Safety Data Sheet: Section 1. Identification

SAFETY DATA SHEET
The information in this Safety Data Sheet is required pursuant to Hazardous Product Regulations 2015.
Date of issue/Date of revision 18 September 2020

Version 11
Section 1. Identification
Product name : AMERCOAT 238 OXIDE RED RESIN
Product code : AT238-72/05
Other means of : Not available.
identification
Product type : Liquid.
Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications, Used by spraying.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.
Supplier : PPG Canada Inc.

5676 Timberlea Blvd
Mississauga ON L4W 4M6
Canada
+1 905-629-7999
PPG Industries, Inc.

One PPG Place
Pittsburgh, PA 15272
Emergency telephone : (412) 434-4515 (U.S.)
number (514) 645-1320 (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Technical Phone Number : 888-977-4762
Section 2. Hazard identification

Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
Health Hazards Not Otherwise Classified - Category 1
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Product code AT238-72/05 Date of issue 18 September 2020 Version 11
Product name AMERCOAT 238 OXIDE RED RESIN
Section 2. Hazard identification

This product contains TiO2 which has been classified as a GHS Carcinogen
Category 2 based on its IARC 2B classification. For many PPG products, TiO2 is
utilized as a raw material in a liquid coating formulation. In this case, the TiO2
particles are bound in a matrix with no meaningful potential for human exposure to
unbound particles of TiO2 when the product is applied with a brush or roller.
Sanding the coating surface or mist from spray applications may be harmful
depending on the duration and level of exposure and require the use of appropriate
personal protective equipment and/or engineering controls (see Section 8).
GHS label elements
Hazard pictograms :
Signal word : Danger

Hazard statements : Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
Prolonged or repeated contact may dry skin and cause irritation.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Wear protective gloves, protective clothing and
eye or face protection. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Use only outdoors or in a well-ventilated
area. Avoid breathing vapor. Wash thoroughly after handling.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of
water. If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Supplemental label : Sanding and grinding dusts may be harmful if inhaled. Repeated exposure to high
elements vapor concentrations may cause irritation of the respiratory system and permanent
brain and nervous system damage. Inhalation of vapor/aerosol concentrations
above the recommended exposure limits causes headaches, drowsiness and
nausea and may lead to unconsciousness or death. Avoid contact with skin and
clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity:
52.7% (oral), 56.8% (dermal), 83.1% (inhalation)
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Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product name : AMERCOAT 238 OXIDE RED RESIN
Other means of : Not available.
identification
CAS number/other identifiers

Ingredient name Synonyms % (w/w) CAS number
aluminium oxide Not available. 30 - 60* 1344-28-1
Mica-group minerals Not available. 3 - 7* 12001-26-2
Polyisocyanate, Alkyl Phenol Blocked Not available. 1 - 5* SUB104447
xylene Not available. 1 - 5* 1330-20-7
Solvent naphtha (petroleum), light aromatic Not available. 1 - 5* 64742-95-6
butan-1-ol Not available. 1 - 5* 71-36-3
1,2,4-trimethylbenzene Not available. 1 - 5* 95-63-6
diiron trioxide Not available. 1 - 5* 1309-37-1
n-butyl acetate Not available. 0.5 - 1.5* 123-86-4
titanium dioxide Not available. 0.5 - 1.5* 13463-67-7
ethylbenzene Not available. 0.1 - 1* 100-41-4
4-nonylphenol, branched Not available. 0.1 - 1* 84852-15-3
*Ranges if listed above for hazardous ingredient(s) are prescribed ranges. The actual concentration(s) or actual
concentration range(s) are being withheld as a trade secret.
SUB codes represent substances without registered CAS Numbers.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First-aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the
eyelids apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.
Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled.
Skin contact : Causes skin irritation. Defatting to the skin.
Ingestion : No known significant effects or critical hazards.
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Section 4. First-aid measures

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : Adverse symptoms may include the following:
Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
metal oxide/oxides
Cyanate and isocyanate.
hydrogen cyanide
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Section 5. Fire-fighting measures

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in
eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
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Section 7. Handling and storage

heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to
a source of ignition and flash back. Vapors are heavier than air and may spread
along floors. If this material is part of a multiple component system, read the Safety
Data Sheet(s) for the other component or components before blending as the
resulting mixture may have the hazards of all of its parts.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
Conditions for safe storage, : Do not store above the following temperature: 50°C (122°F). Store in accordance
including any with local regulations. Store in a segregated and approved area. Store in original
incompatibilities container protected from direct sunlight in a dry, cool and well-ventilated area, away
from incompatible materials (see Section 10) and food and drink. Store locked up.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container
tightly closed and sealed until ready for use. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
aluminium oxide CA Ontario Provincial (Canada).
TWA: 10 mg/m³ Form: Respirable
TWA: 10 mg/m³ Form: Total dust
TWA: 10 mg/m³
CA British Columbia Provincial (Canada,
10/2019).
TWA: 1 mg/m³ 8 hours. Form: Respirable
CA Ontario Provincial (Canada, 6/2019).
fraction.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 10 mg/m³, (as Al) 8 hours. Form:
Total dust.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Mica-group minerals CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 3 mg/m³ 8 hours. Form:
Respirable
10/2019).
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TWAEV: 3 mg/m³ 8 hours. Form:
Respirable dust.
fraction.
7/2013).
STEL: 6 mg/m³ 15 minutes. Form:
respirable fraction
TWA: 3 mg/m³ 8 hours. Form: respirable
fraction
Polyisocyanate, Alkyl Phenol Blocked None.
xylene CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 651 mg/m³ 15 minutes.
15 min OEL: 150 ppm 15 minutes.
8 hrs OEL: 100 ppm 8 hours.
10/2019).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
STEV: 651 mg/m³ 15 minutes.
STEV: 150 ppm 15 minutes.
TWAEV: 434 mg/m³ 8 hours.
TWAEV: 100 ppm 8 hours.
7/2013).
Solvent naphtha (petroleum), light aromatic None.
butan-1-ol CA British Columbia Provincial (Canada,
10/2019).
C: 30 ppm 15 minutes.
Absorbed through skin.
Skin sensitizer.
7/2013).
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1,2,4-trimethylbenzene CA Alberta Provincial (Canada, 6/2018).
10/2019).
7/2013).
diiron trioxide CA British Columbia Provincial (Canada,
10/2019).
TWA: 5 mg/m³, (as Fe) 8 hours. Form: Dust
STEL: 10 mg/m³, (as Fe) 15 minutes. Form:
Fume
TWA: 5 mg/m³, (as Fe) 8 hours. Form:
Fume
TWA: 10 mg/m³ 8 hours. Form: Total dust
8 hrs OEL: 5 mg/m³, (as Fe) 8 hours. Form:
Respirable
fraction.
TWAEV: 5 mg/m³, (as Fe) 8 hours. Form:
dust and fume
7/2013).
STEL: 10 mg/m³, (measured as Fe) 15
minutes. Form: dust and fume
TWA: 5 mg/m³, (measured as Fe) 8 hours.
Form: dust and fume
n-butyl acetate CA Alberta Provincial (Canada, 6/2018).
Skin sensitizer.
10/2019).
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7/2013).
titanium dioxide CA British Columbia Provincial (Canada,

10/2019).
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
TWAEV: 10 mg/m³ 8 hours. Form: Total
dust.
Skin sensitizer.
TWA: 10 mg/m³ 8 hours. Form: total dust
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
ethylbenzene CA Alberta Provincial (Canada, 6/2018).
10/2019).
7/2013).
4-nonylphenol, branched None.
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring
standards. Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.
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Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Gloves : butyl rubber
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If
workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a risk assessment indicates this is
necessary.
Restrictions on use : Persons with a history of asthma, allergies or chronic or recurrent respiratory
disease should not be employed in any process in which this product is used.
Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Not available.
Odor : Characteristic.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
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Section 9. Physical and chemical properties

Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 38°C (100.4°F)
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Evaporation rate : 0.45 (butyl acetate = 1)
Vapor pressure : 0.88 kPa (6.6 mm Hg) [room temperature]
Vapor density : Not available.
Relative density : 1.63
Density ( lbs / gal ) : 13.6
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)
Volatility : 30% (v/v), 15.802% (w/w)
% Solid. (w/w) : 84.198
Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.
Refer to protective measures listed in sections 7 and 8.
Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Hazardous decomposition : Decomposition products may include the following materials: carbon monoxide,
products carbon dioxide, smoke, oxides of nitrogen.
Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
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Product/ingredient name Result Species Dose Exposure
xylene LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
Solvent naphtha (petroleum), LD50 Dermal Rabbit 3.48 g/kg -
light aromatic
LD50 Oral Rat 8400 mg/kg -
butan-1-ol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours
LC50 Inhalation Vapor Rat 8000 ppm 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
1,2,4-trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m³ 4 hours
LD50 Oral Rat 5 g/kg -
diiron trioxide LC50 Inhalation Dusts and mists Rat >5 mg/l 4 hours
LD50 Oral Rat 10 g/kg -
n-butyl acetate LC50 Inhalation Vapor Rat >21.1 mg/l 4 hours
LC50 Inhalation Vapor Rat 2000 ppm 4 hours
LD50 Dermal Rabbit >17600 mg/kg -
titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
4-nonylphenol, branched LD50 Dermal Rabbit 2.14 g/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
4-nonylphenol, branched Skin - Erythema/Eschar Rabbit 4 - -
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitization
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
xylene - 3 -
diiron trioxide - 3 -
titanium dioxide - 2B -
ethylbenzene - 2B -
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Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
Reproductive toxicity
Teratogenicity
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Polyisocyanate, Alkyl Phenol Blocked Category 3 - Respiratory tract
irritation
xylene Category 3 - Respiratory tract
irritation
Solvent naphtha (petroleum), light aromatic Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
butan-1-ol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
1,2,4-trimethylbenzene Category 3 - Respiratory tract
irritation
n-butyl acetate Category 3 - Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
ethylbenzene Category 2 - hearing organs
Target organs : Contains material which causes damage to the following organs: brain, central
nervous system (CNS).
Contains material which may cause damage to the following organs: blood, kidneys,
lungs, the nervous system, liver, upper respiratory tract, skin, ears, eye, lens or
cornea.
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
Solvent naphtha (petroleum), light aromatic ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled.
Skin contact : Causes skin irritation. Defatting to the skin.
Ingestion : No known significant effects or critical hazards.
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Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : Adverse symptoms may include the following:
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary : There are no data available on the mixture itself. Based on the properties of the
isocyanate components and considering toxicological data on similar mixtures, this
mixture may cause acute irritation and/or sensitization of the respiratory system,
leading to an asthmatic condition, wheezing and tightness of the chest. Repeated
exposure may lead to permanent respiratory disability. This product contains TiO2
which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B
classification. For many PPG products, TiO2 is utilized as a raw material in a liquid
coating formulation. In this case, the TiO2 particles are bound in a matrix with no
meaningful potential for human exposure to unbound particles of TiO2 when the
product is applied with a brush or roller. Sanding the coating surface or mist from
spray applications may be harmful depending on the duration and level of exposure
and require the use of appropriate personal protective equipment and/or
engineering controls (see Section 8). Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation
and adverse effects on the kidneys, liver and central nervous system. Symptoms
and signs include headache, dizziness, fatigue, muscular weakness, drowsiness
and, in extreme cases, loss of consciousness. Solvents may cause some of the
above effects by absorption through the skin. There is some evidence that repeated
exposure to organic solvent vapors in combination with constant loud noise can
cause greater hearing loss than expected from exposure to noise alone. If splashed
in the eyes, the liquid may cause irritation and reversible damage. Ingestion may
cause nausea, diarrhea and vomiting. This takes into account, where known,
delayed and immediate effects and also chronic effects of components from short-
term and long-term exposure by oral, inhalation and dermal routes of exposure and
eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
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Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
AMERCOAT 238 OXIDE RED RESIN 9326.8 10304.6 N/A 36.3 4.3
xylene 4300 1700 N/A 11 1.5
Solvent naphtha (petroleum), light aromatic 8400 3480 N/A N/A N/A
butan-1-ol 790 3400 N/A 24 N/A
1,2,4-trimethylbenzene 5000 N/A N/A 18 1.5
diiron trioxide 10000 N/A N/A N/A N/A
n-butyl acetate 10768 N/A N/A N/A N/A
ethylbenzene 3500 17800 N/A 17.8 1.5
4-nonylphenol, branched 1300 2140 N/A N/A N/A
Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Solvent naphtha (petroleum), Acute LC50 8.2 mg/l Fish 96 hours
light aromatic
butan-1-ol Acute LC50 1376 mg/l Fish 96 hours
diiron trioxide Acute EC50 >100 mg/l Daphnia 48 hours
n-butyl acetate Acute LC50 18 mg/l Fish 96 hours
titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
ethylbenzene Acute LC50 150 to 200 mg/l Fresh Fish 96 hours
water
4-nonylphenol, branched Acute LC50 0.221 mg/l Fish 96 hours
Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
n-butyl acetate TEPA and 83 % - Readily - 28 days - -
OECD 301D
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Section 12. Ecological information

Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily
n-butyl acetate - - Readily
ethylbenzene - - Readily
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
xylene 3.16 7.4 to 18.5 low
butan-1-ol 0.88 - low
1,2,4-trimethylbenzene 3.63 120.23 low
n-butyl acetate 1.78 - low
ethylbenzene 3.15 79.43 low
4-nonylphenol, branched - 251.19 low
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL
PROTECTION for additional handling information and protection of employees. Section 6. Accidental release
measures
Section 14. Transport information

TDG IMDG IATA
UN number UN1263 UN1263 UN1263
UN proper shipping PAINT PAINT PAINT
name
Transport hazard class 3 3 3
(es)
Packing group III III III
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Section 14. Transport information

Environmental hazards No. No. No.
Marine pollutant Not applicable. Not applicable. Not applicable.
substances
Additional information
TDG : None identified.
IMDG : None identified.
IATA : None identified.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
Transport in bulk according : Not applicable.

to IMO instruments
Proof of classification : Product classified as per the following sections of the Transportation of Dangerous
statement Goods Regulations: 2.18-2.19 (Class 3).
Section 15. Regulatory information

National Inventory List
Canada inventory ( DSL ) : All components are listed or exempted.
Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 3 * Flammability : 2 Physical hazards : 0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
Health : 3 Flammability : 2 Instability : 0
Date of issue/Date of 18 September 2020
revision
Organization that prepared : EHS
the MSDS
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
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Section 16. Other information

SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Canada Page: 18/18

Safety Data Sheet: Section 1. Identification

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Safety Data Sheet: Section 1. Identification

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SAFETY DATA SHEET

Date of issue/Date of revision 18 September 2020

Supplier : PPG Canada Inc.

PPG Industries, Inc.

Technical Phone Number : 888-977-4762

Section 2. Hazard identification

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Section 2. Hazard identification

Signal word : Danger

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Section 3. Composition/information on ingredients

CAS number/other identifiers

Section 4. First-aid measures

Most important symptoms/effects, acute and delayed

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Section 4. First-aid measures

Indication of immediate medical attention and special treatment needed, if necessary

See toxicological information (Section 11)

Section 5. Fire-fighting measures

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Section 5. Fire-fighting measures

Section 6. Accidental release measures

Methods and materials for containment and cleaning up

Section 7. Handling and storage

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Section 7. Handling and storage

Section 8. Exposure controls/personal protection

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Section 8. Exposure controls/personal protection

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Section 8. Exposure controls/personal protection

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Section 8. Exposure controls/personal protection

titanium dioxide CA British Columbia Provincial (Canada,

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Section 8. Exposure controls/personal protection

Individual protection measures

Section 9. Physical and chemical properties

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Section 9. Physical and chemical properties

Section 10. Stability and reactivity

Chemical stability : The product is stable.

Section 11. Toxicological information

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Section 11. Toxicological information

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Section 11. Toxicological information

Information on the likely routes of exposure

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Section 11. Toxicological information

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Section 11. Toxicological information

Section 12. Ecological information

Persistence and degradability

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Section 12. Ecological information

Section 13. Disposal considerations

Section 14. Transport information

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