PPE Reference Guide 05
PPE Reference Guide 05
2nd Edition
Nov , 2005
Contents General
Annexes
Rotary Kiln………………………………………………………………… 10
Grate Cooler………………………………………………………………. 15
Planetary Cooler…………………………………………………………. 21
Suspension Preheater………………………………………………….. 24
Precalciner………………………………………………………………… 25
Chlorine Limit…………………………………………………………….. 31
AFR…………………………………………………………………………. 36
Petcoke…………………………………………………………………….. 46
Combustion Engineering……………………………………………….. 49
Process Fans……………………………………………………………… 55
Environment……………………………………………………………….. 57
BDP(Best demonstrated practice): The highest historical production rate (t/d) achieved during the
last 24 months before the budget phase.
Gross OEE:
OEE gross [%] = Gross Availabil ity Index [%] * Production Rate Index [%]
Net OEE :
OEEnet [%] = Net Availabil ity Index [%] * Production Rate Index [%]
OEE = Overall Equipment Efficiency
Quality Index [%] = 1 (due to insignificant final product reject)
Above definitions are based on the HARP (Holcim Accounting and Reporting Principles) Manual
Release 6.0. For the most current definition check the HARP Manual on
Holspace.
Thermal Energy:
Rotary Kiln
Key Figures
Specific kiln volume load: < 2.2 t/d m3 SP kilns with ≥ 4 stages
< 5.5 t/d m3 Precalciner kilns
Calculation: Daily clinker production (t/d) divided by kiln volume inside refractory (m3)
Calculation: Total gas volume flow at kiln inlet (actual m3/s) divided by the kiln cross section
area inside refractory (m2)
Rotary Kiln
1.77 ⋅ L ⋅ Θ
t = ⋅F
ν ⋅ (D − 2 ⋅ Lining) ⋅ rpm
200
180
100
80
SP kilns
60
PC kilns
40
20
0
0 1 2 3 4 5
Kiln speed [rpm]
Rotary Kiln
Inclinatio n [%]
Inclinatio n [°] = arctan
100
Inclinatio n [%] = 100 ⋅ tan (Inclinatio n [°])
Kiln Inclination
Percent [%] 2.00 2.50 3.00 3.50 4.00
Degrees [°] 1.15 1.43 1.72 2.00 2.29
Pr oduction ⋅ t
FD = K⋅
Vki ln ⋅ 24
Rotary Kiln
PMotor = (
n ⋅ L ⋅ 0.0237 ⋅ (D − 2 ⋅ Lining)
3
+ 5.79 ⋅ 10 −5 ⋅ D ⋅ (25 ⋅ D + 750 ) )
D=6m
Kiln drive power to be installed [kW]
1500
D = 5.5 m
1250
1000
D=5m
750
D = 4.5 m
500
D=4m
250
0
1 1.5 2 2.5 3 3.5 4 4.5 5 5.5
Installed kiln speed [rpm]
Grate Cooler
Key Figures
Specific grate area load: < 45 t/d m2
Calculation: Daily clinker production (t/d) divided by total active grate surface area (m2).
Note: High grate area load increases the required specific aeration, especially after the
recuperation zone.
Specific grate width load: 1’000 - 1'500 t/d m
Calculation: Daily clinker production (t/d) divided by grate width (m)
Note: High grate width load results in high grate speed. Low values can result in clinker distribution
problems at cooler inlet.
Typical grate speed in strokes / minute for traditional reciprocating grate coolers
(higher speed means higher grate wear)
Installed specific cooling > 2.0 Nm3/kg cli For new coolers
air volume requirement: > 2.3 Nm3/kg cli For old type coolers
Calculation: Installed cooling air volume (Nm3/h) divided by hourly clinker production (kg/h)
Typical specific aeration: 1.3 – 1.8 m3/m2 s For fixed inlet section
(Operation), new coolers 0.8 – 1.4 m3/m2 s For recuperation area
0.4 – 1.0 m3/m2 s For aftercooling zone
Typical specific aeration: 1.5 – 3.0 m3/m2 s For inlet section
(Operation), old type coolers 0.8 – 1.4 m3/m2 s For recuperation area
0.4 – 1.0 m3/m2 s For aftercooling zone
Calculation: Actual cooling air flow (m3/s) per respective area of grate / compartment (m2).
Note: Low values are preferred with regard to heat exchange, but require a low specific cooler grate
area load.
Grate Cooler
Tertiary air take off velocity < 5 m/s For new installations
(cooler roof extraction): < 6 m/s For existing installations
Calculation: Tertiary air volume at actual temperature (m3/s) divided by the cross section
area of the tertiary air duct (m2) at take off.
Waste air take off velocity: < 5 m/s For new installations
< 6 m/s For existing installations
Calculation: Waste air volume at actual temperature (m3/s) divided by the cross section
area of the waste air duct (m2) at take off.
100%
90%
80%
Cooler Efficiency [%]
70%
60%
50%
40%
0%
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4
Recuperation
Recuperation airAir [Nm3/kg
[Nm3/kg cli] cli]
Grate Cooler
Clinker Cooler Recuperation Efficiency
qDust Out : Specific Heat Clinker Dust at Secondary Air Temperatur e [kJ/kg clinker ]
qDust Out : Specific Heat Clinker Dust at Temperatur e of Clinker from the
Kiln (1450 °C) [kJ/kg clinker ]
qClinker Hot : Specific Heat Hot Clinker from the Kiln (1 kg) [kJ/kg clinker ]
0.744
0.8 ≅ ⋅
v v
1− EXP− * 1+
0.77 2.57
Grate Cooler
Grate Cooler Air Distribution
1) Old Cooler without Fixed Inlet
The recommended air profile shows a descending pattern from the cooler
inlet towards the cooler outlet
3 100
typical ranges of specific air load
90
Specific Air Load
2.5
Undergrate Pressure 80
Specific Air Load [m3/m2,s]
70
2
Pressure [mbar]
60
40
Aftercooling Zone
1
30
20
0.5
10
0 0
Comp 1 Comp 2 Comp 3 comp 4 Comp 5 Comp 6
70
2
Pressure [mbar]
60
40
Aftercooling Zone
1
30
20
0.5
10
0 0
Fixed Inlet Comp 1 Comp 2 Comp 3 Comp 4 Comp 5
Grate Cooler
TCli,out − TAmb V
= exp − Air
TCli,in − TAmb 0.77
275
250
225 Ol
Gr d T
200 at yp
eC e(
M o o Lo w
175 od ler
er s Pre
n ss
150 Gr ur
at e
e Fa
125 Co n)
ol
er
100 s
75
50
1.4 1.6 1.8 2 2.2 2.4 2.6
Specific Cooling Air [Nm3/kg Clinker]
Grate Cooler
Typical example of a grate cooler heat balance (modern cooler):
Cooling Air
1
Production ⋅
Cooler Width ⋅ Bed Height
Transport =
1 1
ρCli ⋅ 24 ⋅ 3600 ⋅ Number of Strokes ⋅ ⋅ Stroke Length ⋅
60 1000
Planetary Cooler
Link: https://web.holcim.com/copplcool/
Calculation: Daily clinker production (t/d) divided by total surface area of all cooler tubes (m2)
Note: Use nominal tube length and diameter
Calculation: Daily clinker production (t/d) divided by total cross section area of all cooler tubes (m2)
Note: Use nominal tube diameter
Calculation: Daily clinker production (t/d) divided by total volume of all cooler tubes (m2)
Note: Use nominal tube length and diameter
Planetary Cooler
Suspension Preheater
475
520 3.1%
3.1 - 43
Stage 2
625
660 2.6%
2.6 - 36
Stage 3 Meal
750
780 2.3%
2.3 - 29
Stage 4
860
880 2.0%
2.0 - 22
Stage 5
TGas O2 Press
SP4 [°C] [%] [mbar]
350 3.4%
3.4 - 45
Stage 1
545
550 3.0%
3.0 - 31
Stage 2
690
710 2.6%
2.6 - 23
Stage 3
800
840 2.4%
2.4 - 16
Stage 4
Suspension Preheater
Kiln inlet chamber gas velocity: < 25 m/s existing installations
< 21 m/s new installations
Calculation: Kiln gas at inlet conditions (m3/s) divided by cross section area at the narrowest
location of the kiln inlet chamber at the inclined inlet chute (m2)
Gas velocities in riser ducts and 10 - 15 m/s
cyclone dip tubes:
Calculation: Kiln gas at operating conditions (m3/s) divided by inner cross section area of
riser duct or dip tube (m2). Note: 10 m/s allowed only in case of perfectly working splash boxes
Calculation: Dust loss weigh out relative to the material feed to the top stage.
Precalciner
Gas residence time >3s Oil, lignite
in precalciner (inline): > 3.5 s Gas, bituminous coal
> 4.5 s Petcoke, anthracite
>5s Minimum requirement for new
installations (increased AFR
use)
Applicable for inline calciners. For offline calciners: 0.5 - 1 s less residence time required.
Calculation: Volume of precalciner inside lining until inlet of bottom stage cyclone (m3) divided
by gas volume flow through precalciner (m3/s) at the calciner exit temperature and pressure.
The gas volume at the calciner exit (including all the CO2 released in the calciner) is used.
This leads to a smaller retention time number (conservative calculation).
Note: At normal fuel split calciner / kiln. Sufficient gas velocity to prevent falling through of meal
and solid fuels (e.g. AFR) to kiln inlet.
Precalciner
Because of always present dust cycles between kiln / kiln inlet / kiln riser / bottom
cyclone, the hot meal sample contains a certain amount of dust which was already
in the kiln calcining zone and is higher or even fully calcined.
This means: The higher the dust concentration near the kiln inlet resp. the dust
cycle, the higher the apparent calcination degree.
90
80
Apparent alc. Degree [%]
70
60
1.0
50
40 0.5
30
0.2
20
10 0.0
0
0 20 40 60 80 100
True Calc. Degree [%]
Reference Guide for Process Performance Engineers 26
© 2005 Holcim/Switzerland
Version Nov. 2005
§ Resulting primary air percentage (result of above figures; main criteria impulsion):
with fan 12 – 18 %* existing burners
13 – 15 %* design for new burners
with blower 8 – 14 %* existing burners
9 – 14 %* design for new burners
* percentage of minimum combustion air
§ Burner Position: Position burner tip between +1.5m inwards and –1.0m outwards
of rotary kiln; depends on kiln-L/D and temperature profile;
Note: Planetary coolers need longer internal cooling zone.
Retracting the burner may damage / block the inlet openings.
Usually burner position planetary coolers: >2m inside.
§ Timeframe:
Wait at least 3 days after each change for stabilization of coating in kiln
§ Axial Air: Effect: Ensures mixing of fuel with secondary air. More Axial air/ Higher
Pressure will improve mixing à shorter flame
Guideline: Start optimization with channel at position 0, then open first this
channel
• Radial Air: Effect: More radial air will widen and shorten the flame. Too wide flame with
different fuels (high and low reactive) will create 2 flames and
elongate total flame length also a bad effect on refractory can be
observed.
• Central Air: Effect: Stabilization of flame, cooling of central channel and avoiding of
build up formation on burner tip
• Fuel injection velocities:
Effect: Defines ignition distance of fuel; black plume of 30 – 40 cm is
desirable to avoid damage of the burner tip
Guideline: see separate table for injection velocities
• Fuel Fineness:
Effect: Ensure burnout of solid fuel before the clinker bed; definition of
ignition distance
Guideline: see separate table with fineness guidelines
Note: ‘Design Thermal Power’ for new burner = BDP * Real Heat Consumption *
Real Burning Zone Fuel Ratio + approx. 10% Reserve
Thermal Power from Fuels (alternative calculation):
n
∑ (M
Fuel = 1
Fuel ⋅ NCVFuel )
Pthermal =
3600
Pthermal = Thermal burner power [MW]
Mfuel = Fuel mass flow [t/h or Nm3/h], for the fuels 1 to n
NCVFuel = Net calorific value of the fuel [kJ/kg fuel or kJ/Nm3 fuel] for fuels 1 to n
Specific Burner Impulsion:
∑ (m ⋅ v )i i
G = i
Pthermal
G = Specific impulsion [N/MW]
mi = Mass flow of air flow i [kg/s]
vi = Velocity of air flow i [m/s] calculated with Bernoulli equation (see below)
Pthermal = Thermal burner power [MW]
Chlorine Limit
Kiln Cl extraction method Maximum Remarks
system relevant
Cl input
[g Cl/ t cli]
Any kiln without Cl-extraction 300
system (“closed loop”)
4/5 stage discarding filter dust 300- 400 dep. on available
SP during direct operation time for direct op.
2 stage SP same as above 450 same as above
LEPOL discarding intermediate 600
grate dust
SP 5-10 % Bypass ~ 100 *% applicable for
Bypass 5-10% bypass
Long discarding max. kiln 5000 unusual, needs
wet/dry dust (unlimited CKD) extra CKD outlet
Kiln system Short term [hours] Long term Impact on HCl emission
consequences consequences
Suspension preheater blockages corrosion, none
preheater / à production loss refractory (without bypass)
precalciner damage
Grate high pressure drop in corrosion medium
preheater nodule bed à prod. loss
External cycle
Internal cycle
Kiln feed as fed!
(Raw meal and
direct
dust !) 1
Alte rnative fue ls Coal Oil
operation
compound
operation
Homogenizing
Silo
direct
Fuels 3 operation
Bypass dust or 5
intermediate grate dust (LEPOL)
removed from system
Clinker Balance Boundary
Advantage: - reflects instant situation of kiln system
- low cost, material samples and analysis are part of the daily routine
- chlorine concentrations in dust flows well above detection level
Disadvantage: - external dust cycle needs to be quantified
- dust flow and composition only known during direct operation
- SO3 and Cl emissions at preheater exit (top stage) not directly measured
Excel tool available on CoP AFR Application on kiln à Library à Tools
Ex ternal cycle
B Internal cycle
compound
operation
Raw
Homogenizing
S ilo
Materials
Dust direct
operation
(pure;
discarded before mill !)
(e.g. added
to cement)
Alternative balance boundary for a chlorine and sulfur balance, bulk materials would have to be sampled and analyzed.
Advantage: - Raw material properties are not influenced by kiln dust
- Calculation of relevant input is simple
Disadvantage: - Representative sampling and sample preparation of the raw materials
(before the mill à un-ground) is difficult
- Internal storage effects (large silos) are not considered . The actual kiln input is
not always the average input (e.g.: Cl, Tl)
2. “Calculated Cl in clinker:
No kiln can sustain an output >300g/tcli on a constant basis.
Calculation: "Calculated" Cl in clinker = Total inputs - Dust reused – Emission
- Dust removed - bypass dust
Limits: see “Cl Limits”
Limits: Conservative approach and limits for ideal condition (“challenging limits”): see
“Petcoke Rules”
5. Sulfur Volatility:
The volatility expresses the amount of sulfur circulation vs. sulfur in clinker.
Calculation: SO Cli
3
(100 − LOICli )
Volatility ϕ = 1 −
SO 3 HM
(100 − LOIHM )
SO 3 Cli
Simplified formula for LOI~ <2%: Volatility ϕ = 1 −
SO 3 HM
6. Hot Meal:
Applicable to SP and PC kilns only.
2.0 Fre
Limits: according to graph que
nt blo
Zon cka
e ges
1.4 of in
cre
asin
ge ncr
1.0 usta
ti on
0.8 pro
blem
No e s
ncru
statio
ns
% SO3
0 1.0 2.0 3.0 4.0 5.0
2.5 3.75
a) Determination by weighing:
Weighing of the dust from the kiln filter during direct operation (raw mill stopped).
Before starting the weighing, the mill should be stopped at least for 1 hour. Weighing
time should be at least 2 hours.
b) Determination by estimation:
The normal range of separation efficiency of the top cyclones is 90 - 93 % (based on
feed).
Example:
At 100 t/h of kiln feed and a top cyclone efficiency of 93%, the "Total amount of
dust" leaving the preheater is 7 t/h.
The "Dust returned via kiln feed" = 7 t/h - 2.1 t/h = 4.9 t/h
AFR
AFR Gateway:
Pi Pyramid)
“Pi the group wide tool for
effective AFR-BD implementation”
Link:
https://web.holcim.com/AFR/AFR
Pyramid.nsf
Examples:
- Waste profile database
- AFR Quality control manual
- AFR Policy
© 2005 Holcim/Switzerland
Reference Guide for Process Performance Engineers
These maximum substitution rates reflect the maximum combustion limit for a certain AFR type.
Other limitations such as the maximum Cl-input have to be considered separately.
37
Version Nov. 2005
Version Nov. 2005
AFR
Impact on heat
consumption Impact on kiln capacity (tons lost)
Influence SP/PC
Unit All kilns Unit Grate PH Long wet
factor kiln
t cli
Water GJ/t H2O 2.15* 2.0 1.6 0.8
/t H2O
t cli
Ash GJ/t ash 1.1 0.26 0.22 0.11
/t ash
Additiona
l transp. t cli
GJ/kNm3 1 (0.7)** 0.24 0.2 0.07
air (false /kNm3
air)
Oxygen % q per % cap
1.8 5.7*** 5*** 4.4***
level % O2 per %O2
Note: For proper application of above factors consult definitions/explanations in the LGF study
SP: Suspension Preheater, PC: Precalciner Kiln
* When H2O included in NCV calculation of fuel, when injecting pure water 4.6 GJ/tH2O
** 0.7 GJ/kNm3 applies for Wet kilns only
*** Oxygen increase after last addition of fuel, for more details see LGF study
AFR
Homogeneity of AFR
The required homogeneity of each AFR stream to the kiln depends on the
following factors:
NCV
1. Fluctuation of the calorific value in the AFR - short term [minutes]
2. Fluctuation of the mass flow of the AFR into the kiln,
given by the quality of the AFR dosing system - short term [minutes] Feedrate
3. Substitution rate
The combined influence of the first two factors produces the fluctuation of the
heat input into the kiln by the AFR.
The fluctuation of the total heat input into the kiln has to be kept below a certain
level to avoid negative impacts on production capacity.
Note: This formula does not apply for whole tires and other slow burning lump fuels
Impacts
à Requires +1% O2 to compensate fluctuation (to avoid CO) resulting in:
à Impact on heat consumption = +1.8% fuel consumption
à Impact on kiln production = -6% kiln capacity (dry SP-kiln)
AFR
Heavy Metals
Water Supply PS
PI
Drainage
N2
Foam
Gas Pendulum DN 50
O2
M M
O2
L
L
LAH
LA H
TAH TAH
IR IR
Breathing
Hole
TAH TAH
TAH TAH
Unloading
Standard Solution for Liquid AFR
Filter
Unloading
Feeding Feeding
PI
PI
Pump
DN 100 Filter Pump
FS
PI
© 2005 Holcim/Switzerland
DN 50
PI
PI
PI
FS
DN 50
PSA
Flow
P
PI
IR IR Meter
FS
P SA
1,5%
41
Version Nov. 2005
Version Nov. 2005
AFR
Liquid AFR Installation
Filter screen selection: The smallest filter screen depends on the smallest cross
section in the liquid system (generally injection nozzle)
Pump selection:
Safety – Liquids
For liquids with flash point < 55°C, special safety
installations are required
Further details can be found in the TAM (Technical AFR Manual for liquids)
available on HolSpace: CoP AFR Application on Kiln
AFR
Standard Solution for Solid AFR
Main burner firing
storage hall
bridge crane
mechanical transport to
burner platform
extraction:
- rotating screw VFD
safety
discharge
weigh feeder
double or
triple flap
with safety
shut-off gate
weigh
feed hopper feeder
with activated
bottom
AFR
Extraction system for solids
Planetary screw extraction for flat bottom Push floor hopper with extraction screw,
silos, particle size suitable for main firing particle size < 50 mm
< 300m3
Feed Hopper
with Moving Floor
Apron conveyor with counter rotating “Samson” feeder with counter rotating
stripping roll, particle size < 200 mm stripping roll, particle size < 200 mm
AFR
Rotary valve selection guideline
-Grounding
-Speed mechanical equipment < 1m/s (mechanical sparks)
-Bearings outside of the material (e.g. screw conveyor)
-Automatic safety shut off gate for flap valve, wattless closed
-Fire detector and sprinkler system
Raw coal blending Uniform blending with raw coal (if petcoke < 100%)
Clinker quality More SO3 in clinker (better early strength development, reduced gypsum addition)
Alkali / sulfur For a first "conservative" approach, go for following total inputs (1)
SO3 inputs < 1.5 % (clinker basis)
Molar A/S > 0.8
The following limits for the minimum Alk/SO3 ratio and maximum sulfur input per kiln type have
been defined based on best practices within Holcim according to the ATR 2004 data:
Kiln System Min. Alk/SO3- Max. Sulfur
ratio [-] input [%SO3
in cli]
Petcoke supply Choose quality that fits into the given restrictions for sulfur input and grinding
capacity. Choosing a good quality (<5% S and >55HGI) is not necessarily the
optimum cost option (2)
Raw coal / petcoke preparation Controlled mixing from two feed hoppers
Burnability Good burnability helps (if there is a low cost possibility to improve it) (4)
Assessment methods:
- Holcim Burnability Model (by HGRS / MS / MT)
- Combinability Temperature CT (simple tool):
CT = 436+21*(acid I R90u)+10*LS+3*R150u+32*AR -250*F -20*SO4
- acid I R90u = +90u Acid insoluble residue in raw meal
- LS = Clinker LSF (without SO3 correction)
- R150u = in raw meal
- AR = clinker alumina ratio
- F, SO3 = in clinker
Guidevalue: For 100% high sulfur petcoke firing CT < 1450°C (max. 1500°C)
Kiln Burner & flame Use high momentum burner (new burner 10-11N/MW; existing burner 9-11N/MW) for
compact and short flame. For a given burner/PA-fan (with limited operating range):
Adjust burner for most compact and shortest flame (i.e. max prim. air quantity and
pressure, max. radial air, retract burner). In particular :
Retracting burner tip on grate cooler kilns can have a strong positive impact (5)
Burner orientation : in kiln axis
Petcoke injection velocity 20 -25 m/s
Cooler Stable and high secondary air temperature for stable ignition (cooler optimisation)
Clinker granulometry As a consequence of more SO3, clinker tends to be finer (impact on grate cooler)
If necessary adjust clinker SR/AR to alleviate effects of fine clinker
Ret. time Gas retention time preferably > 3.5 sec (if not available: higher petcoke fineness)
Burn out After precalc.: O2 = 2..3 %, CO < 0.1 % (after PH 1% higher O2 due to FA)
Check hot meal for combustibles (sparkling)
Dust curtain Dust curtain kiln inlet: <20-30% meal from 2nd lowest stage to kiln inlet (splash box!)
If no precalciner : Dust curtain in riser duct by lowering meal entry points
Hot meal analysis Adequate frequency, usually once per shift (LOI, SO3, K2O)
SO3 < 5 % (if chlorine < 0.5%)
Bypass An existing bypass alleviates the sulfur cycles, but installation of a new bypass
can hardly be justified by petcoke. Fight SO3 cycles by enhanced prehater cleaning.
Prehater cleaning Add poking possibilities and air cannons (can be up to 60) where coatings occur.
Removing of heavy blockages can also be done with CARDOX blasting on demand.
Special attention to calciner orifice (restriction), if restricted by coating the problem
will be self-accelerating rapidly due to lack of O2.
How to proceed? Stepwise increments of petcoke use, based on process and quality data
Depending on results further stretch the preliminary limits for S03 input and A/S ratio.
Know your process !
Notes
(1) "Conservative" is relative, it depends : On SP/precalciner kiln SO3 inputs of up to 2.5% and A/S down to 0.4 have
also been achieved by a more aggressive approach. However certain factors act against high sulfur incorporation :
lump fuel (AFR) which reaches the material bed, long kilns or grate preheater kilns.
(2) Burning high grade petcoke ( <5%S, HG>55) as recommended in the past would be easier but the market for
such qualities will stagnate (higher prices) in future. A more aggressive approach towards petcoke 6/7% S and 40
HGI is needed for higher cost savings.
(3) General target for LSF STD of opt. kilns. However if not achieved some plants can still incorporate much sulphur
(Example ML: STD=4.4 BUT 1.34 % SO3 in cli !)
(4) Mineralizers (F) would help to incorporate SO3. However mineralizers were so far applied at simultaneous LSF
increase to improve clinker quality. Experience at constant LSF is rare. (FLS Mineralisation, tests SG)
(5) Example CH : retracted burner -1.1 m outside kiln which made an increase of SO3 in clinker from 0.6% to 1.3%
SO3 possible. Disadvantage of retracting burner: hot kiln outlet, snowman in cooler
Link: https://web.holcim.com/petcoke/
Combustion Engineering
When doing calculations on cement kilns it is usual to work with specific
quantities referred to 1 kg of clinker. Therefore the fuel consumption is
expressed as q in MJ/kg cli and the kiln gas volume is expressed as
VKiln gas in Nm3/kg cli.
The cement kiln exhaust gas results from the following sources:
For wet and semi-dry kiln systems (wet feed slurry, granules or cake):
Combustion Engineering
Excess air
%O2,dry
Excess air = GasCombustion & Raw meal ⋅
21% − %O2,dry
Nm3
Units in formula above :
kg cli
Using the above data the stoichiometric kiln exhaust gas volume
VStoichiometric kiln gas can be calculated for kilns with dry kiln feed:
VN ,dry
VN, wet =
(100 - W% )
Therefore the kiln exhaust gas volume VKiln gas, wet with excess air at
the actual measured O2 concentration (for kilns with dry kiln feed
only):
%O 2, dry
VKilngas, wet = (0.28 + 0.28 ⋅ q) + (0.27 + 0.25 ⋅ q) ⋅
21% − %O 2, dry
Nm 3 MJ
Units in formulas above : V in , q in
kg cli kg cli
The formula above for VKiln gas,wet also is used to calculate the amount of false air
in the kiln exhaust gas system by measuring oxygen concentrations at different
locations in the exhaust gas system.
Combustion Engineering
Further to calculate VKiln inlet gas, wet the heat input from secondary or calciner firing
(%PC) has to be subtracted, as the off-gas released from this fuel portion does not
pass the kiln inlet:
%decarb %PC
VKi ln inlet gas,wet = 0.27 ⋅ 1 − +
0.28 ⋅ q ⋅ 1 − +
100 100
%decarb %PC % O2,dry
+ 0.27 ⋅ 1 − + 0.25 ⋅ q ⋅ 1 − ⋅
100 100 21 % − % O
2 ,dry
Nm 3 MJ
Units in formula above : VKi ln inlet gas ,wet in
, q in
kg cli kg cli
Secondary Air and Air to Kiln
The total air volume VAir to kiln added to the kiln (primary, secondary, transport and
false air) is calculated from the minimum air for combustion Amin (0.26 Nm3/MJ)
and the O2 concentration in the kiln inlet (measured inside the kiln, without false
air from kiln inlet seal).
Combustion Engineering
%PC
VAir to ki ln = 0.26 ⋅ q ⋅ 1 − +
100
%decarb %PC %O2,ddry
+ 0.27 ⋅ 1 − + 0.25 ⋅ q ⋅ 1 − ⋅
100 100 21 % − %O
2 ,dry
Nm 3 MJ
Units in formula above : VAir to ki ln in
, q in
kg cli kg cli
For the calculation of the secondary air volume, the primary, transport and false
air need to be subtracted from the total air volume added to the kiln (see above).
VSecondary Air = VAir to kiln − VPrimary Ai r − VTransport Air − VFalse Air
Nm 3
Units in formula above: VSecondary Air in
kg cli
Tertiary Air
v Tertiary Air = v Combustion Calciner + vExcess After Calciner − vExcess Air Kiln −
Nm3
Units in formula above: VTertiary Air in
kg cli
%PCfuel
v CombustionCaliciner =
0.26 ⋅ q ⋅
100
%O2,PC,dry
vExcess After Calciner = {0.27 + 0.25 ⋅ q} ⋅
21% − %O2,PC,dry
%decarb %PCfuel %O2,dry,KI
vExcess Air Kiln = 0.27 ⋅ 1 − + 0.25 ⋅ q ⋅ 1 − ⋅
100 100 21% − %O
2,dry,KI
3
vFalse Air Kiln Inlet : approx. between 0.02 - 0.05 Nm /kg clinker (estimation)
Density of Air
273 °C p x (mbar)
act = norm ⋅
⋅
T ( °C) + 273 °C 1'013 mbar
Barometric Pressure
The average barometric pressure p at a plant altitude (above sea level) can be
calculated using the following approximation formula.
5.25
Altitude (m)
p = 1'013 ⋅ 1 −
44 '300
VLeakage, N = 0.90 ⋅ A ⋅ p
VLeakage,N = Leakage air [Nm3/s dry]
A = Open area of aperture [m2]
ρAir,N = Air density at normal conditions (=1.29 kg/Nm3)
ρAir = Air density at aperture ≈ Air density at ambient condition [kg/m3]
∆p = Pressure difference over aperture [Pa]
Air inleakage
5000
400 cm2 200 cm2
4500
4000
Air inleakage [Nm3/h]
0
0 10 20 30 40 50 60 70 80
Pressure difference [mbar]
Process Fans
V ⋅ ∆p ⋅ 10 −3
P =
η
0,6 ⋅ γ ⋅ n 2 ⋅ d2 ⋅ π 2
P =
3600
Process Fans
n2
V2 = ⋅ V1
n1
V1, V2 = Quantity of gas at speed 1 and speed 2 (m3/s)
n1, n2 = Fan speed 1 and fan speed 2 (rpm)
2
n2
p st ,2 = ⋅ p st ,1
n1
pst,1, pst,2 = Static pressure at speed 1 and speed 2 (mbar)
n1, n2 = Fan speed 1 and fan speed 2 (rpm)
3
n2
P2 = ⋅ P1
n1
Environment
336 .48
TDP = − 179
5.3362 − 17 .045 + ln %W ⋅ p
100 1000
1000
TAcid = − 273
1.7842 + 0.0269 ⋅ L W − 0.1029 ⋅ L S + 0.0329 ⋅ L W ⋅ L S
Environment
The required amount of cooling water for gas cooling can be estimated as
(Rule of thumb):
MW = 0.6 ⋅ VN,wet ⋅ ∆T
If the temperature at inlet and outlet of the process is known the air inleakage
can be calculated with a heat balance (dust in process gas is neglected).
For air leakage estimation a cp ratio (process gas/air) of 1.1 can be used and the
temperature of the inleakage air can be approximated with the ambient
temperature resulting in:
Environment
Inleakage air can be calculated with an oxygen balance over the filter.
(VGas,in,dry,N ⋅ O 2,in ) ( ) ( )
+ VLeakage ,N ⋅ 21 = VGas,in,dry,N + VLeakage ,N ⋅ O 2,out
Environment
wet à dry
−1 c(dry): dry concentration mg/Nm3
w
c(dry ) = c( wet )×1 − c(wet): wet concentration mg/Nm3
100 w: water content of gas Vol%
21−10
C10 = Cx × C10: concentration mg/Nm3 @ 10% Oxygen
21− x Cx: concentration mg/Nm3 @ X% Oxygen
ppm à mg/Nm3
kg
MW
kmol
MW: molecular weight
mg
c 3 = f • c [ppm] with f= (see periodic table)
Nm Nm3 Nà Norm conditions:
22.41 0°C, 1013 mbar
kmol
H He
1.01
1
Periodic Table 4.00
2
Li
6.94
Be
9.01
of Elements B C N O F Ne
10.82 12.01 14.01 16.00 19.00 20.18
3 4 5 6 7 8 9 10
Na Mg Al Si P S Cl A
22.99 24.32 26.98 28.09 30.98 32.07 35.46 39.94
11 12 13 14 15 16 17 18
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.90 50.95 52.01 54.94 55.85 58.94 58.71 63.54 65.38 69.72 72.60 74.91 78.96 79.92 83.80
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.48 87.63 88.92 91.22 92.91 95.95 99.00 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.6 175.0 178.5 181.0 183.9 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 210.0 (210) (222)
55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Fr Ra Lw Rf Db Sg Bh Hs Mt Ds Rg
(223) 226.1 (260) (261) (262) (263) (262) (265) (266) (269) (272)
87 88 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
138.9 140.1 140.9 144.3 145.0 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.4
57 58 59 60 61 62 63 64 65 66 67 68 69 70
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
227.0 232.1 231.0 238.1 237.0 242.0 243.0 245.0 249.0 249.0 255.0 255.0 256.0 253.0
89 90 91 92 93 94 95 96 97 98 99 100 101 102
For further explanations and emission plausibility checks see EMR Manual
and Guidelines, Edition 2005.
Conversion:
Measured Compound
compound in c in ppm x f expressed in
ppm = c in mg/Nm3 wet*
mg/Nm3
Conversion:
? **
c ( dry ) = c ( wet )×1 −
w
100
−1
c Concentration
w Water content of gas (Vol %)
* Wet according to measurement principle (in situ, hot extractive, etc)
** If measured on dry bases
Examples Factor f
for normal conditions of
0oC and 1013mbar
1. Air-to-cloth ratio
Vact
A /C =
A bags,net
A/C < 1.0 m/min no problems expected i.e. design criteria for
new process filters in normal operation
2. Differential Pressure
ψ
v
∆p ≈ ∆p0 ⋅ F
v
F,0
Sensible Heat cp
The following specific heats are average values between the temperature T and the
reference temperature of 20°C. So the calculation of the sensible heat difference
between two temperatures is as follows:
( )
H(200 °C - 100 °C) = m ⋅ c p, avg (at 200 °C) ⋅ (200 °C − 20 °C ) − c p, avg (at 100 °C) ⋅ (100 °C − 20 °C )
1.30
°C]K]
MgO
[kJ/kg
Kaolin
1.20
[kJ/kg
SiO2
CaCO 3
Raw Meal
value
1.10
value
Metakaolin Clinker
cpcp
1.00
RM
CaO
0.90
0.80
0.70
0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500
Temperature [°C]
2.4
Ref. 20°C
2.3
2.2
SO
2
2.1
CO
2
2.0
kJ / kG °C
vap.
1.9 H 2O
[kJ/Nm3
t kiln
r cemen
1.8 Range fo ses at ~ 3%
ga
exhaust
°C]
1.7
λ= 1
1.6 b u sti on gas at
Com ) O2
example
(typical
Air (≅ CO
1.5 )
1.4
N2
1.3
1.2
100 300 500 700 900 1100 1300 1500 1700 1900
Temperature [°C]
2.5
g/l g/l
0.8k 0.9k
OIL
2.3
g/l
1.0k
2.1
°C
1.9
kJ / kG°C]
[kJ/kg
1.7
latiles
COAL
1.5
40% Vo 30%
1.3
20%
10%
1.1 0%
0.9
0.7
0 50 100 150 200
Temperature [°C]
Reference Guide for Process Performance Engineers 65
© 2005 Holcim/Switzerland
Version Nov. 2005
Cyclone Preheater
Effect of Number of Stages
Control Parameter units 4 è 5 stages 5 è 6 stages
Heat consumption kJ/kg cli -80 -50
Exhaust gas temp °C -40 -20
Exhaus gas flow Nm3/kg cli -0.03 -0.015
SP exit pressure mbar + 5 to 8 + 5 to 8
Drying capacity in raw mill % H2O -1.5 -1.0
60
Increase heat consumption [kJ/kg Cli]
50
stage 1, base: 93.5 %
40 stage 2, base: 83 %
stage 3, base: 77 %
30 stage 4, base: 72 %
20
10
0
-25 -20 -15 -10 -5 0 5 10
-10
-20
Change of separation efficiency of respectiv e stage [% sep. eff.]
Cyclone Preheater
Effect of false air on preheater outlet temperature
Location of leak
12
10
PC5
Temp. difference at preheater outlet [°C]
8 stage 4
6
stage 5
4
2 stage 3
0
-2 0 1 2 3 4 5 6
-4
-6 stage 2
-8
-10 stage 1
-12
Additional false air to respectiv e stage [% false air]
Location of
15 leak stage 4
Temp. difference at preheater outlet [°C]
10
SP4
5 stage 3
0
0 1 2 3 4 5 6 7
-5
stage 2
-10
stage 1
-15
Additional false air to respective stage [% false air]
Cyclone Preheater
70
60 PC5 stage 5
50 stage 4
40
stage 3
30
20 stage 2
10 stage 1
0
0 1 2 3 4 5 6
Additional false air to respective stage [% false air]
90
leak
80 SP4 stage 4
70
60
50 stage 3
40
30 stage 2
20
stage 1
10
0
0 1 2 3 4 5 6 7
Additional false air to respective stage [% false air]
Cyclone Preheater
Effect of false air in SP on clinker production
Effect of false air in SP on production
5.0%
0.0%
-5.0%
PC5 PC St 5
D Production [%]
Stage 1
-10.0%
Stage 2
-15.0%
Stage 3
-20.0%
-25.0%
Stage 4
-30.0%
-35.0%
-4 -2 0 2 4 6 8 10
D False air [% FA]
10.0%
5.0%
0.0%
-5.0%
D Production [%]
-10.0%
-15.0%
SP4 Stage 1
Stage 2
-20.0%
Stage 3
-25.0%
-30.0%
Stage 4
-35.0%
-40.0%
-4 -2 0 2 4 6 8 10
D False air [% FA]
Precalciner
Effect of Excess Air after PC
200
D Heat consumption [kJ/kg}
D SP exit temperature [°C]
150
100
50
0
-2 0 2 4 6
-50
% O2 from 2%
30
100
25
80
20
60
15
40
10
20
5
0 0
1050 1070 1090 1110 1130 1150 0 1 2 3 4 5 6
Lite rw eight [g/l] Increa se of sta tistical a ve ra ge gra in size [mm]
900
Grate Cooler
74
Recuperation efficiency [%]
72
70
68
66
64
Practical
range
62
60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Bed height [m]
3250
System heat consumption [kJ/kg cli]
3200
3150
3100
3050
3000
2950
62 64 66 68 70 72 74 76
Cooler [%]
Grate Cooler
Tertiary Air (TA) Extraction from Kiln Hood vs. Cooler Roof
(typical example, modern cooler)
Secondary air
temperature (TA cooler
roof extraction)
Secondary air and TA
temperature (TA kiln hood
extraction)
TA temperature
(cooler roof
extraction)
0 0.5
1
Note: As for precalciner kilns with tertiary air suitable for burning of petcoke
and AFR both high secondary air and tertiary air temperature are important,
the TA extraction is preferred from the kiln hood for new projects.
Clinker Granulometry
Common Pitfall:
Sampling is critical - no sampling from the top of the conveyor (sample not
representative because of segregation).
Good sampling points: Transfer points or chutes.
90 dust only
80
fine, dusty
70
40
very coarse, no dust
30
20
10
0
0.01 0.10 1.00 10.00 100.00
Grain s ize [m m ]
“Material Technology”
Clinker Minerals…………………………………………………….. 87
Uniformity……………………………………………………………. 91
Physics……………………………………………………………….. 93
Statistics……………………………………………………………… 94
CaO*100
LS =
2.8*SiO2+ 1.18*Al2O3+ 0.65*Fe2O3
SiO2
SR =
Al2O3+ Fe2O3
Al2O3
AR =
Fe2O3
K2O Na 2O CI
+ −
Alkali / sulfur = 94 62 70
Usual 0.80 - 1.20
SO3
80
Degree of precalcination
P2 (100 - P1)
% precalcination = 1 - • 100
P1 (100 - P2)
1.40
Alkalis Excess
1.20
1.00
% Na2O eq.
0.80
0.60
0.40
0.20
Sulfur Excess
0.00
0.00 0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60
% SO3
Red line represents molar Alkalis / Sulfur ratio = 1
Average
ATR2002
LS 94 - 98 95.9
SR 2.35 - 2.75 2.55
AR 1.4 - 1.8 1.65
5 Moderate
3 Good
1 Very Good
33.0
31.0
Liquid Phase 1400 °C
29.0
27.0
25.0
23.0
21.0
19.0
17.0
15.0
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00
Silica Ratio
Coating
Coating Behaviour
AR
thick coating clinker very thin coating
ball or sinter ring dusty clinker
- 1.9 formation (plenty of (little of viscous melt
viscous melt phase) phase)
NORMAL
- 1.6
COATING
Clinker Minerals
AR > 0.64
C3S = 4.07*CaO-7.60*SiO2-6.72*Al 2O3-1.43*Fe 2O3
C2S = 2.87*SiO2 - 0.75*C3S (or = 8.60*SiO2+5.07*Al2O3+1.08*Fe2O3-3.07 CaO)
C3A = 2.65*Al2O3-1.69*Fe2O3
Correlation between the main clinker Minerals and the main moduli
Correlation with Lime Saturation Correlation with Silica Ratio
Clinker Minerals
Correlation with Alumina Ratio
Clinker Minerals
Uniformity
Target: < 3 %
Target: C.o.V. ≤ 3 %
Type I
4000
3000
35 37 39 41 43 45 47 49 51 53
Uniformity
Daily (hourly over one day): Monthly (daily over one month):
strong impact on kiln performance strong impact on product quality
Daily Monthly
Hourly samples Daily values over
over 24 h one month
LS σ < 1.2 < 1.0
Kiln feed
AR σ < 0.04 < 0.03
& clinker
SR σ < 0.04 < 0.03
Raw meal
LS σ < 3.6 < 1.0
(tentative)
C3 S
C2 S
C3 A acc.
C4AF
K2 O
Na2O
SO3 ret.
P2O5 ret.
Gypsum
Fineness acc.
Physics
Electromagnetic spectrum
Radio waves: 0.3 - 1 • 103 m Dualism:
3800 - 7800 Å
-10 -7
Ultra violet: 6 • 10 - 3.8 • 10 m
Radiation
eV = h•c ; h•c =
min = const. = 12.39 ; h•c = const
min eV V kV e
E = energy; e = unite charge of an electron; kV = tension; h = Planck's const.;
ν = frequency; c = light velocity; = wave length
Bragg's law CB + BD = n •
CB = BD = d • sin θ
n• = 2d • sin θ
Statistics (1)
Frequency table
Class Center value Number of Relativ e Cumulativ e
samples frequency frequency
(MPa) (MPa) (%) (%)
18.75 21.25 20.0 1 1.1 1.1
21.25 23.75 22.5 4 4.5 5.6
23.75 26.25 25.0 6 6.7 12.4
26.25 28.75 27.5 9 10.1 22.5
28.75 31.25 30.0 10 11.2 33.7
31.25 33.75 32.5 19 21.3 55.1
33.75 36.25 35.0 16 18.0 73.0
36.25 38.75 37.5 11 12.4 85.4
38.75 41.25 40.0 7 7.9 93.3
41.25 43.75 42.5 2 2.2 95.5
43.75 46.25 45.0 3 3.4 98.9
46.25 48.75 47.5 0 0.0 98.9
48.75 51.25 50.0 1 1.1 100.0
Total 89 100.0
Histogram
20
18
Frequency (number of samples)
16
14
12
10
0
20.0 22.5 25.0 27.5 30.0 32.5 35.0 37.5 40.0 42.5 45.0 47.5 50.0
Class (center value) (Mpa)
90.0
80.0
Cumulative frequency (%)
70.0
60.0
50.0
40.0
30.0
20.0
10.0
0.0
20.0 22.5 25.0 27.5 30.0 32.5 35.0 37.5 40.0 42.5 45.0 47.5 50.0
Center value (MPa)
Statistics (2)
Measure of location
x1 + x2 + x3 + ...xn
Mean x= = 33.2
Median, minimum and maximum
n
i 1 ... 41 42 43 44 45 46 47 48 49 ... 89
xi 20.9 ... 32.5 32.8 32.8 33.0 33.3 33.3 33.4 33.5 33.6 ... 48.9
40
Mean = 4280
30
20
10
0
0 2000 4000 6000 8000 10000 12000 <
Income (Money units)
Measure of variability
Standard deviation
n
∑ ( x − x)
Significance of standard 2
deviation i
s= i =1
= 5.6
n −1
Statistics (3)
Significance of standard deviation
Coefficient of variation
s
C.o.V . = × 100% = 16.7%
x
Range
range = maximum − minimum = 28 . 0
Kurtosis
14.7
normal : p = 3 ±
n
p=
∑ ( x − x)
i
4
pointed : p > 3 +
14.7
s x4 (n − 1) n
14.7
tailed / flat : p < 3 −
n
Statistics (4)
Skewness
p=
∑ x − x)
i
3
s 3x (n − 1)
7.35
normal : p = 0 ±
n
7.35
positive : p <
n
7.35
negative : p >
n
Significance of Z
Example:
Current level and variability of cement mortar strength: Mean: x = 33.2
Standard deviation: s = 5.6
Questions:
How many samples are below the target of 28 MPa?
Which is the target for the mean, that must be set that 95% of the samples are above target?
Statistics (5)
Material Preparation
Crushing…………………………………………………………………….. 164
Handling……………………………………………………………………. .166
Homogenizing……………………………………………………………… 170
Preblending…………………………………………………………………. 175
Idle Time = equipment is not operating but is in a condition for immediate start up
Other downtime = equipment is not operating and not in a condition for immediate start up
Calendar Time = actual operating time + idle time + other downtime
Net OEE :
OEE net [%] = (Net Availabil ity Index ⋅ Production Rate Index ⋅ Quality Index) / 100
OEE net [%] ≥ 85% (guide value)
OEE = Overall Equipment Efficiency
Quality Index [%] = 1 (due to insignificant final product reject)
MTBF
Actual Operating Time [h]
Mean Time Between Failure [h] =
Failures [# ]
Mean Time Between Failure [h] > 250 h (guide value)
Note: Shutdowns to change material and/or product type are not to be considered failures
A Raw Mill shutdown due to a kiln failure should not be considered as failure for the raw mill
Above definitions are based on the HARP (Holcim Accounting and Reporting Principles) Manual
Release 5.1 from 2005. For the most current definition check the HARP Manual on
Holspace.
Industrial Mill : IM OC : IM = LM
Laboratory Mill : LM CC : 1st Genration Separator IM = 0,95 x LM
3rd Generation Separator IM = 0,85 x LM
Vertical mill: IM = 0.45 – 0.55 x LM
100
Ln [Ln ] = n ⋅ [Ln(d) − Ln(d' )]
R d
Rd - % of residue on the d[um] sieve
d’ – particle size for which there is 36.8 % cumulated residue
n – slope of the PSD linear correlation straight line
A level Audit
Fineness – Blaine Conversion for Tube Mills
Blaine 2 − Blaine
1
⋅k
kWh/t 2 = kWh/t 1 ⋅e 1000
2 − log 10 ( R 2 )
kWh / t 2 = kWh / t 1 ⋅
2 − log 10 ( R 1 )
R1 and R2 – only residues on 45 um and 90 um from ball mills
1.1 1.2 1.3 1.4 2.1 2.2 2.3 2.4 2.5 2.6 2.7
Material level
1st Chamber 2nd Chamber
~ 50 [mm] good
Residues
M Radiation/Convection M
Material
Moisture (water)
Material
Grinding heat Evaporation heat
Drying gases Exhaust gases
- kiln exhaust Radiation/Convection
- hot gas generator Residual Moisture
- cooler exhaust air (Dust)
Recirculating gases
OUTPUT
Fresh air
© 2005 Holcim/Switzerland
False air
Grinding Technology - DRYING
INPUT
111
Version Nov. 2005
The necessary energy of a drying gas is expressed by
Q = required energy [kJ/h]
Q = V ⋅ t ⋅ cp V = gas flow rate [Nm3/h]
t = gas temperature [°C]
cp=spec.gas heat [kJ/Nm3 ⋅ °C]
and has to be found through a heat balance
© 2005 Holcim/Switzerland
% m out
Grinding Technology - DRYING
112
moisture m 100 - % m out
Drying
Version Nov. 2005
Version Nov. 2005
Dispersion
20 - 30 < 15 < 200 < 850
dryer
Rapid dryer < 500
< 20 < 200 < 800
(soft material)
Dryer - < 25 (air < 500 (air
< 150 (depends
crusher swept with swept with < 800
on crusher size)
flash dryer) flash dryer)
Flash dryer ~ < 20 (function
of terminal < 35 < 500 < 900
velocity)
Tube mill
without < 30 <5 < 150 < 450
drying comp.
Tube mill EDM: 25 – 30 EDM: < 6 EDM
with drying
Air-swept: Air-swept: Air-swept: Air-swept:
compartment
25 – 30 < 15 < 200 < 450
integrated CDM: 30 – 50 CDM: < 15
Tube mill
with drying EDM: 25 – 30
compartment EDM: ~ 10 EDM < 300 EDM < 600
CDM: 30 – 50
overhang
Vertical roller
mill 80 - 100 < 20 - < 450
NOTE: Air in leakages through holes and apertures can be calculated with the
Bernoulli formula given in the Thermal Process Technology part - page 22
Acid dew pointcan be calculated with the formula given in the Thermal Process
Technology part - page 31
τ τ k
pw
70 343,15 31155,73
0,75
Di = Mill diameter
0,70 inside mill
liners
0,65
0,26
0,24
factor c [-]
0,23
small balls
0,22 (cylpebs)
(<40mm ∅ )
0,21
0,20
20 22 24 26 28 30 32 34 36
filling degree f [%]
η3
P3
P4 =
η3 ~ 0.99
η2
P2
P3 =
η1
P1
P2 =
GEAR
η2 ~ 0.96
η1 ~ 0.96
P1
For rough calculation of the main mill dimensions the mentioned formulas:
π f n crit =
42.3 k
Q=
2
⋅ Di ⋅ L u ⋅ ⋅ n= ⋅ ncrit
4 100 Q
Di 100
P1 = c ⋅ Q ⋅ D i ⋅ n
can be combined to one formula:
π 2 f 42.3 k
P1 = c ⋅ Q ⋅ Di ⋅ n = c ⋅ ⋅ Di ⋅ L u ⋅ ⋅γQ ⋅ ⋅
4 100 Di 100
P1 = 33.22 ⋅ 10 −4 ⋅ c ⋅ L u ⋅ f ⋅ γ Q ⋅ k ⋅ D i
2.5
Lu
Introducing the length to diameter ratio λ = yields the following
Di
equation:
P1 = 33.22 ⋅ 10 −4 ⋅ c ⋅ λ ⋅ f ⋅ γ Q ⋅ k ⋅ Di
3.5
[kW ]
P1= mill net driving power [kW] k = percentage of critical speed [%]
Q = weight of grinding media charge [t] γQ = bulk weight of grinding media [t/m3]:
Di= internal mill diameter [m] § 2nd chamber: 4.6 – 4.7 [t/m3]
Definition
Calculation
Q1 Q2
L1 L2
ES1 = q ⋅ abs q=
Q1 + Q2
Q1 = weight of grinding media charge . 1st chamber [t]
t Q2 = weight of grinding media charge . 2nd chamber [t]
1.Compartment
90 25.0 25.0
80 35.0 35.0
Standard 70 25.0 25.0
60 15.0 15.0
1.Compartment
90 40.0 40.0
Aggressive 80 30.0 30.0
70 20.0 20.0
60 10.0 10.0
1.Compartment
90 45.0 45.0
Very aggressive 80 30.0 30.0
70 25.0 25.0
60
50 4.5 8.0
50 10.0 10.0
40 10.0 10.0
30 16.0 16.0
OPC > 3200 cm2/g 25 16.0 16.0
20 21.0 21.0
17 27.0 27.0
50
REs1>1.2 40 9.0 9.0
30 14.0 14.0
25 17.0 17.0
20 24.0 24.0
17 36.0 36.0
50
40
30 12.9 12.9
25 19.7 19.7
20 26.8 26.8
17 40.6 40.6
Ki ln BDP[t/d Clin ker ] ⋅ Raw Meal Factor [-] ⋅ ( 1 + Wear Facto r [%] )
Design Pr oduction R ate [t/h] = 100
24 [h] ⋅ OEEnet [%]
⋅ 100 [%]
Max monthly production
Seasonality factor =
Monthly average
DM
Motor shaft power at
P4 coupling (P2) P1
PMotor out = PGear in
P Measured Mechanical table
P power at coupling
(P4)
mill to gear (P1) η1 = 0,97
PGear out = PMill in
η 2 = 0,97
η3 = 0,99
Rated power
at terminal box
PMotor in (P3)
η3 η2 η1
P4 P3 P2 P1
P1 P2 P3
P2 = P3 = P4 =
η1 η2 η3
Es = specific electrical energy consumption @ motor shaft (e.g. from grindability test)
* - applies for cement vertical mills – with the exception that the daily
cement production is calculated on the base of peak month demand
Specific roller pressure k: is defined by division of the total roller press force F by the
projected roller section DR x WR. Each mill type has its operating range. The achieved
spec. roller pressure is related to the operating conditions.
Roller pressure force F: consists of the proper roller weight G and the exerted force by
the hydraulic pressure device F2. Force F1 applies for rocker arm type mills, where the
force from the hydraulic cylinder has to be converted to F2 with the lever arm ratio.
Table speed n: is a function of DM for a constant centrifugal force of the material on the
grinding table. Typical speed constant c are given for each supplier. In certain cases,
lower speeds are used for fine and dry feed materials.
Gas speeds: The mill has to be sized to meet the required speed ranges:
Dust load: The gas flow rate must be selected to achieve a dust load of 500 - 600 [g/m3]
raw meal at the mill outlet. The never exceed value for the separator and dust collector is
750 [g/m3].
© 2005 Holcim/Switzerland
WR WR
WR F1 (kN) Mech. force at hydr. piston rod
F2 (kN) Mech. force at roller
DR DR GR (kN) Roller weigth
F c (-) Speed constant (supplier specific)
F DR
-1
F n (min ) Speed of grinding table
DM DM DM
k max. 800[kN/m2]
125
Version Nov. 2005
Spec. Air Load for Vertical Raw Mills (mill exit) for Raw Material, coal and pozzolana
Holcim Standard
3.0
2.2
2.0
1.8
© 2005 Holcim/Switzerland
1.6
1.2
3 4 5 6 7 8 9 10
Note: For cement applications à Specific Air Load ~ 3.2 m3/kg @ mill outlet
126
Version Nov. 2005
Version Nov. 2005
ρ0
α
F
β
d
vu
p
ρG
W
D s
G Product [t/h]
& = w ⋅ s ⋅ vu ⋅ G ⋅ 3,6
M [t/h] ρ GRaw Material 2.3 – 2.4 [t/m3]
P ⋅u E Slag ~ 3 [kWh/t]
Ec = & [kWh/t]
M
Ec= Closed circuit (with separator or/and slab recirculation)
unstable Operation
Stable operation
POLYSIUS
300 - 2500 90 – 700 ~ 6500
(POLYCOM)
(clinker)
FL SMIDTH -
503 - 3024 167 – 995 8000
Fuller
(clinker)
Cyclone
Cyclone nominal diameter (rule of thumb)
4⋅V
d=
n⋅ ⋅ 2.6 ⋅ 3600
d [m] nominal diameter cyclone
Grit Separator
Specific air load (feed): 500 - 1000 g/m3
d = 0.0127 ⋅ V
d [m] nominal diameter
VS - Separator
Guide values for 1700 cm2/g product fineness in closed circuit with roller press:
Dynamic Separators
2600 ~ 11
3000 ~8
Feed A
(t/h)
Feed
≤ 2,5 (kg/m3) Fines F
Air amount (t/h)
Fines
≤ 0,75 (kg/ m3)
Air amount
Rotor values
Coarse R (t/h)
Circumferential speed
vu ~ 5-35 (m/s) (for *cement) Air speed
vu ~ 25 (m/s) (for raw meal and coal) through D
Air speed through rotor rotor v (m/s)
v ~ 4 (m/s) (for *cement)
v ~ 5 (m/s) (for raw meal and coal)
Specific rotor load H
Fines (t/h)
= ~ 10-12 (t/hm2)
D (m) x x H (m)
Circulation Load
The circulating load in closed-circuit grinding is defined as the mass of the separator
feed A divided by the mass of the fine fraction F, or:
A
u= eq. (1)
F
The actual value of the circulating load depends on various factors, such as mill
design, grinding efficiency, product fineness etc., but as a guide the following
values can be given:
- Cement mill low fineness u = 1.5 to 2
high fineness u>2
- Raw mill u = 2 to 2.5
A =F+R (a ) A ⋅a = F ⋅ f +R ⋅r (b ) u=
A
(eq 1)
F
u=
(f - r )
(a - r ) eq. (2)
It is recommended to use the u-values calculated by this formula with caution, because
inevitable errors in the determination of the particle size distributions affect the result
considerably.
Mill feed M - -
Separator A a BA
feed
Fine fraction F f BF
Coarse R r BR
fraction
Definitions fineness
passing (%)
f
a
r
r
0
1 x 10 x x 100 1000
1 2
particle size ( um )
The information given by the efficiency curve is not detailed enough because the
defined fractions 0 to x [um] are wide.
If we ask for the recovery of a feed size class with lower limit x1 and upper limit
x2 (x1 greater zero) into the coarse stream, we arrive at the Tromp value for the
coarse stream.
(R - ∆r ) ⋅ 100 [%]
∆r 1
u= tr = ⋅ 1 − ⋅ 100 [%]
(A - ∆ r )
or
∆a u
eq. (5) eq. (6)
If this ratio is obtained for a number of size classes and plotted against x, there results
the classification curve (Figure 1). It is also called the Tromp curve after the name of
the man to whom it is assigned.
Cut Point
The cut point d50 corresponds to 50 % of the feed passing to the coarse stream as
seen in Figure 2 8next page). It is therefore that size which has equal probability of
passing to either coarse or fine streams.
By-Pass Effect
Ideally, the Tromp curve is asymptotic to the abscissae at ordinate values of zero and
unity.
In practice, it is often the case that the lower asymptote occurs at ordinate values a'
greater than zero (Figure 3), i.e.. a portion of each size fraction bypasses the classifying
action. Expressed in an other way, part of the feed reports to the coarse stream indepen-
dently of its particle size.
Experience has shown that the bypass parameter a' varies with classifier feed rate,
and hence it is difficult to describe a single Tromp curve which is representative of the
classifier.
FIG. 1
% into fines % into coarses
0 (%) 100 (%)
fines coarses
63 (%) 37 (%)
FIG. 2 d
75
sharpness of cut k = d
25
1,00
0,75
cut point
0,50
0,25
d
0 d d 75
25 50
particle size ( um )
FIG. 3
bypass a'
a'
0 particle size ( um )
Static
separator
Air speed over ball charge
(for fan dimensioning)
OC v < 1.0 [m/s]
CC v < 1.5 [m/s]
Tube mill
Free section of
inlet and diaphragms
v < 25 [m/s]
0 [%] open
110 [°C]
Cooling in Separator
© 2005 Holcim/Switzerland
95 [%] Clinker 130 [°C] Mill
5 [%] Gypsum 20 [°C]
50 [t/h] 80 [°C]
110 [°C] 50 [t/h] OPC
Product (example)
138
Version Nov. 2005
Version Nov. 2005
130
counter
120
current
110
Air from
Air from co-current
blower 100
H2O blower H2O
co-current 90
(Double)
Rotary union 80
1st 2nd Comp.
Mill length
detail A detail B
Mill Inlet Mill trunnion
Material feed
A
B Nozzle
Material discharge
Air Water
Water
12 loop
PI Mill 11 PI
setpoint 8 Pressure regulator
9 Flow control valve
FIC FIC
cement
10 10 Flow meter
temperature/
mill exhaust 11 Pressure gauge
9 M
© 2005 Holcim/Switzerland
temperature 12 Solenoid valve
13 Injection nozzle
3 2 Water tank 7 8
1 14 Shut-off valve
140
Version Nov. 2005
Version Nov. 2005
Index
G [t/h] mill production
u [-] circulation factor (feed/product)
t [°C] temperature
P abs. [kW] absorbed power (counter)
η [-] efficiency of drives
cp [kJ/kg] spec. heat value (related to reference temperature)
3
[kJ/Nm ]
© 2005 Holcim/Switzerland
Performance of Raw Grinding Systems
Higher drying capacities can be achieved with predrying facilities (e.g. flash drier etc.)
145
Version Nov. 2005
Version Nov. 2005
30
Spec. Energy (kWh/t)
25
20
15
Systems
10
Mills only
5
0
10 15 20 25 30
30
Spec. Energy (kWh/t)
25
20
15
System
10
Mill + Fan
5
Mill motor
0
10 15 20 25 30
kWh/t
60
1
50
2
40 3
4
30
20
10
cm2/g
Design Guidelines
From experience, we know that the vertical upward vector of the gas flow velocity should
be lower than 1.0 in process dust collectors or maximum 1.3 m/s for auxiliary
dust collecting systems.
No more than six (6) to eight (8) dust sources to vent should be connected to one dust
collector.
Up- and downward sloping for dust-laden air shall have - to avoid dust accumulation –
a slope of 300 for limestone, slag, cement, and 450 for clinker (measured from vertical axis).
The filter bag dimension depends on the cleaning system efficiency and the geometrical
allocation of the filter bags. The diameter of the bags is usually between 120 and 160 mm.
Filter cloth
The filter cloth specification and design data to be provided by the supplier have carefully be
checked by the consumer.
• For general application (dry gas) up to 1200 C (long time operation), needle felt fabric
made from high quality Polyester fibers are used.
• For an application in drying/grinding (humid gas) up to 1200 C (long time operation),
Polyacrylnitrile or similar fiber cloth is recommended.
• Application for temperatures above 1200 C, Polyamide (Nomex), Polyphenylene, Glass-fiber,
Teflon/graphite coated or similar.
Pulse cycle
The cleaning cycle for pulse-jet collectors should be designed, so that the pulse duration
produces a short, crisp pulse in order to create an effective shock wave in the bag. This
duration is generally set to fire for 0.10 to 0.15 second.
The frequency of pulse-jet cleaning is also vital to proper dust cake retention. This frequency
can vary from 7 to 30 seconds or more and is adjusted by means of a potentiometer on the
timer panel. The frequency should be adjusted, so that the differential pressure across the
collector ranges from 75 - 150 mm WG.
Belt Conveyor
Design Guidelines
Belt speed
In general the maximum belt speed shall not exceed 2.0 m/s.
Conveyors handling dry fine material (i.e. raw meal, cement) shall not exceed 1.25 m/s.
Belt speed for conveyors less than 50 meters in length shall not exceed 1.5 m/s.
Conveyors longer than 500 m (overland) can operate faster than 2.0 m/s.
Belt width
Belt width shall not be less than 800 mm, for special applications 650 mm belts may be used.
Packing plants 500 mm flat belts may be applicable.
The minimum belt width for reversible conveyors shall not be less than 800 mm.
Slope:
Vertical (concave) curves to be designed to avoid lifting of the belt from the
idlers under any conditions (minimum radius 300 m).
curve
rtical
s of ve
Belt
trave
l
Radiu
Tangent point
C B
Angle "A"
Working point
Fig. 19: Example
D P E
vertical curve
Belt Conveyor
Idler design
Trough angle shall not be less than 30°
Carrier and return idler diameter shall be designed according to DIN (15207-1 / 22107) or CEMA
(Class C) or equivalent
Belt Conveyor
Pulley design
Pulley lagging
All drive pulleys shall have rubber lagging.
Tail and take-up pulleys: rubber lined or spiral wrapped wing pulleys. Wing type pulleys
without spiral are not acceptable
Belt Conveyor
Table - Minimum Number of Plies Recommended for a Correct Load Support
Belt Conveyor
Table - Maximum Number of Plies Recommended for a Correct
Belt Conveyor
Table - Guide for top and bottom cover thickness for fabric belts
Table - Guide for top and bottom cover thickness for steel cord belts
Belt Conveyor
Troughing Transition Distance for Fabric Belt (Nylon, Polyester, Vinyilon)
Unit: m
Troughing Angle 20° 30° 35° 45° 20° 30° 35° 45°
600 0.55 0.80 0.95 1.20 0.30 0.40 0.50 0.60
650 0.60 0.90 1.05 1.30 0.30 0.45 0.55 0.65
750 0.70 1.00 1.20 1.50 0.35 0.50 0.60 0.75
Belt Width
Troughing Angle 20° 30° 35° 45° 20° 30° 35° 45°
600 1.10 1.65 1.90 2.40 0.55 0.80 0.95 1.20
650 1.20 1.75 2.05 2.60 0.60 0.90 1.05 1.30
750 1.40 2.05 2.40 3.00 0.70 1.00 1.20 1.50
Belt Width
Belt Conveyor
Specific Weights and Properties of Materials
NOTE: The below listed properties of materials are to be used unless the client advises
otherwise. The figures can have a large deviation depending on the material source.
Belt Conveyor
Belt conveyor
capacity
Belt conveyor
discharge
Crusher determination
Most suitable ö
Suitable õ
Not Suitable ÷
Material Conditions Material Crushing Ratio Material Material
Classification Abrasivity Moisture
Soft
Medium
Hard
1:5
1:15
1:30
1:50
Low
Medium
High
Dry
Moist
wet
Crusher Type
Reduction
Crusher type Ratio
Application Operation
Secondary - for
hard abrasive Compression
5 to 1 materials with low
Hydrocone moisture
Mineral Sizer up to
1 st. or 2 ndary. Shear
Soft to hard Compression
Sticky, abrasive
5 to 1
Bulk Density
b =
m solid + m voids m total
Vsolid + Vvoids
=
V total
t/m 3 [ ] b = bulk density (see table1)
Moisture
A common expression for a bulk solid’s moisture content is the percentage of water to wet solid:
mwet = mass wet [kg] mdry = mass dry [kg] mH2O = mass water
The median particle x50 size is probably the most common term used for representing a
bulk solids average particle size. The other definitions for an equivalent diameter are the
mean volume diameter or the mean surface diameter.
Angle of response
Angle of repose Flow behavior
20 - 30 deg free flowing
30 - 38 deg easy flowing
38 - 45 deg fair flowing
45 - 55 deg cohesive
> 55 deg very cohesive
The angle of repose should not be abused as a quantitative guide in bin design.
Bin design
There are some general principles to be observed when designing bulk solid handling systems:
Rule 1: Storage and process feed functions should be separated whenever possible.
Rule 2: Feed bins should be designed for the lowest possible volume and not be abused for
additional storage capacity.
Rule 3: Feed bins should be designed for mass-flow on principle.
diameter
width
length
Circular outlet:
- diameter ~ (6 – 10) x max. grain size
Design for cohesive and fine material only based on Shear testing.
Top size Bulk density Bulk density Bulk density Bulk density Design Angle of Hopper half Abrassive-
[mm] in pneumatic in in silos and in silos and moisture repose angle ness
Material conveyors mechanical stores (vol) stores (load) [%, WB] [ °] [ °] [Low /
[t/m3, DB] conveyors [t/m3, DB] [t/m3, DB] Medium /
[t/m3, DB] High]
High Grade Limestone 1.35 1.50 1.70 38.00 <20 M
Low Grade Limestone 1.35 1.50 1.70 38.00 <20 M
Shale 1.25 1.50 1.70 40.00 <10 M
Clay 1.40 1.60 1.80 0.00 M
Iron Ore 2.00 2.40 2.80 40.00 <20 H
Pyrite pellets 2.10 H
Sand 1.40 1.60 1.70 40.00 <20 H
Mix 1.35 1.50 1.70 38.00 <20 M
Raw Mill Feed 1.35 1.50 1.50 38.00 <20 M
Raw Meal/ Kiln Feed % R 0.09 mm 0.80 0.90 1.20 1.50 0.50 (15) L
Filter Dust 0.40 0.60 0.80 1.00 0.00 (15) L
Bypass Dust
Comments:
Uniformity targets
The targets used for MPR's are taken as given without any error correction:
Short term Long term
hourly samples over 24 h daily values over one month
s LSF < 1.2 < 1.0
Kiln feed
s SM
(or clinker) < 0.04 < 0.03
s AR
Raw meal after mill after mill
no Preblending s LSF < 4.0
< 1.0
with preblending s LSF < 3.0
Characteristic Stdv. s
CaCO3 % < 0.2
CaO % < 0.11 Table can be used to correlate the LSF target to other characteristics:
LSF % < 1.0 sLSF = 1% → sCaCO3 ~ 0.2% → sCaO ~ 0.11%
SiO2 % < 0.1
Al2O3 % < 0.07
Fe2O3 % < 0.04
To achieve the kiln feed uniformity targets the variation of the raw meal chemistry (after mill) is limited by:
Homogenizing silo sLSF < 10
Blending silo sLSF < 5
Blending silos
Aerated homogenising silos
Aeration sequence normally 8 * 10 min for quadrant system. Might be shorter (even 3 min)
to avoid segregation. Airflow for active segments up to 3 m/min and inactive at least 0.5 m/min
based on total cross section.
Segregation factor
The higher the segregation the more attention is given to kiln dust handling and
materials handling → segregation inside silo.
range of not critical raw meals: 0.8 < Sf < 1.2 (LSF or SR using the same rules)
In direct operation the clinker LSF is theoretically the same as the raw meal LSF when
all dust is immediately returned into the kiln feed. LSF raw meal = LSF clinker
Testing procedure
Sampling frequency adapted to achieve the 30 samples
§ Only spot samples
§ Period for batch homogenizing silo: should contain 3 batches (e.g. 3 time 8h = 24 h again
every 30 min. one sample). Discharge of homogenising silo even up to every 5 min.
§ Period for continuous homogenizing silo: 24 h (e.g. every 30 min. one sample = 48 samples).
§ Discharge of silo (kiln feed) normally every 30 minutes
2
Z
2 n number of samples
2
1+ 0.5* = 33
n ≈ 1+ 0.5* 0.25
Zα
ε
probability factor
accuracy (of the stdv)
The minimum number of samples is 30 to allow a failure of < 25% for the standard deviation.
The preferred number of even 50 samples is asked for performances test with suppliers mainly.
Standard deviation
The standard deviation can be rough estimated by dividing the differences of the min
and max values by 6. (Formula for stdv. given in chapter MT)
(x − x )
s ≈ max min
S – standard deviation
xmax – max. value
6 xmin – min.value
(Xmax )
- X / s>G
G - critical value acc. GRUBB’s
G
n significance level
Alpha = 1%
20 2,884
22 2,934
24 2,984
26 3,028
28 3,065 n = number of samples
30 3,103
32 3,133
34 3,163
36 3,190
38 3,215
40 3,240
Error evaluation
The error determinations done by double sampling
2
π 1
serr =
4n ∑ di
s meas = stdv measured
s err = stdv error
s cor = stdv corrected
di = (x1a-x1b) differences
between the double
samples
scor = s2meas − serr
2
H = number of double
samples
Blending factor
The blending factor is the ratio of standard deviation before sin and after sout the
homogenizing process
Bf = sin/sout
LSF stdv s meas s err s cor Shown is the not significant influence of the
Raw meal 5.5 1 5.4 error due to sampling and analyzing based
Kiln feed 1.3 0.4 1.27 on LSF (San Miguel plant - continuous blending silo)
Preblending
Calculation of number of layers (target à 300)
Longitudinal Circular
General Conversion
Column 1
Column 1 Column 2 Column 2
into Column 2 into Column 1
multiply by multiply by
Area
Column 1
Column 2 into
into Column
Column 1 Column 2 Column 1
2 multiply by
multiply by
square centimeter,
6.45 square inch, in2 0.153
cm2 (10-4 m)2
square millimeter,
645 square inch, in2 1.55 x 10-3
mm2 (10-6 m)2
square kilometer,
2.590 square mile, mi2 0.386
km2 (103 m)2
Volume
To convert To convert
Column 1 Column Column 2 Column 2 into
into Column Column 1
Acceptable Unit S1 Unit
2 multiply by multiply by
Mass
Column 1 into Column 2
Column 2 into
Column 1 Column 2
multiply by Column 1
multiply by
hundredweight (short),
4.54 x 10-1 kilogram, kg 2.20 x 10-2
cwt
megapascal, MPa
0.101 atmosphere, atm 9.90
(106 Pa)
megapascal,
0.1 bar 10
MPa (106 Pa)
Temperature
Column 1 into Column 2 into
Column 2 Column 1 Column 2
Column 1
multiply by multiply by
Energy
Column 1 Column 2
into Column Column 1 Column 2 into
2 multiply Column 1
by
multiply by
Notes
Notes
Notes
2nd Edition
Nov , 2005