7.fineness of Cement

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PRACTICAL # 7

Standard test method for fineness of Portland cement

Theory:
• Hydraulic cement refers to material which hardens under water

• Portland cement is obtained by mixing together limestone, silica, alumina and


iron oxide bearing materials, burning them at a clinkering temperature and
grinding the resulting clinker.

• Four compounds are regarded as the major constituents of cement


Trcalcium silicate C3S
Dicalcium silicate C2S
Tricalcium aluminate C3A
Tetracalcium alumino ferrite C4AF

• When water is added to cement, hydration of cement takes place. In the presence
of water, the silicates and aluminates of Portland cement form hydrates which
produce hardened cement paste. The hydration of C3S produces calcium silicate
hydrate (C3S2H3) and calcium hydroxide Ca(OH)2. C2S behaves similarly but
produces less lime.

• The hydration of cement compounds is exothermic, and the quantity of heat per
gram of unhydrated cement, evolved upon complete hydration at a given
temperature, is defined as heat of hydration. For Portland cements, about one half
of the total heat is liberated between 1 and 3 days, about three quarters in 7 days
and nearly 90% in 6 months. Reducing the proportions of C3A and C3S can reduce
the heat of hydration of cement. The values of the heat of hydration of the
compounds used in cement are given below

Compound Heat of hydration (J/g)


C3S 502
C2S 260
C3A 867
C4AF 419

• Hydration starts at the surface of the cement particles, it is the total surface area of
cement that represents the material available for hydration. Thus the rate of
hydration depends on the fineness of cement particles and for a rapid development
of strength a high fineness is necessary.

• Increasing the fineness of cement has the effect of increasing the quantity of C3A
and this raises the gypsum requirement.
Apparatus:
Balance, Sample of cement, Sieve # 200

Procedure:
Take 100g of sample of cement and put it in sieve # 200 and shake it. After that weight
the sample retained on the sieve. If it comes 10g i.e. 10% of given sample weight then it
is fresh because 90% has passed through sieve # 200, other wise not.

Weight of Cement sample taken = W1


Weight retained on Sieve = W2
W1 - W2
∗100
% fineness of Cement = W1

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