SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 3.

2 (30-04-2014) - Page 1/6

DERMANIOS SCRUB CHLORHEXIDINE 4% - 2173000

SAFETY DATA SHEET

(REACH regulation (EC) n° 1907/2006 - n° 453/2010)

SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier
Product name : DERMANIOS SCRUB CHLORHEXIDINE 4%
Product code : 2173000
1.2. Relevant identified uses of the substance or mixture and uses advised against
Hygienic handwashing
Surgical disinfection of hands by washing
For further information on product indication, please see the label.
1.3. Details of the supplier of the safety data sheet
Registered company name : Laboratoires ANIOS.
Address : PAVE DU MOULIN .59260.LILLE - HELLEMMES.FRANCE.
Telephone : + 33 (0)3 20 67 67 67. Fax : + 33 (0)3 20 67 67 68.
e:mail : [email protected]
www.anios.com
1.4. Emergency telephone number : + 33(0)1 45 42 59 59.
Association/Organisation : INRS.

SECTION 2 : HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture
In compliance with directives 67/548/EEC, 1999/45/EC and their amendments.
Aquatic environmental hazard, chronic toxicity: very toxic (N, R 50/53).
This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.
This mixture does not present a health hazard with the exception of possible occupational exposure thresholds (see paragraphs 3 and 8).
2.2. Label elements
In compliance with directives 67/548/EEC, 1999/45/EC and their amendments.
Hazard symbols :

Dangerous for the environment

Risk phrase :
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Safety phrase :
S 61 Avoid release of undiluted product to the environment. Refer to special instructions/Safety
data sheets.
S 51 Use only in well-ventilated areas.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 46 If swallowed, seek medical advice immediately and show this container or label.
S2 Keep out of the reach of children.
S 60 This material and its container must be disposed of as hazardous waste.
2.3. Other hazards
No other hazard identified in the current state of knowledge.

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [16945-45970-14470-018626] - 2014-05-23 - 12:46:12

SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 3.2 (30-04-2014) - Page 2/6
DERMANIOS SCRUB CHLORHEXIDINE 4% - 2173000

SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS

Title for H, EUH and R indications: see § 16.
3.2. Mixtures
Composition :
Identification (EC) 1272/2008 67/548/EEC Note %
CAS: 18472-51-0 GHS05, GHS09 Xi,N 2.5 <= x % < 5
EC: 242-354-0 Dgr Xi;R41
Eye Dam. 1, H318 N;R50/53
D-GLUCONIC ACID, Aquatic Acute 1, H400
COMPOUND WITH M Acute = 10
N,N''-BIS(4-CHLOROPH Aquatic Chronic 1,
ENYL)-3,12-DIIMINO-2 H410
,4,11,13-TETRAAZATET M Chronic = 10
RADECANEDIAMIDINE
(2:1)
CAS: 68155-09-9 GHS05, GHS09 Xi,N 0 <= x % < 2.5
EC: 268-938-5 Dgr Xi;R38-R41
Skin Irrit. 2, H315 N;R51/53
AMIDES, COCO, Eye Dam. 1, H318
N-[3-(DIMETHYLAMINO) Aquatic Chronic 2,
PROPYL], N-OXIDES H411

SECTION 4 : FIRST AID MEASURES

As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing by an unconscious person.
4.1. Description of first aid measures
In the event of exposure by inhalation :
Move the person away from the place of exposure and take him/her outside.
In the event of splashes or contact with eyes :
If applicable, remove contact lenses.
Wash thoroughly with soft clean water for 15 minutes, holding the eyelids open.
If there is any redness, pain or visual impairment, consult an ophthalmologist. Show this container or label.
In the event of swallowing :
Rinse out the mouth, do not induce vomiting, keep the person calm and take him/her to a clinic or a doctor’s. Show the container or label.
4.2. Most important symptoms and effects, both acute and delayed
Cf. § 11
4.3. Indication of any immediate medical attention and special treatment needed
Refer to the recommendation of the doctor.

SECTION 5 : FIREFIGHTING MEASURES

5.1. Extinguishing media
Suitable methods of extinction
Any extinguishing agents are authorized: foam, sand, carbon dioxide, water, powder.
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
5.3. Advice for firefighters
Use autonomous insulating breathing apparatus and a full protective suit.

SECTION 6 : ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Consult the safety measures listed under headings 7 and 8.
Take care not to skid.
6.2. Environmental precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums
for waste disposal.

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [16945-45970-14470-018626] - 2014-05-23 - 12:46:12

SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 3.2 (30-04-2014) - Page 3/6
DERMANIOS SCRUB CHLORHEXIDINE 4% - 2173000

Do not get rid in natural spaces (waterways, ground and vegetations...)

6.3. Methods and material for containment and cleaning up
Absorb any spilled product using absorbent materials and sweep away or remove with a shovel. Wash the contaminated surface thoroughly with
water.
Do not collect the product for re-use.
Do not get rid in natural spaces.
6.4. Reference to other sections
Disposal considerations: see section 13.

SECTION 7 : HANDLING AND STORAGE

7.1. Precautions for safe handling
Product for external use - do not swallow.
Handle in accordance with user instructions on label
Recommended equipment and procedures :
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations.
7.2. Conditions for safe storage, including any incompatibilities
Keep ONLY in the original container
Keep the container tightly closed
Keep out of the reach of children
Store away from light
Recommended storage temperature: from +5°C to +25°C.
Do not use after the expiry date mentioned on the packaging.
7.3. Specific end use(s)
For professional use only
Refer to paragraph 1 for product indication

SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION

The information in this chapter refers to the product specifically described in this document. If the product is handled and/or exposed
simultaneously with other chemical agents, these must be taken into consideration when choosing personal safety equipment.
8.1. Control parameters
Not applicable
8.2. Exposure controls
- Eye / face protection
Avoid contact with eyes.
Water source nearby.
- Hand protection
Not applicable.
- Body protection
Not applicable.
HEALTH MEASURES:
Do not eat, drink or smoke during use.
- Respiratory protection
Not applicable in normal conditions of use.

SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
General information :
Physical state : Fluid liquid.
Important health, safety and environmental information
pH : 5.30 .
Neutral.
Boiling point/boiling range : Not specified.
Flash point interval : Not relevant.
Vapour pressure (50°C) : Not relevant.
Density : +/- 1.02
Water solubility : Soluble.

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [16945-45970-14470-018626] - 2014-05-23 - 12:46:12

SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 3.2 (30-04-2014) - Page 4/6
DERMANIOS SCRUB CHLORHEXIDINE 4% - 2173000

Melting point/melting range : Not specified.

Self-ignition temperature : Not specified.
Decomposition point/decomposition range : Not specified.
9.2. Other information
Odour : Perfumed
Colour: pink

SECTION 10 : STABILITY AND REACTIVITY

10.1. Reactivity
No hazardous reaction if the instructions/indications for storage and handling are respected.
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
Cf. § 10.1 and 10.2
10.4. Conditions to avoid
Avoid :
- frost
10.5. Incompatible materials
Do not mix with other products.
10.6. Hazardous decomposition products
At high temperatures, dangerous decomposition products may be produced, such as fumes, carbon dioxide and carbon monoxide, nitrogen oxide.

SECTION 11 : TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
11.1.1. Substances
Not specified
11.1.2. Mixture
The toxicological data of the mixture (resulting from studies or in accordance with conventional methods) are outlined below.
Acute toxicity :
Inhalation may lead to irritation of the respiratory tracts.
Ingestion may lead to irritation of the buccal cavity.
Sore throat, abdominal pain, nausea.
Acute toxicity estimate (ATE)* :
Oral ATE : > 2000 mg/kg
* according to the method of calculation describe in the CLP regulation (Classification, Labelling, Packaging) Part 3 Chapter 3.1 based on the
data of the different components present in the product.
Serious damage to eyes/eye irritation :
May lead to slight ocular irritation: redness of the conjonctiva and lacrimation.

SECTION 12 : ECOLOGICAL INFORMATION

Avoid any product release into waterways.
Following information is based on data from the compounds.
12.1. Toxicity
12.1.1. Substances
Not specified
12.1.2. Mixtures
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
(according to the conventional method of calculation included in the directive 99/45/CE)
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
No data available.

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [16945-45970-14470-018626] - 2014-05-23 - 12:46:12

SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 3.2 (30-04-2014) - Page 5/6
DERMANIOS SCRUB CHLORHEXIDINE 4% - 2173000

12.6. Other adverse effects

No data available.

SECTION 13 : DISPOSAL CONSIDERATIONS

Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
Do not pour into waterways.
13.1. Waste treatment methods
Waste :
Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air,
soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Soiled packaging :
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.
Codes of wastes (Decision 2001/573/EC, Directive 2006/12/EEC, Directive 94/31/EEC on hazardous waste) :
18 01 06 * chemicals consisting of or containing dangerous substances
For information :
The following waste code is given for indicative purposes only.
The waste code must be determined by the user, according to the application of the product.
18 = Wastes from human or animal health care and/or related research (except kitchen and restaurant wastes not arising from immediate health
care)

SECTION 14 : TRANSPORT INFORMATION

Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR 2011 -
IMDG 2010 - ICAO/IATA 2012).
14.1. UN number
3082
14.2. UN proper shipping name
UN3082=ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(d-gluconic acid, compound with n,n''-bis(4-chlorophenyl)-3,12-diimino-2,4,11,13-tetraazatetradecanediamidine (2:1))
14.3. Transport hazard class(es)
- Classification :

9
14.4. Packing group
III
14.5. Environmental hazards
- Environmentally hazardous material :

14.6. Special precautions for user

ADR/RID Class Code Pack gr. Label Ident. LQ Provis. EQ Cat. Tunnel
9 M6 III 9 90 5L 274 335 E1 3 E
601
IMDG Class 2°Label Pack gr. LQ EMS Provis. EQ
9 - III 5L F-A,S-F 274 335 E1
IATA Class 2°Label Pack gr. Passager Passager Cargo Cargo note EQ
9 - III 964 450 L 964 450 L A97 A158 E1
9 - III Y964 30 kg G - - A97 A158 E1
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [16945-45970-14470-018626] - 2014-05-23 - 12:46:12

SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 3.2 (30-04-2014) - Page 6/6
DERMANIOS SCRUB CHLORHEXIDINE 4% - 2173000

Not applicable

SECTION 15 : REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Particular provisions :
No data available.
15.2. Chemical safety assessment
No data available.

SECTION 16 : OTHER INFORMATION

Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of
knowledge and on national and community regulations.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.
The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a
guarantee of the properties thereof.
It is recommended that the information contained in this safety data sheet is provided to the users, if necessary in an appropriate form.
This information relates to the specifically designated product and may not be valid in combination with any another product. The product must
not be used for applications other than those specified in heading 1 without having first obtained written handling instructions.
UPDATES SINCE PREVIOUS VERSION
- §3
Title for H, EUH and R indications mentioned in section 3 :
H315 Causes skin irritation.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Abbreviations :
ADR : European agreement concerning the international carriage of dangerous goods by Road.
IMDG : International Maritime Dangerous Goods.
IATA : International Air Transport Association.
ICAO : International Civil Aviation Organisation
RID : Regulations concerning the International carriage of Dangerous goods by rail.

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [16945-45970-14470-018626] - 2014-05-23 - 12:46:12