SAFETY DATA SHEET

Revision Date 11-May-2020 Version 5

1. IDENTIFICATION
Product identifier
Product Name SA9 BATTERY PROTECTOR & SEALER 5 OZ AE

Other means of identification

Product Code 80370

Recommended use of the chemical and restrictions on use

Recommended Use Battery Sealant
Uses advised against No information available

Details of the supplier of the safety data sheet

Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, Ohio 44139 USA Oakville, ON Canada L6H 6M5
Telephone: 1-87-Permatex Telephone: (800) 924-6994
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453

E-mail address: [email protected]

2. HAZARDS IDENTIFICATION
Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 2A
Carcinogenicity Category 1B
Reproductive toxicity Category 2
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Flammable liquids Category 1

Label elements

Emergency Overview
Signal word
Danger

Causes skin irritation

Causes serious eye irritation
May cause cancer
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Suspected of damaging fertility or the unborn child

May cause respiratory irritation
May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure
Extremely flammable liquid and vapor

Appearance Purple Physical state Liquid Odor Solvent

Precautionary Statements - Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Wear eye/face protection
Do not breathe dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment
Use non-sparking tools
Take precautionary measures against static discharge
Keep cool

Precautionary Statements - Response

IF exposed or concerned: Get medical advice/attention
Specific treatment (see .? on this label)

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
If skin irritation occurs: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
In case of fire: Use CO2, dry chemical, or foam to extinguish.

Precautionary Statements - Storage

Store locked up
Store in a well-ventilated place. Keep container tightly closed

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information
Toxic to aquatic life with long lasting effects.

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3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%

PROPANE 74-98-6 15-30
ACETONE 67-64-1 15-35
PETROLATUM 8009-03-8 10 - 30
XYLENE 1330-20-7 10 - 30
ETHYL BENZENE 100-41-4 1-5
TOLUENE 108-88-3 0.1 - 1

4. FIRST AID MEASURES

Description of first aid measures

General advice Call 911 or emergency medical service. Remove and isolate contaminated clothing and
shoes.

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.

Skin contact In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

Inhalation Move victim to fresh air. If breathing is irregular or stopped, administer artificial respiration.
Administer oxygen if breathing is difficult.

Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce
vomiting.

Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.

Most important symptoms and effects, both acute and delayed

Symptoms See section 2 for more information.

Indication of any immediate medical attention and special treatment needed

Note to physicians Keep victim warm and quiet.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing agent suitable for type of surrounding fire, Dry chemical or CO2, Water spray, fog or regular foam, Move
containers from fire area if you can do it without risk, Damaged cylinders should be handled only by specialists

Unsuitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire

Specific hazards arising from the chemical

Some may burn but none ignite readily. Ruptured cylinders may rocket.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

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Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Do not touch or walk through spilled material. Stop leak if you can do it without risk.

Other Information Ventilate the area.

Environmental precautions

Environmental precautions Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to
contact spilled material. Prevent entry into waterways, sewers, basements or confined
areas.

Methods and material for containment and cleaning up

Methods for containment If possible, turn leaking containers so that gas escapes rather than liquid. Allow substance
to evaporate.

Methods for cleaning up Do not direct water at spill or source of leak.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Contents under pressure. Do not puncture or incinerate cans.

Conditions for safe storage, including any incompatibilities

Storage Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked
up. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights,
electric motors and static electricity).

Incompatible materials Strong oxidizing agents, Strong bases, Strong acids

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
PROPANE : See Appendix F: Minimal TWA: 1000 ppm IDLH: 2100 ppm
74-98-6 Oxygen Content, explosion hazard TWA: 1800 mg/m3 TWA: 1000 ppm
(vacated) TWA: 1000 ppm TWA: 1800 mg/m3
(vacated) TWA: 1800 mg/m3
ACETONE STEL: 500 ppm TWA: 1000 ppm IDLH: 2500 ppm
67-64-1 TWA: 250 ppm TWA: 2400 mg/m3 TWA: 250 ppm
(vacated) TWA: 750 ppm TWA: 590 mg/m3
(vacated) TWA: 1800 mg/m3
(vacated) STEL: 2400 mg/m3
The acetone STEL does not apply
to the cellulose acetate fiber

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industry. It is in effect for all other

sectors.
(vacated) STEL: 1000 ppm
XYLENE STEL: 150 ppm TWA: 100 ppm -
1330-20-7 TWA: 100 ppm TWA: 435 mg/m3
(vacated) TWA: 100 ppm
(vacated) TWA: 435 mg/m3
(vacated) STEL: 150 ppm
(vacated) STEL: 655 mg/m3
ETHYL BENZENE TWA: 20 ppm TWA: 100 ppm IDLH: 800 ppm
100-41-4 TWA: 435 mg/m3 TWA: 100 ppm
(vacated) TWA: 100 ppm TWA: 435 mg/m3
(vacated) TWA: 435 mg/m3 STEL: 125 ppm
(vacated) STEL: 125 ppm STEL: 545 mg/m3
(vacated) STEL: 545 mg/m3
TOLUENE TWA: 20 ppm TWA: 200 ppm IDLH: 500 ppm
108-88-3 (vacated) TWA: 100 ppm TWA: 100 ppm
(vacated) TWA: 375 mg/m3 TWA: 375 mg/m3
(vacated) STEL: 150 ppm STEL: 150 ppm
(vacated) STEL: 560 mg/m3 STEL: 560 mg/m3
Ceiling: 300 ppm
NIOSH IDLH Immediately Dangerous to Life or Health

Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).

Appropriate engineering controls

Engineering Controls Showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.

Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical state Liquid
Appearance Purple
Odor Solvent
Odor threshold No information available

Property Values Remarks • Method

pH No information available
Melting point / freezing point No information available
Boiling point / boiling range 32 °C / 90 °F
Flash point -104 °C / -155 °F Gives a flame projection at full valve opening or
flashback at any degree of valve opening
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: 12%
Lower flammability limit: 2.5%
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Vapor pressure >60 psig @ 21.1°C (70°F)

Vapor density No information available
Relative density 0.85
Water solubility No information available
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature 451.3°C (844.35°F)
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available

Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) 68.5
Density No information available
Bulk density No information available
SADT (self-accelerating No information available
decomposition temperature)

10. STABILITY AND REACTIVITY

Reactivity
No information available

Chemical stability
Stable under normal conditions

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid
Heat, flames and sparks.

Incompatible materials
Strong oxidizing agents, Strong bases, Strong acids

Hazardous Decomposition Products

Carbon oxides

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation May cause damage to organs through prolonged or repeated exposure if inhaled. May
cause drowsiness or dizziness.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact May cause skin irritation and/or dermatitis.

Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and
pneumonitis.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

PROPANE - - > 800000 ppm ( Rat ) 15 min
74-98-6
ACETONE = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h
67-64-1

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PETROLATUM - = 3600 mg/kg ( Rabbit ) -

8009-03-8
XYLENE = 3500 mg/kg ( Rat ) > 4350 mg/kg ( Rabbit ) > 1700 = 5000 ppm ( Rat ) 4 h = 29.08
1330-20-7 mg/kg ( Rabbit ) mg/L ( Rat ) 4 h
ETHYL BENZENE = 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) = 17.4 mg/L ( Rat ) 4 h
100-41-4
TOLUENE = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h
108-88-3

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Germ cell mutagenicity No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA
XYLENE - Group 3 - -
1330-20-7
ETHYL BENZENE A3 Group 2B - X
100-41-4
TOLUENE - Group 3 - -
108-88-3
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans
Not classifiable as a human carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin.

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 8438 mg/kg
ATEmix (dermal) 5429 mg/kg
ATEmix (inhalation-gas) 1459569 mg/l
ATEmix (inhalation-dust/mist) 8.3 mg/l

12. ECOLOGICAL INFORMATION

Ecotoxicity

0 % of the mixture consists of component(s) of unknown hazards to the aquatic environment

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Mobility
No information available.

Chemical Name Partition coefficient

PROPANE 2.3
74-98-6
ACETONE -0.24
67-64-1
XYLENE 2.77 - 3.15
1330-20-7
ETHYL BENZENE 3.2

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100-41-4
TOLUENE 2.7
108-88-3

Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).

Contaminated packaging Do not reuse container.

US EPA Waste Number D001, U002 U220 U239

Chemical Name RCRA - Halogenated RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes
Organic Compounds
TOLUENE - - Toxic waste -
108-88-3 waste number F025
Waste description:
Condensed light ends, spent
filters and filter aids, and
spent desiccant wastes from
the production of certain
chlorinated aliphatic
hydrocarbons, by free
radical catalyzed processes.
These chlorinated aliphatic
hydrocarbons are those
having carbon chain lengths
ranging from one to and
including five, with varying
amounts and positions of
chlorine substitution.

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Status

ACETONE Ignitable
67-64-1
XYLENE Toxic
1330-20-7 Ignitable
ETHYL BENZENE Toxic
100-41-4 Ignitable
TOLUENE Toxic
108-88-3 Ignitable

14. TRANSPORT INFORMATION

DOT
UN/ID No 1950
Proper shipping name: Aerosols, Limited Quantity (LQ)
Hazard Class 2.1
Emergency Response Guide 126
Number

IATA
UN/ID No ID 8000
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Proper shipping name: Consumer commodity

Hazard Class 9
ERG Code 9L

IMDG
UN/ID No 1950
Proper shipping name: Aerosols, Limited Quantity (LQ)
Hazard Class 2.1
EmS-No F-D, S-U

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Not determined
ENCS Not determined
IECSC Not determined
KECL Not determined
PICCS Not determined
AICS Not determined

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name SARA 313 - Threshold Values %

XYLENE - 1330-20-7 1.0
ETHYL BENZENE - 100-41-4 0.1
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard No
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)

Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
XYLENE 100 lb - - X
1330-20-7
ETHYL BENZENE 1000 lb X X X
100-41-4
TOLUENE 1000 lb X X X
108-88-3
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
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Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

ACETONE 5000 lb - RQ 5000 lb final RQ
67-64-1 RQ 2270 kg final RQ
XYLENE 100 lb - RQ 100 lb final RQ
1330-20-7 RQ 45.4 kg final RQ
ETHYL BENZENE 1000 lb - RQ 1000 lb final RQ
100-41-4 RQ 454 kg final RQ
TOLUENE 1000 lb 1 lb - RQ 1000 lb final RQ
108-88-3 RQ 454 kg final RQ RQ 1 lb final
RQ
RQ 0.454 kg final RQ
US State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
ETHYL BENZENE Carcinogen
100-41-4
TOLUENE Developmental
108-88-3
U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

ACETONE X X X
67-64-1
PROPANE X X X
74-98-6
XYLENE X X X
1330-20-7
ETHYL BENZENE X X X
100-41-4
TOLUENE X X X
108-88-3
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable

WHMIS Hazard Class

A Compressed gases, B5 - Flammable aerosol, D2B - Toxic materials

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA Health hazards 2 Flammability 4 Instability 0 -
HMIS Health hazards 2 Flammability 4 Physical hazards 0 Personal protection B

NFPA (National Fire Protection Association)

HMIS (Hazardous Material Information System)

Revision Date 11-May-2020

Disclaimer
Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled.
However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness
of the information. User is responsible for evaluating whether such information or this product is fit for a particular
purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this
product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc.
disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or
use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web
site.

End of Safety Data Sheet

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