be wat sale ~*~ 201 204 { 205 29 a ane ale 2a ab Aalst -— 8 GIO Aas ay ae ase Ba Hae 209 fo 208 = cAwalols 212 AT} SMS were PCT/KR2018/007890 WO 20191045261 [=9] Bn) eo ee} ee) 2s wl izes ses zee ul size a i (Re aie] ie ey ik Be T sees wes wee ees Te Tee TET FE I 7 Tae ET TE A zarse Bares zenee zenes zaree ane zenes ive HN Be NOH ane tH ee 18H BR NOH ave $00 ane SH sis sets ozs | lees sais zs Liz a3] siz} WO 20191045261 PCT/KR2018/007890 or 10] 238 239 240 Sudal [ea 241 242 243 244 245 246 247 HS} cos} | tcl He HBr) HCN) | NH, 248 [2018.4.14 12:00:00] Monitoring is started [2018.4.15 12:30:04] H,S is detected 300 Sua PCT/KR2018/007890 WO 20191045261 " INTERNATIONAL SEARCH REPORT Tntemational application No PCT/KR2018/007890 ‘A. _ CLASSIFICATION OF SUBJECT MATTER GOBB 21/12(2006.01)i, GOSB 21/02(2006.01)i, GOBB 25/14(2006.01)i, BON 7/18(2006.0)i, HON $77(2006.01), GOT 7711 2017.01), BOLD 53/04(2000.01)8 According to Intemational Patent Classifiation (IPC) orto both national classification and IPC B.__ FIELDS SEARCHED ‘Mininnum documentation searched (classification system followed by clssifiation symbols) ‘GOSB 21/12; BOLD 53/92; BOID 53/06; BOLD 53/30; BOLD 53/86: BOLD 53/70; BOLD 53/77; GLI 3/46; GOLN 21/78; GOSB 21/00; 21092; HON 7/18; GO8B 21102: GORE 25/14; HOIN 5/77; GOST 7/11; BOID $3108 mv documnentation to the extent that such documents are included inthe felis searched ity modes: IPC as above spunese Uilcy modes acl applications for Ullsy made: IPC an abe leetonic data ase consulted during the intentional seach (name of database and, where practicable, search terms wed) eKOMPASS (KIPO intemal) & Keywords: adsomption, multistage, inclination, gs, camera, reation color, comparison, alata (©_DOCUMENTS CONSIDERED TO BE RELEVANT Category* | Citation of document, with indication, where appropriate, ofthe relevant passages Relevant to claim No, KR 10-2010-0123536 A (LPLUS ENG CO., LTD) 24 November 2010 19 See paragraphs {17499 lain Ts a figures 1.5 | KR 10-1358869 BI (SHINPYEONG INDUSTRY, INC. etal) 10 Febuary 2014 Ls See the entire document. | 5 2006312134 4 (NIPPON SODA CO.,LTD. etal) 16 Novernber 2006 19 See the eae document. Y | KR 10-0546367 BI (SAMSUNG ELECTRONICS CO., LTD. eta) 26 Fanuary 2005 1023 See paragraphs {14}452):and figure 3, Y | KR 10-1681630 B1 (OPTOLANE TECHNOLOGIES INC.) 01 Devember 2016 10.23 paragraphs {13}{31), (91}499]: lain fs an figue # Y | KR 10-0843961 81 (KD POWER CO. LTD. eta) 08 faly 2008 13479-2123 See paragraphs (25), (611465) [14] [121} claim 7: and figure 4 Further documents are listed in the continuation of Box C. * Spada eteptis of ced dbase “Petr dant publhed air he iratoal ling dato ploy “AY docu ding era sate oft at wc isnoccomidod "te aan cnfet ae aca Put cs undead soto parca wieance SBe ciple roo sng even uti: application or patent bt published onoraftertheitemationsl x document of particular relevance; the claimed javetion camo be fing te ‘Stdoed velar eamor be contre iqvole ansavendes cn wih may ha dois on iy an or whic Spe te dct an aoe xe psa thé pubjeaton das another etson theF 4 ogy of pair relevance; the chimed avetin eansot be ‘Special can (os ped) Y eiaderad ef tvawe sx tvchive nep wien te documca, “O” docamentrlewing to an ora dstosure, use, exhibition or tier Smned who orca soc docu suchencbiaton ‘teas fg cvio o's penn sled athe ot “P" dcazent published piri he incmntonal ing atc se an Se docrit mblched on 2 "" docunent menberof the sane pen fai Dale ofthe aetual completion ofthe international search 12 OCTOBER 2018 (12.10.2018) Date of mailing of the international search report 12 OCTOBER 2018 (12.10.2018) ‘Name and mailing address of the ISA/RR Facsimile NO. 2428888 “uthorizal officer Telephone No. Form PCT/ISA/2I0 (Second shee amuary 2015) INTERNATIONAL SEARCH REPORT Taternational application No. PCTVKR2018/007890 Box No. Observations where certain claims were found unscarchable (Continuation of item 2of first sheet) ‘This international search report has not beea established in respect of certain claims under Article 17(2)a) forthe following reasons 1 Claims Nos because they relate to subject matier not required 10 be searched by this Authority, namely 2 Claims Nos because they relate to parts of the international application that do not comply with the presribed requirements to such an extent that no meaningful international search can be caried ox, specifically: a Claims Nos Ipecause they are dependent claims and are uot drafted in aecordance with the second and third sentences of Rule 6.43 Box No. IHL Observations where unity of invention is lacking (Cor fnuation of item Sof Fist sheet) ‘This International Searching Authority found multiple inventions inthis international application, as follows ing pas. hod of the apparatus for removing polluting gs. ‘The invention of group 1: claims 1 to 8 pertain io an apparatus for removing pol ‘The invention of group 2: claims 10 to 23 pertain w a monitoring system and mn 1. BR) asatreinedsctiina sere fees were dey paid bythe ap chins ant, this international search report covers all searchable 2 Asal searchable claims could be searched without effort justifying addtional fees, this Authority did not invite payment of ‘dgitional fees, 2 As only some of the required additonal search fees were timely paid by the applicant, dhs international search report covers ‘only those claims for which fees were pai, specifically claims Nos. 4 No required additional search fees were timely paid by the applicant, Consequently, this international search report is restricted o the invention first mentioned inthe clais: itis eovered hy’ clas Nos Remark on Protest “The additonal serch fees were accompanied by the applicant’ protest and, where applicable, the payment ofa proest fee The adltonal search fees were accompanied bythe uppliaats protest bat the applica fee was nt paid within the ime Kimi specie nthe invitation, DX so protest accompanied the payment of additional search fs. le provest Fon PCTASA/210 (continuation of fist sheet (2)) January 2015) INTERNATIONAL SEARCH REPORT Infomation on patent family members ELAS PCT/KR2018/007890 Patent document Publication Patent family Publication cited in search report date member date KR 10-2010-0123586 A 24/11/2010 KR 10-1096596 61 20/12/2011 KR 10-1958869 81 so/02/2014 Nowe WP 2006-312134 & 16/14/2008 JP 4583234 82 17/11/2010 KR 10-0546967 81 26/01/2006 KR 10-2005-0020358 A 04/03/2005 US 2005-0147530 A1 07/07/2005 KR 10-1681630 61 01/12/2016 Nowe KR 10-Oeaa961 61 09/07/2008 KR 10-2008-0043433 A 19/05/2008 Form PCT/ISA/210 (patent family annex) amuary 2015) aaa ae SABA aA PCT/KR2018/007890 A Weel She SRHSATAL HIPC) GORB 21/12(2006.01)i, GOSB 21/02(2006.01)i, GO8B 25/14(2006.01)i, HOAN 7/18(2006,01), HOAN 5/77(2006.01 T11(2017.01)4, BOID 53/04(2006.01)i i, GooT Ba Bo Bd AERA SETS A GO8B 21/12; BOLD 53/02; BOLD 53/06; BOID 53/30; BOID 53/46; BOLD 53/70; BOID 53/77; GOL 3/46; GOIN 21/78; Go8B 21/00: HTL 21/02: HOWN 7/18: GORB 21/02: GORB 25/14; MOIN 5/77: GOST 7/11; BOID 53/04 DASE Fae awa IA Ta PRESALAHTD Y ERRAAB AEM: AL ALKA 71Agt LPC dussdedden 7 deedaedaew: aie AaLe el 74a IPC AZAD GR AT FMAM VAT AAAS BH) CKOWPISS(S 812 U3 BAAR & GEL HAE TL, WAL, he, heh, RA, what, ah © wee aan eed Bae PATE BH a ae are X__| AR 10-2010-0128536 A (HeLarReIoreLAFI) 2010.11.24 ra ee fi7-bohs AF nD eal 1 5 Be. A | AR 10-1958869 BL CADRAESICGE) > 2014.02.10 19 EA AA Ae. A | JP 2006-312134 A (IPPON SODA CO.,LTD. +) 2006.11.16 19 BA aa BS. y KR 10-0546857 BL CALLA} EA) BAF > 2006.01.26 10-23 Wet ful-[sah ee sa Y | ki 10-1681690 BL CE) gt) 2016.12.01 10-28 Be S31), (oi-[o): VFA a ee Be Y | ki 10-0844961 BL A181} ATES] $) 2008.07.00 13-17, 19-2128 Uh (25), (61-(65), (4a): AFB 7 Ra ae FETAL CSA 7A} RE. RM ese wees aaa pattatealatdt a "Ty BAgUU EL fan te Pad gees gua aga Adsl gle oe mele auad ares sae eel as Wade 72 SE De LSS olelapy! ahah IS © gd adsiway gual ae Pde aMRTM Eg ¢ pa PRO Iy Ee te ep ates areas a "Le gee tal ss doles eel me ds ape dla ote SEUa se dine we dad dguee CY Suede le Se 18 ee] dy clas de eed SERS SEE TECIES ODE MI TITTRE EE ON AS ape a ate alae ee ah aaa ae oO” FEA AE, 2 Rel eee deeded EO 2 auge He os ed, sp" pled lol BAsIsLOM BAS Ae clad Bal Ee a" BUG MES IEOA See Eel A ad OL SALA PSE 2018s! 1091 12% (22.10.2018) 20184 10% 12% (12.10.2018) ISARRY 22 FPN WRT fees Sola 0 (25208) AAA AR Bape 189, aw ( 4e ENE, AU) AWS 152424819575 alas. ss242481-3325 ATA PCTISA2I0 CF WA 87) QOS TB) Saeeue eae PCT/KR2018/007890 AZ) 4G AYAFYSR AAS VE BHI AAR WA #219] 29] AS) PCT AMI7HC2Kay] TAA MF} LI VL ols LH AHO elope) L Halse Ab A|y AALsla) ofa} L aee: Oo) APRE 7lalo] Zap a7} gles tol Belated, F, 2 Date: 1UFMe FRO TANS FUT T Me Ee kas Aas sae oaE sae Re Me TPA Se, SREP CTIA 64ayel FAS A Risk abel Gate ube} apsto} sla] ebsrul eh, Ase 232] VIA] BAe BHI TAR VA 8219139) AS) 22 RASA oF Po] eH weg) she Bye. ALE We APA LOE 291 a7] Arlo Be aituet ADE Wea: APA WE La a Ale) dal AZ Lv wa sll, LR) S8t BE PFE 1d Hol easlows, Yd tuateS BE a Hed FTE ORE ue. 2 LP ieee es ose) tae LE aA bet APNE AES ome, BOE EE SFO of aT 3, [Fete eee MMS 71 el halons, B alzupa ade Ppab BMS At 25 Teh palatal BPS ob sh eerele 4. [Batol 1 vol Frees Pes) ob abate, ubopA] & spakeAba seal APL ANS 7] A gol Haste] VO}, aE TPE Obes} ase ch aaa SAUL olay old ALBA V9) EM Fol eHT PSII an SUNY AA A PATER PEMA Y OA WALRAD BALD Prevod PE sha Di cea tol eee pest, AVA PCTASA,210 3 Bll 8121 ASF@y Goissl 2 Sane Spal & APB SLAY AES oo 1 Aa PCT/KR2018/007890 eae ae zat desoeel wAL KR 10-2010-0123536 4 2010/11/24 KR 101096596 BL 2011/12/20 KR 10-1358869 BL 2014/02/10 as JP 2006-312134 A 2006/11/16. JP 4583234 B2 2010/11/17 KR 10-0546367 BL 2006/01/26 KR 10-2005-0020358 A 2005/03/04 US 2005-0147530 Al 2005/07/07 KR 10-1681630 BL 2016/12/01 ae KR 10-0844961 BI 2008/07/09 KR 10-2008-0043433 A 2008/05/19 A148 PCTASANO (1-581 F7EB4)) QOS 1A)

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