SECTION 1: Identification of The Substance/mixture and of The Company/ Undertaking

Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
Acetaldehyde ≥99,5 %, p.a.
article number: 3004 date of compilation: 15.01.2018

Version: 3.0 en Revision: 11.08.2020
Replaces version of: 10.06.2020
Version: (2)
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Acetaldehyde
Article number 3004
Registration number (REACH) 01-2119451152-51-xxxx
Index No 605-003-00-6
EC number 200-836-8
CAS number 75-07-0
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: laboratory chemical
laboratory and analytical use
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany
Telephone: +49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: [email protected]
Website: www.carlroth.de
Competent person responsible for the safety data : Department Health, Safety and Environment
sheet:
e-mail (competent person): [email protected]
1.4 Emergency telephone number
Emergency information service Poison Centre Munich: +49/(0)89 19240
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Classification acc. to GHS
Section Hazard class Hazard class and cat- Hazard

egory state-
ment
2.6 flammable liquid (Flam. Liq. 1) H224
3.1O acute toxicity (oral) (Acute Tox. 4) H302
3.3 serious eye damage/eye irritation (Eye Irrit. 2) H319
3.5 germ cell mutagenicity (Muta. 2) H341
3.6 carcinogenicity (Carc. 1B) H350
Malta (en) Page 1 / 16

Safety data sheet
article number: 3004
Classification acc. to GHS
Section Hazard class Hazard class and cat- Hazard

egory state-
ment
3.8R specific target organ toxicity - single exposure (respiratory tract ir- (STOT SE 3) H335
ritation)
2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word Danger
Pictograms
GHS02, GHS07,
GHS08
Hazard statements
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H350 May cause cancer
Precautionary statements
Precautionary statements - prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P233 Keep container tightly closed.
P261 Avoid breathing mist/vapours.
P280 Wear protective gloves/eye protection.
Precautionary statements - response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
For professional users only

Labelling of packages where the contents do not exceed 125 ml
Signal word: Danger
Symbol(s)
H224 Extremely flammable liquid and vapour.

H341 Suspected of causing genetic defects.
H350 May cause cancer.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P280 Wear protective gloves/eye protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Safety data sheet

2.3 Other hazards
There is no additional information.
SECTION 3: Composition/information on ingredients

3.1 Substances
Name of substance Ethanal
Index No 605-003-00-6
Registration number (REACH) 01-2119451152-51-xxxx
EC number 200-836-8
CAS number 75-07-0
Molecular formula C₂H₄O
Molar mass 44,05 g/mol
SECTION 4: First aid measures

4.1 Description of first aid measures
General notes
Take off contaminated clothing.
Following inhalation
Remove person to fresh air and keep comfortable for breathing. If breathing is irregular or stopped,
immediately seek medical assistance and start first aid actions.
Following skin contact
Rinse skin with water/shower. In case of skin irritation, consult a physician.
Following eye contact
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Consult an
ophthalmologist.
Following ingestion
Rinse mouth immediately and drink plenty of water. Call a doctor.
4.2 Most important symptoms and effects, both acute and delayed
Irritation, Cough, Dyspnoea, Vomiting, Nausea, Spasms
4.3 Indication of any immediate medical attention and special treatment needed
none

Safety data sheet
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media

Co-ordinate fire-fighting measures to the fire surroundings
water spray, foam, dry extinguishing powder, carbon dioxide (CO₂)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Combustible. Vapours can form explosive mixtures with air.
Hazardous combustion products
In case of fire may be liberated: carbon monoxide (CO), carbon dioxide (CO₂)
5.3 Advice for firefighters
Vapours are heavier than air. Beware of reignition. Fight fire with normal precautions from a reason-
able distance. Wear self-contained breathing apparatus.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel

Do not breathe vapour/spray. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid-
ance of ignition sources.
6.2 Environmental precautions
Keep away from drains, surface and ground water. Explosive properties.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains.
Advice on how to clean up a spill
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

Safety data sheet
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Use extractor hood (laboratory). Provide adequate ventilation. When not in use, keep containers
tightly closed.
• Measures to prevent fire as well as aerosol and dust generation
Keep away from sources of ignition - No smoking.
Take precautionary measures against static discharge.

Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
When using do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a cool place.
Incompatible substances or mixtures
Observe hints for combined storage.
Consideration of other advice
• Ventilation requirements
Use local and general ventilation.
• Specific designs for storage rooms or vessels
Recommended storage temperature: 2 – 8 °C.
7.3 Specific end use(s)
No information available.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Data are not available.
8.2 Exposure controls
Individual protection measures (personal protective equipment)
Eye/face protection
Use safety goggle with side protection.

Skin protection

Safety data sheet

• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. The times are approximate values from
measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances,
body heat etc. and a reduction of the effective layer thickness by stretching can lead to a consider-
able reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times
larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply
only to the pure substance. When transferred to substance mixtures, they may only be considered as
a guide.
• type of material
Butyl caoutchouc (butyl rubber)
• material thickness
0,7mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Flame-retardant protective clothing.
Respiratory protection
Respiratory protection necessary at: Aerosol or mist formation. P2 (filters at least 94 % of airborne
particles, colour code: White). Type: AX (gas filters and combined filters against low-boiling point or-
ganic compounds, colour code: Brown).
Environmental exposure controls
Keep away from drains, surface and ground water.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state liquid (fluid)
Colour colourless
Odour pungent
Odour threshold No data available
Other physical and chemical parameters
pH (value) 5 (water: 10 g/l, 20 °C)
Melting point/freezing point -123,5 °C

Initial boiling point and boiling range 20 – 21 °C at 1.013 hPa
Flash point -40 °C
Evaporation rate no data available

Safety data sheet
Flammability (solid, gas) not relevant (fluid)

Explosive limits
• lower explosion limit (LEL) 4 vol% (73 g/m³)
• upper explosion limit (UEL) 57 vol% (1.040 g/m³)
Explosion limits of dust clouds not relevant
Vapour pressure 120,2 kPa at 25 °C
Density 0,785 g/cm³ at 18 °C
Vapour density 1,52 (air = 1)

Bulk density Not applicable
Relative density Information on this property is not available.
Solubility(ies)
Water solubility miscible in any proportion
Partition coefficient
n-octanol/water (log KOW) 0,63 (ECHA)
Auto-ignition temperature 175 °C at 1.013 hPa - ECHA
Decomposition temperature no data available
Viscosity
• kinematic viscosity 0,2692 mm²/s at 20 °C
• dynamic viscosity 0,21 mPa s at 20 °C

Explosive properties Shall not be classified as explosive
Oxidising properties none
9.2 Other information
Temperature class (EU, acc. to ATEX) T4 (Maximum permissible surface temperature
on the equipment: 135°C)
SECTION 10: Stability and reactivity

10.1 Reactivity
Risk of ignition. Vapours can form explosive mixtures with air. May form explosive peroxides.
10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
10.3 Possibility of hazardous reactions
Violent reaction with: Alkali hydroxide (caustic alkali), Alcohols, Amines, Ammonia (NH3), Acetic anhyd-
ride, Iron, Iodine, Ketone, Phenol, Phosphorus, Acids, Chlorates, Nitrate, Oxidisers, Perchlorates, Oxy-
gen,
=> Explosive properties
10.4 Conditions to avoid
Keep away from heat.

Safety data sheet

10.5 Incompatible materials
plastic and rubber
10.6 Hazardous decomposition products
Peroxides.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Exposure route Endpoint Value Species Source
inhalation: vapour LC50 24 mg/l/4h rat TOXNET
oral LD50 661 mg/kg rat TOXNET
dermal LD50 3.540 mg/kg rabbit TOXNET
Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Summary of evaluation of the CMR properties
Germ cell mutagenicity:
Suspected of causing genetic defects
Carcinogenicity:
May cause cancer
• Specific target organ toxicity - single exposure
May cause respiratory irritation.
• Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
gastrointestinal complaints, vomiting, nausea
• If in eyes
Causes serious eye irritation
• If inhaled
irritant effects, cough, Dyspnoea, pulmonary oedema
• If on skin
slightly irritant, risk of absorption via the skin

Safety data sheet

Other information
Other adverse effects: Headache, Spasms, Unconsciousness, Liver and kidney damage, Symptoms
can occur only after several hours
SECTION 12: Ecological information

12.1 Toxicity
acc. to 1272/2008/EC: Shall not be classified as hazardous to the aquatic environment.
Aquatic toxicity (acute)
Endpoint Value Species Source Exposure
time
EC50 48,3 mg/l aquatic invertebrates ECHA 48 h
Aquatic toxicity (chronic)

Endpoint Value Species Source Exposure
time
ErC50 ≤249 mg/l algae ECHA 5d
12.2 Process of degradability

The substance is readily biodegradable.
Theoretical Oxygen Demand: 1,816 mg/mg
Theoretical Carbon Dioxide: 1,998 mg/mg
12.3 Bioaccumulative potential
Does not significantly accumulate in organisms.
n-octanol/water (log KOW) 0,63
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
SECTION 13: Disposal considerations

13.1 Waste treatment methods
This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.

Safety data sheet

13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process.
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.
SECTION 14: Transport information

14.1 UN number 1089
14.2 UN proper shipping name ACETALDEHYDE
Hazardous ingredients Acetaldehyde
14.3 Transport hazard class(es)
Class 3 (flammable liquids)

14.4 Packing group I (substance presenting high danger)
14.5 Environmental hazards none (non-environmentally hazardous acc. to the danger-
ous goods regulations)
14.6 Special precautions for user

Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.
14.8 Information for each of the UN Model Regulations
• Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)
UN number 1089
Proper shipping name ACETALDEHYDE
Particulars in the transport document UN1089, ACETALDEHYDE, 3, I, (D/E)
Class 3
Classification code F1
Packing group I
Danger label(s) 3
Excepted quantities (EQ) E0

Limited quantities (LQ) 0
Transport category (TC) 1
Tunnel restriction code (TRC) D/E
Hazard identification No 33

Safety data sheet

• International Maritime Dangerous Goods Code (IMDG)
UN number 1089
Proper shipping name ACETALDEHYDE
Particulars in the shipper's declaration UN1089, ACETALDEHYDE, 3, I, -40°C c.c.
Class 3
Marine pollutant -
Packing group I
Danger label(s) 3
Special provisions (SP) -

Limited quantities (LQ) 0
EmS F-E, S-D
Stowage category E
• International Civil Aviation Organization (ICAO-IATA/DGR)
UN number 1089
Proper shipping name Acetaldehyde
Particulars in the shipper's declaration UN1089, Acetaldehyde, 3, I
Class 3
Packing group I
Danger label(s) 3
Special provisions (SP) A1

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
• Regulation 649/2012/EU concerning the export and import of hazardous chemicals (PIC)
Not listed.
• Regulation 1005/2009/EC on substances that deplete the ozone layer (ODS)
Not listed.
• Regulation 850/2004/EC on persistent organic pollutants (POP)
Not listed.

Safety data sheet

• Restrictions according to REACH, Annex XVII
Name of substance CAS No Wt% Type of registration Conditions No
of restric-
tion
Acetaldehyde 100 1907/2006/EC annex R3 3

XVII
Acetaldehyde 100 1907/2006/EC annex R28-30 28

XVII
Acetaldehyde 100 1907/2006/EC annex R40 40

XVII
Legend
R28-30 1. Shall not be placed on the market, or used,
- as substances,
- as constituents of other substances, or,
- in mixtures,
for supply to the general public when the individual concentration in the substance or mixture is equal to or great-
er than:
- either the relevant specific concentration limit specified in Part 3 of Annex VI to Regulation (EC) No 1272/2008, or,
- the relevant concentration specified in Directive 1999/45/EC where no specific concentration limit is set out in
Part 3 of Annex VI to Regulation (EC) No 1272/2008.
Without prejudice to the implementation of other Community provisions relating to the classification, packaging
and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the pack-
aging of such substances and mixtures is marked visibly, legibly and indelibly as follows:
‘Restricted to professional users’.
2. By way of derogation, paragraph 1 shall not apply to:
(a) medicinal or veterinary products as defined by Directive 2001/82/EC and Directive 2001/83/EC;
(b) cosmetic products as defined by Directive 76/768/EEC;
(c) the following fuels and oil products:
- motor fuels which are covered by Directive 98/70/EC,
- mineral oil products intended for use as fuel in mobile or fixed combustion plants,
- fuels sold in closed systems (e.g. liquid gas bottles);
(d) artists’ paints covered by Directive 1999/45/EC;
(e) the substances listed in Appendix 11, column 1, for the applications or uses listed in Appendix 11, column 2.
Where a date is specified in column 2 of Appendix 11, the derogation shall apply until the said date.
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in or-
namental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or per-
fume, or both, if they:
- can be used as fuel in decorative oil lamps for supply to the general public, and,
- present an aspiration hazard and are labelled with R65 or H304,
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to
the European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisa-
tion (CEN).
5. Without prejudice to the implementation of other Community provisions relating to the classification, pack-
aging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the mar-
ket, that the following requirements are met:
(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly
marked as follows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December 2010, ‘Just a
sip of lamp oil - or even sucking the wick of lamps - may lead to life-threatening lung damage’;
(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly
marked by 1 December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lung damage’;
(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in
black opaque containers not exceeding 1 litre by 1 December 2010.
6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier,
in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and
fuel for decorative lamps, labelled R65 or H304, intended for supply to the general public.
7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with
R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill
lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member States
shall make those data available to the Commission.

Safety data sheet

Legend
R40 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are inten-
ded for supply to the general public for entertainment and decorative purposes such as the following:
- metallic glitter intended mainly for decoration,
- artificial snow and frost,
- ‘whoopee’ cushions,
- silly string aerosols,
- imitation excrement,
- horns for parties,
- decorative flakes and foams,
- artificial cobwebs,
- stink bombs.
2. Without prejudice to the application of other Community provisions on the classification, packaging and la-
belling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dis-
pensers referred to above is marked visibly, legibly and indelibly with:
‘For professional users only’.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of
Council Directive 75/324/EEC (2).
4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they con-
form to the requirements indicated.
Name acc. to inventory CAS No Wt% Listed in Remarks
Substances and preparations, or the 100 A)

breakdown products of such, which
have been proved to possess carci-
nogenic or mutagenic properties or
properties which may affect steroid-
ogenic, thyroid, reproduction or oth-
er endocrine-related functions in or
via the aquatic environment
Legend
A) Indicative list of the main pollutants
• Restrictions according to REACH, Title VIII

None.
• List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list
not listed
• Seveso Directive
2012/18/EU (Seveso III)
No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements
P5a flammable liquids (cat. 1) 10 50 49)
Notation
49) - Flammable liquids, category 1, or
- flammable liquids category 2 or 3 maintained at a temperature above their boiling point, or
- other liquids with a flash point ≤ 60 °C, maintained at a temperature above their boiling point
• Directive 75/324/EEC relating to aerosol dispensers

Filling batch
Deco-Paint Directive (2004/42/EC)
VOC content 100 %
780 g/l
Directive on industrial emissions (VOCs, 2010/75/EU)

Safety data sheet
VOC content 100 %
VOC content 780 g/l
Directive 2011/65/EU on the restriction of the use of certain hazardous substances in electrical
and electronic equipment (RoHS) - Annex II
not listed
Regulation 166/2006/EC concerning the establishment of a European Pollutant Release and
Transfer Register (PRTR)
not listed
Directive 2000/60/EC establishing a framework for Community action in the field of water policy
(WFD)
Name acc. to inventory CAS No Listed in Remarks
Substances and preparations, or the breakdown products A)

of such, which have been proved to possess carcinogenic
or mutagenic properties or properties which may affect
steroidogenic, thyroid, reproduction or other endocrine-re-
lated functions in or via the aquatic environment
Legend
A) Indicative list of the main pollutants
Regulation 98/2013/EU on the marketing and use of explosives precursors

not listed
Regulation 111/2005/EC laying down rules for the monitoring of trade between the Community
and third countries in drug precursors
not listed
National inventories
Substance is listed in the following national inventories:
Country National inventories Status
AU AICS substance is listed
CA DSL substance is listed
CN IECSC substance is listed
EU ECSI substance is listed
EU REACH Reg. substance is listed
JP CSCL-ENCS substance is listed
KR KECI substance is listed
MX INSQ substance is listed
NZ NZIoC substance is listed
PH PICCS substance is listed
TR CICR substance is listed
TW TCSI substance is listed
US TSCA substance is listed
Legend
AICS Australian Inventory of Chemical Substances

Safety data sheet

Legend
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act
15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.
SECTION 16: Other information

Indication of changes (revised safety data sheet)
Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant
14.8 Particulars in the shipper's declaration: Particulars in the shipper's declaration: yes
UN1089, ACETALDEHYDE, 3, I, -20°C c.c. UN1089, ACETALDEHYDE, 3, I, -40°C c.c.
Abbreviations and acronyms

Abbr. Descriptions of used abbreviations
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation
intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland Wa-
terways)
ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
DGR Dangerous Goods Regulations (see IATA/DGR)
EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50
% changes in response (e.g. on growth) during a specified time interval
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
EmS Emergency Schedule
ErC50 ≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either
growth (EbC50) or growth rate (ErC50) relative to the control
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods Code
index No the Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation (EC)
No 1272/2008

Safety data sheet
Abbr. Descriptions of used abbreviations
LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval
LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")
NLP No-Longer Polymer
PBT Persistent, Bioaccumulative and Toxic
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations
concerning the International carriage of Dangerous goods by Rail)
SVHC Substance of Very High Concern
VOC Volatile Organic Compounds
vPvB very Persistent and very Bioaccumulative
Key literature references and sources for data

- Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
- Regulation (EC) No. 1272/2008 (CLP, EU GHS)
- Dangerous Goods Regulations (DGR) for the air transport (IATA)
- International Maritime Dangerous Goods Code (IMDG)
List of relevant phrases (code and full text as stated in chapter 2 and 3)
Code Text
H224 extremely flammable liquid and vapour
H302 harmful if swallowed
H319 causes serious eye irritation
H335 may cause respiratory irritation
H341 suspected of causing genetic defects
H350 may cause cancer
Disclaimer
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The in-
formation cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily val-
id for the new made-up material.

SECTION 1: Identification of The Substance/mixture and of The Company/ Undertaking

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SECTION 1: Identification of The Substance/mixture and of The Company/ Undertaking

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Safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetaldehyde ≥99,5 %, p.a.

article number: 3004 date of compilation: 15.01.2018